CN106560492A - Antibacterial coating material additive and preparation method thereof - Google Patents
Antibacterial coating material additive and preparation method thereof Download PDFInfo
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- CN106560492A CN106560492A CN201510801399.8A CN201510801399A CN106560492A CN 106560492 A CN106560492 A CN 106560492A CN 201510801399 A CN201510801399 A CN 201510801399A CN 106560492 A CN106560492 A CN 106560492A
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Abstract
The present invention discloses an antibacterial coating material additive and a preparation method thereof. The coating material additive comprises the following raw materials by weight: 33-45 parts of maifanite, 20-28 parts of tourmaline, 5-10 parts of silver ion, 1-5 parts of polyurethane, 5-10 parts of sodium sulfonate diethyl succinate, 1-5 parts of diphenyl dihydroxy silane, 1-3 parts of epoxy sodium carboxymethylcellulose, 10-17 parts of titanium dioxide, and 40-50 parts of water. The preparation method comprises: mixing the raw materials excluding silver ions, carrying out ball milling, adding water to the powder obtained after the ball milling, heating to a temperature of 45 DEG C, carrying out sealed stirring, adding the silver ions, continuously carrying out sealed stirring, and cooling to a room temperature to obtain the product. According to the present invention, after the antibacterial coating material additive is added to an aqueous coating material, the obtained aqueous coating material has advantages of good water resistance, high hiding power and scrub resistance, and has effects of oxygen ion releasing and sterilizing; and the antibacterial coating material additive further can be used in the ceramic tile field, and further has effects of oxygen ion releasing, sterilizing and environmental pollution reducing, wherein the performance of the ceramic tile can be improved, the concave-convex texture of the ceramic tile is clear, the three-dimensional effect of the ceramic tile is strong, the ceramic tile body is effectively protected, and the gloss is enhanced.
Description
Technical field
The present invention relates to paint field, specifically a kind of degerming coating additive and preparation method thereof.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in be protected or decorated body surface; and typically based on resin or oil or emulsion, can add or without pigment, filler with the continuous film of coated article formation firm attachment; addition corresponding additive, the thick liquid being formulated with organic solvent or water.Chinese coating circle is more authoritative《Coating process》What one book was defined as：" coating is a kind of material, and this material can be coated in object surface, be formed and adhered to firmly, with some strength, continuous solid film with different construction technologies.The film common name film for so being formed, also known as paint film or coating." wherein, water paint, only with a small amount of hypotoxicity alcohol ethers organic solvent, safety and environmental protection, economizes on resources using water as decentralized medium, the danger that fire occurs when eliminating construction advantageously reduces atmosphere pollution.Water paint is very good to material surface adaptability, equally can construct in wet environment.But the production cost of existing water paint is higher, the organic volatile residence time is long, and wherein free state formaldehyde, TDI poison big to body, particularly disadvantageous in youngsters and children healthy development, can cause environmental pollution.
The content of the invention
It is an object of the invention to provide a kind of good resistance to water, release oxonium ion, degerming coating additive and preparation method thereof, to solve the problems, such as above-mentioned background technology in propose.
For achieving the above object, the present invention provides following technical scheme：
A kind of degerming coating additive, includes according to the raw material of weight portion：
Medical stone 33-45 parts
Tourmaline 20-28 parts
Silver ion 5-10 parts
Polyurethane 1-5 parts
Sodium sulfonate diethyl succinate 5-10 parts
Diphenylsilanediol 1-5 parts
Epoxy sodium carboxymethylcellulose 1-3 parts
Titanium dioxide 10-17 parts
Water 40-50 parts.
As further scheme of the invention：The degerming coating additive, includes according to the raw material of weight portion：
Medical stone 38-42 parts
Tourmaline 23-26 parts
Silver ion 7-9 parts
Polyurethane 2-4 parts
Sodium sulfonate diethyl succinate 7-9 parts
Diphenylsilanediol 2-4 parts
Epoxy sodium carboxymethylcellulose 1-2 parts
Titanium dioxide 12-15 parts
Water 43-47 parts.
