CN104276795A - High-strength composite inorganic artificial stone and preparing method thereof - Google Patents
High-strength composite inorganic artificial stone and preparing method thereof Download PDFInfo
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Abstract
The invention discloses a high-strength composite inorganic artificial stone and a preparing method thereof; the inorganic artificial stone comprises the following components by the weight percentage: 30-65% of aggregates, 25-60% of cement, 1-10% of a composite modifying agent, 1-5% of a water reducing agent, 0-1.5% of a retarder, and 8-20% of water, wherein the particle sizes of the aggregates are graded according to the weight of the aggregates. The preparing method of the inorganic artificial stone comprises the steps: successively adding the aggregates with predetermined weight particle size graduation, the cement, the composite modifying agent and the water reducing agent into a stirrer successively, uniformly stirring, adding an appropriate weight of water, then uniformly stirring, distributing the material and pressing under a vacuum state, carrying out wet culture and curing, cutting, and polishing to obtain the product. The inorganic artificial stone has the advantages of high bending strength, environmental-protection production process, lower cost, high yield rate of the product, outstanding performance and the like.
Description
Technical field
The present invention relates to a kind of Inorganic artificial stone, relate to a kind of high-strength composite Inorganic artificial stone and preparation method thereof specifically.
Background technology
Rostone be a kind of "dead", pollution-free, can reuse, the architecture indoor new decorative material of environmental protection.As a kind of strategic Novel healthy environment protection product meeting national sustainable development, introduce domestic market the eighties in last century.The organic type rostone of the rostone sold in the market mainly using macromolecule resin material as tackiness agent, is mainly divided three classes: artificial marble (referred to as artificial hilllock stone), artificial quartz in lump and acrylic.Although China starts late in rostone industry, through the fast development of two more than ten years, at the forefront in the world in market scale and application popularization rate.
Artificial hilllock stone with unsaturated polyester resin or thermoplastic polyester for matrix, with the particle of carbonate stone material (marble, Wingdale etc.), powder for main stuffing, through the rostone with certain specification size and dimension of specific processes.Artificial hilllock stone occupies larger share in rostone market, is the main flow of current generation wall tile, floor tile and door pocket brick class.The advantage of such rostone is that texture is good, pattern abundant, easily cutting and deep processing etc., special stone material curved surface deep-processing machine (as numerical control cylinder lathe, duplicator and rope saw etc.) can be utilized to make the different size sheet materials such as various abnormal shape and circular arc, but relative to quartzite material, the hardness of artificial hilllock stone is relatively low (Mohs' hardness >=3), not wear-resistant, for keeping good decorative effect, generally all need regularly to carry out maintenance.The preparation technology of artificial hilllock stone generally adopts batch compression moulding of waste material method to produce, and the famine material produced is again through ambient cure, and gang saw cuts, and makes finished product after polishing and deep processing.
Artificial quartz in lump with unsaturated polyester resin or thermoplastic polyester for matrix, with inorganic materials (its main component is for silicon-dioxide) such as silicate (class) natural stone diamond stone and/or powder, silica sand, mine tailings for main stuffing, through the rostone with certain specification size and dimension of specific processes.Because of its quality hard (Mohs' hardness 5-7), compact structure, there is the characteristic such as wear-resisting, withstand voltage, anticorrosive, impermeable that other finishing material are incomparable.Artificial quartz in lump is widely used in kitchen table top, laboratory table top, windowsill, bar desk, lift port, ground, metope etc.All applicable to the place artificial quartz in lump that material requirements is higher in building.
At present, artificial hilllock stone and artificial quartz in lump are all tackiness agent with unsaturated polyester resin, therefore resin type artificial stone or organic artificial's stone material is also called, there is the features such as thickness is thin, intensity is high, performance is good, glossiness is high, color even, multi-color pattern, decorate properties are good, can be widely used in the interior decoration engineerings such as kitchen guarding, metope, ground.But, resin type artificial stone has irritating smell in process of production, in use have that resistance to elevated temperatures difference, alkaline-resisting Salt Corrosion are poor, loss of properties on aging, easily produce the problems such as distortion, the kitchen range top of temperature drift can not be used for, fire-protection rating requires high public place, uviolizing, the outdoor environment etc. that colds and heat succeed each other.
