CN106633232B - A kind of craftwork and preparation method thereof - Google Patents

A kind of craftwork and preparation method thereof Download PDF

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Publication number
CN106633232B
CN106633232B CN201611196339.9A CN201611196339A CN106633232B CN 106633232 B CN106633232 B CN 106633232B CN 201611196339 A CN201611196339 A CN 201611196339A CN 106633232 B CN106633232 B CN 106633232B
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parts
craftwork
added
preparation
weight
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CN106633232A (en
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马爱忠
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Zhangye Danxia Fengyun Tourism Culture Development Co ltd
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Zhangye Red Rosy Clouds Graceful Bearing Tourist Culture Development Corp Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • C08L9/08Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/10Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adornments (AREA)

Abstract

The invention discloses a kind of craftworks and preparation method thereof.Raw material including following parts by weight:It is 30-80 parts of mineral powder, 30-100 parts of macromolecule resin, 50-100 parts gummy, yellow clay 20-30 parts, 50-200 parts of latex.Craftwork prepared by the present invention, waterproof and fire protecting performance are high, and tension and compression strength are high, and moulding is preferable, is not easy to deform after moulding, and preparation method is simple, are suitble to large-scale industrial production.

Description

A kind of craftwork and preparation method thereof
Technical field
The present invention relates to craftwork Technical Development Area, in particular to a kind of craftwork and preparation method thereof.
Background technique
Craftwork is essential articles in life.Modern crafts product it is many kinds of, have ceramics, plastics work The preparation method of skill product, tendril craftwork, metal handicrafts etc., various craftworks is varied, and metal handicrafts cost is high, system Preparation Method is complicated, and the energy consumption of preparation is higher, and tendril craftwork generally requires hand woven, high labor cost, and plastic crafts produce Raw offensive odour, is harmful to human health, and ceramics preparation is difficult, and yield rate is low, needs to fire, energy consumption It is higher.
Patent 201310001678.7 discloses a kind of craftwork and preparation method thereof., the raw material including following parts by weight: 1000 parts of resin, 2~7 parts of promotor, 3~10 parts of curing agent.The technology overcomes temperature and humidity to the molding shadow of craftwork It rings, avoids because being also easy to produce bubble in humidity bring craftwork, because temperature bring craftwork easy fracture is layered, or be not easy into The problem of type.It is the smooth smooth, uniform in color of craftwork obtained, transparent, original aesthetic feeling of various decorative patterns can be embodied, people's view is given Enjoyment in feel.But the quality of the craftwork depends on the quality of natural peach shell, the product quality of preparation is inhomogenous.Patent 201110419590.8 disclose a kind of fragrant high-hardness gypsum artwork and preparation method thereof, by the raw material system of following weight ratio At:Land plaster CaSO4-2H2O 74.5%, water 20.5-21% are sintered kaolin 3%, siloxane aqueous dispersing agent 1%, DH high Molecular modification resin 0.5-1%.The application range of the craftwork is narrow.
Summary of the invention
The present invention is to propose a kind of craftwork and preparation method thereof to overcome above-mentioned defect in the prior art.
A kind of craftwork, the raw material including following parts by weight:30-80 parts of mineral powder, 30-100 parts of macromolecule resin, tree 50-100 parts of glue, yellow clay 20-30 parts, 50-200 parts of latex.
The mineral powder is sepiolite powder, pyrophyllite powder, iron ore powder, talcum powder, one of silica flour or it is a kind of with On.
The macromolecule resin is epoxy resin, acrylic resin, Styrene-Butadiene-Styrene Block Copolymer, benzene Ethylene-isoprene-styrene block copolymer, one of styrene-ethylene-butylene-styrene block copolymer or one Kind or more.
It is described natural gum be peach gum, bassora gum, ghatti gum, karaya gum, one of tamarind gum or more than one.
The latex is natural emulsion, polybutadiene latex, butadiene-styrene latex, one of carboxylic acrylonitrile butadiene rubber latex glue or one kind More than.
Also contain 1-3 parts of gold sodium sulfides in the craftwork.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, it takes 50-100 parts gummy, is heated to 70-100 DEG C, be added mineral powder 30-80 part, it is yellow to stick It is 20-30 parts native, it stirs evenly;
(2) temperature is risen to 110-130 DEG C, is added macromolecule resin 30-100 parts, stirs evenly;
(3) room temperature is cooled the temperature to, latex 50-200 parts is added, stirs evenly, be poured over die for molding, naturally dry Or drying is made
Compared with prior art, the present invention has the advantages that:Craftwork prepared by the present invention, waterproof and fire line Can be high, tension and compression strength are high, and moulding is preferable, is not easy to deform after moulding, and preparation method is simple, are suitble to heavy industrialization Production.
Specific embodiment
Specific embodiments of the present invention will be described in detail below, it is to be understood that protection scope of the present invention is not It is restricted by specific implementation.
Embodiment 1
A kind of craftwork, the raw material including following parts by weight:50 parts of sepiolite powder, 60 parts of epoxy resin, 70 parts of peach gum, 25 parts of yellow clay, 100 parts of natural emulsion.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 70 parts of peach gum are taken, is heated to 80 DEG C, is added 50 parts of sepiolite powder, 25 parts of yellow clay stirs It mixes uniformly;
(2) temperature is risen to 120 DEG C, is added 60 parts of epoxy resin, stirs evenly;
(3) room temperature is cooled the temperature to, 100 parts of natural emulsion is added, stirs evenly, be poured over die for molding, dry in the air naturally Dry or drying is made.
Embodiment 2
A kind of craftwork, the raw material including following parts by weight:30 parts of pyrophyllite powder, 30 parts of acrylic resin, bassora gum 50 parts, 20 parts of yellow clay, 50 parts of polybutadiene latex.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 50 parts of bassora gum are taken, is heated to 70 DEG C, is added 30 parts of pyrophyllite powder, 20 parts of yellow clay, It stirs evenly;
(2) temperature is risen to 110 DEG C, is added 30 parts of acrylic resin, stirs evenly;
(3) room temperature is cooled the temperature to, 50 parts of polybutadiene latex is added, stirs evenly, be poured over die for molding, it is natural It dries or dries and be made.
Embodiment 3
A kind of craftwork, the raw material including following parts by weight:80 parts of iron ore powder, s-B-S is embedding 00 part of copolymer 1 of section, 100 parts of ghatti gum, 30 parts of yellow clay, 200 parts of butadiene-styrene latex.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 100 parts of ghatti gum are taken, is heated to 100 DEG C, is added 80 parts of iron ore powder, yellow clay 30 Part, it stirs evenly;
(2) temperature is risen to 130 DEG C, is added 100 parts of Styrene-Butadiene-Styrene Block Copolymer, stirs evenly;
(3) room temperature is cooled the temperature to, 200 parts of butadiene-styrene latex is added, stirs evenly, be poured over die for molding, dry in the air naturally Dry or drying is made.
Embodiment 4
A kind of craftwork, the raw material including following parts by weight:45 parts of talcum powder, styrene-isoprene-phenylethene is embedding 56 parts of copolymer of section, 65 parts of karaya gum, 22 parts of yellow clay, 55 parts of carboxylic acrylonitrile butadiene rubber latex glue.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 65 parts of karaya gum are taken, is heated to 76 DEG C, is added 45 parts of talcum powder, 23 parts of yellow clay, It stirs evenly;
(2) temperature is risen to 115 DEG C, is added 56 parts of styrene-isoprene-styrene block copolymer, stirs evenly;
(3) room temperature is cooled the temperature to, 65 parts of karaya gum is added, stirs evenly, be poured over die for molding, naturally dry Or drying is made.
Embodiment 5
A kind of craftwork, the raw material including following parts by weight:66 parts of silica flour, styrene-ethylene-butylene-styrene 66 parts of block copolymer, 55 parts of tamarind gum, 22 parts of yellow clay, 78 parts of polybutadiene latex.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 55 parts of tamarind gum are taken, is heated to 78 DEG C, is added 66 parts of silica flour, 22 parts of yellow clay, It stirs evenly;
(2) temperature is risen to 118 DEG C, is added 66 parts of styrene-ethylene-butylene-styrene block copolymer, stirring is equal It is even;
(3) room temperature is cooled the temperature to, 78 parts of polybutadiene latex is added, stirs evenly, be poured over die for molding, it is natural It dries or dries and be made.
Embodiment 6
A kind of craftwork, the raw material including following parts by weight:66 parts of silica flour, styrene-ethylene-butylene-styrene 66 parts of block copolymer, 55 parts of tamarind gum, 22 parts of yellow clay, 78 parts of polybutadiene latex, 2 parts of gold sodium sulfide.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 55 parts of tamarind gum are taken, is heated to 78 DEG C, is added 66 parts of silica flour, 22 parts of yellow clay, It 2 parts of gold sodium sulfide, stirs evenly;
(2) temperature is risen to 118 DEG C, is added 66 parts of styrene-ethylene-butylene-styrene block copolymer, stirring is equal It is even;
(3) room temperature is cooled the temperature to, 78 parts of polybutadiene latex is added, stirs evenly, be poured over die for molding, it is natural It dries or dries and be made.
Embodiment 7
A kind of craftwork, the raw material including following parts by weight:50 parts of sepiolite powder, 60 parts of epoxy resin, 70 parts of peach gum, 25 parts of yellow clay, 100 parts of natural emulsion, 3- (4,4,5,5- tetramethyls -1,3, penta ring -2- base of 2- dioxy boron) ethyl benzoate 2 Part.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 70 parts of peach gum are taken, is heated to 80 DEG C, is added 50 parts of sepiolite powder, 25 parts of yellow clay stirs It mixes uniformly;
(2) temperature is risen to 120 DEG C, is added 60 parts of epoxy resin, stirs evenly;
(3) room temperature is cooled the temperature to, is added 100 parts of natural emulsion, 3- (4,4,5,5- tetramethyls -1,3,2- dioxy boron penta Ring -2- base) 2 parts of ethyl benzoate, it stirs evenly, is poured over die for molding, naturally dry or drying are made.
Embodiment 8
A kind of craftwork, the raw material including following parts by weight:30 parts of pyrophyllite powder, 30 parts of acrylic resin, bassora gum 50 parts, 20 parts of yellow clay, 50 parts of polybutadiene latex, to 2 parts of isopropoxy methyl benzoate.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 50 parts of bassora gum are taken, is heated to 70 DEG C, is added 30 parts of pyrophyllite powder, 20 parts of yellow clay, It stirs evenly;
(2) temperature is risen to 110 DEG C, is added 30 parts of acrylic resin, stirs evenly;
(3) room temperature is cooled the temperature to, is added 50 parts of polybutadiene latex, to 2 parts of isopropoxy methyl benzoate, stirring is equal It is even, it is poured over die for molding, naturally dry or drying are made.
Comparative example 1
A kind of craftwork, the raw material including following parts by weight:80 parts of iron ore powder, s-B-S is embedding 00 part of copolymer 1 of section, 30 parts of yellow clay, 200 parts of butadiene-styrene latex.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 80 parts of iron ore powder are taken, 30 parts of yellow clay stirs evenly;
(2) temperature is risen to 130 DEG C, is added 100 parts of Styrene-Butadiene-Styrene Block Copolymer, stirs evenly;
(3) room temperature is cooled the temperature to, 200 parts of butadiene-styrene latex is added, stirs evenly, be poured over die for molding, dry in the air naturally Dry or drying is made.
Comparative example 2
A kind of craftwork, the raw material including following parts by weight:45 parts of talcum powder, 65 parts of karaya gum, 22 parts of yellow clay, 55 parts of carboxylic acrylonitrile butadiene rubber latex glue.
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 65 parts of karaya gum are taken, is heated to 76 DEG C, is added 45 parts of talcum powder, 23 parts of yellow clay, It stirs evenly;
(2) room temperature is cooled the temperature to, 65 parts of karaya gum is added, stirs evenly, be poured over die for molding, naturally dry Or drying is made.
Performance test:Using universal testing machine, allow testing machine to mark by speed as defined in GB/T228-2002 standard Quasi- tension sample is stretched, and tensile strength is surveyed, and is surveyed compression strength using compression test machine, be the results are shown in Table 1:
Table 1
Test object Tensile strength Mpa Compression strength Mpa
Embodiment 1 145 221
Embodiment 2 135 222
Embodiment 3 136 221
Embodiment 4 137 212
Embodiment 5 135 221
Embodiment 6 187 251
Embodiment 7 188 260
Embodiment 8 189 253
Comparative example 1 98 133
Comparative example 2 97 132
The embodiment of the above formulation ratio and technique only elaborates the basic principles and features of the invention, and the present invention is not It is limited by the implementation of above-mentioned technique and proportion, without departing from the spirit and scope of the invention, the present invention can also make various Modification and transformation.Therefore these changes and changes belong in the scope of the invention.

Claims (1)

1. a kind of craftwork, which is characterized in that the raw material including following parts by weight:50 parts of sepiolite powder, 60 parts of epoxy resin, 70 parts of peach gum, 25 parts of yellow clay, 100 parts of natural emulsion, 3- (4,4,5,5- tetramethyls -1,3, penta ring -2- base of 2- dioxy boron) benzene 2 parts of Ethyl formate;
The preparation method of above-mentioned craftwork carries out in accordance with the following steps:
(1) according to parts by weight, 70 parts of peach gum are taken, is heated to 80 DEG C, is added 50 parts of sepiolite powder, 25 parts of yellow clay, stirring is It is even;
(2) temperature is risen to 120 DEG C, is added 60 parts of epoxy resin, stirs evenly;
(3) room temperature is cooled the temperature to, is added 100 parts of natural emulsion, 3- (4,4,5,5- tetramethyls -1,3, penta ring -2- of 2- dioxy boron Base) 2 parts of ethyl benzoate, it stirs evenly, is poured over die for molding, naturally dry or drying are made.
CN201611196339.9A 2016-12-22 2016-12-22 A kind of craftwork and preparation method thereof Active CN106633232B (en)

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CN109438785A (en) * 2018-11-27 2019-03-08 青岛金瑞纳橡胶科技有限公司 A kind of vulcanized rubber powder wet process rubber compound and preparation method thereof

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CN1510075A (en) * 2002-12-25 2004-07-07 上海三和科技合作公司 Artist clay material and production thereof
CN101928468A (en) * 2010-08-31 2010-12-29 常熟市恒升工艺品有限公司 Bogus carved-bone artware and manufacturing process thereof
CN104497487A (en) * 2014-12-18 2015-04-08 无锡伊诺永利文化创意有限公司 Environment-friendly artware raw material formula
CN106080006A (en) * 2016-07-13 2016-11-09 叶安生 A kind of high imitative ivory carving and manufacturing process

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