CN111635211A - Plant fiber cement board and preparation method thereof - Google Patents

Plant fiber cement board and preparation method thereof Download PDF

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Publication number
CN111635211A
CN111635211A CN202010472082.5A CN202010472082A CN111635211A CN 111635211 A CN111635211 A CN 111635211A CN 202010472082 A CN202010472082 A CN 202010472082A CN 111635211 A CN111635211 A CN 111635211A
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China
Prior art keywords
parts
plant fiber
cement board
plant
product
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010472082.5A
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Chinese (zh)
Inventor
曹富宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Ecobo Straw Technology Co ltd
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Anhui Ecobo Straw Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Ecobo Straw Technology Co ltd filed Critical Anhui Ecobo Straw Technology Co ltd
Priority to CN202010472082.5A priority Critical patent/CN111635211A/en
Publication of CN111635211A publication Critical patent/CN111635211A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • C04B18/248Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork from specific plants, e.g. hemp fibres
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • C04B18/26Wood, e.g. sawdust, wood shavings
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • C04B18/26Wood, e.g. sawdust, wood shavings
    • C04B18/265Wood, e.g. sawdust, wood shavings from specific species, e.g. birch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention relates to a plant fiber cement board which comprises the following components in parts by weight: 70-85 parts of plant fiber, 3-6 parts of reinforcing agent, 3-5 parts of curing agent, 15-25 parts of inorganic adhesive, 0.2-0.5 part of preservative and 1-3.5 parts of catalyst. The invention has the advantages that: the cement board has high plant fiber content, and improves the utilization rate of agricultural and forestry wastes. The product using the sulfur-magnesium cement as the adhesive overcomes the defects of halogen return, dewing and metal corrosion of the chlorine-magnesium product. The modifier and the additive are added, so that the compression strength and the breaking strength of the sulfur-magnesium cement product are improved, and the water-resistant softening coefficient and the acid-base corrosion resistance are improved; the magnesium oxysulfate cement product mainly made of plant fibers has obvious advantages of construction and energy conservation. The product volume weight is reduced while the product structural strength is ensured, the requirements of light weight and high strength wall materials are met, the heat preservation and sound insulation effects of the product are improved, and the production cost is reduced.

