CN106590402A - 一种防水球阀 - Google Patents
一种防水球阀 Download PDFInfo
- Publication number
- CN106590402A CN106590402A CN201611161688.7A CN201611161688A CN106590402A CN 106590402 A CN106590402 A CN 106590402A CN 201611161688 A CN201611161688 A CN 201611161688A CN 106590402 A CN106590402 A CN 106590402A
- Authority
- CN
- China
- Prior art keywords
- parts
- modified
- silicone
- includes following
- mass fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
- C08G18/348—Hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4845—Polyethers containing oxyethylene units and other oxyalkylene units containing oxypropylene or higher oxyalkylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/61—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6541—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/34
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/6692—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/34
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
- C08G18/673—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing two or more acrylate or alkylacrylate ester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Abstract
本发明公开了一种球阀,球阀的内外表面涂覆一层防水层,防水层按质量份数计包括以下组分:硅氧烷改性的UV固化水性聚氨酯乳液:31‑33份、玻璃鳞片:5‑7份、水合硅酸镁:2‑4份、乙二醇丁醚:1‑3份、丙烯酸异辛酯:7‑9份、烯丙基磺酸钠:1‑3份、硅溶胶:5.1‑5.3份、纳米二氧化钛:3‑5份、钠基膨润土:1‑3份;本发明的防水球阀具有良好的防水效果,使用寿命长。
Description
技术领域
本发明涉及一种球阀,具体涉及一种防水球阀。
背景技术
仓储货架是存储设备,是基于包装、运输、装卸、分拣、信息管理是物流的六大基本功能。随着2014仓储货架行业的不断发展,越来越多的行业和企业运用到了仓储货架,越来越多的企业进入了仓储行业。服务于社会各界朋友 。而货架是仓储的主要设施之一,可以说,货架是现代工业仓库、物流中心、配送中心必不可少的组成部分。
发明内容
本发明所要解决的技术问题是,针对以上现有技术存在的缺点,提出一种防水球阀,该球阀具有良好的防水效果,使用寿命长。
本发明解决以上技术问题的技术方案是:
一种防水球阀,球阀的内外表面涂覆一层防水层,防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:31-33份、玻璃鳞片:5-7份、水合硅酸镁:2-4份、乙二醇丁醚:1-3份、丙烯酸异辛酯:7-9份、烯丙基磺酸钠:1-3份、硅溶胶:5.1-5.3份、纳米二氧化钛:3-5份、钠基膨润土:1-3份;
硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:10-15份,聚醚硅氧烷二元醇:10-15份,聚四氢呋喃二醇:5-10份,二羟基丙酸:5-8份,1,4-丁二醇:5-10份,季戊四醇三丙烯酸酯:15-20份,三乙胺:2-5份。
本发明进一步限定的技术方案为:
前述防水球阀中,防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:31份、玻璃鳞片:5份、水合硅酸镁:2份、乙二醇丁醚:1份、丙烯酸异辛酯:7份、烯丙基磺酸钠:1份、硅溶胶:5.1份、纳米二氧化钛:3份、钠基膨润土:1份;
硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:10份,聚醚硅氧烷二元醇:10份,聚四氢呋喃二醇:5份,二羟基丙酸:5份,1,4-丁二醇:5份,季戊四醇三丙烯酸酯:15份,三乙胺:2份。
前述防水球阀中,防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:33份、玻璃鳞片:7份、水合硅酸镁:4份、乙二醇丁醚:3份、丙烯酸异辛酯:9份、烯丙基磺酸钠:3份、硅溶胶:5.3份、纳米二氧化钛:5份、钠基膨润土:3份;
硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:15份,聚醚硅氧烷二元醇:15份,聚四氢呋喃二醇:10份,二羟基丙酸:8份,1,4-丁二醇:10份,季戊四醇三丙烯酸酯:20份,三乙胺:5份。
前述防水球阀中,防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:32份、玻璃鳞片:6份、水合硅酸镁:3份、乙二醇丁醚:2份、丙烯酸异辛酯:8份、烯丙基磺酸钠:2份、硅溶胶:5.2份、纳米二氧化钛:4份、钠基膨润土:2份;
硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:12份,聚醚硅氧烷二元醇:13份,聚四氢呋喃二醇:8份,二羟基丙酸:6份,1,4-丁二醇:8份,季戊四醇三丙烯酸酯:18份,三乙胺:4份。
前述防水球阀中,硅氧烷改性的UV固化水性聚氨酯乳液制备方法为:
在装有搅拌器、温度计和冷凝管的烧瓶中,加入聚四氢呋喃醚二醇、聚二甲基硅烷、二羟甲基丙酸和异佛尔酮二异氰酸酯,在氮气保护下,缓慢升温到90℃,反应0.5h,然后将体系的温度降到40℃,加入1,4-丁二醇和适量的丙酮,然后缓慢升高温度到80℃,反应1h,再将体系的温度降到40℃以后,加入季戊四醇三丙烯酸酯和适量丙酮,最后将体系温度降到室温,加入三乙胺,加入水,在高速剪切搅拌乳化,搅拌速度为800-1000r/min,最后减压蒸馏除去溶剂丙酮,制的固体含量为35-45%、PH值为7-8的均匀稳定的硅烷改性UV固化水性聚氨酯乳液。
本发明的有益效果是:
本发明防水层具有一定的吸水性,保水性,吸放水性能强,调湿效果好,可用于调节室内的相对湿度,且耐洗刷性能较高。本发明中采用了硅氧烷改性的UV固化水性聚氨酯乳液,与未改性的防腐涂料相比,硅氧烷改性的UV固化水性涂料具有良好的耐水性和耐溶剂性,优异的比表面性能,同时保留了优良的手感。
具体实施方式
实施例1
本实施例提供一种防水球阀,球阀的内外表面涂覆一层防水层,防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:31份、玻璃鳞片:5份、水合硅酸镁:2份、乙二醇丁醚:1份、丙烯酸异辛酯:7份、烯丙基磺酸钠:1份、硅溶胶:5.1份、纳米二氧化钛:3份、钠基膨润土:1份;
硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:10份,聚醚硅氧烷二元醇:10份,聚四氢呋喃二醇:5份,二羟基丙酸:5份,1,4-丁二醇:5份,季戊四醇三丙烯酸酯:15份,三乙胺:2份。
前述防水球阀中,硅氧烷改性的UV固化水性聚氨酯乳液制备方法为:
在装有搅拌器、温度计和冷凝管的烧瓶中,加入聚四氢呋喃醚二醇、聚二甲基硅烷、二羟甲基丙酸和异佛尔酮二异氰酸酯,在氮气保护下,缓慢升温到90℃,反应0.5h,然后将体系的温度降到40℃,加入1,4-丁二醇和适量的丙酮,然后缓慢升高温度到80℃,反应1h,再将体系的温度降到40℃以后,加入季戊四醇三丙烯酸酯和适量丙酮,最后将体系温度降到室温,加入三乙胺,加入水,在高速剪切搅拌乳化,搅拌速度为800r/min,最后减压蒸馏除去溶剂丙酮,制的固体含量为35%、PH值为7的均匀稳定的硅烷改性UV固化水性聚氨酯乳液。
实施例2
本实施例提供一种防水球阀,球阀的内外表面涂覆一层防水层,防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:33份、玻璃鳞片:7份、水合硅酸镁:4份、乙二醇丁醚:3份、丙烯酸异辛酯:9份、烯丙基磺酸钠:3份、硅溶胶:5.3份、纳米二氧化钛:5份、钠基膨润土:3份;
硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:15份,聚醚硅氧烷二元醇:15份,聚四氢呋喃二醇:10份,二羟基丙酸:8份,1,4-丁二醇:10份,季戊四醇三丙烯酸酯:20份,三乙胺:5份。
前述防水球阀中,硅氧烷改性的UV固化水性聚氨酯乳液制备方法为:
在装有搅拌器、温度计和冷凝管的烧瓶中,加入聚四氢呋喃醚二醇、聚二甲基硅烷、二羟甲基丙酸和异佛尔酮二异氰酸酯,在氮气保护下,缓慢升温到90℃,反应0.5h,然后将体系的温度降到40℃,加入1,4-丁二醇和适量的丙酮,然后缓慢升高温度到80℃,反应1h,再将体系的温度降到40℃以后,加入季戊四醇三丙烯酸酯和适量丙酮,最后将体系温度降到室温,加入三乙胺,加入水,在高速剪切搅拌乳化,搅拌速度为1000r/min,最后减压蒸馏除去溶剂丙酮,制的固体含量为45%、PH值为8的均匀稳定的硅烷改性UV固化水性聚氨酯乳液。
实施例3
本实施例提供一种防水球阀,球阀的内外表面涂覆一层防水层,防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:32份、玻璃鳞片:6份、水合硅酸镁:3份、乙二醇丁醚:2份、丙烯酸异辛酯:8份、烯丙基磺酸钠:2份、硅溶胶:5.2份、纳米二氧化钛:4份、钠基膨润土:2份;
硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:12份,聚醚硅氧烷二元醇:13份,聚四氢呋喃二醇:8份,二羟基丙酸:6份,1,4-丁二醇:8份,季戊四醇三丙烯酸酯:18份,三乙胺:4份。
