CN103288397B - A kind of Artificial stone inorganic adhesive and preparation method thereof - Google Patents
A kind of Artificial stone inorganic adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN103288397B CN103288397B CN201310173596.0A CN201310173596A CN103288397B CN 103288397 B CN103288397 B CN 103288397B CN 201310173596 A CN201310173596 A CN 201310173596A CN 103288397 B CN103288397 B CN 103288397B
- Authority
- CN
- China
- Prior art keywords
- artificial stone
- inorganic adhesive
- whiteness
- degree
- stone inorganic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses inorganic adhesive of a kind of artificial stone and preparation method thereof.Artificial stone inorganic adhesive, composed of the following components by weight percentage: white cement 53-87%, dicalcium powder 0-30%, calcining metakaolin 10-30%, inorfil 0.2-2%, rubber powder 0.5-3%, auxiliary agent 0-1%, titanium dioxide 0.5-3%, other pigment 0-0.2%.Artificial stone inorganic adhesive of the present invention, there is the several functions such as shock resistance, wear-resisting, weatherability and good endurance, impermeabilisation and freeze thawing resistance, without any poisonous, harmful material, produce and use procedure meets environmental requirement, can be used for manufacturing artificial stone, decorated articles, sculpture, can also be used for that terrazzo, coating for internal and external wall, stone material be bonding with ceramic tile and jointing, improve service life and the range of application of each based article.<!--1-->
Description
[technical field]
The present invention relates to artificial stone, particularly relate to inorganic adhesive of a kind of artificial stone and preparation method thereof.
[background technology]
In recent years, flourish along with decorations industry, inner-outer wall stone material consumption constantly increases, civilian stone material is divided into lithotome and artificial stone, lithotome is based on granite, marble and jade, artificial stone's aggregate and adhesives are by stirring, vibrations, evacuation, compressing, and after requirement of strength to be achieved, saw blade, polishing, polishing i.e. prepared artificial stone.China more than 90% artificial stone all uses resin as adhesives at present, uses the stone material that resin-made obtains to have the features such as bright-colored, highly polished, uniform color, high intensity, but resin belongs to organic material, and weatherability is poor, it is impossible in outdoor application；And resin has penetrating odor and corrosivity with accelerator, production process does not meet environmental requirement.
In order to solve this problem, Chinese invention patent application " inorganic artificial combining stone and preparation method thereof " (January 10 2010 applying date, number of patent application: in CN201210005418.2) has melted the manufacture method of a kind of inorganic artificial combining stone, wherein, inorganic cementing agent is metakaolin, silicate base solution, adjustable solidification agent, inorganic pigment and fiber.The artificial synthesis stone of this invention not only has a dicoration matched in excellence or beauty with resin type artificial stone, and asepsis environment-protecting, with low cost；Tolerate the corrosion of most of acid-alkali salt, high temperature resistant, excellent durability, it will be apparent that preventing the whiting accumulation of salt in the surface soil phenomenon under life-time service, contamination resistance is also stronger.But this application product early strength is low, curing cycle length, wear no resistance.Due to not cement.Artificial stone pH value is low, and the easy dusting in surface, anti-carbonation properties is bad.
Chinese invention patent application " manufacture method of artificial stone " (April 28 2011 applying date, number of patent application: CN201180021777.0) disclose the production method of a kind of artificial stone, wherein, cementing material is made up of blast-furnace cinder micro-powder end, alkali-activator, Portland cement etc..This application product pluses and minuses are similar with previous patent.
Chinese invention patent application CN200810212034.1(publication date JIUYUE in 2008 12 days,) disclosing formula and the preparation technology of a kind of artificial stone, its formula consists of: according to percentage by weight cement 20-25%, Gypsum Fibrosum 5-10%, silicon ash 10-15%, lithium carbonate 0.1-0.5%, extraordinary water reducer 1-3%, waterproofing agent 1-2%, pigment 5-10%, sand 40-55%.The present invention passes through to prepare product into mould, the demoulding, maintenance, polishing cutting, post-treating and other steps, has tasteless, nontoxic, radiationless, and fire prevention, intensity height, good decorating effect, technique is simple, the features such as cost is low.But the method using a number of silicon ash, color is deeper, it is impossible to produce white and light color artificial stone.