Inorganic artificial combining stone can improve the shortcoming of resin type rostone effectively, the inorganic artificial combining stone can seen on the market at present but cannot reach the folding strength of artificial hilllock stone and artificial quartz in lump, the inorganic artificial combining stone of exploitation high strength, effectively can improve the shortcoming of resin type artificial stone, have again excellent decorative effect, the high breaking strength that simultaneously can also reach artificial hilllock stone and artificial quartz in lump will be with a wide range of applications.
Summary of the invention
The technical problem that the present invention solves is to provide that a kind of High anti bending strength, production process environmental protection, cost are lower, the high-strength composite Inorganic artificial stone of excellent performance.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is: a kind of high-strength composite Inorganic artificial stone, is characterized in that: described Inorganic artificial stone is made up of the component of following weight percent:
Aggregate 30 ~ 65%
Cement 25 ~ 60%
Composite modifier 1 ~ 10%
Water reducer 1 ~ 5%
Retardant 0 ~ 1.5%
Water 8 ~ 20%
The size of described aggregate presses the weight grating of aggregate, particle diameter 1 ~ the 10mm of aggregate accounts for 1 ~ 3.5% of aggregate weigh, its screen size of the particle diameter of aggregate is that 20 ~ 80 objects account for 20 ~ 46% of aggregate weigh, its screen size of the particle diameter of aggregate be greater than that 80 orders are less than or equal to that 400 objects account for aggregate weigh 50 ~ 79%.
Preferably, described aggregate is selected from one or more in marble, quartz sand, granite and aluminium hydroxide.
Preferably, described cement is one or more of ordinary Portland cement, normal silicate white cement or sulphur aluminium cement.Adopt cement as gelatinous material, can product cost be reduced, non-volatility gas, environmental protection can be realized in production process.
Preferably, described composite modifier is one or more of VAE class composite modifier, rubber-like composite modifier, 1 ~ 3mm glass fibre, epoxy resin properties-correcting agent or high reactivity filler.Wherein, epoxy resin properties-correcting agent, VAE class composite modifier and rubber-like composite modifier provide good application property and water-retentivity to newly mixing mixture, extraordinary cohesiveness, snappiness, water tolerance, alkali resistance and good ageing resistance is provided to hardened material, make up the microstructural flaws in cement, prevent generation or the expansion of tiny crack; 1 ~ 3mm glass fibre, high reactivity filler are to the application property mobility of newly mixing mixture and providing good, make up the microstructural flaws in cement, prevent generation or the expansion of tiny crack, improving product intensity, wherein, high reactivity filler comprises silicon ash, flyash, blast-furnace slag, kaolin.
Preferably, described water reducer is one or more of naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent or polycarboxylate dehydragent.This analog high efficiency water reducing agent can increase substantially the mobility of Self-leveling slurry, reduces water consumption during slurry modulation, improves the intensity after slurry setting and harden, reduce volumetric shrinkage.
Preferably, described retardant is molasses system retardant or citric acid system retardant, and this type of retardant can slow down the condensation of polymer cement based composites, extends time of coagulation, improves mobility.
The present invention's beneficial effect is compared with prior art: because the present invention adopts cement as the gelatinous material of rostone, irritating smell can not be produced in process of production, the aggregate adopted is the grating of different-grain diameter rank ratio, in formula, add properties-correcting agent and water reducer simultaneously, using cement as gelatinous material, temper, the rostone produced by this formula has the advantages such as High anti bending strength, production process environmental protection, cost are lower, excellent performance.
