CN106520340A - 一种锰合金切削加工工艺润滑剂组合物 - Google Patents

一种锰合金切削加工工艺润滑剂组合物 Download PDF

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CN106520340A
CN106520340A CN201610966162.XA CN201610966162A CN106520340A CN 106520340 A CN106520340 A CN 106520340A CN 201610966162 A CN201610966162 A CN 201610966162A CN 106520340 A CN106520340 A CN 106520340A
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manganese alloy
alloy cutting
lubricant compositions
cutting technology
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黄福川
陈帆
陈一帆
唐弓斌
肖锋
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Guangxi University
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Abstract

本发明公开了一种锰合金切削加工工艺润滑剂组合物，采用22号全损耗系统用油为基础油，配合多种复合添加剂。包括：抗氧剂、金属减活剂、油性剂、摩擦改进剂、极压剂、抗磨剂、防锈剂、抗泡剂、抗乳化剂、分散剂、抗氧抗腐剂等。本发明的组合物具有良好的冷却、润滑、扩散、清洗、防腐、低挥发性能，热容量大，对油漆的相溶性良好，表面光洁度高，抗腐蚀周期长。

Description

一种锰合金切削加工工艺润滑剂组合物
技术领域
本发明一种锰合金切削加工工艺润滑剂组合物属于金属加工润滑剂领域。
背景技术
锰合金是由锰、硅、铁及少量碳和其它元素组成的合金。主要产品有硅锰和锰铁，锰铁又分为高碳锰铁(C含量7％～7.5％)中碳锰铁(C含量1％～1.5％)低碳锰铁(C含量0.2％～0.7％)。
金属的加工方法繁多，但切削加工始终是最常见，应用最广泛的一种。金属切削是重要的机械加工手段，按其所用切削工具类型可分为两大类；一类是用刀具进行的切削加工；另一类是用磨料进行磨削加工。金属切削和磨削加工是一种利用带刃口的切削工具(刀具或砂轮)在切削机床上将工件的多余金属切去，从而是工件获得规则的几何形状，尺寸精度和表面质量的加工方法。金属切削过程通常可分为两个阶段，即切削的产生和及时清除。这两个阶段存在着刀具与工件、刀具与切屑之间的摩擦，这种摩擦消耗的能量转变为热，它会影响加工效率和工件质量。由于严重的摩擦产生大量的热，使刀具和工件过热，降低刀具寿命，影响产品精度。为了冷却和润滑刀具及工件，必须使用切削润滑剂以及时带走切削产生的热量，降低刀具和工件的温度并起到润滑作用；提高工件表面光洁度，并延长刀具的使用寿命。
切削油与普通润滑油使用工况不同，普通润滑油是处在反复移动的不变摩擦面之间，尽管有的压力很大，但容易形成润滑油膜。而切削油则是时时接触切削所形成的新鲜表面，加工面连续发生弹性形变，因而刀具与被加工面间所承受的压力要比一般润滑状态大得多。锰合金切削加工工艺润滑剂是要提高高强度、耐热、耐蚀、抗热氧合金材料的切削、成型效率，提高刀具的使用寿命及加工件质量；同时保证切屑、排渣过程的工业安全及防护。
发明内容
本发明要解决的技术问题是提供一种具有良好的冷却、润滑、扩散、清洗、防腐、低挥发性能，热容量大，对油漆的相溶性良好，表面光洁度高，抗腐蚀周期长的锰合金切削加工工艺润滑剂组合物。
本发明通过如下技术方案解决上述技术问题：
一种锰合金切削加工工艺润滑剂组合物，采用22号全损耗系统用油为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.06％～0.2％
金属减活剂 0.05％～0.2％
油性剂 4％～8％
摩擦改进剂 0.5％～1.5％
极压剂 3％～6％
抗磨剂 3％～5％
防锈剂 0.06％～0.2％
抗泡剂 10ppm～30ppm
抗乳化剂 0.08％～0.3％
分散剂 1％～4％
抗氧抗腐剂 0.5％～1.5％
以上各组分的质量百分比总和是100％。
抗氧剂是质量比50％的硫化烷基酚T504与50％的含铜抗氧剂T542复合。
金属减活剂是苯三唑衍生物T551。
油性剂是棕榈油。
摩擦改进剂是苯三唑脂肪酸胺盐T406。
极压剂是氯化石蜡T302。
抗磨剂是硫化异丁烯T321。
防锈剂是质量比50％的石油磺酸钡T701与50％的羊毛脂复合。
抗泡剂是甲基硅油。
抗乳化剂是聚醚高分子化合物DL32。
分散剂是硼化聚异丁烯基丁二酰亚胺T162。
抗氧抗腐剂是硫磷丁辛基锌盐T202。
本发明的显著优点：本发明的组合物具有良好的冷却、润滑、扩散、清洗、防腐、低挥发性能，热容量大，对油漆的相溶性良好，表面光洁度高，抗腐蚀周期长；稳定性、润滑性、抗腐蚀性能好，热氧化安定性优良。
具体实施方式
实施例1：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
22号全损耗系统用油 余量
质量比50％的硫化烷基酚(T504)与50％的含铜抗氧剂(T542)复合 0.06％
苯三唑衍生物(T551) 0.05％
棕榈油 4％
苯三唑脂肪酸胺盐(T406) 0.5％
氯化石蜡(T302) 3％
硫化异丁烯(T321) 3％
质量比50％的石油磺酸钡(T701)与50％的羊毛脂复合 0.06％
甲基硅油 10ppm
聚醚高分子化合物(DL32) 0.08％
硼化聚异丁烯基丁二酰亚胺(T162) 1％
硫磷丁辛基锌盐(T202) 0.5％
以上各组分质量百分比含量总和为100％。
实施例2：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
22号全损耗系统用油 余量
质量比50％的硫化烷基酚(T504)与50％的含铜抗氧剂(T542)复合 0.1％
苯三唑衍生物(T551) 0.1％
棕榈油 6％
苯三唑脂肪酸胺盐(T406) 1％
氯化石蜡(T302) 4％
硫化异丁烯(T321) 4％
质量比50％的石油磺酸钡(T701)与50％的羊毛脂复合 0.1％
甲基硅油 20ppm
聚醚高分子化合物(DL32) 0.2％
硼化聚异丁烯基丁二酰亚胺(T162) 2％
硫磷丁辛基锌盐(T202) 1％
以上各组分质量百分比含量总和为100％。
实施例3：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
22号全损耗系统用油 余量
质量比50％的硫化烷基酚(T504)与50％的含铜抗氧剂(T542)复合 0.2％
苯三唑衍生物(T551) 0.2％
棕榈油 8％
苯三唑脂肪酸胺盐(T406) 1.5％
氯化石蜡(T302) 6％
硫化异丁烯(T321) 5％
质量比50％的石油磺酸钡(T701)与50％的羊毛脂复合 0.2％
甲基硅油 30ppm
聚醚高分子化合物(DL32) 0.3％
硼化聚异丁烯基丁二酰亚胺(T162) 4％
硫磷丁辛基锌盐(T202) 1.5％
以上各组分质量百分比含量总和为100％。
实施例3产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 21.8
闪点(开口)/℃ 177
凝点/℃ -13
粘度指数 92
摩擦系数 0.039
氧化安定性(旋转氧弹，150℃)/min 279
剪切安定性(40℃运动粘度下降率)/％ 4.2
四球机试验/Pb/N 879
烧结负荷/PD/N 6725
梯姆肯/N 306
FZG/级 13
腐蚀性(铜片，100℃，3h)/级 1
抗乳化度，54℃(40-37-3)/min 12
机械杂质，％ 无
水分，％ 痕迹
蒸发损失(Noack法,250℃,1h)(m),％ 8.8
实施例2产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 23.6
闪点(开口)/℃ 187
凝点/℃ -15
粘度指数 91
摩擦系数 0.041
氧化安定性(旋转氧弹，150℃)/min 271
剪切安定性(40℃运动粘度下降率)/％ 3.9
四球机试验/Pb/N 885
烧结负荷/PD/N 6775
梯姆肯/N 314
FZG/级 13
腐蚀性(铜片，100℃，3h)/级 1
抗乳化度，54℃(40-37-3)/min 14
机械杂质，％ 无
水分，％ 痕迹
蒸发损失(Noack法,250℃,1h)(m),％ 9.2
实施例1产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 22.3
闪点(开口)/℃ 178
凝点/℃ -12
粘度指数 95
摩擦系数 0.040
氧化安定性(旋转氧弹，150℃)/min 272
剪切安定性(40℃运动粘度下降率)/％ 4.1
四球机试验/Pb/N 872
烧结负荷/PD/N 6712
梯姆肯/N 296
FZG/级 13
腐蚀性(铜片，100℃，3h)/级 1
抗乳化度，54℃(40-37-3)/min 10
机械杂质，％ 无
水分，％ 痕迹
蒸发损失(Noack法,250℃,1h)(m),％ 8.6

