CN105885589A - Novel acrylic fireproof floor paint - Google Patents

Novel acrylic fireproof floor paint Download PDF

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Publication number
CN105885589A
CN105885589A CN201610457996.8A CN201610457996A CN105885589A CN 105885589 A CN105885589 A CN 105885589A CN 201610457996 A CN201610457996 A CN 201610457996A CN 105885589 A CN105885589 A CN 105885589A
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China
Prior art keywords
parts
floor paint
acrylic
novel acrylic
novel
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CN201610457996.8A
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Chinese (zh)
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吴国强
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Individual
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Priority to CN201610457996.8A priority Critical patent/CN105885589A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses novel acrylic fireproof floor paint. The novel acrylic fireproof floor paint comprises, by weight, 75-90 parts of water-based acrylic resin, 18-26 parts of co-condensed resin, 3-5 parts of glycidyl tertiary carboxylic ester, 10-12 parts of ethylene diamine tetraacetic acid, 8-12 parts of acrylic dispersing agents, 15-25 parts of polyvinyl acetate emulsion, 6-8 parts of hexamethyldisiloxane, 10-13 parts of polytetrafluoroethylene wax, 12-16 parts of calcite powder, 4-13 parts of acrylic curing agents, 5-9 parts of dipropylene glycol mono butyl ether, 3-7 parts of vinyltriethoxysilane and 10-15 parts of mica powder. The novel acrylic fireproof floor paint has the advantages that the novel acrylic fireproof floor paint is free of solvents, is non-toxic, harmless and green and is environmentally friendly, accordingly, harm to the human health due to the organic solvents can be prevented, and construction and application can be completely environmentally friendly; the novel acrylic fireproof floor paint is excellent in water resistance, fireproof property and yellowing resistance and high in coloring power; layers are high in surface brightness and excellent in physical performance and have bright colors.

