CN112408854A - Diatom composite fiber board and preparation method thereof - Google Patents

Diatom composite fiber board and preparation method thereof Download PDF

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Publication number
CN112408854A
CN112408854A CN202011278624.1A CN202011278624A CN112408854A CN 112408854 A CN112408854 A CN 112408854A CN 202011278624 A CN202011278624 A CN 202011278624A CN 112408854 A CN112408854 A CN 112408854A
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parts
raw materials
composite fiber
fiber board
diatomite
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CN202011278624.1A
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Chinese (zh)
Inventor
童彬原
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Blue Sky Dolphin Green Building Materials Co ltd
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Blue Sky Dolphin Green Building Materials Co ltd
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Priority to CN202011278624.1A priority Critical patent/CN112408854A/en
Publication of CN112408854A publication Critical patent/CN112408854A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/045Polyalkenes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/08Diatomaceous earth
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • C04B18/26Wood, e.g. sawdust, wood shavings
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • C04B18/26Wood, e.g. sawdust, wood shavings
    • C04B18/265Wood, e.g. sawdust, wood shavings from specific species, e.g. birch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/062Oxides, Hydroxides of the alkali or alkaline-earth metals
    • C04B22/064Oxides, Hydroxides of the alkali or alkaline-earth metals of the alkaline-earth metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

A diatom composite fiber board and a preparation method thereof relate to the technical field of decoration boards. The diatom composite fiber board is composed of the following raw materials: diatomite, zeolite, jade powder, calcium carbonate, polyethylene and wood fiber. The preparation method comprises the following steps: 1) mixing materials: weighing the raw materials according to the weight part ratio, putting the raw materials into a mixer, and uniformly mixing to obtain a mixture; 2) and (3) granulation: fusing and extruding the mixture in a screw extruder to obtain granular materials; the fusion temperature is 60-70 ℃, and the fusion time is 15-20 min; 3) pressing: pressing and molding the granular materials in a press to obtain a plate; 4) and (3) cooling: and cooling and maintaining the plate. The composite mineral board obtained by the invention has the advantages of beautiful appearance, decoration, environmental protection, free formaldehyde content of less than 0.005mg/kg, no heavy metal substance, zero-grade mildew resistance, fire resistance and flame retardance, and can well meet the requirements of modern people on environmental protection and decoration.

