CN105482334B - A kind of disposable feel slurry for artificial flowers and its preparation method and application - Google Patents
A kind of disposable feel slurry for artificial flowers and its preparation method and application Download PDFInfo
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- CN105482334B CN105482334B CN201610022571.4A CN201610022571A CN105482334B CN 105482334 B CN105482334 B CN 105482334B CN 201610022571 A CN201610022571 A CN 201610022571A CN 105482334 B CN105482334 B CN 105482334B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G2/00—Vegetative propagation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
Starched the present invention relates to a kind of disposable feel for artificial flowers and its preparation method and application, the feel slurry contains the following raw material component by weight：Component A, it includes：Polyacrylate dispersion 50~70 part of the glass transition temperature at 5 DEG C~10 DEG C；Mass fraction is 40% 5~10 parts of polythene wax emulsion；2~5 parts of plasticizer；2~5 parts of aerosil；8~40 parts of pure water；0.05~0.15 part of pH stabilizers；1~3 part of thickener；B component, it includes：1~5 part of organo-silicon coupling agent.Feel slurry prepared by the present invention, applied to using textile cloth and EVA expanded materials as in the artificial flowers of base material, both this type artificial flowers moulding advantage true to nature, convenient for production and cheap cost had been remained, and can significantly improves the feel of artificial flowers, accomplish good hand feeling, bright-colored have levels, and need to only increase by a procedure, and it is simple to operate, there are important market prospects.
Description
Technical field
The present invention relates to artificial flowers production field, more particularly to a kind of disposable feel for artificial flowers to starch and its prepare
Methods and applications.
Background technology
It is the artificial flowers of base material (in artificial flowers using textile cloth and EVA expanded materials with the continuous heating in artificial flowers market
Both industries are referred to as silk flower and foaming flower) by moulding is true to nature, superiority development convenient for production and cheap cost is swift and violent, it is fast
Speed captures artificial flowers market, but the feel of product and the vividness of color constrain its development simultaneously.
The appearance of imitation polyurethane flower, compensate for gaps in market.But this artificial flowers also have the following disadvantages：Cost
Height, price；Some color solidification degree are spent not as silk, such as the easy yellow fading of white；With really spend cracky, touch and improper tend to have hand
Nail presses line；Have certain thickness, cause its when making elegant, petite petal, pistil effect not as silk flower.
Want artificial flowers market further to develop, it is necessary to the high emulation that a kind of feel is excellent, moulding is true to nature, cost is controllable
Flower.Artificial flowers industry is directed to this problem at present, is surface-treated more by using vulcanization rubber, forms one layer of rubber coating,
To reach the effect for improving good hand feeling degree.CN1167693A discloses a kind of preparation method of glue modeling artificial flowers, and it is provided
There is Bu Ji and without two kinds of manufacture crafts of cloth base, reach the effect of raising good hand feeling degree by increasing vulcanization rubber coating；
But this method is while feel is improved, there is also weak point, such as rubber poor adhesive force, bright-colored degree is insufficient and weather-proof
Property is poor, adds pre-treatment and starching two procedures, makes the production cycle extend.
In addition, the artificial flowers using textile cloth as base material are made using modified EVA emulsion or polyacrylate dispersion more at present
For feel coating, though the type feel coating adhesive force is good, but occurs the tacky phenomenon of feel, therefore actual production technique meeting
Starch adhesive release treatment is carried out again, and the main component of starch adhesive is emulsifying wax.
CN104262576A discloses imitation polyurethane flower and preparation method thereof, and it provides one kind and prepares imitation polyurethane
Colored formula and technique, fidelity is high, is not afraid of washing, color solidification degree is good and operates relatively simple；But raw materials used excitant
Greatly and there is certain toxicity, itself has certain thickness, and when making elegant, petite petal pistil, effect is not ideal.