Description

A kind of novel acrylic fire prevention floor paint
Technical field
The present invention relates to a kind of floor paint, particularly relate to a kind of novel acrylic fire prevention floor paint.
Background technology
Floor paint is in invention in 1934 the earliest by Germany, mainly by oil plant, tree material, face Color, solvent etc. are made, and are broadly divided into ornamental floor paint, heavy antisepsis floor paint, resistance to heavy duty ground Level ground paint etc..Many roads such as floor paint is blended by multiple different material, dissolve, dispersion produce works Skill manufacture and form.Floor paint has beautiful, true, attractive in appearance, wear-resisting, waterproof, anticorrosion etc. Feature.Many end production process such as floor paint is blended by multiple different material, dissolve, dispersion Manufacture and form.Different by the effect of each component of floor paint, typically can divide main membrane material, secondary Want film forming matter and auxiliary film forming matter.Eighties of last century middle and late stage starts, and America and Europe occurs in that many Dust proof workshop terrace, such as epoxide terrace, abrasion-proof terrace etc., finally, these terraces gradually enter Entering every country, nowadays, in some factories, parking lot, the application of laboratory is the most universal. Terrace paint coating is developed so far, because it has an excellent physical and mechanical properties, and electrical insulation capability, The performances such as resistance to chemical attack, the every field in national economy is widely applied, its yield Being continuously increased, quality improves constantly, and new varieties continue to bring out.The epoxy resin of China's floor paint Development of raw materials and applied research quickly grow, yearly productive capacity develop into less than 1.5 ten thousand tons About 300000 tons.The general trend of floor paint development is that production capacity quickly increases, and produces and tends to collection In;Product develops to seriation, functionalization, and quality generally improves;Adapt to international market demand Change, strengthening Special Resin and the exploitation of auxiliary aid.The floor paint consumption market that China is maximum It it is paint field.The floor paint of China's paint field year consumption at present accounts for the 32% of aggregate consumption.Mesh Before, floor paint industry competition is fierce, but the competition of product price is not as " being worth competition ". Meet client be worth point upwards and downward two kinds, value upwards, pursuit is sexual valence Ratio, more time-consuming, higher efficiency, happy process, the advantage such as safety and reliability.According to specially Family is introduced, and downward value refers to lower price competition, and price, always to decline, does not has Low, the lowest, until enterprise is profitless, cause more multiple enterprises to be used inferior materials and turned out substandard goods, degrade fall Amount, there is malignant development in product.Along with the development of market economy, competition is also more to drill more Strong, nowadays floor coatings industry, under the stagnant situation of market environment in 2012, terrace How enterprise is will be in the face of the competition in market?Its essence is also to revert to the value of client, former material Material price constantly increases, and enterprise only can increasingly difficulty or ease support by curtailing expenditures, the most downward Value should not develop, and this most commercially bases oneself upon?That be accomplished by enterprise technology and Be developed in production capacity, from traditional antiseepage, dust-proof, be easy to sterilization and the function such as cleaning Progressively being upgraded to have beautiful decoration, the aspect such as artistry and environmental-protecting performance strides forward.
Fire prevention floor paint has a globality, seamless, environmental protection, and nontoxic non-stimulated abnormal flavour is wear-resisting Damage, anticorrosion, waterproof, dust-proof, the advantages such as appearance is beautiful.Fire prevention floor paint is liquid form, In solid film-shaped uniformly densely after having constructed, can be widely applied to fabrication facility floor, resident lives Homestead table or metope, institutional settings, warehouse, wait the vast field to fire protection requirement, the most right The environment not having fire protection requirement can use too, because fire prevention floor paint appearance is beautiful, and shape Same epoxide terrace, and cost performance is higher, is a kind of universal ornament materials.Along with life Improving constantly of level, the environmental consciousness of present people is more and more higher, and Novel fireproof terrace is this Excellent multi-functional environment-protection product will obtain accreditation and the use of increasing people, its market Prospect will be wide infinitely.And floor paint kind is broadly divided into epoxy floor paint at present, third Olefin(e) acid floor paint, polyurethane floor paint.Wherein acrylic acid floor paint industry can be used for outdoor, and ratio is poly- The construction of urethane floor paint is simple and convenient, low price, but logistic strength is not as good as polyurethane floor Paint.Acrylic acid floor paint thermostability and solvent resistance are poor simultaneously, when heating temperature exceedes 177-232 DEG C is degraded to monomer, meets strong solvent and can occur from dissolubility stickness after solidification.At present Floor paint is divided into solvent-borne type and no-solvent type, solvent-borne type floor coatings construction