Another technical problem that the present invention solves is to provide that a kind of High anti bending strength, production process environmental protection, product yield are high, the high-strength composite Inorganic artificial stone preparation method of excellent performance.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is: a kind of high-strength composite Inorganic artificial stone preparation technology, it is characterized in that, comprise the steps: a, the aggregate of size weight percentage grating, cement, composite modifier, water reducer added successively in stirrer and carry out uniform stirring; B, add in the material of step a approrpiate wts water and carry out uniform stirring; C, the material of step b to be vacuumized, under vacuum conditions material to be arranged in mould and to carry out vibration under vacuum conditions and suppress; D, the mould suppressed by step c put at room temperature naturally wet foster solidification or wet foster solidification under being warmed up to optimum temps; E, to steps d solidification famine material cuts, polishing gets product.
Further illustrating as such scheme, the stirrer of described step a is horizontal mixer, and the process that horizontal mixer is stirring conveniently can stir evenly material, and the pug after simultaneously also making stirring realizes predetermined pattern.
Preferably, also retardant is added with in the stirrer of described step a.
Preferably, the vacuum tightness of described step c is more than 0.077MPa, and being arranged in by material in mould and vibrating the operation of suppressing is complete under vacuum tightness is the environment of more than 0.077MPa.Carry out vibration compacting after the material after stirring being arranged in mould under this vacuum state again, the space of storeroom can be reduced like this, improve folding strength and performance, the greatly yield of improving product of product.
The present invention's beneficial effect is compared with prior art: because the present invention adopts cement as the gelatinous material of rostone, irritating smell can not be produced in process of production, by stirrer, aggregate, cement, composite modifier, water reducer, water are stirred, carry out under vacuum conditions arranging and suppressing, the rostone produced by present method has the advantages such as the high and excellent performance of High anti bending strength, production process environmental protection, product yield.
[embodiment]
Describe the present invention below in conjunction with specific embodiment, following embodiment and explanation are only used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1:
Aggregate is 30%, aggregate can be selected from marble, quartz sand, granite and aluminium hydroxide one or more, the aggregate of the present embodiment selects marble and quartz sand, the size of quartz sand and marble aggregate presses the weight grating of aggregate, particle diameter 1 ~ the 4mm of quartz sand aggregate accounts for 1.5% of aggregate weigh, its screen size of the particle diameter of marble aggregate is that 20 ~ 80 objects account for 29% of aggregate weigh, its screen size of the particle diameter of marble aggregate is that 80 ~ 200 objects account for 31.5% of aggregate weigh, and its screen size of the particle diameter of marble aggregate is that 200 ~ 400 objects account for 38% of aggregate weigh.Cement is 48%, and the cement that the present embodiment adopts is ordinary Portland cement and sulphur aluminium cement, and ordinary Portland cement accounts for 40% of cement weight, and sulphur aluminium cement accounts for 60% of cement weight.Composite modifier is 1%, composite modifier is one or more of VAE class composite modifier, rubber-like composite modifier, 1 ~ 3mm glass fibre properties-correcting agent, epoxy resin properties-correcting agent or high reactivity filler, wherein, VAE class composite modifier comprises ethylene-vinyl acetate copolymer emulsion, vinyl acetate-ethylene ester-ethylene copolymer latex powder, vinyl acetate-generating vinyl carboxylate copolymer latices powder and vinylchlorid-vinyl laurate-ethylene-dien terpolymer latex powder; Rubber-like composite modifier comprises styrene-butadiene copolymer emulsion/latex powder; High reactivity filler comprises silicon ash, flyash, blast-furnace slag, kaolin; The composite modifier that the present embodiment adopts is ethylene-vinyl acetate copolymer emulsion and vinyl acetate-ethylene ester-ethylene copolymer latex powder, and described ethylene-vinyl acetate copolymer emulsion and vinyl acetate-ethylene ester-ethylene copolymer latex powder account for 50% of composite modifier weight respectively.Water reducer is 1%, water reducer is one or more of naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent or polycarboxylate dehydragent, the water reducer that the present embodiment adopts is naphthalene series high-efficiency water-reducing agent and melamine series high-efficiency water-reducing agent, and naphthalene series high-efficiency water-reducing agent and melamine series high-efficiency water-reducing agent account for 50% of water reducer weight respectively.Water is 20%.
