CN104845465A - Safe pollution-free fireproof coating - Google Patents
Safe pollution-free fireproof coating Download PDFInfo
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- CN104845465A CN104845465A CN201510197883.4A CN201510197883A CN104845465A CN 104845465 A CN104845465 A CN 104845465A CN 201510197883 A CN201510197883 A CN 201510197883A CN 104845465 A CN104845465 A CN 104845465A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
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- C08K3/2279—Oxides; Hydroxides of metals of antimony
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- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C08K3/36—Silica
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- C08K3/38—Boron-containing compounds
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- C08K5/00—Use of organic ingredients
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- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C08K7/00—Use of ingredients characterised by shape
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- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
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- C08K7/00—Use of ingredients characterised by shape
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- C08K7/14—Glass
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
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- C08K2003/3054—Ammonium sulfates
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C08K2003/387—Borates
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Health & Medical Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Fireproofing Substances (AREA)
Abstract
The invention discloses a safe pollution-free fireproof coating. The safe pollution-free fireproof coating is prepared from, by weight, 15-25 parts of acrylic resin, 10-20 parts of ammonium polyphosphate, 2-4 parts of zinc borate, 2-5 parts of silica, 3-5 parts of titanium dioxide, 2-5 parts of magnesium hydroxide, 2-5 parts of titanium dioxide, 2-5 parts of borax, 3-10 parts of silicon nitride fiber, 5-10 parts of water, 2-5 parts of acetone, 3-20 parts of expandable graphite, 3-6 parts of glass fiber, 2-5 parts of dipentaerythritol and 3-5 parts of a fire retardant; and the fire retardant is composed 13-14% of antimony dioxide, 0.2-0.3% of ammonium sulfate, 10-20% of magnesium hydroxide, 10-20% of citric acid, and the balance of diatomite. The safe pollution-free fireproof coating has the advantages of strong waterproof property, tight combination to materials, high bonding strength, no shedding after meeting water, no release of poisonous and harmful gases, safety and no pollution; and the fire retardant has the advantages of reasonable formula, low cost and good fire retardation effect.
Description
Technical field
The present invention relates to fire-proof product field, specifically a kind of frie retardant coating of safety non-pollution.
Background technology
Frie retardant coating is for flammable substrates surface, can reduce by the rapid spread of the combustibility of painting material surface, retardance fire, in order to improve by a kind of speciality coating being coated with material fire endurance.Frie retardant coating itself has flame retardancy or uninflammability, and protected base material is not directly contacted with air, postpones the speed that object catches fire and reduces burning, improves the refractory ability of material, slows down propagation of flame velocity of propagation, or can stop burning within a certain period of time.
In preparation and construction in a large number with an organic solvent, can all there is very large harm to environment and operator in solvent-borne type fire-retardant material.Aqueous fire-proof coating is environment-friendly and green comparatively speaking, meets the developing direction of Environmentally friendly coatings, but aqueous fire-proof coating exists, and cohesive strength is low, the shortcoming of poor water resistance, and the time has been grown and easily come off later.
At present, known a lot of articles for daily use comprise furniture, floor, wallpaper etc., and it, while bringing practicality, attractive in appearance, fashion for life, also also exists a lot of hidden danger; Produce a large amount of obnoxious flavoures during burning, it is unfavorable not only to bring the healthy safety of people, also destroys the ecotope of periphery simultaneously.Although fire retardant is widely used in all respects of life, when fire-retardant finish is carried out to article, still there is new technical problem.