time to base material humidity Require higher with ambient humidity;Base material and ambient humidity are not had the most too by the aqueous terrace of no-solvent type Big requirement, does not fire the most quick-fried character because of it, producing, transport, store, the link such as construction more Add safety and environmental protection, but, compare solvent-borne type floor coatings, aqueous terrace has compact in paint film The shortcomings such as low, application property is poor, the market share is less.Fast along with modern science and technology and production Speed development, proposes the highest requirement to terraces such as Factory Building, workshop, laboratorys and is accomplished by The performance of floor paint is proposed higher requirement.Can overcome above accordingly, it would be desirable to develop one The aqueous acrylic acid fireproof floor paint of described problem.
Summary of the invention
It is an object of the invention to provide a kind of novel acrylic fire prevention floor paint.
To achieve these goals, the invention provides a kind of novel acrylic fire prevention floor paint, Comprise following parts by weight of component: water-borne acrylic resin 75-90 part, condensation copolymerization resin 18-26 Part, tertiary carbonic acid glycidyl ester 3-5 part, disodiumedetate 10-12 part, acrylic acid Type dispersant 8-12 part, polyvinyl acetate emulsion 15-25 part, hexamethyl disiloxane 6-8 Part, polytetrafluoroethylwax wax 10-13 part, calcite in powder 12-16 part, acrylic acid firming agent 4-13 Part, dipropylene 5-9 part, VTES 3-7 part, mica powder 10-15 Part.
It also comprises citric acid 4-7 part.
It also comprises p-methyl benzenesulfonic acid 3-5 part.
It also comprises Oleum Sesami 10-16 part of being equal to.
The preparation technology of the present invention is common process, without any technological improvement, common for this area Technical staff skillfully grasps.
Beneficial effect: acrylic acid fireproof floor paint of the present invention is solvent-free, nontoxic, green ring Protect, it is to avoid the organic solvent harm to health, the complete of construction and application can be realized The feature of environmental protection.There is preferable resistance to water, fire line, high coloring power, the feature of color inhibition.Layer Surface brightness is higher, color and luster is vivider, physical property more preferably.
Detailed description of the invention
Embodiment 1
The acrylic acid fireproof floor paint of the present embodiment, comprises following parts by weight of component: aqueous acrylamide Acid resin 75 parts, condensation copolymerization resin 18 parts, tertiary carbonic acid glycidyl ester 3 parts, ethylenediamine tetraacetic Acetic acid disodium 10 parts, acrylic type dispersant 8 parts, polyvinyl acetate emulsion 15 parts, pregnancy Base disiloxane 6 parts, polytetrafluoroethylwax wax 10 parts, calcite in powder 12 parts, acrylic acid solidify Agent 4 parts, dipropylene 5 parts, VTES 3 parts, mica powder 10 Part.
Embodiment 2
The acrylic acid fireproof floor paint of the present embodiment, comprises following parts by weight of component: aqueous acrylamide Acid resin 90 parts, condensation copolymerization resin 26 parts, tertiary carbonic acid glycidyl ester 5 parts, ethylenediamine tetraacetic Acetic acid disodium 12 parts, acrylic type dispersant 12 parts, polyvinyl acetate emulsion 25 parts, six Tetramethyldisiloxane 8 parts, polytetrafluoroethylwax wax 13 parts, calcite in powder 16 parts, acrylic acid are solid Agent 13 parts, dipropylene 9 parts, VTES 7 parts, mica powder 15 parts, citric acid 7 parts.
Embodiment 3
The acrylic acid fireproof floor paint of the present embodiment, comprises following parts by weight of component: aqueous acrylamide Acid resin 75 parts, condensation copolymerization resin 18 parts, tertiary carbonic acid glycidyl ester 3 parts, ethylenediamine tetraacetic Acetic acid disodium 10 parts, acrylic type dispersant 8 parts, polyvinyl acetate emulsion 15 parts, pregnancy Base disiloxane 6 parts, polytetrafluoroethylwax wax 10 parts, calcite in powder 12 parts, acrylic acid solidify Agent 4 parts, dipropylene 5 parts, VTES 3 parts, mica powder 10 Part, citric acid 4 parts, p-methyl benzenesulfonic acid 3 parts.
Embodiment 4
The acrylic acid fireproof floor paint of the present embodiment, comprises following parts by weight of component: aqueous acrylamide Acid resin 90 parts, condensation copolymerization resin 26 parts, tertiary carbonic acid glycidyl ester 5 parts, ethylenediamine tetraacetic Acetic acid disodium 12 parts, acrylic type dispersant 12 parts, polyvinyl acetate emulsion 25 parts, six Tetramethyldisiloxane 8 parts, polytetrafluoroethylwax wax 13 parts, calcite in powder 16 parts, acrylic acid are solid Agent 13 parts, dipropylene 9 parts, VTES 7 parts, mica powder 15 parts, citric acid 7 parts, p-methyl benzenesulfonic acid 5 parts, be equal to 16 parts of Oleum Sesami.
The above, be only presently preferred embodiments of the present invention, not makees the present invention any Pro forma restriction, although the present invention is disclosed above with preferred embodiment, but and is not used to Limiting the present invention, any those skilled in the art, without departing from technical solution of the present invention In the range of, when the technology contents of available the disclosure above makes a little change or is modified to equivalent change The Equivalent embodiments changed, as long as being the content without departing from technical solution of the present invention, according to the present invention Technical spirit any simple modification, equivalent variations and modification that above example is made, all Still fall within the range of technical solution of the present invention.