As further scheme of the invention：The degerming coating additive, includes according to the raw material of weight portion：
40 parts of medical stone
24 parts of Tourmaline
8 parts of silver ion
3 parts of polyurethane
8 parts of sodium sulfonate diethyl succinate
3 parts of Diphenylsilanediol
2 parts of epoxy sodium carboxymethylcellulose
13 parts of titanium dioxide
45 parts of water.
The preparation method of the degerming coating additive, after medical stone, Tourmaline, polyurethane, diethyl succinate sodium sulfonate, Diphenylsilanediol, sodium carboxymethylcellulose, titanium dioxide mixing, ball milling 60-70 minutes, then in the powder after ball milling water is added again, it is warming up to 45 DEG C of sealing stirring 50-60 minutes, silver ion is added, continues to seal stirring 50-60 minutes, be down to room temperature and obtain final product.
Compared with prior art, the invention has the beneficial effects as follows：
Inventive formulation is simple, preparation process is extremely easy, and being added in water paint makes water paint have good resistance to water, high covering power and abrasion resistance, while after testing it also has functions that to discharge oxonium ion, sterilization, environmental quality is improved, is not endangered healthy.Ceramic tile field is present invention may be equally applicable to, in being added to the glazing type material of ceramic tile, after entering klining system, not only improves the performance of ceramic tile, Z-Correct bump mapping Z-correct is clear, and third dimension is strong, is effectively protected ceramic tile body, enhances glossiness；But also have functions that to discharge oxonium ion, sterilization, environmental pollution is reduced, with high social benefit and the value of environmental protection.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made belongs to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of degerming coating additive includes according to the raw material of weight portion：33 parts of medical stone, 20 parts of Tourmaline, 5 parts of silver ion, 1 part of polyurethane, 5 parts of sodium sulfonate diethyl succinate, 1 part of Diphenylsilanediol, 1 part of epoxy sodium carboxymethylcellulose, 10 parts of titanium dioxide, 40 parts of water.After medical stone, Tourmaline, polyurethane, diethyl succinate sodium sulfonate, Diphenylsilanediol, sodium carboxymethylcellulose, titanium dioxide mixing, ball milling 60 minutes, then in the powder after ball milling water is added again, it is warming up to 45 DEG C of sealings to stir 50 minutes, add silver ion, continue to seal stirring 50 minutes, be down to room temperature and obtain final product.
Embodiment 2
In the embodiment of the present invention, a kind of degerming coating additive includes according to the raw material of weight portion：45 parts of medical stone, 28 parts of Tourmaline, 10 parts of silver ion, 5 parts of polyurethane, 10 parts of sodium sulfonate diethyl succinate, 5 parts of Diphenylsilanediol, 3 parts of epoxy sodium carboxymethylcellulose, 17 parts of titanium dioxide, 50 parts of water.After medical stone, Tourmaline, polyurethane, diethyl succinate sodium sulfonate, Diphenylsilanediol, sodium carboxymethylcellulose, titanium dioxide mixing, ball milling 70 minutes, then in the powder after ball milling water is added again, it is warming up to 45 DEG C of sealings to stir 60 minutes, add silver ion, continue to seal stirring 60 minutes, be down to room temperature and obtain final product.
Embodiment 3
In the embodiment of the present invention, a kind of degerming coating additive includes according to the raw material of weight portion：38 parts of medical stone, 23 parts of Tourmaline, 7 parts of silver ion, 2 parts of polyurethane, 7 parts of sodium sulfonate diethyl succinate, 2 parts of Diphenylsilanediol, 1 part of epoxy sodium carboxymethylcellulose, 12 parts of titanium dioxide, 43 parts of water.After medical stone, Tourmaline, polyurethane, diethyl succinate sodium sulfonate, Diphenylsilanediol, sodium carboxymethylcellulose, titanium dioxide mixing, ball milling 62 minutes, then in the powder after ball milling water is added again, it is warming up to 45 DEG C of sealings to stir 52 minutes, add silver ion, continue to seal stirring 52 minutes, be down to room temperature and obtain final product.