CN101233960A discloses a kind of preparation method for emulating yulan leaf, is first put into the fresh yulan leaf of collection
In more than 90 DEG C of water, and dilute sulfuric acid is added, mesophyll is removed after carrying out fermentation process, be left vein, and carry out disinfection and clean
Processing；Then vein specification on demand and shape are subjected to stamp, and carry out drying process；Iron wire is pasted again after drying
Vein back master pulse network on, and by vein feel slurry in impregnation and coloring；Afterwards by after impregnation and coloring treatment
Vein dips in slurry in matt slurry, and the surface treatment such as color spray, polishing is carried out after naturally dry.Manufactured emulation yulan leaf finished product gloss
Spend, fidelity height, but its feel slurry cost used is higher, and the feel of artificial flowers is poor, and operation is more complicated.
Therefore, how to produce it is a kind of be used for artificial flowers in can retain artificial flowers moulding advantage true to nature, and can substantially carries
The feel of high artificial flowers, accomplish good hand feeling, it is bright-colored have levels, feel simple to operate slurry turns into the weight studied at present
Point.
The content of the invention
For the above-mentioned deficiency of prior art, the invention provides a kind of disposable feel being used in artificial flowers to starch, this
The prepared feel slurry of invention, applied to using textile cloth and EVA expanded materials in the artificial flowers of base material, both to have remained this type
Artificial flowers moulding advantage true to nature, convenient for production and cheap cost, and can significantly improve the feel of artificial flowers, accomplish that feel is rich
It is full, bright-colored to have levels, and need to only increase by a procedure, it is simple to operate.
For up to this purpose, present invention employs following technical scheme：
In a first aspect, the invention provides a kind of disposable feel slurry for artificial flowers, the feel slurry is by weight
Contain the following raw material component：
Component A, it includes：
B component, it includes：
1~5 part of organo-silicon coupling agent.
In the present invention, the glass transition temperature -5 DEG C~-10 DEG C polyacrylate dispersion the feel slurry in
Parts by weight are 50~70 parts, for example, can be 50 parts, 52 parts, 54 parts, 56 parts, 58 parts, 60 parts, 62 parts, 64 parts, 65 parts, 66 parts,
67 parts, 68 parts, more preferably 69 parts, 70 parts, preferably 60~70 parts, 70 parts.
In the present invention, the parts by weight of polythene wax emulsion that the mass fraction is 40% in feel slurry are 5~
10 parts, for example, can be 5 parts, 5.5 parts, 5.8 parts, 6 parts, 6.2 parts, 6.8 parts, 7 parts, 7.5 parts, 8 parts, 8.2 parts, 9 parts, 9.5 parts,
10 parts, preferably 5~8 parts, more preferably 8 parts.
In the present invention, parts by weight of the plasticizer in feel slurry are 2~5 parts, for example, can be 2 parts, 2.5
Part, 2.8 parts, 3 parts, 3.2 parts, 3.8 parts, 4 parts, 4.1 parts, 4.3 parts, 4.5 parts, preferably 4.8 parts, 5 parts, 2~3 parts, further
Preferably 3 parts.
In the present invention, the parts by weight in feel slurry described in the aerosil are 2~5 parts, such as can be 2 parts,
2.5 parts, 2.8 parts, 3 parts, 3.2 parts, 3.8 parts, 4 parts, 4.1 parts, 4.3 parts, 4.5 parts, preferably 4.8 parts, 5 parts, 2~4 parts, enter one
Step is preferably 4 parts.
In the present invention, parts by weight of the pure water in feel slurry are 8~40 parts, for example, can be 8 parts, 9 parts,
10.5 parts, 11 parts, 12.5 parts, 13.5 parts, 14 parts, 15 parts, 17 parts, 19 parts, 21 parts, 23 parts, 25 parts, 27 parts, 29 parts, 31 parts,
33 parts, 34 parts, 36 parts, 37 parts, more preferably 39 parts, 40 parts, preferably 8~20 parts, 13.95 parts.
In the present invention, the pH stabilizers feel slurry in parts by weight be 0.05~0.15 part, such as can with 0.05 part,
0.06 part, 0.07 part, 0.08 part, 0.09 part, 0.10 part, 0.11 part, 0.12 part, 0.13 part, 0.14 part, 0.15 part, it is preferably
0.05~0.1 part, more preferably 0.05 part.
In the present invention, parts by weight of the thickener in feel slurry are 1~3 part, for example, can be 1 part, 1.2 parts, 1.5
Part, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, 2 parts, 2.1 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8
Part, more preferably 2.9 parts, 3 parts, preferably 1~2 part, 1 part.
In the present invention, parts by weight of the organo-silicon coupling agent in feel slurry are 1~5 part, for example, can be 1 part, 1.2
Part, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, 2 parts, 2.1 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7
Part, 2.8 parts, 2.9 parts, 3 parts, 3.2 parts, 3.5 parts, 3.7 parts, 3.8 parts, 4 parts, 4.2 parts, 4.3 parts, 4.4 parts, 4.6 parts, 4.8 parts,
4.9 parts, 5 parts, preferably 1~4 part, more preferably 4 parts.
Preferably, the disposable feel of the present invention for artificial flowers is starched, by weight containing the following raw material component：
Component A, it includes：
B component, it includes：
1~4 part of organo-silicon coupling agent.
It is further preferred that the disposable feel of the present invention for artificial flowers is starched, by weight containing following former
Expect component：
Component A, it includes：
B component, it includes：
4 parts of organo-silicon coupling agent.
Wherein, the plasticizer is the mixture of butyl stearate, any one or two kinds in Ethylhexyl stearate,
Such as can be the mixture of butyl stearate or Ethylhexyl stearate or butyl stearate and Ethylhexyl stearate.
Plasticizer selected in the present invention is stearic acid ester plasticizer, using this kind of plasticizer, not only makes polypropylene
Feel is more soft after acid esters emulsion film forming, and effectively reduces the viscous hand situation after film forming.
Wherein, the specific surface area of the aerosil is 100-300m2/ g, such as can be 100m2/g、120m2/
g、130m2/g、150m2/g、180m2/g、200m2/g、220m2/g、250m2/g、260m2/g、270m2/g、290m2/g、300m2/
G, preferably 200m2/g。
The present invention adds polythene wax emulsion and aerosil simultaneously in feel slurry, and both play after combining
Synergistic function, the combination not only effectively increase the heat resistance of polyacrylate, also make feel slurry resistance to blocking good, and
Feel is more smooth.
Wherein, the pH stabilizers are AMP-95.
Wherein, the thickener is any one in swollen class thickener MC35, the MC200 of association type alkali soluble or two kinds
Mixture, such as can be MC35 or MC200 or MC35 and MC200 mixture.
Wherein, the organo-silicon coupling agent is any one in organo silane coupling agent A-172, A-186 or two kinds
Mixture, such as can be A-172 or A-186 or A-172 and A-186 mixture.
The present invention adds silane coupler in feel slurry, can significantly improve adhesive force of the feel slurry to base material, by
PH stabilizers while used in employing to hydrolyze slower coupling agent and arrange in pairs or groups simultaneously, substantially prolongs the holding time of slurry,
Its holding time is set to can reach more than 7 days, so as to avoid the waste of slurry.
Second aspect, present invention also offers the preparation that the disposable feel for artificial flowers as described in relation to the first aspect is starched
Method, it comprises the following steps：
(1) component A is prepared：It is kept stirring under state, the polythene wax emulsion, plasticizer, gas for being 40% by mass fraction
Aerosil and pure water are sequentially added into glass transition temperature in -5 DEG C~-10 DEG C of polyacrylate dispersion, with 800~
1000r/min rotating speed continues to be dispersed with stirring 10-20min；According to slurry pH value, PH is adjusted to 7 in addition pH stabilizers；Root
According to viscosity requirement, slurry is thickened using thickener, and improves rotating speed to the scattered 10-20min of 2000~2500r/min；Use
100-150 mesh grenadine filters, and obtains component A slurry；
(2) starch before use, in the component A slurry that B component addition step (1) is obtained, stir in the feel, starch
Expect to preserve at 30 DEG C, obtain the disposable feel for artificial flowers and starch.
In the preparation method that the disposable feel for artificial flowers is starched, each raw material components match somebody with somebody such as first aspect
It is described.
Preferably, the preparation method that the disposable feel of the present invention for artificial flowers is starched comprises the following steps：
(1) component A is prepared：It is kept stirring under state, by polythene wax emulsion of the mass fraction for 40%, stearic acid fourth
Ester, specific surface area 100-300m2/ g aerosil and pure water is sequentially added into glass transition temperature at -5 DEG C~-10 DEG C
Polyacrylate dispersion in, continue to be dispersed with stirring 15min with 800~1000r/min rotating speed；According to slurry pH value, addition
PH is adjusted to 7 in AMP-95；According to viscosity requirement, slurry is thickened using association type alkali soluble swollen class thickener MC35, and carries
High rotating speed to 2000~2500r/min disperse 15min；Filtered using 150 mesh grenadines, obtain component A slurry；
(2) starched in the feel before use, the component A slurry that organo silane coupling agent A-172 addition steps (1) are obtained
In, stir, slurry preserves at 30 DEG C, obtains the disposable feel for artificial flowers and starches.
In the present invention, stirred using in component A slurry before use, adding B component, preserve, have at 30 DEG C of slurry
The effect phase is 7 days.
The third aspect, present invention also offers a kind of preparation method of artificial flowers, methods described is using such as first party
Feel slurry described in face carries out impregnation and coloring.
Feel slurry prepared by the present invention, applied to using textile cloth and EVA expanded materials in the artificial flowers of base material, both to protect
This type artificial flowers moulding advantage true to nature, convenient for production and cheap cost is stayed, and can significantly improves the feel of artificial flowers, done
To good hand feeling, it is bright-colored have levels, and need to only increase by a procedure, its specific production procedure as shown in figure 1,
Specially：
First, the main Making programme of cloth-based material artificial flowers：
1. colouring：In blank cloth, the petal and leaf pattern needed for silk-screen printing are used.
2. flower pattern processed：The Cloth Cutting after stamp into blade or other required shapes, then on forming machine mould
High-temperature shaping and thermal synthesis anthocaulus, petiole (temperature and time is depending on cloth species) are carried out, obtains artificial flowers flower pattern.
3. gluing：Two components that the disposable feel of the present invention is starched are well mixed, toning is standby；Artificial flowers flower pattern
Soaking paste processing is carried out, can be dried after soaking paste in 50-60 DEG C of drying room.
4. assembling sizing：By the artificial flowers after preceding 3 step heat seal, leaf be fixed on by by hand wind or the plastic cement bar of mechanism on
Whole manufacturing process can be completed.
2nd, the main Making programme of EVA expanded materials artificial flowers：
1. flower pattern processed：Required flower piece and blade are cut out as requested；By high-temperature shaping and thermal synthesis anthocaulus, leaf
Handle.
2. gluing：Two components that the disposable feel of the present invention is starched are well mixed, toning is standby；Artificial flowers flower pattern
Soaking paste processing is carried out, can be dried after soaking paste in 50-60 DEG C of drying room.
3. assembling sizing：By after preceding 2 step heat seal finished product flower, leaf be fixed on by by hand wind or the plastic cement bar of mechanism on
Whole manufacturing process can be completed.
Compared with prior art, the present invention at least has the advantages that：
(1) present invention abandons highly toxic phthalate in the disposable feel slurry for artificial flowers
The environment-friendly plasticizer such as plasticizer and terephthalic acid ester, epoxidized soybean oil, its major defect are not environmentally with influenceing feel slurry
The adhesive of coating, glue hand situation and aggravate；Present invention selection stearic acid ester plasticizer, not only makes polyacrylate dispersion film forming
Feel is more soft afterwards, and effectively reduces the viscous hand situation after film forming；
(2) for the present invention by using polythene wax emulsion and aerosil simultaneously, both have played collaboration after combining
Synergistic effect, the combination not only effectively increase the heat resistance of polyacrylate, also make feel slurry resistance to blocking good, and feel is more
It is smooth；
(3) present invention can significantly improve adhesive force of the feel slurry to base material by adding silane coupler, due to adopting simultaneously
PH stabilizers while used with the slower coupling agent of hydrolysis and arranging in pairs or groups, it is 7 to keep slurry pH, can effectively extend the preservation of slurry
Time, so as to avoid the waste of slurry；
(4) the feel slurry prepared by the present invention, applied to using textile cloth and EVA expanded materials as in the artificial flowers of base material,
Both this type artificial flowers moulding advantage true to nature, convenient for production and cheap cost had been remained, and can significantly improves the hand of artificial flowers
Sense, accomplish good hand feeling, it is bright-colored have levels, and need to only increase by a procedure, it is simple to operate.
Brief description of the drawings
Fig. 1 is the production procedure for utilizing the disposable feel slurry for artificial flowers of the present invention to make artificial flowers.
Embodiment
Below in conjunction with the accompanying drawings and specific embodiment, the present invention is expanded on further.These embodiments are interpreted as being only used for
It is bright the present invention rather than limit the scope of the invention.After the content of the invention recorded has been read, art technology
Personnel can make various changes or modification to the present invention, and these equivalence changes and modification equally fall into the claims in the present invention and limited
Fixed scope.
Preparation example：
The preparation method that disposable feel for artificial flowers is starched, comprises the following steps：
(1) component A is prepared：It is kept stirring under state, the polythene wax emulsion, plasticizer, gas for being 40% by mass fraction
Aerosil and pure water are sequentially added into glass transition temperature in -5 DEG C~-10 DEG C of polyacrylate dispersion, with 800~
1000r/min rotating speed continues to be dispersed with stirring 10-20min；According to slurry pH value, PH is adjusted to 7 in addition pH stabilizers；Root
According to viscosity requirement, slurry is thickened using thickener, and improves rotating speed to the scattered 10-20min of 2000~2500r/min；Use
100-150 mesh grenadine filters, and obtains component A slurry；
(2) starch before use, B component is added in step (1) obtained component A slurry, stir in feel, slurry in
Preserved at 30 DEG C, obtain the disposable feel slurry for artificial flowers.
Following examples all carry out the preparation of feel slurry using the preparation example.
Embodiment 1：
Component A：
| Material name | Proportioning/part | Remarks |
| JN-230 | 70 | Tg:- 10 DEG C, solid content:49 parts |
| HA-40 | 8 | |
| Plasticizer | 3 | |
| HDK N20 | 4 | |
| AMP-95 | 0.05 | |
| Pure water | 13.95 | |
| MC35 | 1 |
B component：
| Material name | Proportioning/part | Remarks |
| Silane coupling A -186 | 4 | It is uniformly added into before use |
Embodiment 2：
Component A：
B component：
| Material name | Proportioning/part | Remarks |
| Silane coupling A -172 | 3 | It is uniformly added into before use |
Embodiment 3：
Component A：
| Material name | Proportioning/part | Remarks |
| JN-230 | 50 | Tg:- 10 DEG C, solid content:49 parts |
| HA-40 | 4 | |
| Plasticizer | 5 | |
| AEROSIL 200 | 2 | |
| AMP-95 | 0.15 | |
| Pure water | 35.85 | |
| MC35 | 3 |
B component：
| Material name | Proportioning/part | Remarks |
| Silane coupling A -172 | 2 | It is uniformly added into before use |
Performance test：
Feel mainly include soft durometer, smooth degree, greasy feeling, plumpness this in terms of four, because artificial flowers industry is to feel
Evaluation lack standard, therefore artificial flowers, after feel is handled, evaluation method mainly uses digital palpation for examination of trauma, right respectively by lab assistant
Feel emulation flower pattern carries out touch scoring, then synthesis chooses stamp feel grade, and optimal is 5 grades, and worst is 1 grade.After tested, have
Body result is as shown in the table.
It can be seen from above-described embodiment that prepared by the present invention for artificial flowers disposable feel starch, for
During the making of artificial flowers, its obtained artificial flowers has soft full, has voluptuousness, smooth non-greasy, is suitable for petal
With leaf area is larger or the characteristics of the artificial flowers such as pistil is smaller, it is and simple to operate, there are important market prospects.
Applicant states that the present invention illustrates the detailed process equipment of the present invention and technological process by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, it is above-mentioned detailed not mean that the present invention has to rely on
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
The addition of equivalence replacement and auxiliary element to each raw material of product of the present invention, selection of concrete mode etc., all fall within the present invention's
Within the scope of protection domain and disclosure.
Claims (8)
1. a kind of disposable feel for artificial flowers is starched, it is characterised in that the feel slurry contains the following raw material component by weight：
Component A, it includes：
Polyacrylate dispersion 50 ~ 70 part of the glass transition temperature at -5 DEG C ~ -10 DEG C；
Mass fraction is 40% 5 ~ 10 parts of polythene wax emulsion；
2 ~ 5 parts of plasticizer；
2 ~ 5 parts of aerosil；
8 ~ 40 parts of pure water；
0.05 ~ 0.15 part of pH stabilizers；
1 ~ 3 part of thickener；
B component, it includes：
1 ~ 5 part of organo-silicon coupling agent；
The plasticizer is the mixture of any one or two kinds in butyl stearate, Ethylhexyl stearate；
The pH stabilizers are AMP-95；
The thickener is the mixture of any one or two kinds in swollen class thickener MC35, the MC200 of association type alkali soluble；
The organo-silicon coupling agent is the mixture of any one or two kinds in organo silane coupling agent A-172, A-186.
2. the disposable feel according to claim 1 for artificial flowers is starched, it is characterised in that the feel slurry is by weight
Part contains the following raw material component：
Component A, it includes：
Polyacrylate dispersion 60 ~ 70 part of the glass transition temperature at -5 DEG C ~ -10 DEG C；
Mass fraction is 40% 5 ~ 8 parts of polythene wax emulsion；
2 ~ 3 parts of plasticizer；
2 ~ 4 parts of aerosil；
8 ~ 20 parts of pure water；
0.05 ~ 0.1 part of pH stabilizers；
1 ~ 2 part of thickener；
B component, it includes：
1 ~ 4 part of organo-silicon coupling agent.
3. the disposable feel according to claim 1 or 2 for artificial flowers is starched, it is characterised in that the feel slurry is pressed
Parts by weight contain the following raw material component：
Component A, it includes：
Polyacrylate dispersion 70 part of the glass transition temperature at -5 DEG C ~ -10 DEG C；
Mass fraction is 40% 8 parts of polythene wax emulsion；
3 parts of plasticizer；
4 parts of aerosil；
13.95 parts of pure water；
0.05 part of pH stabilizers；
1 part of thickener；
B component, it includes：
4 parts of organo-silicon coupling agent.
4. the disposable feel according to claim 1 for artificial flowers is starched, it is characterised in that the aerosil
Specific surface area be 100-300m2/g。
5. the disposable feel according to claim 1 for artificial flowers is starched, it is characterised in that the aerosil
Specific surface area be 200m2/g。
6. the preparation method that the disposable feel according to claim 1 for artificial flowers is starched, it is characterised in that the side
Method comprises the following steps：
（1）Prepare component A：It is kept stirring under state, the polythene wax emulsion, plasticizer, gas phase dioxy for being 40% by mass fraction
SiClx and pure water are sequentially added into glass transition temperature in -5 DEG C ~ -10 DEG C of polyacrylate dispersion, with 800 ~ 1000r/min
Rotating speed continue to be dispersed with stirring 10-20min；According to slurry pH value, PH is adjusted to 7 in addition pH stabilizers；Will according to viscosity
Ask, slurry is thickened using thickener, and improve rotating speed to the scattered 10-20min of 2000 ~ 2500r/min；Use 100-150 mesh
Grenadine filters, and obtains component A slurry；
（2）Starched in the feel before use, B component is added into step（1）In obtained component A slurry, stir, slurry in
Preserved at 30 DEG C, obtain the disposable feel for artificial flowers and starch.