The aggregate of the size grating of the present embodiment formula, cement, composite modifier, water reducer are put into horizontal mixer successively and carried out uniform stirring, in the material stirred, adds the water of the present embodiment formula, secondary uniform stirring is carried out to material.Above-mentionedly once to stir and the stirrer rotating speed of secondary stirring is 10 ~ 18 revs/min, churning time is 4 ~ 15 minutes, prerequisite be even to above-mentioned material stirring till.Closedown stirrer vacuumizes, and when vacuumizing, stirrer stirs material simultaneously, and the adjustment of rotational speed of stirrer is 2 ~ 5 revs/min, can reduce the space between material like this.Vacuum tightness starts material when reaching more than 0.077MPa toward mould lining material, after completing cloth, reach the environment of more than 0.077MPa in vacuum tightness under, the material of mould is suppressed, suppress mould and put at room temperature naturally wet foster solidification or wet foster solidification under being warmed up to optimum temps, the optimum temps heated up is 30 ~ 35 DEG C, stripper member is generally 7 ~ 10 days, and after demoulding, maintenance is generally 12 ~ 16 days.Finally the famine material of solidification is cut by gang saw, then the polished finish of table machine is carried out to the sheet material of well cutting namely obtain finished product of the present invention.
Embodiment 2:
Aggregate is 30%, granite selected by aggregate, granitic size presses the weight grating of aggregate, particle diameter 1 ~ the 10mm of granite aggregate accounts for 1% of aggregate weigh, its screen size of the particle diameter of granite aggregate is that 20 ~ 80 objects account for 20% of aggregate weigh, its screen size of the particle diameter of granite aggregate is that 80 ~ 200 objects account for 35% of aggregate weigh, and its screen size of the particle diameter of granite aggregate is that 200 ~ 400 objects account for 44% of aggregate weigh.Cement is 60%, and the cement that the present embodiment adopts is normal silicate white cement.Composite modifier is 1%, composite modifier is one or more of VAE class composite modifier, rubber-like composite modifier, 1 ~ 3mm glass fibre, epoxy resin properties-correcting agent or high reactivity filler, wherein, VAE class composite modifier comprises ethylene-vinyl acetate copolymer emulsion, vinyl acetate-ethylene ester-ethylene copolymer latex powder, vinyl acetate-generating vinyl carboxylate copolymer latices powder and vinylchlorid-vinyl laurate-ethylene-dien terpolymer latex powder; Rubber-like composite modifier comprises styrene-butadiene copolymer emulsion/latex powder, and high reactivity filler comprises silicon ash, flyash, blast-furnace slag, kaolin; The composite modifier that the present embodiment adopts is 1 ~ 3mm glass fibre and high reactivity filler, and 1 ~ 3mm glass fibre and high reactivity filler account for 50% of composite modifier weight respectively.Water reducer is 1%, water reducer is one or more of naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent or polycarboxylate dehydragent, the water reducer that the present embodiment adopts is melamine series high-efficiency water-reducing agent and polycarboxylate dehydragent, and melamine series high-efficiency water-reducing agent and polycarboxylate dehydragent account for 50% of water reducer weight respectively.Water is 8%.
The aggregate of the size grating of the present embodiment formula, cement, composite modifier, water reducer are put into horizontal mixer successively and carried out uniform stirring, in the material stirred, adds the water of the present embodiment formula, secondary uniform stirring is carried out to material.Above-mentionedly once to stir and the stirrer rotating speed of secondary stirring is 12 ~ 16 revs/min, churning time is 5 ~ 10 minutes, prerequisite be even to above-mentioned material stirring till.Closedown stirrer vacuumizes, and when vacuumizing, stirrer stirs material simultaneously, and the adjustment of rotational speed of stirrer is 3 ~ 4 revs/min, can reduce the space between material like this.Vacuum tightness starts material when reaching more than 0.077MPa toward mould lining material, after completing cloth, reach the environment of more than 0.077MPa in vacuum tightness under, the material of mould is suppressed, suppress mould and put at room temperature naturally wet foster solidification or wet foster solidification under being warmed up to optimum temps, the optimum temps heated up is 30 ~ 35 DEG C, stripper member is generally 7 ~ 9 days, and after demoulding, maintenance is generally 13 ~ 18 days.Finally the famine material of solidification is cut by gang saw, then the polished finish of table machine is carried out to the sheet material of well cutting namely obtain finished product of the present invention.