[summary of the invention]
The technical problem to be solved in the present invention is to provide Artificial stone inorganic adhesive and the preparation method of a kind of weatherability and excellent durability, production and use link environmental protection.
The present invention to solve the problem of technology further and be to provide a kind of Artificial stone inorganic adhesive with shock resistance, impermeabilisation.
In order to solve above-mentioned technical problem, the technical solution used in the present invention is, a kind of Artificial stone inorganic adhesive, composed of the following components by weight percentage:
Above-described Artificial stone inorganic adhesive, described auxiliary agent includes one or more in water reducer, defoamer and exciting agent.
Above-described Artificial stone inorganic adhesive, described water reducer is white powder polycarboxylate water-reducer, and water-reducing rate is more than 25%.
Above-described Artificial stone inorganic adhesive, described defoamer is silicone based powdery defoamer.
Above-described Artificial stone inorganic adhesive, described exciting agent is sodium chloride or calcium chloride.
Above-described Artificial stone inorganic adhesive, described white cement strength grade is 52.5 grades, and whiteness is more than 85 degree.
Above-described Artificial stone inorganic adhesive, described dicalcium powder is agstone, and whiteness is more than 86 degree, and specific surface area is 450-600m2/ kg.The calcining heat of described calcining metakaolin is 750-850 DEG C, and aluminium sesquioxide content is 25-45% by weight, whiteness more than 83 degree, specific surface area 450-600m2/kg。
Above-described Artificial stone inorganic adhesive, described titanium dioxide whiteness is more than 90 degree, and specific surface area is more than 1000m2/kg.
Above-described Artificial stone inorganic adhesive, composed of the following components by weight percentage:
The preparation method of more than one described Artificial stone inorganic adhesive, comprises the following steps:
(1) raw material is weighed according to the percentage by weight of claim 1；
(2) by the raw material that weighs except inorfil, with batch mixer mixing 3-10 minute；
(3) batch mixer mix homogeneously is used after adding inorfil.
Artificial stone inorganic adhesive of the present invention, there is the several functions such as shock resistance, wear-resisting, weatherability and good endurance, impermeabilisation and freeze thawing resistance, without any poisonous, harmful material, produce and use procedure meets environmental requirement, can be used for manufacturing artificial stone, decorated articles, sculpture, can also be used for that terrazzo, coating for internal and external wall, stone material be bonding with ceramic tile and jointing, improve service life and the use scope of each based article.
[detailed description of the invention]
By the examples below the present invention is further elaborated:
Artificial stone inorganic adhesive is composed of the following components by weight percentage: white cement 53-87%, dicalcium powder 0-30%, calcining metakaolin 10-30%, inorfil 0.2-2%, rubber powder 0.5-3%, auxiliary agent 0-1%, titanium dioxide 0.5-3%, other pigment 0-0.2%.
The effect of each component of Artificial stone inorganic adhesive of the present invention is, white cement is primary intensity component；Dicalcium powder filling pore, reduction are shunk；Calcining metakaolin absorbs the calcium hydroxide that white cement aquation precipitates out, and improves later strength and anti-permeability performance, and solves whiting, accumulation of salt in the surface soil problem；Inorfil improves shock resistance and anti-wear performance；Rubber powder blocking pore, raising surface smoothness, anti-permeability performance and non-deformability；Water reducer reduces water consumption, improves early stage and later strength；Defoamer eliminates bubble, improves surface property；Exciting agent accelerates calcining metakaolin hydration rate, improves early strength；Titanium dioxide improves whiteness, fills micropore；Pigment adjusts color.
The production method of Artificial stone inorganic adhesive of the present invention is as follows: white cement, dicalcium powder, calcined kaolin, inorfil, rubber powder, water reducer, defoamer, exciting agent measure in proportion, enters batch mixer and mixes 5 minutes；It is subsequently adding appropriate inorfil, prepares product after mix homogeneously, with screw machine, elevator, product is delivered to product storage tank；Metering packing.
