CN106543876A - A kind of fire prevention nano-polyurethane floor paint - Google Patents

A kind of fire prevention nano-polyurethane floor paint Download PDF

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Publication number
CN106543876A
CN106543876A CN201610933388.XA CN201610933388A CN106543876A CN 106543876 A CN106543876 A CN 106543876A CN 201610933388 A CN201610933388 A CN 201610933388A CN 106543876 A CN106543876 A CN 106543876A
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CN
China
Prior art keywords
parts
nano
floor paint
fire prevention
polyurethane
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610933388.XA
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Chinese (zh)
Inventor
陈健
张建光
杨文乾
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Suzhou Futong New Material and High Tech Co Ltd
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Suzhou Futong New Material and High Tech Co Ltd
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Priority to CN201610933388.XA priority Critical patent/CN106543876A/en
Publication of CN106543876A publication Critical patent/CN106543876A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The nano-polyurethane floor paint the invention discloses one kind is prevented fires, the floor paint include following parts by weight of component:70 90 parts of waterborne polyurethane resin, 5 11 parts of VTES, 4.5 6.5 parts of nano magnesia, 46 parts of actinolite powder, 37 parts of zinc naphthenate, 48 parts of divinyl dimethoxysilane, 59 parts of polyether Glycols, 7 10 parts of pure-acrylic emulsion, 49 parts of tetraethyl orthosilicate, 2.4 3.6 parts of DBSA, 14 parts of butyl titanate, 58 parts of lauryl magnesium sulfate, 59 parts of Nano titanium nitride.Present invention fire prevention nano-polyurethane floor paint is solvent-free, nontoxic, environmental protection, it is to avoid harm of the organic solvent to health, is capable of achieving construction and the complete feature of environmental protection applied.The characteristics of with preferable resistance to water, fire line, high coloring power, color inhibition.Layer surface brightness is higher, color and luster is vivider, physical property more preferably.