Embodiment 4
In the embodiment of the present invention, a kind of degerming coating additive includes according to the raw material of weight portion：42 parts of medical stone, 26 parts of Tourmaline, 9 parts of silver ion, 4 parts of polyurethane, 9 parts of sodium sulfonate diethyl succinate, 4 parts of Diphenylsilanediol, 2 parts of epoxy sodium carboxymethylcellulose, 15 parts of titanium dioxide, 47 parts of water.
After medical stone, Tourmaline, polyurethane, diethyl succinate sodium sulfonate, Diphenylsilanediol, sodium carboxymethylcellulose, titanium dioxide mixing, ball milling 67 minutes, then in the powder after ball milling water is added again, it is warming up to 45 DEG C of sealings to stir 57 minutes, add silver ion, continue to seal stirring 57 minutes, be down to room temperature and obtain final product.
Embodiment 5
In the embodiment of the present invention, a kind of degerming coating additive includes according to the raw material of weight portion：40 parts of medical stone, 24 parts of Tourmaline, 8 parts of silver ion, 3 parts of polyurethane, 8 parts of sodium sulfonate diethyl succinate, 3 parts of Diphenylsilanediol, 2 parts of epoxy sodium carboxymethylcellulose, 13 parts of titanium dioxide, 45 parts of water.
After medical stone, Tourmaline, polyurethane, diethyl succinate sodium sulfonate, Diphenylsilanediol, sodium carboxymethylcellulose, titanium dioxide mixing, ball milling 65 minutes, then in the powder after ball milling water is added again, it is warming up to 45 DEG C of sealings to stir 55 minutes, add silver ion, continue to seal stirring 55 minutes, be down to room temperature and obtain final product.
Jing tests understand, the coating additive of above-described embodiment 1-5 is added separately in the glazing type material of water paint and ceramic tile, after testing after water paint and ceramic tile construction per square metre can discharge 10-20ion, also with the effect for killing the common bacterias such as staphylococcus aureus.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing from the spirit or essential characteristics of the present invention, can in other specific forms realize the present invention.Therefore, no matter from the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by claims rather than described above is limited, it is intended that all changes in the implication and scope of the equivalency of claim that will fall are included in the present invention.
In addition, it should be understood that, although this specification is been described by according to embodiment, but not each embodiment only includes an independent technical scheme, this narrating mode of specification is only for clarity, those skilled in the art should using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, formed it will be appreciated by those skilled in the art that other embodiment.
Claims (4)
1. a kind of degerming coating additive, it is characterised in that the raw material according to weight portion includes：
Medical stone 33-45 parts
Tourmaline 20-28 parts
Silver ion 5-10 parts
Polyurethane 1-5 parts
Sodium sulfonate diethyl succinate 5-10 parts
Diphenylsilanediol 1-5 parts
Epoxy sodium carboxymethylcellulose 1-3 parts
Titanium dioxide 10-17 parts
Water 40-50 parts.
2. degerming coating additive according to claim 1, it is characterised in that according to the original of weight portion
Material includes：
Medical stone 38-42 parts
Tourmaline 23-26 parts
Silver ion 7-9 parts
Polyurethane 2-4 parts
Sodium sulfonate diethyl succinate 7-9 parts
Diphenylsilanediol 2-4 parts
Epoxy sodium carboxymethylcellulose 1-2 parts
Titanium dioxide 12-15 parts
Water 43-47 parts.