前述防水球阀中,硅氧烷改性的UV固化水性聚氨酯乳液制备方法为:
在装有搅拌器、温度计和冷凝管的烧瓶中,加入聚四氢呋喃醚二醇、聚二甲基硅烷、二羟甲基丙酸和异佛尔酮二异氰酸酯,在氮气保护下,缓慢升温到90℃,反应0.5h,然后将体系的温度降到40℃,加入1,4-丁二醇和适量的丙酮,然后缓慢升高温度到80℃,反应1h,再将体系的温度降到40℃以后,加入季戊四醇三丙烯酸酯和适量丙酮,最后将体系温度降到室温,加入三乙胺,加入水,在高速剪切搅拌乳化,搅拌速度为900r/min,最后减压蒸馏除去溶剂丙酮,制的固体含量为39%、PH值为8的均匀稳定的硅烷改性UV固化水性聚氨酯乳液。
除上述实施例外,本发明还可以有其他实施方式。凡采用等同替换或等效变换形成的技术方案,均落在本发明要求的保护范围。
Claims (5)
1.一种防水球阀,其特征在于:球阀的内外表面涂覆一层防水层,所述的防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:31-33份、玻璃鳞片:5-7份、水合硅酸镁:2-4份、乙二醇丁醚:1-3份、丙烯酸异辛酯:7-9份、烯丙基磺酸钠:1-3份、硅溶胶:5.1-5.3份、纳米二氧化钛:3-5份、钠基膨润土:1-3份;
所述硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:10-15份,聚醚硅氧烷二元醇:10-15份,聚四氢呋喃二醇:5-10份,二羟基丙酸:5-8份,1,4-丁二醇:5-10份,季戊四醇三丙烯酸酯:15-20份,三乙胺:2-5份。
2.根据权利要求1所述的防水球阀,其特征在于:所述的防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:31份、玻璃鳞片:5份、水合硅酸镁:2份、乙二醇丁醚:1份、丙烯酸异辛酯:7份、烯丙基磺酸钠:1份、硅溶胶:5.1份、纳米二氧化钛:3份、钠基膨润土:1份;
所述硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:10份,聚醚硅氧烷二元醇:10份,聚四氢呋喃二醇:5份,二羟基丙酸:5份,1,4-丁二醇:5份,季戊四醇三丙烯酸酯:15份,三乙胺:2份。
3.根据权利要求1所述的防水球阀,其特征在于:所述的防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:33份、玻璃鳞片:7份、水合硅酸镁:4份、乙二醇丁醚:3份、丙烯酸异辛酯:9份、烯丙基磺酸钠:3份、硅溶胶:5.3份、纳米二氧化钛:5份、钠基膨润土:3份;
所述硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:15份,聚醚硅氧烷二元醇:15份,聚四氢呋喃二醇:10份,二羟基丙酸:8份,1,4-丁二醇:10份,季戊四醇三丙烯酸酯:20份,三乙胺:5份。
4.根据权利要求1所述的防水球阀,其特征在于:所述的防水层按质量份数计包括以下组分:
硅氧烷改性的UV固化水性聚氨酯乳液:32份、玻璃鳞片:6份、水合硅酸镁:3份、乙二醇丁醚:2份、丙烯酸异辛酯:8份、烯丙基磺酸钠:2份、硅溶胶:5.2份、纳米二氧化钛:4份、钠基膨润土:2份;
所述硅氧烷改性的UV固化水性聚氨酯乳液按质量份数计包括以下组分:异氟尔酮二异氰酸酯:12份,聚醚硅氧烷二元醇:13份,聚四氢呋喃二醇:8份,二羟基丙酸:6份,1,4-丁二醇:8份,季戊四醇三丙烯酸酯:18份,三乙胺:4份。
5.根据权利要求1所述的防水球阀,其特征在于:所述的硅氧烷改性的UV固化水性聚氨酯乳液制备方法为:
在装有搅拌器、温度计和冷凝管的烧瓶中,加入聚四氢呋喃醚二醇、聚二甲基硅烷、二羟甲基丙酸和异佛尔酮二异氰酸酯,在氮气保护下,缓慢升温到90℃,反应0.5h,然后将体系的温度降到40℃,加入1,4-丁二醇和适量的丙酮,然后缓慢升高温度到80℃,反应1h,再将体系的温度降到40℃以后,加入季戊四醇三丙烯酸酯和适量丙酮,最后将体系温度降到室温,加入三乙胺,加入水,在高速剪切搅拌乳化,搅拌速度为800-1000r/min,最后减压蒸馏除去溶剂丙酮,制的固体含量为35-45%、PH值为7-8的均匀稳定的硅烷改性UV固化水性聚氨酯乳液。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611161688.7A CN106590402A (zh) | 2016-12-15 | 2016-12-15 | 一种防水球阀 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611161688.7A CN106590402A (zh) | 2016-12-15 | 2016-12-15 | 一种防水球阀 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106590402A true CN106590402A (zh) | 2017-04-26 |
Family
ID=58802767