Description

Plant fiber cement board and preparation method thereof
Technical Field
The invention relates to the technical field of building materials, in particular to a plant fiber cement board and a preparation method thereof.
Background
The traditional building wallboard contains more cement materials and wood materials, and the existing wallboard has the defects of heavier mass, poor impact resistance, rupture resistance and shock resistance, large heat conductivity coefficient, poor heat insulation performance and the like, so that the requirement of building energy-saving standard cannot be met. Along with the continuous improvement of environmental awareness of people, the building wallboard has higher requirements on various performances of the building wallboard, and the existing cement-based wallboard adopts magnesium oxychloride as a cementing material and has the problems of halogen return, condensation, metal corrosion and the like. And the volume weight and the production cost of the existing building board are both large.
Disclosure of Invention
In order to solve the technical problems, the invention provides a plant fiber cement board and a preparation method thereof.
In order to achieve the purpose, the invention provides the following technical scheme:
a plant fiber cement board is characterized in that: the paint comprises the following components in parts by weight: 60-85 parts of plant fiber, 3-6 parts of reinforcing agent, 3-5 parts of curing agent, 15-35 parts of inorganic adhesive, 0.2-0.5 part of preservative and 1-3.5 parts of catalyst.
On the basis of the above scheme, the following technical scheme can be adopted:
the water content of the plant fiber is 8-12%, and the plant straw is straw of wheat, rice, corn, cotton, grass, pasture and reed, wood fiber, bamboo fiber and the like.
The flame retardant is also included, and the weight portion of the flame retardant is 3-5.
The flame retardant is organophosphorus methyl dimethyl phosphonate.
The reinforcing agent is light calcium powder, the inorganic adhesive is magnesium sulfate heptahydrate or light-burned magnesium oxide, the curing agent is p-hydroxybenzene sulfonic acid, and the preservative is nitrite.
The preparation method of the plant fiber cement board is characterized by comprising the following steps:
s1, crushing, namely crushing the plant straws by a crusher and then grinding by a grinder;
s2, air-drying, wherein the ground plant fiber is air-dried by a dryer to enable the water content to be 8-12%;
s3, mixing the glue, and uniformly mixing the air-dried plant fibers and the rare-earth adhesive in a glue applicator;
s4, mixing materials, adding a reinforcing agent, a curing agent, a preservative and a catalyst into the vegetable fiber after glue mixing, and uniformly mixing;
s5, extrusion molding, and extruding and molding the mixed materials through a hot-pressing extruder;
s6, cutting the formed plate into required size;
s7, maintaining, namely maintaining the cut plate for 28 days in an environment with the humidity of 30-65% and the temperature of 15-35 ℃;
and S8, packaging into a finished product warehouse.
The hot pressing temperature in the S5 is 75 to 150 c,
the pressure of the extruder in the S5 is 5-10 Mpa.
The invention has the beneficial effects that: the cement board has high plant fiber content, and improves the utilization rate of agricultural and forestry wastes. The sulfur-magnesium cement adhesive product overcomes the defects of halogen return, dewing and metal corrosion of chlorine-magnesium products. The modifier and the additive are added, so that the compression strength and the breaking strength of the sulfur-magnesium cement product are improved, and the water-resistant softening coefficient and the acid-base corrosion resistance are improved; the magnesium oxysulfate cement product mainly made of plant fibers has obvious advantages of construction and energy conservation. The product volume weight is reduced while the product structural strength is ensured, the requirements of light weight and high strength wall materials are met, the heat preservation and sound insulation effects of the product are improved, and the production cost is reduced.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The embodiment I, the plant fiber cement board comprises the following components in parts by weight: 80 parts of plant fiber, 5 parts of reinforcing agent, 4 parts of curing agent, 20 parts of inorganic adhesive, 0.4 part of preservative, 2.5 parts of catalyst and 4 parts of flame retardant. The plant straw is straw of wheat, rice, corn, cotton, grass, pasture or reed, wood fiber, bamboo fiber and the like, the wheat straw is preferably selected, the flame retardant is organophosphorus methyl dimethyl phosphonate, the reinforcing agent is light calcium powder, the inorganic adhesive is magnesium oxysulfate cement slurry, the curing agent is p-hydroxybenzene sulfonic acid, and the preservative is nitrite.
A preparation method of a plant fiber cement board comprises the following steps:
s1, smashing, bundling wheat straws from the field, transporting the bundled wheat straws to a powder workshop, conveying the bundled wheat straws to a bale breaker through a conveyer, scattering the bundled wheat straws, smashing the smashed wheat straws through a smashing machine, and grinding the smashed wheat straws into plant fibers with required fineness through a grinding machine.
And S2, air-drying, and conveying the ground plant fibers to a dryer through a conveyor for air-drying to enable the water content of the plant fibers to be 10%.
S3, mixing glue, uniformly mixing the air-dried plant fibers and the inorganic adhesive in a glue applicator by adopting magnesium oxysulfate cement slurry, adding a catalyst into the magnesium oxysulfate cement slurry, wherein the catalyst is the prior art and has the functions of adjusting the viscosity and the setting time of the magnesium oxysulfate cement and enhancing the strength and the flexural strength of the magnesium oxysulfate cement.
S4, mixing materials, adding dimethyl organophosphate methyl, light calcium powder, p-hydroxybenzene sulfonic acid and nitrite into the vegetable fiber after glue mixing, and mixing uniformly.
And S5, carrying out extrusion molding, conveying the mixed materials to a hot-pressing extruder through a conveyer, and carrying out hot-pressing extrusion molding. The pressure of the extruder was 8Mpa and the hot pressing temperature was 150 ℃.
And S6, cutting the formed plate into blanks with required sizes by a cross cutting saw, and stacking.
And S7, maintaining, and maintaining the cut plate for 28 days in an environment with the humidity of 50% and the temperature of 35 ℃.
And S8, packaging into a finished product warehouse.
The second embodiment is a plant fiber cement board, which comprises the following components in parts by weight: 75 parts of plant fiber, 4 parts of reinforcing agent, 3.5 parts of curing agent, 18 parts of inorganic adhesive, 0.35 part of preservative, 2.2 parts of catalyst and 3.5 parts of flame retardant. The plant straw is made of wood fiber, and the inorganic adhesive is light-burned magnesium oxide.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and the preferred embodiments of the present invention are described in the above embodiments and the description, and are not intended to limit the present invention. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (8)