The using method of Artificial stone inorganic adhesive of the present invention is as follows: Artificial stone inorganic adhesive of the present invention produce artificial stone time, by 600-900kg/m3Add, add agstone or the silica flour 1100-1400kg/m of different fineness by artificial stone kind requirement3, add water 240-450kg/m3, stir 5-10 minute with blender；Pour the mortar stirred into mould, carry out vibrating, suppress, evacuation；Mould is delivered to appointment position, exposure plastic sheeting or wet cloth cover, the maintenance demoulding in 3-7 days；After the demoulding, raw artificial stone is by cutting, polish, polishing, and prepares artificial slabstone.
Inorganic adhesive of the present invention has the advantage that shock resistance, wear-resisting, weatherability and good endurance, impermeabilisation and the several functions such as indeformable, is suitable for the various occasion such as ground, inner-outer wall and uses；Do not use any poisonous, harmful material, produce and use procedure meets environmental requirement.
In the examples below, white cement is from Anqing, and strength grade is 52.5 grades, and whiteness is more than 85 degree.
Calcining metakaolin from Liaoning Huludao City, calcining metakaolin calcining heat be 750-850 DEG C, aluminium sesquioxide content is 25-45% by weight, whiteness more than 83 degree, specific surface area 450-600m2/ kg；
Dicalcium powder is from Shenzhen, and for agstone, whiteness is more than 86 degree, and specific surface area is 450-600m2/ kg；
Inorfil is from Zhejiang Hangzhou omeprazole inorfil, length 3-5mm；
Rubber powder is 5011 rubber powders that Germany's goldschmidt chemical corporation produces, and belongs to redispersible latex powder；
Water reducer is the Law Firm Suzhou Jiangsu not gram PC---1030P produced, and for white powder polycarboxylate water-reducer, water-reducing rate is more than 25%；
Defoamer is the silicone based powdery defoamer 118G that catalyst company of Japan produces；
Exciting agent is sodium chloride or calcium chloride (in below example is sodium chloride)
Titanium dioxide whiteness is more than 90 degree, and specific surface area is more than 1000m2/ kg.Other pigment should embody in an embodiment.
The agstone of making artificial stone material and silica flour are from Yunfu, guangdong Province.
Embodiment 1
By weight percentage, white cement 87%, calcining metakaolin 10%, inorfil 1%, rubber powder 1%, after mixing 5 minutes with conical mixer, add after titanium dioxide 1% remixes 20 minutes and prepare product.
Embodiment 2
By weight percentage, white cement 53%, metakaolin 30%, dicalcium powder 10%, inorfil 1%, rubber powder 2%, exciting agent 0.5%, water reducer 0.3%, defoamer 0.1%, after mixing 5 minutes with conical mixer, add titanium dioxide 3%, pigment 0.1% prepares product after remixing 20 minutes.
Embodiment 3
By weight percentage, white cement 58.24%, metakaolin 10%, dicalcium powder 30%, inorfil 0.2%, rubber powder 0.5%, exciting agent 0.2%, water reducer 0.2%, defoamer 0.06%, after mixing 5 minutes with conical mixer, add titanium dioxide 0.5%, pigment 0.1% prepares product after remixing 20 minutes.
One. strength character is tested:
In order to compare the artificial stone intensity of inorganic adhesive different amounts, stone powder different amounts, test determination 3,7,28 days resistance to compressions and rupture strengths.GB/T17671-1999 " Test method for strength of hydraulic cement mortar " is pressed in test.
Wherein, comparative example 1 adopts CN201210005418.2 embodiment 1, comparative example 2 to adopt CN201180021777.0 embodiment 1, comparative example 3 to adopt CN200810212034.1 embodiment 1, and water and inorganic adhesive ratio are 0.5.Result of the test is in Table 1.
Table 1: artificial stone's strength character test chart
From experimental result it will be seen that the intensity of comparative example 1-3 is relatively low, especially early strength is on the low side, and curing time is long, a large amount of occupied grounds and mould；Embodiment of the present invention 1-3 is respectively provided with significantly high early stage and later strength, and maintenance is short with the demoulding time.