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611161688.7A Pending CN106590402A (zh) | 2016-12-15 | 2016-12-15 | 一种防水球阀 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106590402A (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107603460A (zh) * | 2017-09-29 | 2018-01-19 | 五邑大学 | 一种改性的uv固化水性聚氨酯丙烯酸酯涂料及其制备方法 |
CN109353876A (zh) * | 2018-10-29 | 2019-02-19 | 扬中市华龙橡塑电器有限公司 | 一种易撕测量胶带 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104263230A (zh) * | 2014-09-18 | 2015-01-07 | 江苏海晟涂料有限公司 | 一种水性塑料涂料及其制备方法 |
CN205401825U (zh) * | 2016-03-03 | 2016-07-27 | 上海阳一阀门有限公司 | 一种四通球阀 |
-
2016
- 2016-12-15 CN CN201611161688.7A patent/CN106590402A/zh active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104263230A (zh) * | 2014-09-18 | 2015-01-07 | 江苏海晟涂料有限公司 | 一种水性塑料涂料及其制备方法 |
CN205401825U (zh) * | 2016-03-03 | 2016-07-27 | 上海阳一阀门有限公司 | 一种四通球阀 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107603460A (zh) * | 2017-09-29 | 2018-01-19 | 五邑大学 | 一种改性的uv固化水性聚氨酯丙烯酸酯涂料及其制备方法 |
CN109353876A (zh) * | 2018-10-29 | 2019-02-19 | 扬中市华龙橡塑电器有限公司 | 一种易撕测量胶带 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103555192B (zh) | 一种有机硅改性的水性uv涂料及其制备方法 | |
CN105086916B (zh) | 一种高透光uv‑湿气双固化胶黏剂 | |
CN106854432B (zh) | 一种辐射固化水性涂料树脂及其制备方法 | |
RU2520454C2 (ru) | Отверждающиеся в условиях окружающей среды покрытия на водной основе для поверхностей, допускающих запись и стирание | |
KR101565940B1 (ko) | 금속 밴드를 코팅하는 방법 | |
CN107138375A (zh) | 一种木制品油漆施工工艺 | |
CN109486384A (zh) | 一种聚脲型聚天门冬氨酸酯涂料原料组合物、源自其的涂料及其制备方法和应用 | |
CN106590402A (zh) | 一种防水球阀 | |
CN107298932A (zh) | 涂料组合物和涂膜形成方法 | |
AU2011351531A1 (en) | Radiation curable coating compositions for metal | |
CN108192490B (zh) | 一种水性复合树脂组合物、水性塑胶漆及其制备方法 | |
CN103194124A (zh) | 一种三组份全环保水性木器漆 | |
CN101412887A (zh) | 一种地板漆 | |
CN103173109A (zh) | 用于木制品涂装的高固体、抗划伤不饱和聚酯哑光清面漆 | |
CN107033761A (zh) | 一种水性无氟防指纹防污聚合物复合涂层及其使用方法 | |
JP2016113610A (ja) | 1回塗装用ソフトフィール塗料組成物 | |
CN100436560C (zh) | 紫外光固化涂料及其制备方法 | |
CN105461888A (zh) | 氨基甲酸酯(甲基)丙烯酸酯化合物和含有该化合物的紫外线固化型树脂组合物 | |
CN102167798B (zh) | 一种水性聚氨酯固化剂和水性聚氨酯分散体 | |
JP4451390B2 (ja) | 低臭気性溶剤型塗料組成物 | |
JPH10298493A (ja) | 超耐候性塗料組成物 | |
CN201793176U (zh) | 涂覆有腐蚀保护系统的集装箱或钢结构 | |
KR101904176B1 (ko) | 수분 경화성 코팅제의 저습형 경화 | |
CN105949954B (zh) | 一种水性赤泥防锈防腐漆及其制备方法 | |
RU2703131C1 (ru) | Отверждаемые пленкообразующие композиции с увеличенным временем перекрытия |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170426 |
|
RJ01 | Rejection of invention patent application after publication |