CN106544115A - 一种钴合金磨削加工工艺润滑剂组合物 - Google Patents

一种钴合金磨削加工工艺润滑剂组合物 Download PDF

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CN106544115A
CN106544115A CN201610962471.XA CN201610962471A CN106544115A CN 106544115 A CN106544115 A CN 106544115A CN 201610962471 A CN201610962471 A CN 201610962471A CN 106544115 A CN106544115 A CN 106544115A
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cobalt alloy
lubricant compositions
grinding technique
alloy grinding
technique lubricant
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黄福川
张姗姗
肖锋
唐弓斌
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Guangxi University
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Abstract

本发明公开了一种钴合金磨削加工工艺润滑剂组合物，采用质量比50％的HVIH4基础油与50％的聚α‑烯烃基础油复合为基础油，配合多种复合添加剂。包括：抗氧剂、金属减活剂、油性剂、摩擦改进剂、极压剂、抗磨剂、防锈剂、抗泡剂、抗乳化剂、分散剂、抗氧抗腐剂等。本发明的组合物具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性、低挥发性、低烟雾性，减少加工件表面划痕和刮伤以及热容量大。

Description

一种钴合金磨削加工工艺润滑剂组合物
技术领域
本发明一种钴合金磨削加工工艺润滑剂组合物属于金属加工润滑剂领域。
背景技术
钴基高温合金是高温合金中的一种，它是以钴作为主要成分，含有相当数量的镍、铬、钨和少量的钼、铌、钽、钛、镧等合金元素，偶而也还含有铁的一类合金。根据合金中成分不同，它们可以制成焊丝，粉末用于硬面堆焊，热喷涂、喷焊等工艺，也可以制成铸锻件和粉末冶金件。与其它高温合金不同，钴基高温合金不是由与基体牢固结合的有序沉淀相来强化，而是由已被固溶强化的奥氏体fcc基体和基体中分布少量碳化物组成。钴基高温合金中碳化物的热稳定性较好。钴基高温合金是含钴量40～65％的奥氏体高温合金。在730～1100℃条件下具有一定的高温强度、良好的抗热腐蚀和抗氧化能力。适于制作航空喷气发动机、工业燃气轮机、舰船燃气轮机的导向叶片和喷嘴导叶以及柴油机喷嘴等。
磨削液是一种用在金属磨削加工过程中，用来冷却和润滑刀具与加工件的工业用液体。金属切削是重要的机械加工手段，按其所用切削工具类型可分为两大类。一类是用刀具进行切削加工，如车削、钻削、镗削、铣削、创削和拉削等；另一类是用磨料进行的磨削加工，如磨削、珩削、研削和超精研加工等。按加工苛刻程度排列，切削加工可分为16种，其中磨削排名第一。切削润滑剂以使用上分为两大类，即切削润滑剂，都需要有良好的冷却和润滑效果，但两种加工方式存在着根本的不同。在磨削加工中，磨削速度高达1000r/min以上，温度超过1100℃，因此要求有更高的冷却性能；另外，磨具(如砂轮)孔隙容易堵塞，也因此需要更高的清净性。钴合金磨削加工工艺润滑剂要求能提高高强度、耐热、耐蚀、抗氧化合金材料的磨削、成型效率，提高刀具的使用寿命及加工件质量；同时保证磨屑、排渣过程的工业安全。
发明内容
本发明要解决的技术问题是提供一种具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性、低挥发性、低烟雾性，减少加工件表面划痕和刮伤以及热容量大的钴合金磨削加工工艺润滑剂组合物。
本发明通过如下技术方案解决上述技术问题：
一种钴合金磨削加工工艺润滑剂组合物，采用质量比50％的HVIH4基础油与50％的聚α-烯烃基础油复合为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.04％～0.2％
金属减活剂 0.08％～0.3％
油性剂 6％～8％
摩擦改进剂 2％～3％
极压剂 4％～6％
抗磨剂 4％～6％
防锈剂 0.05％～0.2％
抗泡剂 20ppm～40ppm
抗乳化剂 0.08％～0.2％
分散剂 2％～4％
抗氧抗腐剂 0.8％～1.5％
以上各组分的质量百分比总和是100％。
抗氧剂是质量比50％的酚酯型抗氧剂T508与50％的N-苯基-α-萘胺复合。
金属减活剂是质量比50％的苯三唑衍生物T551与50％的噻二唑衍生物T561复合。
油性剂是硫化棉籽油T404。摩擦改进剂是磷酸酯T451。
极压剂是氯化石蜡T301。抗磨剂是硫磷酸含氮衍生物T305。
防锈剂是质量比50％的苯并三氮唑与50％的羊毛脂复合。
抗泡剂是甲基硅油。抗乳化剂是胺与环氧化合物缩合物T1001。
分散剂是聚异丁烯丁二酰亚胺T155。抗氧抗腐剂是硫磷双辛基碱性锌盐T203。
本发明的优点在于：本发明的组合物具有良好的冷却性、润滑性、扩散性、清洗性、防锈性、抗氧防腐性、低挥发性、低烟雾性，减少加工件表面划痕和刮伤以及热容量大，能提高高强度、耐热、耐蚀、抗氧化合金材料的磨削、成型效率，提高刀具的使用寿命及加工件质量；同时保证磨屑、排渣过程的工业安全。
具体实施方式
实施例1：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例2：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例3：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例3产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 15.7
粘度指数 149
闪点(开口)/℃ 237
凝点/℃ -43
摩擦系数 0.036
氧化安定性(旋转氧弹，150℃)/min 347
剪切安定性(40℃运动粘度下降率)/％ 3.0
四球机试验/Pb/N 955
烧结负荷/PD/N 6785
梯姆肯/N 344
FZG/级 14
腐蚀性(铜片，100℃，3h)/级 1
抗乳化度，54℃(40-37-3)/min 6
机械杂质，％ 无
水分，％ 痕迹
蒸发损失(Noack法,250℃,1h)(m),％ 5.3
实施例2产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 14.9
粘度指数 156
闪点(开口)/℃ 237
凝点/℃ -44
摩擦系数 0.034
氧化安定性(旋转氧弹，150℃)/min 351
剪切安定性(40℃运动粘度下降率)/％ 3.3
四球机试验/Pb/N 948
烧结负荷/PD/N 6725
梯姆肯/N 341
FZG/级 14
腐蚀性(铜片，100℃，3h)/级 1
抗乳化度，54℃(40-37-3)/min 6
机械杂质，％ 无
水分，％ 痕迹
蒸发损失(Noack法,250℃,1h)(m),％ 5.5
实施例1产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 15.1
粘度指数 151
闪点(开口)/℃ 247
凝点/℃ -44
摩擦系数 0.035
氧化安定性(旋转氧弹，150℃)/min 347
剪切安定性(40℃运动粘度下降率)/％ 3.1
四球机试验/Pb/N 965
烧结负荷/PD/N 6765
梯姆肯/N 341
FZG/级 14
腐蚀性(铜片，100℃，3h)/级 1
抗乳化度，54℃(40-37-3)/min 6
机械杂质，％ 无
水分，％ 痕迹
蒸发损失(Noack法,250℃,1h)(m),％ 5.1

