CN101654583A - Compound epoxy flooring coating and preparation method thereof - Google Patents
Compound epoxy flooring coating and preparation method thereof Download PDFInfo
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- CN101654583A CN101654583A CN 200910093507 CN200910093507A CN101654583A CN 101654583 A CN101654583 A CN 101654583A CN 200910093507 CN200910093507 CN 200910093507 CN 200910093507 A CN200910093507 A CN 200910093507A CN 101654583 A CN101654583 A CN 101654583A
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Abstract
The invention relates to compound epoxy flooring coating adopting the mixture of epoxide resin and modified resin as a base material and further comprising organic solvent, dispersant, wetting agent,antifoaming agent, flatting agent, scratch resistance agent, pigment and stuffing as well as reactive diluent selected according to requirements. When in use, the coating is mixed and solidified withthe components of firming agent, accelerant, etc. By regulating the content of the components, the compound epoxy flooring coating of the invention can be used for manufacturing a solvent or solvent-free autolevelling epoxy floor. The compound epoxy flooring coating of the invention has favorable over-all properties, and not only has the characteristics of high mechanical strength, favorable anti-corrosion property, high adhesive force and good wear resistance property of the epoxide resin but also has the characteristics of good weather resistance, high decorative property and hardness and shock resistance of the modified resin; and the preparation method thereof is simple and practicable, is low-cost, and is suitable for mass preparation.
Description
Technical field
The present invention relates to coating technology, particularly a kind of compound epoxy flooring coating based on modified resin and preparation method thereof.
Background technology
At present, terrace paint has been the recognition and acceptance of users institute gradually, just is being widely used in hospital, parking lot, vault, playground, workshop, pharmaceutical factory, apartment or the like civilian and Industrial buildings and facility.
According to the filmogen classification, terrace paint can be divided into kinds such as mineral-type, polyurethanes, polyureas, acrylic acid or the like, epoxies.Every kind of terrace paint all has its advantage and defective.For the epoxies terrace, defective such as exist acid resistance and weathering resistance is poor, and matter is crisp easily to be split, not shock-resistant.
Present terms of settlement, the one, utilize the snappiness of solidifying agent to carry out modification, the 2nd, the method that adopts chemical modification is to redesign of Resins, epoxy molecule and modification.The first method effect is limited, is subjected to the restriction of solidifying agent molecular structure.Second method need be carried out in the synthetic workshop of resin, has not only limited the coating material production producer that lacks synthetic workshop, and has lacked the handiness at terrace paint different application occasion.
Therefore be necessary to provide a kind of modified resin that utilizes, only by simply mixing the new type compound epoxy flooring coating that just can overcome Resins, epoxy terrace paint shortcoming with Resins, epoxy.
Summary of the invention
The purpose of this invention is to provide a kind of compound epoxy flooring coating.
The present invention adopts modified resin such as C9 petroleum resin, Gum Rosin and Hydroxylated acrylic resin to mix with Resins, epoxy, prepares that weather resistance is good, hardness is high, shock resistance, compound epoxy flooring coating that wear resistance is good.
Compound epoxy flooring coating of the present invention, adopting mass fraction is that the Resins, epoxy of 20-60 and 5-30 and the mixture of modified resin are base-material, described modified resin is one or more in C9 petroleum resin, Gum Rosin and the Hydroxylated acrylic resin, wherein said Resins, epoxy and modified resin adopt the product of this area range of solid content commonly used, the solid content that is Resins, epoxy is 45-100%, and the solid content of modified resin is 40～100%.
Described compound epoxy flooring coating also contains solvent and/or reactive thinner, and its content is respectively mass fraction 0.01-20,5-25.
Generally, can add solvent separately and prepare coating; If do not use solvent, use simultaneously under the situation of low Resins, epoxy of viscosity and reactive thinner, can make solvent-free self leveling epoxy flooring; When using solvent to use reactive thinner simultaneously, the gained terrace paint is the solvent-borne type terrace paint; Also can only use reactive thinner (not with an organic solvent), preparation no-solvent type terrace paint.
