CN104263221A - Flame-retardant water-based polyurethane paint formula - Google Patents

Flame-retardant water-based polyurethane paint formula Download PDF

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Publication number
CN104263221A
CN104263221A CN201410470867.3A CN201410470867A CN104263221A CN 104263221 A CN104263221 A CN 104263221A CN 201410470867 A CN201410470867 A CN 201410470867A CN 104263221 A CN104263221 A CN 104263221A
Authority
CN
China
Prior art keywords
parts
sodium
flame
polyurethane
retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410470867.3A
Other languages
Chinese (zh)
Inventor
魏书元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Hi Tech Patent Technology Transfer Platform Co Ltd
Original Assignee
Qingdao Hi Tech Patent Technology Transfer Platform Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Hi Tech Patent Technology Transfer Platform Co Ltd filed Critical Qingdao Hi Tech Patent Technology Transfer Platform Co Ltd
Priority to CN201410470867.3A priority Critical patent/CN104263221A/en
Publication of CN104263221A publication Critical patent/CN104263221A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a flame-retardant water-based polyurethane paint formula which comprises 70 parts of polyurethane, 15 parts of ethyl acetate, 8 parts of sodium hydroxide, 1 part of diphenyl dihydroxy silane, 4 parts of sodium epoxy carboxymethyl cellulose, 2 parts of medical stone, 4 parts of chitosan, 5 parts of sorbitol, 7 parts of titanium dioxide, 2 parts of casein, 4 parts of N,N-dimethylamino propylamine, 5 parts of sodium dodecyl benzene sulfonate, 2 parts of sodium polyacrylate, 8 parts of polyvinyl alcohol, 1 part of cationic polyacrylamide, 5 parts of sodium silicate and 7 parts of sodium hexametaphosphate. The smoke released in the flame-retardant water-based polyurethane paint combustion process is greatly lowered as compared with the traditional flame-retardant polyurethane, and the cost performance for flame retardancy is high; and the catalyst selected in the prepolymer synthesis process is substituted for the traditional dibutyltin dilaurate to overcome the defect of poor surface of the polyurethane film, and thus, the product has the advantages of smooth surface and favorable toughness.

Description

A kind of formula of extinguishing waterborn polyurethane coating
Technical field
The present invention relates to a kind of Chemicals, especially a kind of formula of extinguishing waterborn polyurethane coating.
Background technology
Aqueous polyurethane (also known as waterbased urethane) is a kind of urethane resin containing hydrophilic radical in the molecular chain of urethane, has very strong affinity, adopt specific technique can make it disperse in water and form stable system with glassware for drinking water.Aqueous polyurethane is mainly used in the aspects such as leather finish, textile printing and dyeing, paper-making industry, building coating, tackiness agent, steel moulder's paint, involved is nearly all inflammable material, these materials as without fire-retardant finish, must become the potential safety hazard of initiation fire in use.Aqueous polyurethane flame-retarded is one of important directions of aqueous polyurethane functionalization.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of formula of extinguishing waterborn polyurethane coating.
For solving the problems of the technologies described above, the formula of extinguishing waterborn polyurethane coating of the present invention, comprises following component, urethane 70 parts, vinyl acetic monomer 15 parts, 8 parts, sodium hydroxide, Diphenylsilanediol, 1 part, epoxy Xylo-Mucine 4 parts, medical stone 2 parts, chitosan 4 parts, Sorbitol Powder 5 parts, titanium dioxide 7 parts, casein 2 parts, N, N-dimethylamino propylamine 4 parts, Sodium dodecylbenzene sulfonate 5 parts, sodium polyacrylate 2 parts, polyvinyl alcohol 8 parts, cationic polyacrylamide 1 part, water glass 5 parts, Sodium hexametaphosphate 99 7 parts.
It also comprises Mierocrystalline cellulose 5 parts.
The invention has the beneficial effects as follows: the smog comparing traditional flame retardant polyurethane release when prepared flame-retardant aqueous polyurethane coating burns significantly reduces, and fire-retardant cost performance is high; Obtained by the traditional dibutyl tin laurate of catalyst replaced selected in performed polymer synthesis, the defect of polyurethane film surface difference, makes product surface flat smooth, good toughness.
Embodiment
Embodiment 1
The formula of extinguishing waterborn polyurethane coating of the present invention, comprises following component, urethane 70 parts, vinyl acetic monomer 15 parts, 8 parts, sodium hydroxide, Diphenylsilanediol, 1 part, epoxy Xylo-Mucine 4 parts, medical stone 2 parts, chitosan 4 parts, Sorbitol Powder 5 parts, titanium dioxide 7 parts, casein 2 parts, N, N-dimethylamino propylamine 4 parts, Sodium dodecylbenzene sulfonate 5 parts, sodium polyacrylate 2 parts, polyvinyl alcohol 8 parts, cationic polyacrylamide 1 part, water glass 5 parts, Sodium hexametaphosphate 99 7 parts.
Embodiment 2
The formula of extinguishing waterborn polyurethane coating of the present invention, comprises following component, urethane 70 parts, vinyl acetic monomer 15 parts, 8 parts, sodium hydroxide, Diphenylsilanediol, 1 part, epoxy Xylo-Mucine 4 parts, medical stone 2 parts, chitosan 4 parts, Sorbitol Powder 5 parts, titanium dioxide 7 parts, casein 2 parts, N, N-dimethylamino propylamine 4 parts, Sodium dodecylbenzene sulfonate 5 parts, sodium polyacrylate 2 parts, polyvinyl alcohol 8 parts, cationic polyacrylamide 1 part, water glass 5 parts, Sodium hexametaphosphate 99 7 parts, Mierocrystalline cellulose 5 parts.

Claims (2)

1. a formula for extinguishing waterborn polyurethane coating, is characterized in that: comprise following component, urethane 70 parts, vinyl acetic monomer 15 parts, 8 parts, sodium hydroxide, Diphenylsilanediol, 1 part, epoxy Xylo-Mucine 4 parts, medical stone 2 parts, chitosan 4 parts, Sorbitol Powder 5 parts, titanium dioxide 7 parts, casein 2 parts, N, N-dimethylamino propylamine 4 parts, Sodium dodecylbenzene sulfonate 5 parts, sodium polyacrylate 2 parts, polyvinyl alcohol 8 parts, cationic polyacrylamide 1 part, water glass 5 parts, Sodium hexametaphosphate 99 7 parts.
2. according to the formula of extinguishing waterborn polyurethane coating according to claim 1, it is characterized in that: it also comprises Mierocrystalline cellulose 5 parts.
CN201410470867.3A 2014-09-16 2014-09-16 Flame-retardant water-based polyurethane paint formula Pending CN104263221A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410470867.3A CN104263221A (en) 2014-09-16 2014-09-16 Flame-retardant water-based polyurethane paint formula

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410470867.3A CN104263221A (en) 2014-09-16 2014-09-16 Flame-retardant water-based polyurethane paint formula

Publications (1)

Publication Number Publication Date
CN104263221A true CN104263221A (en) 2015-01-07

Family

ID=52154812

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410470867.3A Pending CN104263221A (en) 2014-09-16 2014-09-16 Flame-retardant water-based polyurethane paint formula

Country Status (1)

Country Link
CN (1) CN104263221A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106560492A (en) * 2015-11-19 2017-04-12 赖永建 Antibacterial coating material additive and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106560492A (en) * 2015-11-19 2017-04-12 赖永建 Antibacterial coating material additive and preparation method thereof

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Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150107

WD01 Invention patent application deemed withdrawn after publication