7. according to the method for claim 6, it is characterised in that the described method comprises the following steps：
（1）Prepare component A：It is kept stirring under state, by polythene wax emulsion that mass fraction is 40%, butyl stearate, compares table
Area is 100-300m2/ g aerosil and pure water is sequentially added into polypropylene of the glass transition temperature at -5 DEG C ~ -10 DEG C
In acid esters emulsion, continue to be dispersed with stirring 15min with 800 ~ 1000r/min rotating speed；According to slurry pH value, addition AMP-95 is carried out
Adjust PH to 7；According to viscosity requirement, slurry is thickened using association type alkali soluble swollen class thickener MC35, and improve rotating speed extremely
2000 ~ 2500r/min disperses 15min；Filtered using 150 mesh grenadines, obtain component A slurry；
（2）Starched in the feel before use, organo silane coupling agent A-172 is added into step（1）In obtained component A slurry,
Stir, slurry preserves at 30 DEG C, obtains the disposable feel for artificial flowers and starches.
8. a kind of preparation method of artificial flowers, it is characterised in that methods described is starched using feel as claimed in claim 1
Carry out impregnation and coloring.
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| CN201610022571.4A CN105482334B (en) | 2016-01-12 | 2016-01-12 | A kind of disposable feel slurry for artificial flowers and its preparation method and application |
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| CN201610022571.4A CN105482334B (en) | 2016-01-12 | 2016-01-12 | A kind of disposable feel slurry for artificial flowers and its preparation method and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107746453A (en) * | 2017-09-19 | 2018-03-02 | 河南花思源工艺品有限公司 | The preparation method of Multifunction cloth base rubber modeling flower |
| CN107488274A (en) * | 2017-09-20 | 2017-12-19 | 界首市希捷仿真花卉有限公司 | A kind of preparation method of emulating plastics flower filler |
| CN107573577A (en) * | 2017-09-20 | 2018-01-12 | 界首市希捷仿真花卉有限公司 | A kind of preparation method of artificial flower fragrance slow-release plastic |
| CN110256761A (en) * | 2019-07-03 | 2019-09-20 | 东莞市海纳丝花工艺品有限公司 | A kind of emulation plant and preparation method thereof |
| CN114622413A (en) * | 2022-04-14 | 2022-06-14 | 聂燕兰 | Formula and preparation method of quick-drying hand feeling glue with improved artificial flower effect |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1632013A (en) * | 2004-11-24 | 2005-06-29 | 广州电器科学研究院 | Aqueous dumb paint and method for preparing same |
| CN102505527A (en) * | 2011-11-04 | 2012-06-20 | 东莞长联新材料科技有限公司 | Rubber cement for improving printing rubbing color fastness and dryness and preparation method thereof |
| CN103194917A (en) * | 2013-03-05 | 2013-07-10 | 广州市唯佳安达新材料科技有限公司 | Desizing-free polyacrylate emulsion slurry for one-step dyeing and weaving and preparation method thereof |
| CN104947463A (en) * | 2015-07-23 | 2015-09-30 | 百宁纺织化工(中山)有限公司 | Formula of printing white glue |
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2016
- 2016-01-12 CN CN201610022571.4A patent/CN105482334B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632013A (en) * | 2004-11-24 | 2005-06-29 | 广州电器科学研究院 | Aqueous dumb paint and method for preparing same |
| CN102505527A (en) * | 2011-11-04 | 2012-06-20 | 东莞长联新材料科技有限公司 | Rubber cement for improving printing rubbing color fastness and dryness and preparation method thereof |
| CN103194917A (en) * | 2013-03-05 | 2013-07-10 | 广州市唯佳安达新材料科技有限公司 | Desizing-free polyacrylate emulsion slurry for one-step dyeing and weaving and preparation method thereof |
| CN104947463A (en) * | 2015-07-23 | 2015-09-30 | 百宁纺织化工(中山)有限公司 | Formula of printing white glue |
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