Description

Diatom composite fiber board and preparation method thereof
Technical Field
The invention relates to the technical field of decoration plates, in particular to a diatom composite fiber plate and a preparation method thereof.
Background
The diatom board is divided into two types according to the technical formula, wherein one type is a diatom mineral board which mainly comprises natural mineral materials such as kieselguhr, ash calcium, heavy calcium, gypsum and the like; the other is a diatom wood fiberboard which mainly comprises diatomite, wood fiber or bamboo fiber materials, and the functions and the performances of the two diatom boards are slightly different. The diatom mineral board is hard and heavy, has high fireproof performance, and is more suitable for being used as a door, a kitchen cabinet and a partition board; the diatom wood fiberboard has good nail-holding power and toughness, and is more suitable for manufacturing various cabinet furniture and mould pressing modeling. . Therefore, the invention aims to develop the environment-friendly diatom composite fiber board which has the functions of moisture and mildew prevention, water and bacteria prevention, health preservation, health care and the like, does not contain any adhesive, has good nail holding power and toughness, and is particularly suitable for manufacturing various cabinet furniture and mould pressing modeling.
Disclosure of Invention
The invention aims to provide a diatom composite fiber board and a preparation method thereof aiming at overcoming the defects and shortcomings of the prior art, and aims to solve the problem that diatom mineral boards are poor in nail holding power and toughness.
In order to achieve the purpose, the invention adopts the following technical scheme: the diatom composite fiber board is composed of the following raw materials in parts by weight: 45-60 parts of diatomite, 5-12 parts of bamboo fiber, 15-20 parts of jade powder, 10-15 parts of gray calcium, 5-10 parts of polyethylene and 1-3 parts of wood fiber.
Further, the feed comprises the following raw materials in parts by weight: 45 parts of diatomite, 12 parts of bamboo fiber, 20 parts of jade powder, 10 parts of ash calcium, 10 parts of polyethylene and 3 parts of wood fiber.
Further, the feed comprises the following raw materials in parts by weight: 50 parts of diatomite, 8 parts of bamboo fiber, 20 parts of jade powder, 10 parts of ash calcium, 10 parts of polyethylene and 2 parts of wood fiber.
Further, the feed comprises the following raw materials in parts by weight: 60 parts of diatomite, 7 parts of bamboo fiber, 15 parts of jade powder, 10 parts of ash calcium, 5 parts of polyethylene and 3 parts of wood fiber.
Further, the diatomite is food-grade non-calcined diatomite in Changbai mountain areas of Jilin.
Further, the diatomite and the jade powder are sieved by a 325-mesh sieve.
The preparation method of the diatom composite fiber board is based on the raw material formula and comprises the following steps:
1) mixing materials: weighing the raw materials according to the weight part ratio, putting the raw materials into a mixer, and uniformly mixing to obtain a mixture;
2) and (3) granulation: fusing and extruding the mixture in a screw extruder to obtain granular materials; the fusion temperature is 60-70 ℃, and the fusion time is 15-20 min;
3) pressing: pressing and molding the granular materials in a pressing machine to obtain a plate, wherein the temperature is maintained at 60-70 ℃ during pressing;
4) and (3) cooling: and cooling and maintaining the plate.
Further, in the step 1), the mixing is carried out at normal temperature and normal pressure, and the mixing time is 10-15 min.
Further, in the step 3), the thickness of the press-formed plate is 0.1-20 mm, the width is 1.8m, and the length is 2.4 m.
Further, in the step 4), normal-temperature tap water is adopted for cooling circularly for maintenance.
Furthermore, the content of free formaldehyde in the board is less than 0.005mg/kg, heavy metals are not detected, and the mildew-proof grade is zero grade.
After the technical scheme is adopted, the invention has the beneficial effects that: the diatomite is food-grade non-calcined diatomite which is large in area, light in porous and light in weight and can endow the board with super-strong adsorption performance, and the bamboo fiber has the effects of light in weight and toughness enhancement; the jade powder has good filling effect, gives terahertz waves to the product, improves the health function of the product, enhances the density of the plate, can inhibit the propagation of bacteria and microorganisms, has obvious antibacterial effect, ensures that the plate does not form mildew stains for a long time, removes harmful gases, food, smoke and other various living odors generated by building materials, has no radioactivity, is healthy and environment-friendly, can block combustion, and can preserve heat and prevent frosting; the main component of the gray calcium is Ca (OH)2Is a natural air-hardening cementing material; the wood fiber provides excellent water retention property, prolongs the opening time of the slurry, and simultaneously can form a three-dimensional net structure after being mixed, so that the supporting force of a system is enhanced, the compression molding of the plate is facilitated, and the good reinforcing and anti-cracking effects can be achieved; polyethylene is a thermoplastic resin that functions as an adhesive during the fusion process.