According to the needs of product, during as preparation finish paint or intermediate coat, described compound epoxy flooring coating also contains filler and/or pigment, and its content is respectively mass fraction 15-100 and 5-20.
For guaranteeing the flowability and the coating of coating, during the preparation terrace paint, also need one or more in the additive that this areas such as interpolation wetting agent, dispersion agent, defoamer, flow agent, scratching resistant and thickening material are used always according to the purposes needs.
Described compound epoxy flooring coating also contains dispersion agent and/or wetting agent, and its content is respectively mass fraction 0.01-10,0.01-10.
As required, described compound epoxy flooring coating also contains defoamer, and its content is mass fraction 0.05-5.
In addition, described compound epoxy flooring coating also comprises scratching resistant and/or thickening material, and its content is respectively mass fraction 0.5-15,0.5-8.
According to the needs of product, during as the preparation finish paint, described compound epoxy flooring coating also comprises flow agent, and its content is mass fraction 0.05-2; Flow agent can be do not added during the preparation intermediate coat and also flow agent can be added.
The most important thing is that described compound epoxy flooring coating also contains the solidifying agent and the promotor of independent packing, its mass fraction is respectively 8-30,0-15.The slow occasions of curing speed such as lower or Gum Rosin amount ratio is bigger at construction temperature recommend to add promotor, and curing speed is than can not using under the situation faster.
Preferably, compound epoxy flooring coating of the present invention, form by the component of following mass fraction:
| Resins, epoxy | 30～50; |
| Modified resin | 8～15; |
| Reactive thinner | 5～15 |
| Pigment | 5～8; |
| Filler | 20～100; |
| Dispersion agent | 0.05～5; |
| Wetting agent | 1～8; |
| Solidifying agent | 8～30; |
| Promotor | 0～3; |
| Flow agent | 0.5～1 |
| Defoamer | 0.05～2; |
| Scratching resistant | 0.5～2; |
| Organic solvent | 0.01～20; |
| Thickening material | 0.5～2. |
The mechanism of composite epoxy terrace paint of the present invention is: the base-material that adopt (1) is a Resins, epoxy, forms the cross-linked network macromolecular structure and film forming with the solidifying agent reaction; (2) consistency of C9 petroleum resin, Gum Rosin and Hydroxylated acrylic resin and Resins, epoxy is good, is undertaken compound by methods such as simple dispersion stirrings; (3) after the crosslinked film forming of Resins, epoxy and solidifying agent, modified resin is that petroleum resin, Gum Rosin and Hydroxylated acrylic resin are dispersed in the cross-linked network, plays modifying function; (4) small amount of hydroxyl groups in C9 petroleum resin, Gum Rosin and the Hydroxylated acrylic resin molecule might react with solidifying agent and form chemically crosslinked with cross-linked network, thereby further improves the performance of paint film.
In the composite epoxy terrace paint of the present invention, described Resins, epoxy is optional with terrace paint Resins, epoxy commonly used, and preferred bisphenol A type epoxy resin can be that the trade mark commonly used is one or more among E44, E20 and the E12;
Described dispersion agent is the unsaturated polycarboxylic acid polymers soln of lower molecular weight; Mainly can select BYK-P104, BYK-P105, the BYK163 of German BYK company, one or both in 5040 dispersion agents of German HenKel company;
Described wetting agent is polyether-modified polysiloxane-based wetting agent, and it can effectively reduce the interfacial tension between material, can significantly improve flow characteristics, makes the interface produce smooth, smooth appearance effect; Can select BYK163, one or more of Tego Wet KL 245, BYK346;
Described thickening material is one or more in HEUR (nonionic hydrophobic nature modified epoxy ethane block polymers of polyurethane) serial thickening material and the organobentonite;
Described defoamer is polyether-modified polysiloxane solution; Can be defoamer BYK-022, BYK-320, the BYK-066 of German BYK company, the EFKA-2550 of the SN313 of the Henkel company of Germany, Dutch Efka company, among the EFKA-2722 one or more;
Described flow agent is this area fluorine carbon flow agent (fluorine-carbon modified polymers soln) commonly used; As selecting the EFKA3777 of Dutch Efka company for use;