Embodiment 3:
Aggregate is 65%, marble selected by aggregate, the size of marble aggregate presses the weight grating of aggregate, particle diameter 1 ~ the 10mm of marble aggregate accounts for 3.5% of aggregate weigh, its screen size of the particle diameter of marble aggregate is that 20 ~ 80 objects account for 46% of aggregate weigh, its screen size of the particle diameter of marble aggregate is that 80 ~ 200 objects account for 20% of aggregate weigh, and its screen size of the particle diameter of marble aggregate is that 200 ~ 400 objects account for 30.5% of aggregate weigh.Cement is 25%, and the cement that the present embodiment adopts is ordinary Portland cement.Composite modifier is 1%, composite modifier is one or more of VAE class composite modifier, rubber-like composite modifier, 1 ~ 3mm glass fibre properties-correcting agent, epoxy resin properties-correcting agent or high reactivity filler, wherein, VAE class composite modifier comprises ethylene-vinyl acetate copolymer emulsion, vinyl acetate-ethylene ester-ethylene copolymer latex powder, vinyl acetate-generating vinyl carboxylate copolymer latices powder and vinylchlorid-vinyl laurate-ethylene-dien terpolymer latex powder; Rubber-like composite modifier comprises styrene-butadiene copolymer emulsion/latex powder, and high reactivity filler comprises silicon ash, flyash, blast-furnace slag, kaolin; The composite modifier that the present embodiment adopts is vinyl acetate-generating vinyl carboxylate copolymer latices powder and vinylchlorid-vinyl laurate-ethylene-dien terpolymer latex powder, and vinyl acetate-generating vinyl carboxylate copolymer latices powder and vinylchlorid-vinyl laurate-ethylene-dien terpolymer latex powder account for 50% of composite modifier weight respectively.Water reducer is 1%, and water reducer is one or more of naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent or polycarboxylate dehydragent, and the water reducer that the present embodiment adopts is naphthalene series high-efficiency water-reducing agent.Water is 8%.
The aggregate of the size grating of the present embodiment formula, cement, composite modifier, water reducer are put into horizontal mixer successively and carried out uniform stirring, in the material stirred, adds the water of the present embodiment formula, secondary uniform stirring is carried out to material.Above-mentionedly once to stir and the stirrer rotating speed of secondary stirring is 13 ~ 15 revs/min, churning time is 6 ~ 8 minutes, prerequisite be even to above-mentioned material stirring till.Closedown stirrer vacuumizes, and when vacuumizing, stirrer stirs material simultaneously, and the adjustment of rotational speed of stirrer is 3 revs/min, can reduce the space between material like this.Vacuum tightness starts material when reaching more than 0.077MPa toward mould lining material, after completing cloth, reach the environment of more than 0.077MPa in vacuum tightness under, the material of mould is suppressed, suppress mould and put at room temperature naturally wet foster solidification or wet foster solidification under being warmed up to optimum temps, the optimum temps heated up is 30 ~ 35 DEG C, stripper member is generally 7 ~ 8 days, and after demoulding, maintenance is generally 14 ~ 16 days.Finally the famine material of solidification is cut by gang saw, then the polished finish of table machine is carried out to the sheet material of well cutting namely obtain finished product of the present invention.