Summary of the invention
A frie retardant coating for safety non-pollution, be made up of the raw material of following weight part: acrylic resin 15 ~ 25 parts, polyphosphoric acid by 10 ~ 20 parts, zinc borate 2 ~ 4 parts, silicon-dioxide 2 ~ 5 parts, 3 ~ 5 parts, white powder of admiring, magnesium hydroxide 2 ~ 5 parts, titanium dioxide admire 2 ~ 5 parts, borax 2 ~ 5 parts, silicon nitride fiber 3 ~ 10 parts, 5 ~ 10 parts, water, 2 ~ 5 parts, acetone, expanded graphite 3 ~ 20 parts, 3 ~ 6 parts, glass fibre, Dipentaerythritol 2 ~ 5 parts, fire retardant 3 ~ 5 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
As further scheme, be made up of the raw material of following weight part: acrylic resin 15 parts, polyphosphoric acid by 10 parts, zinc borate 2 parts, silicon-dioxide 2 parts, 3 parts, white powder of admiring, magnesium hydroxide 2 parts, titanium dioxide admire 2 parts, borax 2 parts, silicon nitride fiber 3 parts, 5 parts, water, 2 parts, acetone, expanded graphite 3 parts, 3 parts, glass fibre, Dipentaerythritol 2 parts, fire retardant 3 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
As further scheme, be made up of the raw material of following weight part: acrylic resin 20 parts, polyphosphoric acid by 15 parts, zinc borate 3 parts, silicon-dioxide 3 parts, 4 parts, white powder of admiring, magnesium hydroxide 4 parts, titanium dioxide admire 4 parts, borax 4 parts, silicon nitride fiber 8 parts, 8 parts, water, 4 parts, acetone, expanded graphite 17 parts, 3 parts, glass fibre, Dipentaerythritol 2 parts, fire retardant 4 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
As further scheme, be made up of the raw material of following weight part: acrylic resin 25 parts, polyphosphoric acid by 20 parts, zinc borate 4 parts, silicon-dioxide 5 parts, 5 parts, white powder of admiring, magnesium hydroxide 5 parts, titanium dioxide admire 5 parts, borax 5 parts, silicon nitride fiber 10 parts, 10 parts, water, 5 parts, acetone, expanded graphite 20 parts, 6 parts, glass fibre, Dipentaerythritol 5 parts, fire retardant 5 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
The present invention in the preparation, according to recipe ingredient ratio by polyphosphoric acid by, zinc borate, silicon-dioxide, white powder of admiring, magnesium hydroxide, titanium dioxide recognize, borax and water mix in stirring tank, speed lapping, when to grind to fineness be 100 order left and right.Then expanded graphite, glass fibre, Dipentaerythritol, silicon nitride fiber, fire retardant are added together, then stir, after high-speed stirring dispersion, namely obtain the present invention.
Compared with prior art, the invention has the beneficial effects as follows: the frie retardant coating of safety non-pollution provided by the invention, water tolerance is strong, and be combined closely with material, cohesive strength is high, can not meet water and come off; For water-borne coatings, only use a small amount of solvent, can not toxic and harmful be discharged, safety non-pollution.The formula of fire retardant is reasonable, with low cost, good flame retardation effect.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a frie retardant coating for safety non-pollution, be made up of the raw material of following weight part: acrylic resin 15 parts, polyphosphoric acid by 10 parts, zinc borate 2 parts, silicon-dioxide 2 parts, 3 parts, white powder of admiring, magnesium hydroxide 2 parts, titanium dioxide admire 2 parts, borax 2 parts, silicon nitride fiber 3 parts, 5 parts, water, 2 parts, acetone, expanded graphite 3 parts, 3 parts, glass fibre, Dipentaerythritol 2 parts, fire retardant 3 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
Raw material is weighed in proportion, according to recipe ingredient ratio by polyphosphoric acid by, zinc borate, silicon-dioxide, white powder of admiring, magnesium hydroxide, titanium dioxide drink, borax and water mixes in stirring tank, speed lapping, when to grind to fineness be 100 order left and right.Then expanded graphite, glass fibre, Dipentaerythritol, silicon nitride fiber, fire retardant are added together, then stir, after high-speed stirring dispersion, namely obtain the present invention.
Embodiment 2
In the embodiment of the present invention, a frie retardant coating for safety non-pollution, be made up of the raw material of following weight part: acrylic resin 20 parts, polyphosphoric acid by 15 parts, zinc borate 3 parts, silicon-dioxide 3 parts, 4 parts, white powder of admiring, magnesium hydroxide 4 parts, titanium dioxide admire 4 parts, borax 4 parts, silicon nitride fiber 8 parts, 8 parts, water, 4 parts, acetone, expanded graphite 17 parts, 3 parts, glass fibre, Dipentaerythritol 2 parts, fire retardant 4 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
Preparation method is with embodiment 1.