3. degerming coating additive according to claim 2, it is characterised in that according to the original of weight portion
Material includes：
40 parts of medical stone
24 parts of Tourmaline
8 parts of silver ion
3 parts of polyurethane
8 parts of sodium sulfonate diethyl succinate
3 parts of Diphenylsilanediol
2 parts of epoxy sodium carboxymethylcellulose
13 parts of titanium dioxide
45 parts of water.
4. the preparation method of the degerming coating additive as described in claim 1-3 is arbitrary, it is characterised in that
By medical stone, Tourmaline, polyurethane, diethyl succinate sodium sulfonate, Diphenylsilanediol, carboxymethyl
After sodium cellulosate, titanium dioxide mixing, ball milling 60-70 minutes, then in the powder after ball milling water is added again,
45 DEG C of sealing stirring 50-60 minutes are warming up to, silver ion is added, continue to seal stirring 50-60 minutes,
It is down to room temperature to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510801399.8A CN106560492A (en) | 2015-11-19 | 2015-11-19 | Antibacterial coating material additive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510801399.8A CN106560492A (en) | 2015-11-19 | 2015-11-19 | Antibacterial coating material additive and preparation method thereof |
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| CN106560492A true CN106560492A (en) | 2017-04-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510801399.8A Pending CN106560492A (en) | 2015-11-19 | 2015-11-19 | Antibacterial coating material additive and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107721266A (en) * | 2017-11-17 | 2018-02-23 | 枣庄市博源人造石有限公司 | A kind of Z-Correct bump mapping Z-correct artificial stone and preparation method thereof |
| CN109354915A (en) * | 2018-10-15 | 2019-02-19 | 西安金海礁建筑节能科技有限公司 | The environmental protection type nano material multifunctional water and preparation method thereof of the water-soluble finishing product of dilution |
| CN110564199A (en) * | 2019-09-30 | 2019-12-13 | 吴应琼 | Material capable of improving environmental protection performance of coating |
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| CN101225273A (en) * | 2008-01-07 | 2008-07-23 | 石峻青 | Medical stone water paint |
| CN103849265A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Environmental protection coating capable of generating negative ions, and preparation method thereof |
| CN104073072A (en) * | 2014-06-30 | 2014-10-01 | 南通蛇类治疗研究所 | Nano functional ecological environmental-friendly coating |
| CN104263221A (en) * | 2014-09-16 | 2015-01-07 | 青岛市高科专利技术转移平台有限公司 | Flame-retardant water-based polyurethane paint formula |
| CN104893462A (en) * | 2015-05-26 | 2015-09-09 | 康圣科 | Silver ion antimicrobial fiber paint |
-
2015
- 2015-11-19 CN CN201510801399.8A patent/CN106560492A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225273A (en) * | 2008-01-07 | 2008-07-23 | 石峻青 | Medical stone water paint |
| CN103849265A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Environmental protection coating capable of generating negative ions, and preparation method thereof |
| CN104073072A (en) * | 2014-06-30 | 2014-10-01 | 南通蛇类治疗研究所 | Nano functional ecological environmental-friendly coating |
| CN104263221A (en) * | 2014-09-16 | 2015-01-07 | 青岛市高科专利技术转移平台有限公司 | Flame-retardant water-based polyurethane paint formula |
| CN104893462A (en) * | 2015-05-26 | 2015-09-09 | 康圣科 | Silver ion antimicrobial fiber paint |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107721266A (en) * | 2017-11-17 | 2018-02-23 | 枣庄市博源人造石有限公司 | A kind of Z-Correct bump mapping Z-correct artificial stone and preparation method thereof |
| CN109354915A (en) * | 2018-10-15 | 2019-02-19 | 西安金海礁建筑节能科技有限公司 | The environmental protection type nano material multifunctional water and preparation method thereof of the water-soluble finishing product of dilution |
| CN110564199A (en) * | 2019-09-30 | 2019-12-13 | 吴应琼 | Material capable of improving environmental protection performance of coating |
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Application publication date: 20170412 |