Embodiment 4:
Aggregate is 40%, quartz sand selected by aggregate, the size of quartz sand presses the weight grating of aggregate, particle diameter 1 ~ the 10mm of quartz sand aggregate accounts for 2% of aggregate weigh, its screen size of the particle diameter of quartz sand aggregate is that 20 ~ 80 objects account for 30% of aggregate weigh, its screen size of the particle diameter of quartz sand aggregate is that 80 ~ 200 objects account for 32% of aggregate weigh, and its screen size of the particle diameter of quartz sand aggregate is that 200 ~ 400 objects account for 36% of aggregate weigh.Cement is 31.5%, and the cement that the present embodiment adopts is sulphur aluminium cement.Composite modifier is 10%, composite modifier is one or more of VAE class composite modifier, rubber-like composite modifier, 1 ~ 3mm glass fibre properties-correcting agent, epoxy resin properties-correcting agent or high reactivity filler, wherein, VAE class composite modifier comprises ethylene-vinyl acetate copolymer emulsion, vinyl acetate-ethylene ester-ethylene copolymer latex powder, vinyl acetate-generating vinyl carboxylate copolymer latices powder and vinylchlorid-vinyl laurate-ethylene-dien terpolymer latex powder; Rubber-like composite modifier comprises styrene-butadiene copolymer emulsion/latex powder, and high reactivity filler comprises silicon ash, flyash, blast-furnace slag, kaolin; The composite modifier that the present embodiment adopts is epoxy resin properties-correcting agent and styrene-butadiene copolymer emulsion, and epoxy resin properties-correcting agent and styrene-butadiene copolymer emulsion account for 50% of composite modifier weight respectively.Water reducer is 5%, and water reducer is one or more of naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent or polycarboxylate dehydragent, and the water reducer that the present embodiment adopts is melamine series high-efficiency water-reducing agent.Retardant is 1.5%, and described retardant can select molasses system retardant or citric acid system retardant, and the retardant that the present embodiment adopts is molasses system retardant
.water is 12%.
The aggregate of the size grating of the present embodiment formula, cement, composite modifier, water reducer are put into horizontal mixer successively and carried out uniform stirring, in the material stirred, adds the water of the present embodiment formula, secondary uniform stirring is carried out to material.Above-mentionedly once to stir and the stirrer rotating speed of secondary stirring is 15 ~ 16 revs/min, churning time is 7 ~ 8 minutes, prerequisite be even to above-mentioned material stirring till.Closedown stirrer vacuumizes, and when vacuumizing, stirrer stirs material simultaneously, and the adjustment of rotational speed of stirrer is 4 ~ 5 revs/min, can reduce the space between material like this.Vacuum tightness starts material when reaching more than 0.077MPa toward mould lining material, after completing cloth, reach the environment of more than 0.077MPa in vacuum tightness under, the material of mould is suppressed, suppress mould and put at room temperature naturally wet foster solidification or wet foster solidification under being warmed up to optimum temps, the optimum temps heated up is 32 ~ 34 DEG C, stripper member is generally 7 ~ 9 days, and after demoulding, maintenance is generally 14 ~ 16 days.Finally the famine material of solidification is cut by gang saw, then the polished finish of table machine is carried out to the sheet material of well cutting namely obtain finished product of the present invention.
The model of above-mentioned ordinary Portland cement can select 325R, 425R or 525R.
The above is only in order to conveniently to illustrate the present invention, and in the scope not departing from the present invention's creation, the various simple covert and modification that the those skilled in the art being familiar with this technology does should belong to protection scope of the present invention.
Claims (10)
1. a high-strength composite Inorganic artificial stone, is characterized in that: described Inorganic artificial stone is made up of the component of following weight percent:
Aggregate 30 ~ 65%
Cement 25 ~ 60%
Composite modifier 1 ~ 10%
Water reducer 1 ~ 5%
Retardant 0 ~ 1.5%
Water 8 ~ 20%
The size of described aggregate presses the weight grating of aggregate, particle diameter 1 ~ the 10mm of aggregate accounts for 1 ~ 3.5% of aggregate weigh, its screen size of the particle diameter of aggregate is that 20 ~ 80 objects account for 20 ~ 46% of aggregate weigh, its screen size of the particle diameter of aggregate be greater than that 80 orders are less than or equal to that 400 objects account for aggregate weigh 50 ~ 79%.
2. high-strength composite Inorganic artificial stone according to claim 1, is characterized in that: described aggregate be selected from marble, quartz sand, granite and aluminium hydroxide one or more.
3. high-strength composite Inorganic artificial stone according to claim 1, is characterized in that: described cement is one or more of ordinary Portland cement, normal silicate white cement or sulphur aluminium cement.
4. high-strength composite Inorganic artificial stone according to claim 1, is characterized in that: described composite modifier is one or more of VAE class composite modifier, rubber-like composite modifier, 1 ~ 3mm glass fibre, epoxy resin properties-correcting agent or high reactivity filler.
5. high-strength composite Inorganic artificial stone according to claim 1, is characterized in that: described water reducer is one or more of naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent or polycarboxylate dehydragent.
6. high-strength composite Inorganic artificial stone according to claim 1, is characterized in that: described retardant is molasses system retardant or citric acid system retardant.
7. high-strength composite Inorganic artificial stone preparation technology according to claim 1, is characterized in that, comprise the steps:
A, the aggregate of size weight percentage grating, cement, composite modifier, water reducer added successively in stirrer and carry out uniform stirring;
B, add in the material of step a approrpiate wts water and carry out uniform stirring;
C, the material of step b to be vacuumized, under vacuum conditions material to be arranged in mould and to carry out vibration under vacuum conditions and suppress;
D, the mould suppressed by step c put at room temperature naturally wet foster solidification or wet foster solidification under being warmed up to optimum temps;
E, to steps d solidification famine material cuts, polishing gets product.
8. high-strength composite Inorganic artificial stone preparation technology according to claim 7, is characterized in that: the stirrer of described step a is horizontal mixer.
9. high-strength composite Inorganic artificial stone preparation technology according to claim 7, is characterized in that: be also added with retardant in the stirrer of described step a.
10. high-strength composite Inorganic artificial stone preparation technology according to claim 7, it is characterized in that: the vacuum tightness of described step c is more than 0.077MPa, being arranged in by material in mould and vibrating the operation of suppressing is complete under vacuum tightness is the environment of more than 0.077MPa.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0170611B1 (en) * | 1996-09-04 | 1999-05-01 | 황익현 | Method for manufacturing artificial marble |
| CN101007727A (en) * | 2007-01-25 | 2007-08-01 | 上海交通大学 | Cladded cement based artificial moulded stone material |
| CN101357841A (en) * | 2008-09-12 | 2009-02-04 | 青岛金炫建材有限公司 | Artificial stone formula and technique of preparing the same |
| CN101497512A (en) * | 2008-01-30 | 2009-08-05 | 谭克峰 | Preparation of polymer modified artificial marble |
| CN101913806A (en) * | 2010-07-26 | 2010-12-15 | 刘龙诚 | Cement-based artificial stone and production process thereof |
-
2013
- 2013-07-01 CN CN201310271381.2A patent/CN104276795A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0170611B1 (en) * | 1996-09-04 | 1999-05-01 | 황익현 | Method for manufacturing artificial marble |
| CN101007727A (en) * | 2007-01-25 | 2007-08-01 | 上海交通大学 | Cladded cement based artificial moulded stone material |
| CN101497512A (en) * | 2008-01-30 | 2009-08-05 | 谭克峰 | Preparation of polymer modified artificial marble |
| CN101357841A (en) * | 2008-09-12 | 2009-02-04 | 青岛金炫建材有限公司 | Artificial stone formula and technique of preparing the same |
| CN101913806A (en) * | 2010-07-26 | 2010-12-15 | 刘龙诚 | Cement-based artificial stone and production process thereof |
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| CN114477895A (en) * | 2021-12-30 | 2022-05-13 | 广东海龙建筑科技有限公司 | Inorganic artificial stone imitating natural marble texture and preparation process thereof |
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