CN107572891A - One kind synthesis toughness marble and its manufacture method - Google Patents

One kind synthesis toughness marble and its manufacture method Download PDF

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Publication number
CN107572891A
CN107572891A CN201710754310.6A CN201710754310A CN107572891A CN 107572891 A CN107572891 A CN 107572891A CN 201710754310 A CN201710754310 A CN 201710754310A CN 107572891 A CN107572891 A CN 107572891A
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China
Prior art keywords
parts
marble
toughness
synthesis
accelerator
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CN201710754310.6A
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Chinese (zh)
Inventor
张明
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Wuwei County Xin Shi Stone Industry Co Ltd
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Wuwei County Xin Shi Stone Industry Co Ltd
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Priority to CN201710754310.6A priority Critical patent/CN107572891A/en
Publication of CN107572891A publication Critical patent/CN107572891A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to marble manufacturing field, is specifically a kind of synthesis toughness marble and its manufacture method, includes according to weight composition point:60 70 parts of marble defective material, 35 40 parts of epoxy resin, 30 40 parts of lime stone, 20 30 parts of aqueous polyurethane, 15 20 parts of Paris white, 18 23 parts of hibbsite, 13 15 parts of curing agent, 10 12 parts of accelerator, 8 10 parts of initiator, it is comprised the following steps that:(1) smash;(2) heat;(3) it is molded, substitutes the synthetic marble of in the market, there is certain toughness, will not ftracture easily broken;A large amount of epoxy resin are added, improve toughness and cohesive;Color can unrestricted choice, suitable for house ornamentation field.