Claims (8)

1.一种钴合金磨削加工工艺润滑剂组合物，其特征在于是：采用质量比50％的HVIH4基础油与50％的聚α-烯烃基础油复合为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.04％～0.2％ 金属减活剂 0.08％～0.3％ 油性剂 6％～8％ 摩擦改进剂 2％～3％ 极压剂 4％～6％ 抗磨剂 4％～6％ 防锈剂 0.05％～0.2％ 抗泡剂 20ppm～40ppm 抗乳化剂 0.08％～0.2％ 分散剂 2％～4％ 抗氧抗腐剂 0.8％～1.5％
以上各组分的质量百分比总和是100％。
2.如权利要求1所述的一种钴合金磨削加工工艺润滑剂组合物，其特征在于抗氧剂是质量比50％的酚酯型抗氧剂T508与50％的N-苯基-α-萘胺复合。
3.如权利要求1所述的一种钴合金磨削加工工艺润滑剂组合物，其特征在于金属减活剂是质量比50％的苯三唑衍生物T551与50％的噻二唑衍生物T561复合。
4.如权利要求1所述的一种钴合金磨削加工工艺润滑剂组合物，其特征在于油性剂是硫化棉籽油T404；摩擦改进剂是磷酸酯T451。
5.如权利要求1所述的一种钴合金磨削加工工艺润滑剂组合物，其特征在于极压剂是氯化石蜡T301；抗磨剂是硫磷酸含氮衍生物T305。
6.如权利要求1所述的一种钴合金磨削加工工艺润滑剂组合物，其特征在于防锈剂是质量比50％的苯并三氮唑与50％的羊毛脂复合。
7.如权利要求1所述的一种钴合金磨削加工工艺润滑剂组合物，其特征在于抗泡剂是甲基硅油；抗乳化剂是胺与环氧化合物缩合物T1001。
8.如权利要求1所述的一种钴合金磨削加工工艺润滑剂组合物，其特征在于分散剂是聚异丁烯丁二酰亚胺T155；抗氧抗腐剂是硫磷双辛基碱性锌盐T203。
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