Description

A kind of fire prevention nano-polyurethane floor paint
Technical field
The present invention relates to a kind of floor paint, more particularly to a kind of fire prevention nano-polyurethane floor paint.
Background technology
Fire prevention floor paint has globality, and seamless, environmental protection, nontoxic non-stimulated peculiar smell, wear-resistant, anti-corrosion, waterproof are prevented Dirt, the advantages of appearance is beautiful.Fire prevention floor paint is liquid form, in uniformly densely solid film-shaped after the completion of construction, can be extensive Fabrication facility floor, residential building earth's surface or metope, institutional settings, warehouse are applied to, the vast field to fire protection requirement is waited.Wherein prevent Fiery nano-polyurethane floor paint has preferable mechanical performance, and general hardness is all higher, but also with wear and shock-resistant Ability, chemical resistance are good, good weatherability.And terrace paint coating is developed so far, because which has excellent Physical Mechanical The performances such as energy, electrical insulation capability, resistance to chemical attack, are widely applied in the every field of national economy, and its yield is continuous Increase, quality is improved constantly, new varieties are continued to bring out.With the continuous development of market economy, competition is also to grow in intensity, and that is just Needs are developed in the technology and production capacity of enterprise, promote coating to update, and nano paint, with existing floor paint Raw materials used to have compared unrivaled ultra-fine property and uniqueness, its product combination property and quality are significantly better than its similar product Product, and cost is less than traditional product, has caused the great attention of countries in the world, and by leader's building coating industry new trend, into For the new fashion of decoration industry, nanometer terrace paint coating has become the inexorable trend of terrace paint coating development.Accordingly, it would be desirable to develop A kind of fire prevention nano-polyurethane floor paint that can overcome problem described above.
The content of the invention
It is an object of the invention to provide a kind of fire prevention nano-polyurethane floor paint.
To achieve these goals, the nano-polyurethane floor paint the invention provides one kind is prevented fires, comprising following weight portion Component:Waterborne polyurethane resin 70-90 parts, VTES 5-11 parts, nano magnesia 4.5-6.5 parts, sun rise Stone flour 4-6 parts, zinc naphthenate 3-7 parts, divinyl dimethoxysilane 4-8 parts, polyether Glycols 5-9 parts, pure-acrylic emulsion 7- 10 parts, tetraethyl orthosilicate 4-9 parts, DBSA 2.4-3.6 parts, butyl titanate 1-4 parts, lauryl magnesium sulfate 5-8 parts, Nano titanium nitride 5-9 parts.
Which also includes HMDS 4-9 parts.
Which also includes nano-pearl rock 8-15 parts.
Which also includes carboxymethylcellulose calcium 10-15 parts.
Beneficial effect:Present invention fire prevention nano-polyurethane floor paint is solvent-free, nontoxic, environmental protection, it is to avoid have Harm of the machine solvent to health, is capable of achieving construction and the complete feature of environmental protection applied.With preferable resistance to water, fire line, The characteristics of high coloring power, color inhibition.Layer surface brightness is higher, color and luster is vivider, physical property more preferably.
Specific embodiment
Embodiment 1
The fire prevention nano-polyurethane floor paint of the present embodiment, comprising following parts by weight of component:70 parts of waterborne polyurethane resin, ethene 5 parts of ethyl triethoxy silicane alkane, 4.5 parts of nano magnesia, actinolite powder 4-6 parts, 3 parts of zinc naphthenate, divinyl dimethoxy 4 parts of silane, 5 parts of polyether Glycols, 7 parts of pure-acrylic emulsion, 4 parts of tetraethyl orthosilicate, 2.4 parts of DBSA, butyl titanate 1 Part, 5 parts of lauryl magnesium sulfate, 5 parts of Nano titanium nitride.Above-mentioned material is put in agitator tank, agitator tank temperature is 50 DEG C, stirring Mix, be obtained after normal temperature is cooled to after mixing.
The performance that the present embodiment is obtained floor paint is measured, the performance test data for detecting are:Paint film is smooth, light It is sliding, pencil hardness:1H, adhesive force:≤ 1 grade, pliability:≤ 2mm, resistance to impact:>=30mm, compression strength:80MPa, resistance to combustion Time:>=30min, flame propagation ratio:≤ 20, burning quality loss:< 4g, char volume≤20cm3, resistance to water, immersion 7 After it:Unchanged, bubble-free is wrinkle resistant, do not fall off;Salt fog resistance 5 days:1 grade.
Embodiment 2
The fire prevention nano-polyurethane floor paint of the present embodiment, comprising following parts by weight of component:90 parts of waterborne polyurethane resin, ethene 11 parts of ethyl triethoxy silicane alkane, 6.5 parts of nano magnesia, 46 parts of actinolite powder, 7 parts of zinc naphthenate, divinyl dimethoxy 8 parts of silane, polyether Glycols 5-9 parts, 10 parts of pure-acrylic emulsion, 9 parts of tetraethyl orthosilicate, 3.6 parts of DBSA, metatitanic acid fourth 4 parts of ester, 8 parts of lauryl magnesium sulfate, 9 parts of Nano titanium nitride, 9 parts of HMDS.Above-mentioned material is put in agitator tank, Agitator tank temperature is 80 DEG C, stirs and evenly mixs, is obtained after being cooled to normal temperature after mixing.
The performance that the present embodiment is obtained floor paint is measured, the performance test data for detecting are:Paint film is smooth, light It is sliding, pencil hardness:1H, adhesive force:≤ 1 grade, pliability:≤ 2mm, resistance to impact:>=30mm, compression strength:82MPa, resistance to combustion Time:>=30min, flame propagation ratio:≤ 20, burning quality loss:< 4g, char volume≤20cm3, resistance to water, immersion 7 After it:Unchanged, bubble-free is wrinkle resistant, do not fall off;Salt fog resistance 5 days:1 grade.
Embodiment 3
The fire prevention nano-polyurethane floor paint of the present embodiment, comprising following parts by weight of component:70 parts of waterborne polyurethane resin, ethene 5 parts of ethyl triethoxy silicane alkane, 4.5 parts of nano magnesia, actinolite powder 4-6 parts, 3 parts of zinc naphthenate, divinyl dimethoxy 4 parts of silane, 5 parts of polyether Glycols, 7 parts of pure-acrylic emulsion, 4 parts of tetraethyl orthosilicate, 2.4 parts of DBSA, butyl titanate 1 Part, 5 parts of lauryl magnesium sulfate, 5 parts of Nano titanium nitride, 4 parts of HMDS, 8 parts of nano-pearl rock.Above-mentioned material is put Enter in agitator tank, agitator tank temperature is 50 DEG C, stirs and evenly mixs, is obtained after being cooled to normal temperature after mixing.
The performance that the present embodiment is obtained floor paint is measured, the performance test data for detecting are:Paint film is smooth, light It is sliding, pencil hardness:1H, adhesive force:≤ 1 grade, pliability:≤ 2mm, resistance to impact:>=30mm, compression strength:85MPa, resistance to combustion Time:>=30min, flame propagation ratio:≤ 20, burning quality loss:< 4g, char volume≤20cm3, resistance to water, immersion 7 After it:Unchanged, bubble-free is wrinkle resistant, do not fall off;Salt fog resistance 5 days:1 grade.
Embodiment 4
The fire prevention nano-polyurethane floor paint of the present embodiment, comprising following parts by weight of component:90 parts of waterborne polyurethane resin, ethene 11 parts of ethyl triethoxy silicane alkane, 6.5 parts of nano magnesia, 46 parts of actinolite powder, 7 parts of zinc naphthenate, divinyl dimethoxy 8 parts of silane, polyether Glycols 5-9 parts, 10 parts of pure-acrylic emulsion, 9 parts of tetraethyl orthosilicate, 3.6 parts of DBSA, metatitanic acid fourth 4 parts of ester, 8 parts of lauryl magnesium sulfate, 9 parts of Nano titanium nitride, 9 parts of HMDS, 15 parts of nano-pearl rock, carboxymethyl are fine 15 parts of dimension element.Above-mentioned material is put in agitator tank, agitator tank temperature is 80 DEG C, is stirred and evenly mixed, after being cooled to normal temperature after mixing It is obtained.
The performance that the present embodiment is obtained floor paint is measured, the performance test data for detecting are:Paint film is smooth, light It is sliding, pencil hardness:1H, adhesive force:≤ 1 grade, pliability:≤ 2mm, resistance to impact:>=30mm, compression strength:88MPa, resistance to combustion Time:>=30min, flame propagation ratio:≤ 20, burning quality loss:< 4g, char volume≤20cm3, resistance to water, immersion 7 After it:Unchanged, bubble-free is wrinkle resistant, do not fall off;Salt fog resistance 5 days:1 grade.
The above, is only presently preferred embodiments of the present invention, not makees any pro forma restriction to the present invention, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people Member, in the range of without departing from technical solution of the present invention, when making a little change or modification using the technology contents of the disclosure above For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention Any simple modification, equivalent variations and the modification made to above example, still falls within the scope of technical solution of the present invention It is interior.