Description

One kind synthesis toughness marble and its manufacture method
Technical field
The present invention relates to marble manufacturing field, is specifically a kind of synthesis toughness marble and its manufacture method.
Background technology
Now in order to which the remaining leftover pieces of marble and residue are reused, there are many new technical methods, such as Synthetic marble, but this kind of marble excessive high hardness, toughness is low, easily dry and cracked to go to sticks and staves, it is therefore desirable to one when as fixture Kind with certain toughness, to be not easy dry and cracked marble for people to use.
The content of the invention
In order to solve the above problems, the present invention proposes a kind of synthesis toughness marble and its manufacture method.
One kind synthesis toughness marble, include the component of following mass fraction:
Marble defective material 60-70 parts, epoxy resin 35-40 parts, lime stone 30-40 parts, aqueous polyurethane 20-30 parts, carbon Sour calcium powder 15-20 parts, hibbsite 18-23 parts, curing agent 13-15 parts, accelerator 10-12 parts, initiator 8-10 parts.
Described initiator is that benzophenone, benzophenone, benzophenone are any.
Described accelerator is lauric acid ester or the mixture of cobalt iso-octoate and styrene.
Described curing agent includes acid anhydrides, imidazoles, polyamine, polymercaptan, one kind or any combination in poly- phenol.
One kind synthesis toughness method for producing marble, it is comprised the following steps that:
(1) smash:Marble defective material, lime stone are smashed using beating crusher, then mixed using mixer, is added simultaneously Paris white stirring turns into mixture;
(2) heat:Mixture in step (1) is inserted in boiler and melted at high temperature under high pressure, and is added water-based Polyurethane, epoxy resin and hibbsite are stirred;
(3) it is molded:Curing agent, accelerator, initiator will be added in fused mass in step (2), inserted after stirring In mould, high-pressure molding is shaken.
The beneficial effects of the invention are as follows:The synthetic marble for the alternative in the market of marble that the present invention supports, have one Fixed toughness, it will not ftracture easily broken;A large amount of epoxy resin are added, improve toughness and cohesive;Color can unrestricted choice, fit For house ornamentation field.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, below it is right The present invention is expanded on further.
Embodiment one:
One kind synthesis toughness marble, include the component of following mass fraction:
60 parts of marble defective material, 37 parts of epoxy resin, 40 parts of lime stone, 20 parts of aqueous polyurethane, 17 parts of Paris white, three 23 parts of hydrated alumina, 13 parts of curing agent, 11 parts of accelerator, 10 parts of initiator.
Described initiator is that benzophenone, benzophenone, benzophenone are any.
Described accelerator is lauric acid ester or the mixture of cobalt iso-octoate and styrene.
Described curing agent includes acid anhydrides, imidazoles, polyamine, polymercaptan, one kind or any combination in poly- phenol.
One kind synthesis toughness method for producing marble, it is comprised the following steps that:
(1) smash:Marble defective material, lime stone are smashed using beating crusher, then mixed using mixer, is added simultaneously Paris white stirring turns into mixture;
(2) heat:Mixture in step (1) is inserted in boiler and melted at high temperature under high pressure, and is added water-based Polyurethane, epoxy resin and hibbsite are stirred;
(3) it is molded:Curing agent, accelerator, initiator will be added in fused mass in step (2), inserted after stirring In mould, high-pressure molding is shaken.
Embodiment two:
One kind synthesis toughness marble, include the component of following mass fraction:
65 parts of marble defective material, 40 parts of epoxy resin, 30 parts of lime stone, 25 parts of aqueous polyurethane, 20 parts of Paris white, three 18 parts of hydrated alumina, 14 parts of curing agent, 12 parts of accelerator, 8 parts of initiator.
Described initiator is that benzophenone, benzophenone, benzophenone are any.
Described accelerator is lauric acid ester or the mixture of cobalt iso-octoate and styrene.
Described curing agent includes acid anhydrides, imidazoles, polyamine, polymercaptan, one kind or any combination in poly- phenol.
One kind synthesis toughness method for producing marble, it is comprised the following steps that:
(1) smash:Marble defective material, lime stone are smashed using beating crusher, then mixed using mixer, is added simultaneously Paris white stirring turns into mixture;
(2) heat:Mixture in step (1) is inserted in boiler and melted at high temperature under high pressure, and is added water-based Polyurethane, epoxy resin and hibbsite are stirred;
(3) it is molded:Curing agent, accelerator, initiator will be added in fused mass in step (2), inserted after stirring In mould, high-pressure molding is shaken.
Embodiment three:
One kind synthesis toughness marble, include the component of following mass fraction:
70 parts of marble defective material, 35 parts of epoxy resin, 38 parts of lime stone, 30 parts of aqueous polyurethane, 15 parts of Paris white, three 20.5 parts of hydrated alumina, 15 parts of curing agent, 10 parts of accelerator, 9 parts of initiator.
Described initiator is that benzophenone, benzophenone, benzophenone are any.
Described accelerator is lauric acid ester or the mixture of cobalt iso-octoate and styrene.
Described curing agent includes acid anhydrides, imidazoles, polyamine, polymercaptan, one kind or any combination in poly- phenol.
One kind synthesis toughness method for producing marble, it is comprised the following steps that:
(1) smash:Marble defective material, lime stone are smashed using beating crusher, then mixed using mixer, is added simultaneously Paris white stirring turns into mixture;
(2) heat:Mixture in step (1) is inserted in boiler and melted at high temperature under high pressure, and is added water-based Polyurethane, epoxy resin and hibbsite are stirred;
(3) it is molded:Curing agent, accelerator, initiator will be added in fused mass in step (2), inserted after stirring In mould, high-pressure molding is shaken.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry For personnel it should be appreciated that the present invention is not limited to the above embodiments, that described in above-described embodiment and specification is the present invention Principle, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these change and Improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its equivalent Thing defines.

Claims (5)

1. one kind synthesis toughness marble, it is characterised in that:Include the component of following mass fraction:Marble defective material 60-70 parts, Epoxy resin 35-40 parts, lime stone 30-40 parts, aqueous polyurethane 20-30 parts, Paris white 15-20 parts, hibbsite 18-23 parts, curing agent 13-15 parts, accelerator 10-12 parts, initiator 8-10 parts.
A kind of 2. synthesis toughness marble according to claim 1, it is characterised in that:Described initiator is hexichol first Ketone, benzophenone, benzophenone are any.
A kind of 3. synthesis toughness marble according to claim 1, it is characterised in that:Described accelerator is lauric acid The mixture of ester or cobalt iso-octoate and styrene.
A kind of 4. synthesis toughness marble according to claim 1, it is characterised in that:Described curing agent include acid anhydrides, Imidazoles, polyamine, polymercaptan, one kind or any combination in poly- phenol.
5. utilize a kind of synthesis toughness method for producing marble described in any one of Claims 1-4 4, it is characterised in that:Its Comprise the following steps that:
(1) smash:Marble defective material, lime stone are smashed using beating crusher, then mixed using mixer, while adds carbonic acid Calcium powder stirring turns into mixture;
(2) heat:Mixture in step (1) is inserted in boiler and melted at high temperature under high pressure, and adds water-based poly- ammonia Ester, epoxy resin and hibbsite are stirred;
(3) it is molded:Curing agent, accelerator, initiator will be added in fused mass in step (2), mould is inserted after stirring In, shake high-pressure molding.
CN201710754310.6A 2017-08-29 2017-08-29 One kind synthesis toughness marble and its manufacture method Pending CN107572891A (en)