Claims (4)

1. a novel acrylic fire prevention floor paint, it is characterised in that comprise following weight portion group Point: water-borne acrylic resin 75-90 part, condensation copolymerization resin 18-26 part, versatic acid shrink sweet Grease 3-5 part, disodiumedetate 10-12 part, acrylic type dispersant 8-12 part, Polyvinyl acetate emulsion 15-25 part, hexamethyl disiloxane 6-8 part, polytetrafluoroethylwax wax 10-13 part, calcite in powder 12-16 part, acrylic acid firming agent 4-13 part, dipropylene glycol fourth Ether 5-9 part, VTES 3-7 part, mica powder 10-15 part.
Novel acrylic the most according to claim 1 fire prevention floor paint, it is characterised in that: It also comprises citric acid 4-7 part.
Novel acrylic the most according to claim 2 fire prevention floor paint, it is characterised in that: It also comprises p-methyl benzenesulfonic acid 3-5 part.
Novel acrylic the most according to claim 3 fire prevention floor paint, it is characterised in that: It also comprises Oleum Sesami 10-16 part of being equal to.
CN201610457996.8A 2016-06-20 2016-06-20 Novel acrylic fireproof floor paint Pending CN105885589A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433347A (en) * 2016-09-21 2017-02-22 苏州瑞斯格电子科技有限公司 High-wear-resistance nano crylic acid terrace paint
CN106543876A (en) * 2016-10-25 2017-03-29 苏州富通高新材料科技股份有限公司 A kind of fire prevention nano-polyurethane floor paint
CN106543788A (en) * 2016-10-25 2017-03-29 苏州富通高新材料科技股份有限公司 A kind of anti-skidding nano-polyurethane floor paint
CN106543826A (en) * 2016-10-25 2017-03-29 苏州富通高新材料科技股份有限公司 A kind of antistatic nano acrylic acid floor paint
CN106590237A (en) * 2016-10-25 2017-04-26 苏州富通高新材料科技股份有限公司 Fireproofing nano acrylic terrace paint

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CN101654583A (en) * 2009-09-24 2010-02-24 北京红狮漆业有限公司 Compound epoxy flooring coating and preparation method thereof
CN102477240A (en) * 2010-11-24 2012-05-30 深圳市名雕装饰股份有限公司 Floor protective paint
CN103343505A (en) * 2013-07-15 2013-10-09 纪永明 Acrylic elastic material system for laying on ground of field and laying method thereof
CN104693926A (en) * 2015-02-15 2015-06-10 淄博世纪联合新型建筑材料有限公司 Preparation method of water-based floor paint and construction process of water-based floor paint

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CN101654583A (en) * 2009-09-24 2010-02-24 北京红狮漆业有限公司 Compound epoxy flooring coating and preparation method thereof
CN102477240A (en) * 2010-11-24 2012-05-30 深圳市名雕装饰股份有限公司 Floor protective paint
CN103343505A (en) * 2013-07-15 2013-10-09 纪永明 Acrylic elastic material system for laying on ground of field and laying method thereof
CN104693926A (en) * 2015-02-15 2015-06-10 淄博世纪联合新型建筑材料有限公司 Preparation method of water-based floor paint and construction process of water-based floor paint

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433347A (en) * 2016-09-21 2017-02-22 苏州瑞斯格电子科技有限公司 High-wear-resistance nano crylic acid terrace paint
CN106543876A (en) * 2016-10-25 2017-03-29 苏州富通高新材料科技股份有限公司 A kind of fire prevention nano-polyurethane floor paint
CN106543788A (en) * 2016-10-25 2017-03-29 苏州富通高新材料科技股份有限公司 A kind of anti-skidding nano-polyurethane floor paint
CN106543826A (en) * 2016-10-25 2017-03-29 苏州富通高新材料科技股份有限公司 A kind of antistatic nano acrylic acid floor paint
CN106590237A (en) * 2016-10-25 2017-04-26 苏州富通高新材料科技股份有限公司 Fireproofing nano acrylic terrace paint

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Application publication date: 20160824

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