CN102850881B - A kind of Environment-friendlyfire-retardant fire-retardant paint - Google Patents

A kind of Environment-friendlyfire-retardant fire-retardant paint Download PDF

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Publication number
CN102850881B
CN102850881B CN201210337313.7A CN201210337313A CN102850881B CN 102850881 B CN102850881 B CN 102850881B CN 201210337313 A CN201210337313 A CN 201210337313A CN 102850881 B CN102850881 B CN 102850881B
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China
Prior art keywords
retardant
paint
fire
friendlyfire
environment
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Expired - Fee Related
Application number
CN201210337313.7A
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Chinese (zh)
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CN102850881A (en
Inventor
朱玉国
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SHANDONG CHANGXING GROUP CO Ltd
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SHANDONG CHANGXING GROUP CO Ltd
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Priority to CN201210337313.7A priority Critical patent/CN102850881B/en
Publication of CN102850881A publication Critical patent/CN102850881A/en
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Publication of CN102850881B publication Critical patent/CN102850881B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses a kind of Environment-friendlyfire-retardant fire-retardant paint, belong to decorative materials technology.Its component and weight part thereof are: water 20 ~ 30, Hydroxylated acrylic resin 10 ~ 15, urethane resin 10 ~ 15, urea 5 ~ 8, tetramethylolmethane 5 ~ 8, polyphosphoric acid amine 5 ~ 8, melamine phosphate 5 ~ 8, white carbon black 10 ~ 12, water glass 5 ~ 8, titanium dioxide 3 ~ 5, dioctyl phthalate (DOP) 2 ~ 3, dithiocarbamate 2 ~ 3.The present invention adopts nontoxic or that toxicity is lower raw material to form, can not to human body, and especially workmen can not work the mischief in normal construction process, and the flame retardant paint made is transparent.

Description

A kind of Environment-friendlyfire-retardant fire-retardant paint
Technical field
The present invention relates to a kind of Environment-friendlyfire-retardant fire-retardant paint (coating), belong to decorative materials technology.
Background technology
Flame retardant paint is by a kind of anti-flaming dope of the multiple material manufactures such as membrane-forming agent, fire retardant, whipping agent; Owing to using the inflammable material such as timber, cloth in a large number in current household, so fire prevention has been a subject under discussion being worth mentioning.Existing flame retardant paint can be divided into facing flame retardant paint, fire retarding wood protection paint, three kinds, steel structure fireproofing paint.Facing type fireproofing paint is a kind of novel paint kind integrating decoration and fire prevention, when it is coated on flammable base material, can play certain decoration function at ordinary times; Occur once fire, then there is prevention fire spreading, thus reach the object protecting flammable base material.Apply more in facing flame retardant paint, effect is expansion fire-proof paint preferably.
Facing type expansible fireproof paint (coating), can be divided into solvent-borne type and water-based two class.The filmogen of solvent-borne type flame retardant paint generally selects chlorinated rubber, chlorinated polyvinyl chloride, aminoresin, resol etc., and the solvent of employing is No. 200 industrial napthas, lacquer thinner, N-BUTYL ACETATEs etc.The filmogen of water-based fireproof paint generally selects vinylchlorid-vinylidene chloride emulsion, benzene emulsion, pure acrylic latex, polyvinyl acetate emulsion etc., and these materials are all solvent with water.But current solvent-borne type and water-based fireproof paint great majority are containing the material such as a large amount of organic solvents or halide-containing, comparatively large to Health Impact, and there is the not high problem of flame retardant paint transparency.
Summary of the invention
Instant invention overcomes above-mentioned the deficiencies in the prior art, provide a kind of Environment-friendlyfire-retardant fire-retardant paint, this paint has on the basis of good flameproof effect in guarantee, achieves the environmental protection of paint and transparent.
Technical scheme of the present invention is: a kind of Environment-friendlyfire-retardant fire-retardant paint, and its component and weight part thereof are: water 20 ~ 30, Hydroxylated acrylic resin 10 ~ 15, urethane resin 10 ~ 15, urea 5 ~ 8, tetramethylolmethane 5 ~ 8, polyphosphoric acid amine (polymerization degree n is 200 ~ 500) 5 ~ 8, melamine phosphate 5 ~ 8, white carbon black 10 ~ 12, water glass 5 ~ 8, titanium dioxide 3 ~ 5, dioctyl phthalate (DOP) 2 ~ 3, dithiocarbamate 2 ~ 3.
Preparation method: said components is uniformly mixed.
Above-mentioned raw materials is commercially available prod, wherein Hydroxylated acrylic resin is by methacrylic acid monomer, Acrylic Acid Monomer and vinylbenzene, by the initiator high molecular polymer (have at least in comonomer a kind of for hydroxyl monomer) that obtains of polyreaction in a solvent.
The present invention is with above-mentioned raw materials prescription, and Hydroxylated acrylic resin and urethane resin make paint have good tack, oil-proofness, toughness, wear resistance and ageing resistance; Urea, tetramethylolmethane and polyphosphoric acid amine make it have good foaming and become carbon promotion functions; Melamine phosphate, white carbon black and water glass combine, and make it have good anti-flaming function, the weathering resistance having added flame retardant paint perfect further of titanium dioxide, dioctyl phthalate (DOP) and dithiocarbamate, plasticity and mildew resistance; Various composition cooperatively interacts and makes the various aspects of performance of flame retardant paint more excellent.
Application approach: for decoration and the fire prevention of various building, furniture or decoration.
The invention has the beneficial effects as follows: adopt nontoxic or that toxicity is lower raw material to form, can not to human body, especially workmen can not work the mischief in normal construction process, and the flame retardant paint made is transparent.
Embodiment
Embodiment 1
Proportioning (weight part): water 30, Hydroxylated acrylic resin 15, urethane resin 15, urea 8, tetramethylolmethane 8, polyphosphoric acid amine (polymerization degree n is 200 ~ 500) 8, melamine phosphate 8, white carbon black 12, water glass 8, titanium dioxide 5, dioctyl phthalate (DOP) 3, dithiocarbamate 3; Said components is uniformly mixed.
Embodiment 2
Proportioning (weight part): water 20, Hydroxylated acrylic resin 10, urethane resin 10, urea 5, tetramethylolmethane 5, polyphosphoric acid amine (polymerization degree n is 200 ~ 500) 5, melamine phosphate 5, white carbon black 10, water glass 5, titanium dioxide 3, dioctyl phthalate (DOP) 2, dithiocarbamate 2; Said components is uniformly mixed.
Embodiment 3
Proportioning (weight part): water 25, Hydroxylated acrylic resin 12, urethane resin 12, urea 6, tetramethylolmethane 6, polyphosphoric acid amine (polymerization degree n is 200 ~ 500) 6, melamine phosphate 6, white carbon black 11, water glass 6, titanium dioxide 4, dioctyl phthalate (DOP) 2.5, dithiocarbamate 2.5; Said components is uniformly mixed.
Embodiment 4
Proportioning (weight part): water 28, Hydroxylated acrylic resin 14, urethane resin 14, urea 7, tetramethylolmethane 7, polyphosphoric acid amine (polymerization degree n is 200 ~ 500) 7, melamine phosphate 7, white carbon black 11.5, water glass 7, titanium dioxide 4.5, dioctyl phthalate (DOP) 2.8, dithiocarbamate 2.8; Said components is uniformly mixed.
The performance index of flame retardant paint of the present invention are as follows: outward appearance: transparent; Splitting resistance: flawless; Cohesive strength >=1.2MPa; Resistance to expose to the sun hot: 720h coating without bubbling, come off, hollowing, cracking; Humidity resistance: 600h coating is without bubbling, coming off; Chemicals-resistant immersion property (3% ammoniacal liquor, 3% hydrochloric acid): 360 coatings are intact; The thick fire endurance of fire endurance: 2mm is 2 hours.

Claims (1)

1. an Environment-friendlyfire-retardant fire-retardant paint, it is characterized in that, its component and weight part thereof are: water 20 ~ 30, Hydroxylated acrylic resin 10 ~ 15, urethane resin 10 ~ 15, urea 5 ~ 8, tetramethylolmethane 5 ~ 8, ammonium polyphosphate 5 ~ 8, melamine phosphate 5 ~ 8, white carbon black 10 ~ 12, water glass 5 ~ 8, titanium dioxide 3 ~ 5, dioctyl phthalate (DOP) 2 ~ 3, dithiocarbamate 2 ~ 3; The polymerization degree n of described ammonium polyphosphate is 200 ~ 500.
CN201210337313.7A 2012-09-12 2012-09-12 A kind of Environment-friendlyfire-retardant fire-retardant paint Expired - Fee Related CN102850881B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210337313.7A CN102850881B (en) 2012-09-12 2012-09-12 A kind of Environment-friendlyfire-retardant fire-retardant paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210337313.7A CN102850881B (en) 2012-09-12 2012-09-12 A kind of Environment-friendlyfire-retardant fire-retardant paint

Publications (2)

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CN102850881A CN102850881A (en) 2013-01-02
CN102850881B true CN102850881B (en) 2015-12-16

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Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103275538B (en) * 2013-06-03 2016-02-10 苏州富通高新材料科技股份有限公司 A kind of acrylic Resin Coating for Anti-Fire
CN103387760A (en) * 2013-08-22 2013-11-13 吴江市冰心文教用品有限公司 Transparent fireproof pigment
CN104017456B (en) * 2014-06-15 2016-03-23 段宝荣 A kind of fast light preparation method with aqueous flame retardant acrylic resin coating
CN104448964A (en) * 2014-12-31 2015-03-25 江阴市天邦涂料股份有限公司 Preparing method for water-based fire retardant coating
CN106497197A (en) * 2015-09-08 2017-03-15 广东百安涂料科技有限公司 The preparation method of expanding fire-proof paint filled by a kind of hollow nano calcium silicates
CN105199510A (en) * 2015-09-22 2015-12-30 天长市开林化工有限公司 High-strength wear-resistant flame-retardant water-based paint and preparation method thereof
CN105176166A (en) * 2015-10-21 2015-12-23 苏州赛斯德工程设备有限公司 Water-based paint with flame retarding function and preparation method of water-based paint
CN105820625A (en) * 2016-06-02 2016-08-03 扬州兰都塑料科技有限公司 Water-based fireproof coating for coating outside of cable
CN106398425A (en) * 2016-09-13 2017-02-15 广西大学 Fireproof paint and preparation method thereof
CN107141947A (en) * 2017-05-31 2017-09-08 安庆永大体育用品有限公司 A kind of plank fireproof coating and preparation method thereof
CN108864860A (en) * 2018-05-18 2018-11-23 侯伟旗 A kind of fire resistant doorsets surface fireproof paint
CN108641450A (en) * 2018-05-18 2018-10-12 侯伟旗 A kind of fire resistant doorsets fire prevention water-proof paint
CN110128926A (en) * 2019-04-24 2019-08-16 广西大学 A kind of water expansion plastic flame coating and preparation method thereof
IT201900012156A1 (en) * 2019-07-17 2021-01-17 Sherwin Williams Italy S R L Flame retardant crosslinkable coating composition
CN114921166A (en) * 2022-06-30 2022-08-19 北京同人电力发展有限公司 Fireproof curing type coating material with high viscosity and coating method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55765A (en) * 1979-04-06 1980-01-07 Takashi Ishikawa Fire and heat resistant phenolic resin foam
CN1708562A (en) * 2002-11-29 2005-12-14 宇振技术21有限公司 Flame retardant coating composition and method of preparing the same
CN101143988A (en) * 2006-09-14 2008-03-19 刘炳义 Water anti-flaming carpentry paint
CN101440249A (en) * 2008-05-23 2009-05-27 海洋化工研究院 Ultrathin section steel structure fire-resisting paint and preparation thereof
CN101691470A (en) * 2009-10-12 2010-04-07 东莞市艾斯迪新材料有限公司 Conductive and fire-retardant waterborne coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55765A (en) * 1979-04-06 1980-01-07 Takashi Ishikawa Fire and heat resistant phenolic resin foam
CN1708562A (en) * 2002-11-29 2005-12-14 宇振技术21有限公司 Flame retardant coating composition and method of preparing the same
CN101143988A (en) * 2006-09-14 2008-03-19 刘炳义 Water anti-flaming carpentry paint
CN101440249A (en) * 2008-05-23 2009-05-27 海洋化工研究院 Ultrathin section steel structure fire-resisting paint and preparation thereof
CN101691470A (en) * 2009-10-12 2010-04-07 东莞市艾斯迪新材料有限公司 Conductive and fire-retardant waterborne coating

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Granted publication date: 20151216

Termination date: 20160912