Described scratching resistant is one or more in polyethylene wax, tetrafluoroethylene wax, the silicon dioxide microparticle, and as BYK-996, its auxiliary agent is the mixture of micronization polyethylene wax and poly-four ethylene waxes;
Described reactive thinner can be the Racemic glycidol ester compound, as propylene oxide benzylic ether, propylene oxide phenyl ether, epoxy propane butyl ether, C
12-14Alcohol glycidyl ether etc.;
Described solvent is one or more in dimethylbenzene, phenylcarbinol, butanols, hexone, the N-BUTYL ACETATE;
Described pigment can be organic class or mineral-type pigment as required, for example the mixture of one or more in titanium white, phthalocyanine, chrome yellow, organic yellow, red iron oxide, iron oxide black, the carbon black etc.;
Described filler is one or more in kaolin, quartz sand, talcum powder, barium sulfate, sericite, pure aluminium silicate, lime carbonate, the wollastonite; Kaolin can improve hardness, talcum powder can improve suspension, minimizing crack and the space of coating, quartz sand and barium sulfate can increase the wear resisting property and the hardness of terrace, sericite can improve weathering resistance, reduction perviousness, the chemicals-resistant ability that improves of terrace, can select the cooperation and the consumption that are fit to as required.
Described solidifying agent is one or more in modified fat class solidifying agent, urethane, polymeric amide, isocyanic ester, amine, the organic acid anhydride, as modification aliphatic cyclic amine 5701,115 solidifying agent, 3225 modified amine curing agents etc.;
Described promotor is imidazoles or amine epoxy curing catalyst, for example DMP-30 (2,4,6-three (dimethylamino methyl) phenol), glyoxal ethyline etc.
Compound epoxy flooring coating of the present invention can be made solvent-borne type or no-solvent type epoxy flooring coating according to the adjustment of solvent, reactive thinner content in the prescription; Also can select not use solvent, use low Resins, epoxy of viscosity and reactive thinner simultaneously, make solvent-free self leveling epoxy flooring; And, according to the adjustment of resin-pigment ratio, auxiliary agent in the prescription, also can make the compound epoxy flooring coating that can be used as priming paint, finish paint, intermediate coat.
The present invention also provides the preparation method of above-mentioned compound epoxy flooring coating.
The preparation method of described compound epoxy flooring coating may further comprise the steps:
(1) solvent, reactive thinner, dispersion agent, wetting agent, the flow agent of adding formula ratio 1/3～2/3 in Scattered Kettle stirred under the rotating speed of 900～1000rpm 15～30 minutes, made mixing of materials even;
(2) 1/3～2/3 of the adding formula ratio Resins, epoxy, all or part of modified resin stirred under the rotating speed of 400～500rpm 20～30 minutes, made mixing of materials even, and wherein partially modified resin is more than 50% of formula ratio;
(3) add the defoamer of pigment, filler, formula ratio 1/3～2/3 successively, stirred under 600～700rpm rotating speed 1.5～2 hours, make mixing of materials even, wherein partially modified resin is more than 50% of formula ratio;
(4) add remaining Resins, epoxy, balance solvent, remaining defoamer and scratching resistant, under the rotating speed of 400～500rpm, stirred 10-30 minute, make mixing of materials even, add thickening material regulation system viscosity at last;
(5) above-mentioned material package is as the A component;
(6) add solidifying agent, promotor in Scattered Kettle, partially modified resin stirred under the rotating speed of 400-1000rpm 0.5～1 hour, made mixing of materials even, packed as the B component.
Wherein, modified resin should be tried one's best and all be added in the A component, if because solvability or consistency have in limited time, then remaining modified resin can be added in the B component.
Before using A, B component are mixed according to 1～1.3 times of the curing reaction metered proportions between Resins, epoxy and the solidifying agent.
Compound epoxy flooring coating of the present invention is up-to-standard, and main performance index satisfies State Standard of the People's Republic of China GB/T22374-2008 " (terrace coating material "; Its preparation method is simple, need not complex apparatus and substantial contribution input, and cost is low, is fit to produce in enormous quantities.