Claims (9)

1.一种锰合金切削加工工艺润滑剂组合物，其特征在于：采用22号全损耗系统用油为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.06％～0.2％ 金属减活剂 0.05％～0.2％ 油性剂 4％～8％ 摩擦改进剂 0.5％～1.5％ 极压剂 3％～6％ 抗磨剂 3％～5％ 防锈剂 0.06％～0.2％ 抗泡剂 10ppm～30ppm 抗乳化剂 0.08％～0.3％ 分散剂 1％～4％ 抗氧抗腐剂 0.5％～1.5％
以上各组分的质量百分比总和是100％。
2.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于抗氧剂是质量比50％的硫化烷基酚T504与50％的含铜抗氧剂T542复合；金属减活剂是苯三唑衍生物T551。
3.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于油性剂是棕榈油；摩擦改进剂是苯三唑脂肪酸胺盐T406。
4.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于极压剂是氯化石蜡T302；抗磨剂是硫化异丁烯T321。
5.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于防锈剂是质量比50％的石油磺酸钡T701与50％的羊毛脂复合。
6.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于抗泡剂是甲基硅油。
7.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于抗乳化剂是聚醚高分子化合物DL32。
8.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于分散剂是硼化聚异丁烯基丁二酰亚胺T162。
9.如权利要求1所述的一种锰合金切削加工工艺润滑剂组合物，其特征在于抗氧抗腐剂是硫磷丁辛基锌盐T202。
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