Two. anti-wear performance is tested:
Have detected dissimilar, different amounts inorganic adhesive and different cultivars and the artificial stone anti-wear performance of fineness stone powder preparation by JC/T421-2004 " cement mortar abrasion test method ", result is in Table 2:
Table 2: artificial stone's anti-wear performance test chart
Three. anti-permeability performance and freezing and thawing performance test:
Checking inorganic adhesive anti-permeability performance of the present invention and freeze thawing resistance cycle performance by GB/T50082-2009 " Standard for test methods of longterm performance and durability of ordinary concrete standard ", result of the test is in Table 3, table 4:
Table 3: artificial stone's anti-permeability performance test chart
Table 4: artificial stone's freeze thawing resistance cycle performance test chart
Embodiments of the invention have the advantages that
1. product of the present invention has shock resistance, wear-resisting, weatherability and good endurance, impermeabilisation and the several functions such as indeformable, with the artificial stone of its production be suitable for the various occasion such as ground, inner-outer wall, various weather uses.
2. product of the present invention does not use any poisonous, harmful material, produces and use procedure cleaning, meets environmental requirement.
3. product of the present invention is used for producing artificial stone, and material cost reduces 20-30 unit/m than resin type artificial stone2, there are good economic results in society.
Claims (6)
1. an Artificial stone inorganic adhesive, it is characterised in that composed of the following components by weight percentage:
Described exciting agent is sodium chloride or calcium chloride；Described dicalcium powder is agstone, and whiteness is more than 86 degree, and specific surface area is 450-600m2/ kg；The calcining heat of described calcining metakaolin is 750-850 DEG C, and aluminium sesquioxide content is 25-45% by weight, whiteness more than 83 degree, specific surface area 450-600m2/kg。
2. Artificial stone inorganic adhesive according to claim 1, it is characterised in that described water reducer is white powder polycarboxylate water-reducer, and water-reducing rate is more than 25%.
3. Artificial stone inorganic adhesive according to claim 1, it is characterised in that described defoamer is silicone based powdery defoamer.
4. Artificial stone inorganic adhesive according to claim 1, it is characterised in that described white cement strength grade is 52.5 grades, whiteness is more than 85 degree.
5. Artificial stone inorganic adhesive according to claim 1, it is characterised in that described titanium dioxide whiteness is more than 90 degree, and specific surface area is more than 1000m2/kg。
6. the preparation method of Artificial stone inorganic adhesive described in a claim 1, it is characterised in that comprise the following steps:
(1) raw material is weighed according to the percentage by weight of claim 1；
(2) by the raw material that weighs except inorfil, with batch mixer mixing 3-10 minute；
(3) batch mixer mix homogeneously is used after adding inorfil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310173596.0A CN103288397B (en) | 2013-05-11 | 2013-05-11 | A kind of Artificial stone inorganic adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310173596.0A CN103288397B (en) | 2013-05-11 | 2013-05-11 | A kind of Artificial stone inorganic adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103288397A CN103288397A (en) | 2013-09-11 |
| CN103288397B true CN103288397B (en) | 2016-06-29 |
Family
ID=49090006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310173596.0A Expired - Fee Related CN103288397B (en) | 2013-05-11 | 2013-05-11 | A kind of Artificial stone inorganic adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103288397B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106045379A (en) * | 2016-06-08 | 2016-10-26 | 石磊 | Manufacturing method of artificial stone |
| CN106396563A (en) * | 2016-08-26 | 2017-02-15 | 派丽(上海)管理有限公司 | Artificial stone adhesive |
| CN107522446A (en) * | 2017-09-29 | 2017-12-29 | 江苏闽江矿业有限公司 | A kind of modified artificial stone |
| CN109056329A (en) * | 2018-06-26 | 2018-12-21 | 福建荣宏光电科技有限公司 | A kind of architectural engineering impregnated carbon fiber glue caking agent and its preparation process |
| CN109369106A (en) * | 2018-11-27 | 2019-02-22 | 贵州中景石雕有限公司 | A kind of stone material adhesive and preparation method thereof |
| CN111574144B (en) * | 2020-04-15 | 2022-05-13 | 华润水泥技术研发有限公司 | Formula and preparation method of high-toughness cement-based artificial stone |