1. A plant fiber cement board is characterized in that: the paint comprises the following components in parts by weight: 60-85 parts of plant fiber, 3-6 parts of reinforcing agent, 3-5 parts of curing agent, 15-35 parts of inorganic adhesive, 0.2-0.5 part of preservative and 1-3.5 parts of catalyst.
2. The plant fiber cement board as claimed in claim 1, wherein: the water content of the plant fiber is 8-12%, and the plant straw is straw of wheat, rice, corn, cotton, grass, pasture and reed, wood fiber and bamboo fiber.
3. The plant fiber cement board as claimed in claim 1, wherein: the flame retardant is also included, and the weight portion of the flame retardant is 3-5.
4. The plant fiber cement board as claimed in claim 3, wherein: the flame retardant is organophosphorus methyl dimethyl phosphonate.
5. The plant fiber cement board as claimed in claim 1, wherein: the reinforcing agent is light calcium powder, the inorganic adhesive is magnesium oxysulfate cement, the curing agent is p-hydroxybenzene sulfonic acid, and the preservative is nitrite.
6. The method for preparing plant fiber cement board according to claim 1, comprising the following steps:
s1, crushing, namely crushing the plant straws by a crusher and then grinding by a grinder;
s2, air-drying, wherein the ground plant fiber is air-dried by a dryer to enable the water content to be 8-12%;
s3, mixing the glue, and uniformly mixing the air-dried plant fibers and the rare-earth adhesive in a glue applicator;
s4, mixing materials, adding a reinforcing agent, a curing agent, a preservative and a catalyst into the vegetable fiber after glue mixing, and uniformly mixing;
s5, extrusion molding, and extruding and molding the mixed materials through a hot-pressing extruder;
s6, cutting the formed plate into required size;
s7, maintaining, namely maintaining the cut plate for 28 days in an environment with the humidity of 30-65% and the temperature of 15-35 ℃;
and S8, packaging into a finished product warehouse.
7. The method for preparing a plant fiber cement board according to claim 6, wherein: the hot pressing temperature in the S5 is 75-150 ℃.
8. The method for preparing a plant fiber cement board according to claim 6, wherein: the pressure of the extruder in the S5 is 5-10 Mpa.
CN202010472082.5A 2020-05-29 2020-05-29 Plant fiber cement board and preparation method thereof Pending CN111635211A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010472082.5A CN111635211A (en) 2020-05-29 2020-05-29 Plant fiber cement board and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202010472082.5A CN111635211A (en) 2020-05-29 2020-05-29 Plant fiber cement board and preparation method thereof

Publications (1)

Publication Number Publication Date
CN111635211A true CN111635211A (en) 2020-09-08

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115196940A (en) * 2022-07-15 2022-10-18 中国建筑西南设计研究院有限公司 Composite fiber reinforced basic magnesium sulfate cement and preparation method thereof
WO2022267109A1 (en) * 2021-06-24 2022-12-29 中福海峡(平潭)发展股份有限公司 Juncao fiberboard and preparation method therefor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102493598A (en) * 2011-12-20 2012-06-13 浙江天仁风管有限公司 Magnesium oxysulfate cement board and method for preparing same by using semidry method
CA2869579A1 (en) * 2012-04-05 2013-10-10 Premier Magnesia, Llc Method and compositions for improving performance properties of magnesium oxychloride cements
CN204876310U (en) * 2015-08-14 2015-12-16 孔德玲 Compound cement plate of carbonization bamboo xylon bamboo silk
CN107344838A (en) * 2017-05-24 2017-11-14 四川路带生态科技有限公司 A kind of composite material of plant fiber and preparation method thereof
CN110436844A (en) * 2019-09-09 2019-11-12 安徽省中坤元新型建材有限公司 A kind of improved environment protection cement plate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102493598A (en) * 2011-12-20 2012-06-13 浙江天仁风管有限公司 Magnesium oxysulfate cement board and method for preparing same by using semidry method
CA2869579A1 (en) * 2012-04-05 2013-10-10 Premier Magnesia, Llc Method and compositions for improving performance properties of magnesium oxychloride cements
CN204876310U (en) * 2015-08-14 2015-12-16 孔德玲 Compound cement plate of carbonization bamboo xylon bamboo silk
CN107344838A (en) * 2017-05-24 2017-11-14 四川路带生态科技有限公司 A kind of composite material of plant fiber and preparation method thereof
CN110436844A (en) * 2019-09-09 2019-11-12 安徽省中坤元新型建材有限公司 A kind of improved environment protection cement plate

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022267109A1 (en) * 2021-06-24 2022-12-29 中福海峡(平潭)发展股份有限公司 Juncao fiberboard and preparation method therefor
CN115196940A (en) * 2022-07-15 2022-10-18 中国建筑西南设计研究院有限公司 Composite fiber reinforced basic magnesium sulfate cement and preparation method thereof

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Application publication date: 20200908

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