Claims (4)

1. a kind of fire prevention nano-polyurethane floor paint, it is characterised in that comprising following parts by weight of component:Waterborne polyurethane resin 70- 90 parts, VTES 5-11 parts, nano magnesia 4.5-6.5 parts, actinolite powder 4-6 parts, zinc naphthenate 3-7 Part, divinyl dimethoxysilane 4-8 parts, polyether Glycols 5-9 parts, pure-acrylic emulsion 7-10 parts, tetraethyl orthosilicate 4-9 parts, DBSA 2.4-3.6 parts, butyl titanate 1-4 parts, lauryl magnesium sulfate 5-8 parts, Nano titanium nitride 5-9 parts.
2. the fire prevention nano-polyurethane floor paint according to claim 1, it is characterised in that:Which also includes two silicon of hexamethyl Azane 4-9 parts.
3. the fire prevention nano-polyurethane floor paint according to claim 2, it is characterised in that:Which also includes nano-pearl rock 8-15 parts.
4. it is according to claim 3 fire prevention nano-polyurethane floor paint, it is characterised in that:Which also includes carboxymethyl cellulose Plain 10-15 parts.
CN201610933388.XA 2016-10-25 2016-10-25 A kind of fire prevention nano-polyurethane floor paint Pending CN106543876A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610933388.XA CN106543876A (en) 2016-10-25 2016-10-25 A kind of fire prevention nano-polyurethane floor paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610933388.XA CN106543876A (en) 2016-10-25 2016-10-25 A kind of fire prevention nano-polyurethane floor paint

Publications (1)

Publication Number Publication Date
CN106543876A true CN106543876A (en) 2017-03-29

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Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260446A (en) * 2011-04-29 2011-11-30 广州立邦涂料有限公司 Hydrophobic single-component polyurethane lawn paint and preparing method thereof
CN105885589A (en) * 2016-06-20 2016-08-24 吴国强 Novel acrylic fireproof floor paint
CN105907145A (en) * 2016-06-14 2016-08-31 苏州科淼新材料有限公司 Epoxy fireproof terrace paint
CN105925159A (en) * 2016-06-14 2016-09-07 苏州科淼新材料有限公司 Polyurethane anticorrosive floor paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260446A (en) * 2011-04-29 2011-11-30 广州立邦涂料有限公司 Hydrophobic single-component polyurethane lawn paint and preparing method thereof
CN105907145A (en) * 2016-06-14 2016-08-31 苏州科淼新材料有限公司 Epoxy fireproof terrace paint
CN105925159A (en) * 2016-06-14 2016-09-07 苏州科淼新材料有限公司 Polyurethane anticorrosive floor paint
CN105885589A (en) * 2016-06-20 2016-08-24 吴国强 Novel acrylic fireproof floor paint

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Application publication date: 20170329