Embodiment 3
In the embodiment of the present invention, a frie retardant coating for safety non-pollution, be made up of the raw material of following weight part: acrylic resin 25 parts, polyphosphoric acid by 20 parts, zinc borate 4 parts, silicon-dioxide 5 parts, 5 parts, white powder of admiring, magnesium hydroxide 5 parts, titanium dioxide admire 5 parts, borax 5 parts, silicon nitride fiber 10 parts, 10 parts, water, 5 parts, acetone, expanded graphite 20 parts, 6 parts, glass fibre, Dipentaerythritol 5 parts, fire retardant 5 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
Preparation method is with embodiment 1.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (4)
1. the frie retardant coating of a safety non-pollution, it is characterized in that, be made up of the raw material of following weight part: acrylic resin 15 ~ 25 parts, polyphosphoric acid by 10 ~ 20 parts, zinc borate 2 ~ 4 parts, silicon-dioxide 2 ~ 5 parts, 3 ~ 5 parts, white powder of admiring, magnesium hydroxide 2 ~ 5 parts, titanium dioxide admire 2 ~ 5 parts, borax 2 ~ 5 parts, silicon nitride fiber 3 ~ 10 parts, 5 ~ 10 parts, water, 2 ~ 5 parts, acetone, expanded graphite 3 ~ 20 parts, 3 ~ 6 parts, glass fibre, Dipentaerythritol 2 ~ 5 parts, fire retardant 3 ~ 5 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
2. the frie retardant coating of a kind of safety non-pollution according to claim 1, it is characterized in that, be made up of the raw material of following weight part: acrylic resin 15 parts, polyphosphoric acid by 10 parts, zinc borate 2 parts, silicon-dioxide 2 parts, 3 parts, white powder of admiring, magnesium hydroxide 2 parts, titanium dioxide admire 2 parts, borax 2 parts, silicon nitride fiber 3 parts, 5 parts, water, 2 parts, acetone, expanded graphite 3 parts, 3 parts, glass fibre, Dipentaerythritol 2 parts, fire retardant 3 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
3. the frie retardant coating of a kind of safety non-pollution according to claim 1, it is characterized in that, be made up of the raw material of following weight part: acrylic resin 20 parts, polyphosphoric acid by 15 parts, zinc borate 3 parts, silicon-dioxide 3 parts, 4 parts, white powder of admiring, magnesium hydroxide 4 parts, titanium dioxide admire 4 parts, borax 4 parts, silicon nitride fiber 8 parts, 8 parts, water, 4 parts, acetone, expanded graphite 17 parts, 3 parts, glass fibre, Dipentaerythritol 2 parts, fire retardant 4 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
4. the frie retardant coating of a kind of safety non-pollution according to claim 1, it is characterized in that, be made up of the raw material of following weight part: acrylic resin 25 parts, polyphosphoric acid by 20 parts, zinc borate 4 parts, silicon-dioxide 5 parts, 5 parts, white powder of admiring, magnesium hydroxide 5 parts, titanium dioxide admire 5 parts, borax 5 parts, silicon nitride fiber 10 parts, 10 parts, water, 5 parts, acetone, expanded graphite 20 parts, 6 parts, glass fibre, Dipentaerythritol 5 parts, fire retardant 5 parts; Consisting of of fire retardant: tellurium dioxide 13% ~ 14%, amine sulfate 0.2% ~ 0.3%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, all the other are diatomite.
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Cited By (5)
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CN105295613A (en) * | 2015-12-04 | 2016-02-03 | 常熟市福达金属制件有限公司 | Novel tonnage barrel base |
CN106752587A (en) * | 2016-12-26 | 2017-05-31 | 广西宾阳县荣良新材料科技有限公司 | A kind of kitchen wall surface fireproof mould-proof coating and its production method |
WO2017131995A1 (en) * | 2016-01-29 | 2017-08-03 | Dow Global Technologies Llc | Polymeric foam board with flexible water resistant intumescent coating |
CN110128928A (en) * | 2019-05-08 | 2019-08-16 | 中国京冶工程技术有限公司 | A kind of novel fire resistant environmental protection fire-resistant coating for steel structure and preparation method thereof |
US20210378334A1 (en) * | 2019-04-30 | 2021-12-09 | Honghan Nantong Protection of Science &Technology Co.,Ltd. | Dipping composite material for enhancing cut resistance of chemical-resistant gloves |
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CN1876740A (en) * | 2006-07-12 | 2006-12-13 | 海洋化工研究院 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
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Application publication date: 20150819 |