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Application Number Priority Date Filing Date Title
CN201710754310.6A CN107572891A (en) 2017-08-29 2017-08-29 One kind synthesis toughness marble and its manufacture method

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CN107572891A true CN107572891A (en) 2018-01-12

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115872670A (en) * 2022-10-27 2023-03-31 广东省科学院资源利用与稀土开发研究所 High-performance organic artificial marble and preparation method thereof
CN115925321A (en) * 2023-02-17 2023-04-07 江苏百代节能建材有限公司 High-strength ecological stone slab and preparation method thereof

Citations (9)

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CN1321706A (en) * 2000-10-20 2001-11-14 珠海保税区宝丽杜邦建材有限公司 Production method of high wear-resisting solid surfacing material
JP2002137949A (en) * 2000-10-27 2002-05-14 Toto Ltd Resin composition for artificial marble and formed body for waterworks
CN1373156A (en) * 2001-03-06 2002-10-09 蔡庆华 Synthetic resin marble
CN1458107A (en) * 2003-06-18 2003-11-26 王新 Synthetic marble and process for preparing its plate
CN101163651A (en) * 2006-06-02 2008-04-16 Lg化学株式会社 Artificial marble using low specific gravity material as chip and process for preparing the same
CN101255049A (en) * 2008-03-17 2008-09-03 石磊 Flexible tapestry brick of external wall outer insulation system and production method thereof
CN101633197A (en) * 2009-07-30 2010-01-27 华南理工大学 Method for producing energy-saving scagliola containing microencapsulated phase change materials
CN103243879A (en) * 2012-02-09 2013-08-14 平湖市法而特建筑保温科技有限公司 High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials
CN104276795A (en) * 2013-07-01 2015-01-14 万峰石材科技股份有限公司 High-strength composite inorganic artificial stone and preparing method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321706A (en) * 2000-10-20 2001-11-14 珠海保税区宝丽杜邦建材有限公司 Production method of high wear-resisting solid surfacing material
JP2002137949A (en) * 2000-10-27 2002-05-14 Toto Ltd Resin composition for artificial marble and formed body for waterworks
CN1373156A (en) * 2001-03-06 2002-10-09 蔡庆华 Synthetic resin marble
CN1458107A (en) * 2003-06-18 2003-11-26 王新 Synthetic marble and process for preparing its plate
CN101163651A (en) * 2006-06-02 2008-04-16 Lg化学株式会社 Artificial marble using low specific gravity material as chip and process for preparing the same
CN101255049A (en) * 2008-03-17 2008-09-03 石磊 Flexible tapestry brick of external wall outer insulation system and production method thereof
CN101633197A (en) * 2009-07-30 2010-01-27 华南理工大学 Method for producing energy-saving scagliola containing microencapsulated phase change materials
CN103243879A (en) * 2012-02-09 2013-08-14 平湖市法而特建筑保温科技有限公司 High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials
CN104276795A (en) * 2013-07-01 2015-01-14 万峰石材科技股份有限公司 High-strength composite inorganic artificial stone and preparing method thereof

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Title
王啟泰: "《王啟泰说陶质文物修复》", 30 September 2012, 中国书店 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115872670A (en) * 2022-10-27 2023-03-31 广东省科学院资源利用与稀土开发研究所 High-performance organic artificial marble and preparation method thereof
CN115872670B (en) * 2022-10-27 2024-04-02 广东省科学院资源利用与稀土开发研究所 Organic artificial marble and preparation method thereof
CN115925321A (en) * 2023-02-17 2023-04-07 江苏百代节能建材有限公司 High-strength ecological stone slab and preparation method thereof

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Application publication date: 20180112