The diatom composite fiber board provided by the invention is scientific in raw material proportion, and the preparation process strictly controls the conditions in the steps of mixing, granulating, pressing and cooling, so that a decorative board with an excellent compact structure can be obtained without high temperature and high pressure, the energy is saved, the obtained board is beautiful and decorative, green and environment-friendly, the content of free formaldehyde reaches an undetected level, heavy metals are not detected, the mildew-proof grade is zero, and the diatom composite fiber board can prevent fire and retard flame, and can well meet the requirements of modern people on environment-friendly decoration.
Detailed Description
In order to make the technical means, the creation features, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
Example 1
The composite mineral board comprises the following raw materials in parts by weight: 45 parts of diatomite, 12 parts of bamboo fiber, 20 parts of jade powder, 10 parts of ash calcium, 10 parts of polyethylene and 3 parts of wood fiber.
The preparation method comprises the following steps:
1) mixing materials: weighing the raw materials according to the weight part ratio, putting the raw materials into a mixer, and uniformly mixing the raw materials at normal temperature and normal pressure to obtain a mixture, wherein the mixing time is 10-15 min;
2) and (3) granulation: fusing and extruding the mixture in a screw extruder to obtain granular materials; the fusion temperature is 65 ℃, and the fusion time is 18 min;
3) pressing: pressing and molding the granules in a press to obtain a plate, wherein the thickness of the pressed and molded plate is 10 mm, the width of the plate is 1.8m, and the length of the plate is 2.4 m;
4) and (3) cooling: and cooling and maintaining the plate, wherein the cooling and maintaining are carried out by adopting normal-temperature tap water for circulating cooling.
The plate obtained in the embodiment is subjected to free formaldehyde, VOC, heavy metal and anti-mold detection, wherein the execution standard of free formaldehyde detection is GB18580-2001, the execution standard of VOC detection is HJ571-2010, and the execution standard of heavy metal detection is: LY/T2870-2017, and an antimycotic performance detection execution standard: JC/T2177-2013, the results are shown in the table I.
Example 2
The composite mineral board comprises the following raw materials in parts by weight: 50 parts of diatomite, 8 parts of bamboo fiber, 20 parts of jade powder, 10 parts of ash calcium, 10 parts of polyethylene and 2 parts of wood fiber.
The preparation method comprises the following steps:
1) mixing materials: weighing the raw materials according to the weight part ratio, putting the raw materials into a mixer, and uniformly mixing the raw materials at normal temperature and normal pressure to obtain a mixture, wherein the mixing time is 10-15 min;
2) and (3) granulation: fusing and extruding the mixture in a screw extruder to obtain granular materials; the fusion temperature is 70 ℃, and the fusion time is 15 min;
3) pressing: pressing and molding the granules in a press to obtain a plate, wherein the thickness of the pressed and molded plate is 20 mm, the width of the plate is 1.8m, and the length of the plate is 2.4 m;
4) and (3) cooling: and cooling and maintaining the plate, wherein the cooling and maintaining are carried out by adopting normal-temperature tap water for circulating cooling.
The plate obtained in the embodiment is subjected to free formaldehyde, VOC, heavy metal and anti-mold detection, wherein the execution standard of free formaldehyde detection is GB18580-2001, the execution standard of VOC detection is HJ571-2010, and the execution standard of heavy metal detection is: LY/T2870-2017, and an antimycotic performance detection execution standard: JC/T2177-2013, the results are shown in the table I.
Example 3
The composite mineral board comprises the following raw materials in parts by weight: 60 parts of diatomite, 7 parts of bamboo fiber, 150 parts of jade powder, 10 parts of ash calcium, 5 parts of polyethylene and 3 parts of wood fiber.
The preparation method comprises the following steps:
1) mixing materials: weighing the raw materials according to the weight part ratio, putting the raw materials into a mixer, and uniformly mixing the raw materials at normal temperature and normal pressure to obtain a mixture, wherein the mixing time is 10-15 min;
2) and (3) granulation: fusing and extruding the mixture in a screw extruder to obtain granular materials; the fusion temperature is 60 ℃, and the fusion time is 20 min;
3) pressing: pressing and molding the granules in a press to obtain a plate, wherein the thickness of the pressed and molded plate is 0.1 mm, the width of the plate is 1.8m, and the length of the plate is 2.4m
4) And (3) cooling: and cooling and maintaining the plate, wherein the cooling and maintaining are carried out by adopting normal-temperature tap water for circulating cooling.
The plate obtained in the embodiment is subjected to free formaldehyde, VOC, heavy metal and anti-mold detection, wherein the execution standard of free formaldehyde detection is GB18580-2001, the execution standard of VOC detection is HJ571-2010, and the execution standard of heavy metal detection is: LY/T2870-2017, and an antimycotic performance detection execution standard: JC/T2177-2013, the results are shown in the table I.
The results of the performance tests of the sheets obtained in examples 1 to 3 are shown in Table I.
Table one test result table
Figure DEST_PATH_IMAGE002
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
The above description is only for the purpose of illustrating the technical solutions of the present invention and not for the purpose of limiting the same, and other modifications or equivalent substitutions made by those skilled in the art to the technical solutions of the present invention should be covered within the scope of the claims of the present invention without departing from the spirit and scope of the technical solutions of the present invention.