| CN111574147B (en) * | 2020-04-21 | 2022-02-18 | 深圳市润丰新材料科技有限公司 | Formula and preparation method of snowflake white inorganic artificial stone raw material |
| CN115215602A (en) * | 2021-04-14 | 2022-10-21 | 广东博智林机器人有限公司 | Stone dry powder and method for preparing artificial stone by using same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100873051B1 (en) * | 2008-05-06 | 2008-12-09 | (주)삼우종합건축사사무소 | Finish composition of inorganic polymer resin mortar with eco-friendly and high-functionality and construction method using them |
| CN101643346A (en) * | 2009-09-08 | 2010-02-10 | 邢献军 | Novel jointing agent |
| CN102206066A (en) * | 2011-04-08 | 2011-10-05 | 厦门力嘉诚防水工程有限公司 | Tile glue |
| CN102924015A (en) * | 2012-11-16 | 2013-02-13 | 深圳广田高科新材料有限公司 | Landscape stone binding mortar and preparation and use methods |
-
2013
- 2013-05-11 CN CN201310173596.0A patent/CN103288397B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100873051B1 (en) * | 2008-05-06 | 2008-12-09 | (주)삼우종합건축사사무소 | Finish composition of inorganic polymer resin mortar with eco-friendly and high-functionality and construction method using them |
| CN101643346A (en) * | 2009-09-08 | 2010-02-10 | 邢献军 | Novel jointing agent |
| CN102206066A (en) * | 2011-04-08 | 2011-10-05 | 厦门力嘉诚防水工程有限公司 | Tile glue |
| CN102924015A (en) * | 2012-11-16 | 2013-02-13 | 深圳广田高科新材料有限公司 | Landscape stone binding mortar and preparation and use methods |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103288397A (en) | 2013-09-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103288397B (en) | A kind of Artificial stone inorganic adhesive and preparation method thereof | |
| CN104254504B (en) | The geopolymer formulation and method of dimensionally stable | |
| RU2470884C2 (en) | Light cementing compositions and construction products and methods for production thereof | |
| CN105218024A (en) | A kind of ceramic tile bond | |
| CN104045307B (en) | A kind of facing mortar and preparation method thereof | |
| CN100450963C (en) | Cladded cement based artificial moulded stone material | |
| CN101544856B (en) | External wall putty | |
| CN104276795A (en) | High-strength composite inorganic artificial stone and preparing method thereof | |
| CN104245621A (en) | Print control device capable of generating image data using plurality of error matrices | |
| CN109809779A (en) | Surface layer mortar, grinding stone, plate and preparation method thereof | |
| CN106517870A (en) | Efficient-spraying type dry-mixing and wet-mixing mortar plasticizer composition as well as preparation method and application method thereof | |
| CN106673553B (en) | A kind of low cost ceramic tile adhesive and preparation method thereof | |
| CN102731041A (en) | Surface modifier for vitreous micro-bead insulation aggregate and modified vitreous micro-bead insulation aggregate | |
| CN102503345A (en) | Novel inorganic artificial quartzite and preparation method thereof | |
| CN110922149B (en) | High-toughness high-strength gypsum product and preparation method thereof | |
| CN109354462A (en) | recycled concrete | |
| CN106673577A (en) | Gypsum-based ceramic tile binder and preparation method thereof | |
| CN110183165A (en) | The concrete and its preparation process of fly ash base geopolymer concrete and normal concrete knot | |
| CN109809753A (en) | Corrosion-resistant inorganic artificial stone of cracking resistance and its preparation method and application | |
| WO2020206650A1 (en) | Cementitious composition with fast development of tensile adhesion strength | |
| CN107935518B (en) | Environment-friendly high-content steel slag self-leveling mortar and preparation method thereof | |
| JP2021181402A (en) | System and method for preparing and applying non-portland cement-based material | |
| CN106277979A (en) | A kind of high-intensity inorganic quartzite slate and preparation thereof and application | |
| CN104609807B (en) | A kind of modified form Venice plaster and application | |
| CN107500674A (en) | A kind of environment-friendly type decoration cement |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210106 Address after: No. 320, Danping Road, Pinghu street, Longgang District, Shenzhen, Guangdong 518111 Patentee after: Shenzhen Deyi New Material Technology Co.,Ltd. Address before: 518000 room 313, 3rd floor, building FL3, lianhuabei high rise community, Futian District, Shenzhen City, Guangdong Province Patentee before: SHENZHEN ROCK BUILDING MATERIALS TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160629 Termination date: 20210511 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |