CN106854054A - A kind of diatomite technique product and preparation method thereof - Google Patents
A kind of diatomite technique product and preparation method thereof Download PDFInfo
- Publication number
- CN106854054A CN106854054A CN201611196318.7A CN201611196318A CN106854054A CN 106854054 A CN106854054 A CN 106854054A CN 201611196318 A CN201611196318 A CN 201611196318A CN 106854054 A CN106854054 A CN 106854054A
- Authority
- CN
- China
- Prior art keywords
- parts
- diatomite
- latex
- technique product
- gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/28—Polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00956—Uses not provided for elsewhere in C04B2111/00 for making sculptures or artistic casts
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
Abstract
The invention discloses a kind of diatomite technique product and preparation method thereof.Raw material including following parts by weight：300 500 parts of diatomite, 30 100 parts of resin, 30 50 parts of natural gum, 20 50 parts of plasticizer, 20 50 parts of attapulgite, 50 200 parts of latex.Handicraft prepared by the present invention, waterproof and fire protecting performance be high, and tension and compression strength are high, it is moulding preferably, it is moulding after do not allow yielding, preparation method is simple, is adapted to large-scale industrial production.
Description
Technical field
The present invention relates to handicraft Technical Development Area, more particularly to a kind of diatomite technique product and preparation method thereof.
Background technology
Handicraft is articles for use essential in living.The species of modern crafts product is various, there is ceramics, plastics work
Skill product, tendril handicraft, metal handicrafts etc., the preparation method of various handicrafts is varied, and metal handicrafts cost is high, system
Preparation Method is complicated, and the energy consumption of preparation is higher, and tendril handicraft generally requires hand woven, and cost of labor is high, and plastic crafts are produced
Raw offensive odour, unfavorable to health, ceramics prepares difficulty, and yield rate is low, it is necessary to fire, energy consumption
It is higher.
Patent 201310001678.7 discloses a kind of handicraft and preparation method thereof., including following weight portion raw material：
1000 parts of resin, 2~7 parts of accelerator, 3~10 parts of curing agent.The technology overcomes the shadow that temperature and humidity is molded to handicraft
Ring, it is to avoid be also easy to produce bubble in the handicraft that is brought by humidity, because of the handicraft easy fracture layering that temperature band is come, or be difficult into
The problem of type.It is the obtained smooth smooth, uniform in color of handicraft, transparent, original aesthetic feeling of various decorative patterns can be embodied, give people to regard
Enjoyment in feel.But, the quality of the handicraft depends on the quality of natural peach shell, the product quality heterogeneity of preparation.Patent
201110419590.8 disclose a kind of fragrant high-hardness gypsum artwork and preparation method thereof, by following weight than raw material system
Into：Land plaster CaSO4-2H2O 74.5%, water 20.5-21%, sintering kaolin 3%, siloxane aqueous dispersant 1%, DH is high
Molecular modification resin 0.5-1%.The range of application of the handicraft is narrow.
The content of the invention
The present invention is, in order to overcome above-mentioned defect in the prior art, to propose a kind of diatomite technique product and preparation method thereof.
A kind of diatomite technique product, including following parts by weight raw material：Diatomite 300-500 parts, resin 30-100 parts,
It is gummy 30-50 parts, plasticizer 20-50 parts, attapulgite 20-50 parts, latex 50-200 parts.
The natural gum is peach gum, bassora gum, ghatti gum, karaya gum, one or more in tamarind gum.
The resin be epoxy resin, acrylic resin, SBS, styrene-
Isoprene-styrene block copolymer, one kind or one kind in styrene-ethylene-butylene-styrene block copolymer with
On.
The plasticizer be diethyl phthalate, methyl methacrylate, diethylenetriamine, N- fluorenylmethyloxycarbonyls-
L-3,3- diphenylalamine, one or more in 3,5- double (trifluoromethyl) -2- chloroanilines.
The latex is natural emulsion, polybutadiene latex, butadiene-styrene latex, one kind or one kind in carboxylic acrylonitrile butadiene rubber latex glue
More than.
Also contain 1-3 parts of gold sodium sulfide in the handicraft.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, take gummy 30-50 parts, be heated to 60-80 DEG C, add 300-600 parts of diatomite, it is concavo-convex
20-50 parts of rod soil, stirs；
(2) temperature is risen to 80-90 DEG C, adds 30-100 parts of resin, plasticizer 20-50 parts, stirred；
(3) room temperature is cooled the temperature to, 50-200 parts of latex is added, is stirred, be poured over die for molding, dried naturally
Or drying is made.
Compared with prior art, the present invention has the advantages that：The present invention prepare diatomite technique product, waterproof and
Fire protecting performance is high, and tension and compression strength are high, it is moulding preferably, it is moulding after do not allow yielding, preparation method is simple, is adapted to extensive
Industrialized production.
Specific embodiment
Specific embodiment of the invention is described in detail below, it is to be understood that protection scope of the present invention is not
Limited by specific embodiment.
Embodiment 1
A kind of diatomite technique product, including following parts by weight raw material：400 parts of diatomite, 70 parts of epoxy resin, peach gum
40 parts, 30 parts of diethyl phthalate, 30 parts of attapulgite, 100 parts of natural emulsion.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 40 parts of peach gum is taken, is heated to 70 DEG C, add 400 parts of diatomite, 30 parts of attapulgite to stir
Mix uniform；
(2) temperature is risen to 85 DEG C, adds 70 parts of epoxy resin, 30 parts of diethyl phthalate to stir；
(3) room temperature is cooled the temperature to, 100 parts of natural emulsion is added, is stirred, be poured over die for molding, dried in the air naturally
Dry or drying is made.
Embodiment 2
A kind of diatomite technique product, including following parts by weight raw material：300 parts of diatomite, 30 parts of acrylic resin is yellow
30 parts of alpine yarrow glue, 20 parts of methyl methacrylate, 20 parts of attapulgite, 50 parts of polybutadiene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 30 parts of bassora gum is taken, is heated to 60 DEG C, add 300 parts of diatomite, 20 parts of attapulgite,
Stir；
(2) temperature is risen to 80 DEG C, adds 30 parts of acrylic resin, 20 parts of methyl methacrylate to stir；
(3) room temperature is cooled the temperature to, 50 parts of polybutadiene latex is added, is stirred, be poured over die for molding, it is natural
Dry or dry and be made.
Embodiment 3
A kind of diatomite technique product, including following parts by weight raw material：450 parts of diatomite, styrene-butadiene-benzene
66 parts of ethylene block copolymer, 40 parts of ghatti gum, 40 parts of N- fluorenylmethyloxycarbonyls-L-3,3- diphenylalamine, attapulgite 33
Part, 88 parts of carboxylic acrylonitrile butadiene rubber latex glue.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 40 parts of ghatti gum is taken, is heated to 70 DEG C, add 450 parts of diatomite, 33 parts of attapulgite,
Stir；
(2) temperature is risen to 88 DEG C, adds 66 parts of SBS, N- fluorenes methoxy carbonyls
40 parts of base-L-3,3- diphenylalamine, stirs；
(3) room temperature is cooled the temperature to, 88 parts of carboxylic acrylonitrile butadiene rubber latex glue is added, is stirred, be poured over die for molding, from
So dry or dry and be made.
Embodiment 4
A kind of diatomite technique product, including following parts by weight raw material：345 parts of diatomite, styrene-isoprene-
55 parts of styrene block copolymer, 45 parts of karaya gum, 3,5- double 25 parts of (trifluoromethyl) -2- chloroanilines, 25 parts of attapulgite,
88 parts of butadiene-styrene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, take gummy 30-50 parts, be heated to 60-80 DEG C, add 300-600 parts of diatomite, it is concavo-convex
20-50 parts of rod soil, stirs；
(2) temperature is risen to 80-90 DEG C, adds 30-100 parts of resin, plasticizer 20-50 parts, stirred；
(3) room temperature is cooled the temperature to, 50-200 parts of latex is added, is stirred, be poured over die for molding, dried naturally
Or drying is made.
Embodiment 5
A kind of diatomite technique product, including following parts by weight raw material：355 parts of diatomite, styrene-ethylene-butadiene-
55 parts of styrene block copolymer, 44 parts of tamarind gum, 3,5- double 44 parts of (trifluoromethyl) -2- chloroanilines, 44 parts of attapulgite,
123 parts of butadiene-styrene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 44 parts of tamarind gum is taken, is heated to 78 DEG C, add 355 parts of diatomite, attapulgite 44
Part, stir；
(2) temperature is risen to 82 DEG C, adds 55 parts of styrene-ethylene-butylene-styrene block copolymer, 3,5- double (three
Methyl fluoride) 44 parts of -2- chloroanilines, stir；
(3) room temperature is cooled the temperature to, 123 parts of butadiene-styrene latex is added, is stirred, be poured over die for molding, dried in the air naturally
Dry or drying is made.
Embodiment 6
A kind of diatomite technique product, including following parts by weight raw material：355 parts of diatomite, styrene-ethylene-butadiene-
55 parts of styrene block copolymer, 44 parts of tamarind gum, 3,5- double 44 parts of (trifluoromethyl) -2- chloroanilines, 44 parts of attapulgite,
123 parts of butadiene-styrene latex, 2 parts of gold sodium sulfide.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 44 parts of tamarind gum is taken, is heated to 78 DEG C, add 355 parts of diatomite, attapulgite 44
Part, 2 parts of gold sodium sulfide stirs；
(2) temperature is risen to 82 DEG C, adds 55 parts of styrene-ethylene-butylene-styrene block copolymer, 3,5- double (three
Methyl fluoride) 44 parts of -2- chloroanilines, stir；
(3) room temperature is cooled the temperature to, 123 parts of butadiene-styrene latex is added, is stirred, be poured over die for molding, dried in the air naturally
Dry or drying is made.
Embodiment 7
A kind of diatomite technique product, including following parts by weight raw material：400 parts of diatomite, 70 parts of epoxy resin, peach gum
40 parts, 30 parts of diethyl phthalate, 30 parts of attapulgite, 100 parts of natural emulsion, 2 parts of connection boric acid DOPCP.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 40 parts of peach gum is taken, is heated to 70 DEG C, add 400 parts of diatomite, 30 parts of attapulgite to stir
Mix uniform；
(2) temperature is risen to 85 DEG C, adds 70 parts of epoxy resin, 30 parts of diethyl phthalate to stir；
(3) room temperature is cooled the temperature to, adds 100 parts of natural emulsion, 2 parts of connection boric acid DOPCP to stir, topple over
It is molded in a mold, dries naturally or dry and be made.
Embodiment 8
A kind of diatomite technique product, including following parts by weight raw material：300 parts of diatomite, 30 parts of acrylic resin is yellow
30 parts of alpine yarrow glue, 20 parts of methyl methacrylate, 20 parts of attapulgite, 50 parts of polybutadiene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 30 parts of bassora gum is taken, is heated to 60 DEG C, add 300 parts of diatomite, 20 parts of attapulgite,
Stir；
(2) temperature is risen to 80 DEG C, adds 30 parts of acrylic resin, 20 parts of methyl methacrylate to stir；
(3) room temperature is cooled the temperature to, 50 parts of polybutadiene latex, N- (the bromo- 2- aminomethyl phenyls of 4-) carbamic acid uncle is added
10 parts of butyl ester, stirs, and is poured over die for molding, dries naturally or dries and is made.
Comparative example 1
A kind of diatomite technique product, including following parts by weight raw material：400 parts of diatomite, 70 parts of epoxy resin, peach gum
40 parts, 30 parts of attapulgite, 100 parts of natural emulsion.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 40 parts of peach gum is taken, is heated to 70 DEG C, add 400 parts of diatomite, 30 parts of attapulgite to stir
Mix uniform；
(2) temperature is risen to 85 DEG C, adds 70 parts of epoxy resin, stirred；
(3) room temperature is cooled the temperature to, 100 parts of natural emulsion is added, is stirred, be poured over die for molding, dried in the air naturally
Dry or drying is made.
Embodiment 2
A kind of diatomite technique product, including following parts by weight raw material：300 parts of diatomite, 30 parts of acrylic resin is yellow
30 parts of alpine yarrow glue, 20 parts of methyl methacrylate, 50 parts of polybutadiene latex.
The preparation method of above-mentioned handicraft, is carried out in accordance with the following steps：
(1) according to parts by weight, 30 parts of bassora gum is taken, is heated to 60 DEG C, add 300 parts of diatomite, stirred；
(2) temperature is risen to 80 DEG C, adds 30 parts of acrylic resin, 20 parts of methyl methacrylate to stir；
(3) room temperature is cooled the temperature to, 50 parts of polybutadiene latex is added, is stirred, be poured over die for molding, it is natural
Dry or dry and be made.
Performance test:Using universal testing machine, the speed specified by GB/T228-2002 standards allows testing machine to mark
Quasi- tension sample is stretched, and surveys tensile strength, and compression strength is surveyed using compression test machine, the results are shown in Table 1：
Table 1
| Detection object | Tensile strength Mpa | Compression strength Mpa |
| Embodiment 1 | 133 | 212 |
| Embodiment 2 | 136 | 212 |
| Embodiment 3 | 129 | 215 |
| Embodiment 4 | 136 | 211 |
| Embodiment 5 | 135 | 219 |
| Embodiment 6 | 177 | 243 |
| Embodiment 7 | 187 | 241 |
| Embodiment 8 | 181 | 242 |
| Comparative example 1 | 93 | 121 |
| Comparative example 2 | 96 | 122 |
The embodiment of above formulation ratio and technique is to elaborate general principle of the invention and characteristic, and the present invention is not
Limited by the implementation of above-mentioned technique and proportioning, without departing from the spirit and scope of the invention, the present invention can also make various
Modification and conversion.Therefore these changes and modifications are belonged in the scope of the invention.
Claims (7)
1. a kind of diatomite technique product, it is characterised in that the raw material including following parts by weight：Diatomite 300-500 parts, natural gum
30-50 parts, resin 30-100 parts, plasticizer 20-50 parts, attapulgite 20-50 parts, latex 50-200 parts.
2. diatomite technique product according to claim 1, it is characterised in that the natural gum is peach gum, and bassora gum, eggplant is replaced
Glue, karaya gum, one or more in tamarind gum.
3. diatomite technique product according to claim 1, it is characterised in that the resin is epoxy resin, acrylic acid tree
Fat, SBS, SIS, styrene-second
One or more in alkene-butylene-styrene block copolymer.
4. diatomite technique product according to claim 1, it is characterised in that the plasticizer is phthalic acid diethyl
Ester, methyl methacrylate, diethylenetriamine, N- fluorenylmethyloxycarbonyls-L-3,3- diphenylalamine, 3,5- double (fluoroforms
Base) one or more in -2- chloroanilines.
5. diatomite technique product according to claim 1, it is characterised in that the latex is natural emulsion, polybutadiene
Latex, butadiene-styrene latex, one or more in carboxylic acrylonitrile butadiene rubber latex glue.
6. diatomite technique product according to claim 1, it is characterised in that also contain 1-3 parts of sulfurous in the handicraft
Sour gold sodium.
7. the preparation method of the diatomite technique product described in claim 1, it is characterised in that carry out in accordance with the following steps：
(1) according to parts by weight, take gummy 30-50 parts, be heated to 60-80 DEG C, add 300-600 parts of diatomite, attapulgite
20-50 parts, stir；
(2) temperature is risen to 80-90 DEG C, adds 30-100 parts of resin, plasticizer 20-50 parts, stirred；
(3) cool the temperature to room temperature, add 50-200 parts of latex, stir, be poured over die for molding, dry naturally or
Drying is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611196318.7A CN106854054A (en) | 2016-12-22 | 2016-12-22 | A kind of diatomite technique product and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611196318.7A CN106854054A (en) | 2016-12-22 | 2016-12-22 | A kind of diatomite technique product and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106854054A true CN106854054A (en) | 2017-06-16 |
Family
ID=59126582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611196318.7A Pending CN106854054A (en) | 2016-12-22 | 2016-12-22 | A kind of diatomite technique product and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106854054A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314257A (en) * | 2001-04-16 | 2001-09-26 | 赵庆华 | Sand-plastic handicraft and its producing technique |
| CN2732502Y (en) * | 2004-09-13 | 2005-10-12 | 李强国 | Art ware capable of cleaning harmful gases in room |
| CN1935908A (en) * | 2006-10-18 | 2007-03-28 | 樊有增 | Natural diatomaceous earth unsaturated polyester putty and its production process |
| CN103553527A (en) * | 2013-10-17 | 2014-02-05 | 青岛川山新材料有限公司 | Diatom ooze powder and method for manufacturing environmental-friendly diatom ooze crafts |
| CN104529366A (en) * | 2014-12-22 | 2015-04-22 | 山东晨泰环保科技有限公司 | Multifunctional environment-friendly diatom craftwork for decomposing formaldehyde and production method of multifunctional environment-friendly diatom craftwork |
| CN104860624A (en) * | 2015-05-14 | 2015-08-26 | 汪培杰 | Multifunctional environment-friendly diatom artware material |
| CN105564116A (en) * | 2014-10-17 | 2016-05-11 | 侯霞 | Sand sculpture handicraft and making technology thereof |
| CN105885224A (en) * | 2016-05-03 | 2016-08-24 | 江苏锦禾高新科技股份有限公司 | Walnut shell powder plastic and preparation method thereof |
-
2016
- 2016-12-22 CN CN201611196318.7A patent/CN106854054A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314257A (en) * | 2001-04-16 | 2001-09-26 | 赵庆华 | Sand-plastic handicraft and its producing technique |
| CN2732502Y (en) * | 2004-09-13 | 2005-10-12 | 李强国 | Art ware capable of cleaning harmful gases in room |
| CN1935908A (en) * | 2006-10-18 | 2007-03-28 | 樊有增 | Natural diatomaceous earth unsaturated polyester putty and its production process |
| CN103553527A (en) * | 2013-10-17 | 2014-02-05 | 青岛川山新材料有限公司 | Diatom ooze powder and method for manufacturing environmental-friendly diatom ooze crafts |
| CN105564116A (en) * | 2014-10-17 | 2016-05-11 | 侯霞 | Sand sculpture handicraft and making technology thereof |
| CN104529366A (en) * | 2014-12-22 | 2015-04-22 | 山东晨泰环保科技有限公司 | Multifunctional environment-friendly diatom craftwork for decomposing formaldehyde and production method of multifunctional environment-friendly diatom craftwork |
| CN104860624A (en) * | 2015-05-14 | 2015-08-26 | 汪培杰 | Multifunctional environment-friendly diatom artware material |
| CN105885224A (en) * | 2016-05-03 | 2016-08-24 | 江苏锦禾高新科技股份有限公司 | Walnut shell powder plastic and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106479262B (en) | IMR matte ink and preparation and use methods thereof | |
| CN104044240B (en) | Injection moulding fag end and preparation method thereof | |
| CN105482334B (en) | A kind of disposable feel slurry for artificial flowers and its preparation method and application | |
| CN102863934A (en) | Method for preparing heat-resistant modified water-based chloroprene rubber adhesive and application | |
| CN106633986B (en) | A kind of wood powder craftwork and preparation method thereof | |
| CN106633232B (en) | A kind of craftwork and preparation method thereof | |
| CN105201165B (en) | Diatom ooze metope preparation method with 3D relief painting blocks | |
| CN106854054A (en) | A kind of diatomite technique product and preparation method thereof | |
| CN102115550A (en) | Color clay composition | |
| KR101066202B1 (en) | The tall scandal manufacturing method which uses lacquering | |
| CN104652756B (en) | Bottom contains sound-absorbing damping floor and the manufacture method thereof of sound-absorbing damping particle | |
| ATE548172T1 (en) | METHOD AND DEVICE FOR PRODUCING A PRODUCT USING A FLEXIBLE SHAPING SHELL | |
| CN105859182B (en) | A kind of multi-functional inner wall surface material of mud negative ion powder and preparation method thereof | |
| CN107090270B (en) | A kind of water-resistance soy adhesive and preparation method thereof | |
| CN105398069B (en) | A kind of technique for producing toy inflatable bladder using the outer demoulding | |
| CN103274664A (en) | Artware and fabrication method thereof | |
| CN108312765A (en) | A kind of super realistic painted sculptures production method of craft | |
| CN104262576A (en) | Polyurethane simulation flower and preparation method thereof | |
| CN108147712A (en) | A kind of diatom ooze integrated wall plate and preparation method thereof | |
| CN109429782A (en) | A kind of gas permeability flowerpot and its manufacture craft with sand production | |
| CN106799918A (en) | A kind of manufacture craft of pulp handicraft | |
| RU2559448C2 (en) | Polymer clay for artistic modelling | |
| CN102229308A (en) | Imitated resin craft and production method thereof | |
| CN106365543B (en) | A kind of diatom ooze powder and a kind of diatom ooze goods of furniture for display rather than for use and preparation method thereof | |
| CN105294007B (en) | A kind of good fortune board and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170616 |
|
| RJ01 | Rejection of invention patent application after publication |