CN106544142A - 一种锌合金强力旋压加工工艺润滑剂组合物 - Google Patents

一种锌合金强力旋压加工工艺润滑剂组合物 Download PDF

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CN106544142A
CN106544142A CN201610969051.4A CN201610969051A CN106544142A CN 106544142 A CN106544142 A CN 106544142A CN 201610969051 A CN201610969051 A CN 201610969051A CN 106544142 A CN106544142 A CN 106544142A
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黄福川
李康春
邓富康
唐弓斌
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Guangxi University
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Abstract

本发明公开了一种锌合金强力旋压加工工艺润滑剂组合物，采用MVI500基础油作为基础油，配合多种复合添加剂。包括：抗氧剂、金属减活剂、极压抗磨剂、油性剂、摩擦改进剂、防锈剂、抗氧抗腐剂、粘度指数改进剂等。本发明的组合物具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性及粘附性，能减少表面擦伤和划痕。

Description

一种锌合金强力旋压加工工艺润滑剂组合物
技术领域
本发明一种锌合金强力旋压加工工艺润滑剂组合物属于金属加工润滑剂领域。
背景技术
锌合金是以锌为基础加入其他元素组成的合金。常加的合金元素有铝、铜、镁、镉、铅、钛等低温锌合金。锌合金熔点低，流动性好，易熔焊，钎焊和塑性加工，在大气中耐腐蚀，残废料便于回收和重熔；但蠕变强度低，易发生自然时效引起尺寸变化。熔融法制备，压铸或压力加工成材。按制造工艺可分为铸造锌合金和变形锌合金。特点：1.相对比重大。2.铸造性能好，可以压铸形状复杂、薄壁的精密件，铸件表面光滑。3.可进行表面处理：电镀、喷涂、喷漆、抛光、研磨等。4.熔化与压铸时不吸铁，不腐蚀压型，不粘模。5.有很好的常温机械性能和耐磨性。6.熔点低，在385℃熔化，容易压铸成型。锌合金的主要添加元素有铝、铜和镁等，锌合金按加工工艺可分为形变与铸造锌合金两类。铸造锌合金流动性和耐腐蚀性较好，适用于压铸仪表，汽车零件外壳等。不同的锌合金有不同的物理和机械特性，这样为压铸件设计提供了选择的空间。
强力旋压工艺主要依靠坯料厚度的变薄来实现成形的，坯料外径基本保持不变。通常在进行强力旋压时，旋轮加于坯料的压强要比普通旋压时大得多，坯料的变形情况和普通旋压时大得多，坯料的变形情况和普通旋压时也大不相同。在普通旋压过程中，坯料厚度变化不大，但直径变化很大——由大变小或由小变大。而在强旋压过程中，坯料直径基本保持不变，但厚度变化很大——由厚变薄。因此强力旋压又称为变薄旋压。从工艺过程分析认为：强力旋压属轴向延展，变形区材料处在二向或三向应力状态，因而可产生较高的变形程度。根据旋压件的类型和金属变形机理的差异，强力旋压可分为锥形件强力旋压——剪切旋压和筒形件强力旋压——挤出强旋等两种。强力旋压用于各种、锥体等形体的旋压成型壳体的加工技术，是一种比较成熟的方法和工艺，也叫烫板法。
发明内容
本发明要解决的技术问题是提供一种具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性、减少表面擦伤和划痕以及粘附性的锌合金强力旋压加工工艺润滑剂组合物。
本发明通过如下技术方案解决上述技术问题：
一种锌合金强力旋压加工工艺润滑剂组合物，采用MVI500基础油为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.03～0.3％
金属减活剂 0.03～0.1％
极压抗磨剂 3～5％
油性剂 3～6％
摩擦改进剂 0.5～1％
防锈剂 0.08～0.3％
抗氧抗腐剂 0.5～1.0％
粘度指数改进剂 2～4％
以上各组分的质量百分比总和是100％。
抗氧剂是2,6-二叔丁基混合酚T502A。
金属减活剂是质量比50％噻重氮的和50％的苯三唑衍生物T551复合。
极压抗磨剂是氯化石蜡T502。
油性剂是工业猪油。
于摩擦改进剂是硬脂酸锌。
防锈剂是质量比50％的甲基苯并三氮唑和50％的环烷酸锌T704复合。
抗氧抗腐剂是硫磷丁辛基锌盐T202。
粘度指数改进剂是乙丙共聚物T603D。
本发明的显著优点在于：
本发明的组合物具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性及粘附性，能减少表面擦伤和划痕。
具体实施方式
实施例1：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
MVI500基础油 余量
2,6-二叔丁基混合酚(T502A) 0.15％
质量比50％噻重氮的和50％的苯三唑衍生物(T551)复合 0.05％
氯化石蜡(T502) 4.0％
工业猪油 4.0％
硬脂酸锌 0.8％
质量比50％的甲基苯并三氮唑和50％的环烷酸锌(T704)复合 0.2％
硫磷丁辛基锌盐(T202) 0.8％
乙丙共聚物(T603D) 3.2％
以上各组分质量百分比含量总和为100％。
实施例2：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
MVI500基础油 余量
2,6-二叔丁基混合酚(T502A) 0.25％
质量比50％噻重氮的和50％的苯三唑衍生物(T551)复合 0.05％
氯化石蜡(T502) 4.4％
工业猪油 3.5％
硬脂酸锌 0.6％
质量比50％的甲基苯并三氮唑和50％的环烷酸锌(T704)复合 0.2％
硫磷丁辛基锌盐(T202) 0.9％
乙丙共聚物(T603D) 3.3％
以上各组分质量百分比含量总和为100％。
实施例3：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
MVI500基础油 余量
2,6-二叔丁基混合酚(T502A) 0.15％
质量比50％噻重氮的和50％的苯三唑衍生物(T551)复合 0.05％
氯化石蜡(T502) 4.8％
工业猪油 3.2％
硬脂酸锌 0.9％
质量比50％的甲基苯并三氮唑和50％的环烷酸锌(T704)复合 0.1％
硫磷丁辛基锌盐(T202) 0.9％
乙丙共聚物(T603D) 3.6％
以上各组分质量百分比含量总和为100％。
实施例1产品的主要技术指标
项目 指标
40℃运动粘度/(mm2﹒s-1) 97.9
闪点(开口)/℃ 248
倾点/℃ -9
粘度指数 121
腐蚀(铜片、100℃、3h)/级 1
抗乳化度82℃(40-37-3) 8
四球机试验，PD/N 886
烧结负荷，PD/N 6555
梯姆肯，N 286
水分，％ 痕迹
机械杂质，％ 无
氧化安定性，(旋转氧弹，150℃)，min 298
FZG，级 13
实施例2产品的主要技术指标
项目 指标
40℃运动粘度/(mm2﹒s-1) 101.5
闪点(开口)/℃ 242
倾点/℃ -8
粘度指数 112
腐蚀(铜片、100℃、3h)/级 1
抗乳化度82℃(40-37-3) 9
四球机试验，PD/N 881
烧结负荷，PD/N 6585
梯姆肯，N 279
水分，％ 痕迹
机械杂质，％ 无
氧化安定性，(旋转氧弹，150℃)，min 301
FZG，级 13
实施例3产品的主要技术指标
项目 指标
40℃运动粘度/(mm2﹒s-1) 99.5
闪点(开口)/℃ 232
倾点/℃ -8
粘度指数 116
腐蚀(铜片、100℃、3h)/级 1
抗乳化度82℃(40-37-3) 9
四球机试验，PD/N 896
烧结负荷，PD/N 6752
梯姆肯，N 301
水分，％ 痕迹
机械杂质，％ 无
氧化安定性，(旋转氧弹，150℃)，min 306
FZG，级 13

