CN106520307A - 一种锌合金旋压加工工艺润滑剂组合物 - Google Patents

一种锌合金旋压加工工艺润滑剂组合物 Download PDF

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CN106520307A
CN106520307A CN201610962499.3A CN201610962499A CN106520307A CN 106520307 A CN106520307 A CN 106520307A CN 201610962499 A CN201610962499 A CN 201610962499A CN 106520307 A CN106520307 A CN 106520307A
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lubricant composition
kirsite
processing technology
pressing processing
rotary pressing
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黄福川
李康春
邓富康
唐弓斌
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Guangxi University
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Abstract

本发明公开了一种锌合金旋压加工工艺润滑剂组合物，采用MIV750基础油作为基础油，配合多种复合添加剂。包括：抗氧剂、金属减活剂、油性剂、摩擦改进剂、抗磨剂、防锈剂、抗泡剂、抗氧抗腐剂、粘度指数改进剂等。本发明的组合物具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性、粘附性，减少表面擦伤和刮痕。

Description

一种锌合金旋压加工工艺润滑剂组合物
技术领域
本发明一种锌合金旋压加工工艺润滑剂组合物属于金属加工润滑剂领域。
背景技术
锌合金是以锌为基础加入其他元素组成的合金。常加的合金元素有铝、铜、镁、镉、铅、钛等低温锌合金。锌合金熔点低，流动性好，易熔焊，钎焊和塑性加工，在大气中耐腐蚀，残废料便于回收和重熔；但蠕变强度低，易发生自然时效引起尺寸变化。熔融法制备，压铸或压力加工成材。按制造工艺可分为铸造锌合金和变形锌合金。特点：1.相对比重大。2.铸造性能好，可以压铸形状复杂、薄壁的精密件，铸件表面光滑。3.可进行表面处理：电镀、喷涂、喷漆、抛光、研磨等。4.熔化与压铸时不吸铁，不腐蚀压型，不粘模。5.有很好的常温机械性能和耐磨性。6.熔点低，在385℃熔化，容易压铸成型。锌合金的主要添加元素有铝、铜和镁等，锌合金按加工工艺可分为形变与铸造锌合金两类。铸造锌合金流动性和耐腐蚀性较好，适用于压铸仪表，汽车零件外壳等。不同的锌合金有不同的物理和机械特性，这样为压铸件设计提供了选择的空间。
旋压技术起源于古代制陶工艺，是一种综合了锻造、挤压、拉件、弯曲、环轧、横轧和滚挤等工艺特点的少无切削加工的先进工艺。通常将金属简坯、平板毛坯或预制坯用尾顶顶紧在旋压机模上，由主轴带动芯棒和坯料旋转；同时旋压轮从毛坯一侧将材料挤压在旋转的芯模上，使材料产生逐点连续的塑性变形，从而获得各种母线形状的空心旋转体零件。根据旋压加工过程中的毛坯厚度变化情况，把旋压工艺分为普通旋压和强力旋压两种。
普通旋压简称普旋。普旋过程中毛坯的厚度基本保持不变，成形主要依靠坯料沿圆周的收缩及沿半径方向上伴长不变形来实现。其主要特征是在成形过程中，可以明显看出坯料外径的变化。普通旋压的基本方式有：拉深旋压(拉旋)、缩径旋压(缩旋)和扩径旋压(扩旋)等三种。锌合金普通旋压的润滑剂要求解决表面质量要求高，防锈，下压加工力大，不易对称成型的技术困难。
发明内容
本发明要解决的技术问题是提供一种具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性、粘附性，减少表面擦伤和刮痕的锌合金旋压加工工艺润滑剂组合物。
本发明通过如下技术方案解决上述技术问题：
一种锌合金旋压加工工艺润滑剂组合物，采用MIV750基础油为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.05～0.2％
金属减活剂 0.03～0.2％
油性剂 3～6％
抗磨剂 2～4％
摩擦改进剂 1～2％
抗氧抗腐剂 0.3～1％
抗泡剂 10～50ppm
防锈剂 0.1～0.3％
增粘剂 3～5％
以上各组分的质量百分比总和是100％。
抗氧剂是酚酯型抗氧剂T508。金属减活剂是苯三唑衍生物T551。油性剂是大豆油；
抗磨剂是氯化石蜡T301。摩擦改进剂是硬脂酸锌。抗氧抗腐剂是硫磷丁辛基锌盐T202。
抗泡剂是甲基硅油T901。防锈剂是质量比50％的石油磺酸钠T701和50％的环烷酸锌T704复合。粘度指数改进剂是乙丙共聚物T611。
本发明的显著优点在于：本发明的组合物具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性、粘附性，减少表面擦伤和刮痕。
具体实施方式
实施例1：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比
MIV750基础油 余量
酚酯型抗氧剂(T508) 0.1％
苯三唑衍生物(T551) 0.1％
大豆油 5.0％
氯化石蜡(T301) 3.0％
硬脂酸锌 2.0％
硫磷丁辛基锌盐(T202) 0.5％
甲基硅油(T901) 20ppm
质量比50％的石油磺酸钠(T701)和50％的环烷酸锌(T704)复合 0.2％
乙丙共聚物(T611) 4.0％
以上各组分质量百分比含量总和为100％。
实施例2：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比
MIV750基础油 余量
酚酯型抗氧剂(T508) 0.15％
苯三唑衍生物(T551) 0.15％
大豆油 4.0％
氯化石蜡(T301) 3.1％
硬脂酸锌 1.5％
硫磷丁辛基锌盐(T202) 0.8％
甲基硅油(T901) 20ppm
质量比50％的石油磺酸钠(T701)和50％的环烷酸锌(T704)复合 0.2％
乙丙共聚物(T611) 4.2％
以上各组分质量百分比含量总和为100％。
实施例3：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比
MIV750基础油 余量
酚酯型抗氧剂(T508) 0.15％
苯三唑衍生物(T551) 0.05％
大豆油 5.5％
氯化石蜡(T301) 2.5％
硬脂酸锌 1.5％
硫磷丁辛基锌盐(T202) 0.7％
甲基硅油(T901) 20ppm
质量比50％的石油磺酸钠(T701)和50％的环烷酸锌(T704)复合 0.5％
乙丙共聚物(T611) 3.5％
以上各组分质量百分比含量总和为100％。
实施例1产品的主要技术指标
项目 指标
40℃运动粘度/(mm2﹒s-1) 157.3
闪点(开口)/℃ 241
倾点/℃ -12
粘度指数 121
腐蚀(铜片、100℃、3h)/级 1
抗乳化度82℃(40-37-3) 12
四球机试验，Pb/N 685
烧结负荷，PD/N 4110
梯姆肯，N 245
机械杂质，％ 无
水分，％ 痕迹
氧化安定性(旋转氧弹法，150℃)/min 296
蒸发损失(Noack法,250℃,1h)(m),％ 10
实施例2产品的主要技术指标
项目 指标
40℃运动粘度/(mm2﹒s-1) 156.9
闪点(开口)/℃ 252
倾点/℃ -10
粘度指数 116
腐蚀(铜片、100℃、3h)/级 1
抗乳化度82℃(40-37-3) 11
四球机试验，Pb/N 668
烧结负荷，PD/N 4135
梯姆肯，N 253
机械杂质，％ 无
水分，％ 痕迹
氧化安定性(旋转氧弹法，150℃)/min 287
蒸发损失(Noack法,250℃,1h)(m),％ 11
实施例3产品的主要技术指标
项目 指标
40℃运动粘度/(mm2﹒s-1) 158.5
闪点(开口)/℃ 247
倾点/℃ -8
粘度指数 135
腐蚀(铜片、100℃、3h)/级 1
抗乳化度82℃(40-37-3) 13
四球机试验，Pb/N 795
烧结负荷，PD/N 4150
梯姆肯，N 288
机械杂质，％ 无
水分，％ 痕迹
氧化安定性(旋转氧弹法，150℃)/min 310
蒸发损失(Noack法,250℃,1h)(m),％ 7