Claims (10)

1. The diatom composite fiber board is characterized by comprising the following raw materials in parts by weight: 45-60 parts of diatomite, 5-12 parts of bamboo fiber, 15-20 parts of jade powder, 10-15 parts of gray calcium, 5-10 parts of polyethylene and 1-3 parts of wood fiber.
2. The preparation method of the diatom composite fiber board is characterized by comprising the following steps: 1) mixing materials: weighing the raw materials according to the weight part ratio, putting the raw materials into a mixer, and uniformly mixing to obtain a mixture;
2) and (3) granulation: fusing and extruding the mixture in a screw extruder to obtain granular materials; the fusion temperature is 60-70 ℃, and the fusion time is 15-20 min;
3) pressing: pressing and molding the granular materials in a pressing machine to obtain a plate, wherein the temperature is maintained at 60-70 ℃ during pressing;
4) and (3) cooling: and cooling and maintaining the plate.
3. The diatom composite fiber board according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 45 parts of diatomite, 12 parts of bamboo fiber, 20 parts of jade powder, 10 parts of ash calcium, 10 parts of polyethylene and 3 parts of wood fiber.
4. The diatom composite fiber board according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 60 parts of diatomite, 7 parts of bamboo fiber, 15 parts of jade powder, 10 parts of ash calcium, 5 parts of polyethylene and 3 parts of wood fiber.
5. The diatom composite fiber board according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 50 parts of diatomite, 8 parts of bamboo fiber, 20 parts of jade powder, 10 parts of ash calcium, 10 parts of polyethylene and 2 parts of wood fiber.
6. The diatom composite fiber board according to claim 1, which is characterized by comprising the following raw materials in parts by weight: the diatomite is food-grade non-calcined diatomite in the Changbai mountain area of Jilin.
7. The method for preparing the diatom composite fiber board according to claim 2, wherein the method comprises the following steps: in the step 1), mixing is carried out at normal temperature and normal pressure, and the mixing time is 10-15 min.
8. The method for preparing the diatom composite fiber board according to claim 2, wherein the method comprises the following steps: in the step 3), the thickness of the press-formed plate is 0.1-20 mm, the width is 1.8m, and the length is 2.4 m.
9. The method for preparing the diatom composite fiber board according to claim 2, wherein the method comprises the following steps: in the step 4), normal-temperature tap water is adopted for cooling and maintenance in a circulating manner.
10. The method for preparing the diatom composite fiber board according to claim 2, wherein the method comprises the following steps: the free formaldehyde content of the plate reaches the undetected level, heavy metals are not detected, and the mildew-proof grade is zero grade.
CN202011278624.1A 2020-11-16 2020-11-16 Diatom composite fiber board and preparation method thereof Pending CN112408854A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113072356A (en) * 2021-04-20 2021-07-06 白山市和一硅藻科技有限公司 Calcination-free plate prepared from diatomite and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108147712A (en) * 2017-12-28 2018-06-12 海南科技职业学院 A kind of diatom ooze integrated wall plate and preparation method thereof
JP6367505B1 (en) * 2017-12-22 2018-08-01 寧波豊爾泰建材科技有限公司Ningbo Fengertai Building Materials Technology Co.,Ltd. Diatomite water absorption panel and method for producing the same
CN108774042A (en) * 2018-05-24 2018-11-09 武汉格林森建筑科技有限公司 One seeds algae calcium and magnesium composite material, ecological composite plate and its preparation and application
CN111187048A (en) * 2020-01-16 2020-05-22 蓝天豚绿色建筑新材料有限公司 Composite mineral board and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6367505B1 (en) * 2017-12-22 2018-08-01 寧波豊爾泰建材科技有限公司Ningbo Fengertai Building Materials Technology Co.,Ltd. Diatomite water absorption panel and method for producing the same
CN108147712A (en) * 2017-12-28 2018-06-12 海南科技职业学院 A kind of diatom ooze integrated wall plate and preparation method thereof
CN108774042A (en) * 2018-05-24 2018-11-09 武汉格林森建筑科技有限公司 One seeds algae calcium and magnesium composite material, ecological composite plate and its preparation and application
CN111187048A (en) * 2020-01-16 2020-05-22 蓝天豚绿色建筑新材料有限公司 Composite mineral board and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113072356A (en) * 2021-04-20 2021-07-06 白山市和一硅藻科技有限公司 Calcination-free plate prepared from diatomite and preparation method thereof

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Application publication date: 20210226