Claims (9)

1.一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于：采用MVI500基础油为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.03～0.3％ 金属减活剂 0.03～0.1％ 极压抗磨剂 3～5％ 油性剂 3～6％ 摩擦改进剂 0.5～1％ 防锈剂 0.08～0.3％ 抗氧抗腐剂 0.5～1.0％ 粘度指数改进剂 2～4％
以上各组分的质量百分比总和是100％。
2.如权利要求1所述的一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于抗氧剂是2,6-二叔丁基混合酚T502A。
3.如权利要求1所述的一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于金属减活剂是质量比50％噻重氮的和50％的苯三唑衍生物T551复合。
4.如权利要求1所述的一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于极压抗磨剂是氯化石蜡T502。
5.如权利要求1所述的一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于油性剂是工业猪油。
6.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于摩擦改进剂是硬脂酸锌。
7.如权利要求1所述的一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于防锈剂是质量比50％的甲基苯并三氮唑和50％的环烷酸锌T704复合。
8.如权利要求1所述的一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于抗氧抗腐剂是硫磷丁辛基锌盐T202。
9.如权利要求1所述的一种锌合金强力旋压加工工艺润滑剂组合物，其特征在于粘度指数改进剂是乙丙共聚物T603D。
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104862035A (zh) * 2015-06-05 2015-08-26 广西大学 冷旋压钛合金管润滑剂组合物

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104862035A (zh) * 2015-06-05 2015-08-26 广西大学 冷旋压钛合金管润滑剂组合物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
熊云等: "《油品应用及管理》", 30 May 2004, 中国石化出版社 *

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