Claims (10)

1.一种锌合金旋压加工工艺润滑剂组合物，其特征在于：采用MIV750基础油为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.05～0.2％ 金属减活剂 0.03～0.2％ 油性剂 3～6％ 抗磨剂 2～4％ 摩擦改进剂 1～2％ 抗氧抗腐剂 0.3～1％ 抗泡剂 10～50ppm 防锈剂 0.1～0.3％ 增粘剂 3～5％
以上各组分的质量百分比总和是100％。
2.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于抗氧剂是酚酯型抗氧剂T508。
3.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于金属减活剂是苯三唑衍生物T551。
4.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于油性剂是大豆油。
5.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于抗磨剂是氯化石蜡T301。
6.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于摩擦改进剂是硬脂酸锌。
7.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于抗氧抗腐剂是硫磷丁辛基锌盐T202。
8.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于抗泡剂是甲基硅油T901。
9.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于防锈剂是质量比50％的石油磺酸钠T701和50％的环烷酸锌T704复合。
10.如权利要求1所述的一种锌合金旋压加工工艺润滑剂组合物，其特征在于粘度指数改进剂是乙丙共聚物T611。
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CN108865364A (zh) * 2018-07-26 2018-11-23 中国石油化工股份有限公司 钢管扩径油组合物及其用途
CN113444565A (zh) * 2021-07-26 2021-09-28 湖南金裕环保科技有限公司 一种高温水基芯棒润滑剂、制备方法及其应用

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CN108865364A (zh) * 2018-07-26 2018-11-23 中国石油化工股份有限公司 钢管扩径油组合物及其用途
CN108865364B (zh) * 2018-07-26 2021-11-12 中国石油化工股份有限公司 钢管扩径油组合物及其用途
CN113444565A (zh) * 2021-07-26 2021-09-28 湖南金裕环保科技有限公司 一种高温水基芯棒润滑剂、制备方法及其应用

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