Compared with prior art, industrial coating of the present invention also has following advantage and effect:
(1) shortcoming of improved that the acid resistance of filming that Resins, epoxy films is poor, matter crisply being split easily, weathering resistance is bad, both had Resins, epoxy physical strength height, Corrosion Protection is good, sticking power is high, wear resistance is good characteristics, has good, the ornamental height of acrylic resin weather resistance again, therefore petroleum resin and Gum Rosin hardness height, shock resistance, the characteristics that wear resistance is good can adapt to the needs of different application occasion;
(2) composite instant, simple.Mix by solvent or reactive thinner dissolving, perhaps simple dispersion is stirred, and just can realize the compound of modified resin and Resins, epoxy, and is easy to operation;
(3) Resins, epoxy and modified resin compound after, not only improved over-all properties, and can reduce cost, improve product market competitiveness.
Embodiment
Following examples are used to illustrate the present invention, but are not used for limiting the scope of the invention.Specialize as nothing, each feed composition that the present invention adopts all adopts coating industry commercial raw material commonly used.
Embodiment 1 solvent-borne type modified epoxy terrace priming paint
Press composition shown in the table 1 and mass fraction, preparation solvent-borne type composite epoxy terrace priming paint:
The composition of table 1 composite epoxy terrace priming paint
| Component | Charging capacity (kilogram) |
| Resins, epoxy | ??550 |
| 424 Gum Rosins | ??200 |
| ??BYK-P104 | ??2 |
| Dimethylbenzene | ??100 |
| Butanols | ??50 |
| Hexone | ??98 |
| Curing agent modified aliphatic cyclic amine 5701 | ??100 |
| Curing catalyst DMP-30 | ??10 |
| Add up to | ??1110 |
The preparation method of this solvent-borne type epoxide terrace priming paint is:
(1) solvent xylene, butanols and first class isobutyl ketone, the BYK-P104 of adding formula ratio in Scattered Kettle stirred 10 minutes under the rotating speed of 450rpm, made mixing of materials even.
(2) add formula ratio 424 Gum Rosins, under the rotating speed of 600rpm, stirred 4 hours, make material dissolution, and mix.
(3) Resins, epoxy of adding formula ratio stirred 50 minutes under the 700rpm rotating speed, made mixing of materials even.
(4) above-mentioned slurries filtration packing is as the A component.
(5) solidifying agent and the promotor of adding formula ratio in Scattered Kettle were stirred 30 minutes under the rotating speed of 450rpm, made mixing of materials even.Pack then, as the B component.
A, B component is even by 1: 1.3 mixed, and the performance of the solvent-borne type modified epoxy terrace priming paint for preparing is listed as 2 tables:
The performance of table 2 composite epoxy terrace priming paint
Embodiment 2 solvent-borne type epoxide terrace intermediate coats
Press composition shown in the table 3 and mass fraction, preparation solvent-borne type epoxide terrace intermediate coat:
The composition of table 3 composite epoxy terrace priming paint
| Component | Charging capacity (kilogram) |
| 115 solidifying agent (115# low molecule pa resin) | ??30 |
| Resins, epoxy E50 | ??53 |
| C9 petroleum resin (available from Dexing, Shandong petroleum resin company limited) | ??20 |
| A-01 Hydroxylated acrylic resin (available from Liaoning three ring resin company limiteds) | ??5 |
| Titanium white | ??15 |
| Wollastonite | ??15 |
| Talcum powder | ??22.5 |
| Lime carbonate | ??36 |
| Thickening material organobentonite SD-2 | ??0.6 |
| ??BYK163 | ??0.3 |
| Hexone | ??18 |
| Dimethylbenzene | ??30 |
| Butanols | ??10 |
The preparation method of this solvent-borne type modified epoxy terrace intermediate coat is:
(1) 1/2 solvent, dispersion agent, the wetting agent of adding formula ratio in Scattered Kettle stirred 30 minutes under the rotating speed of 900rpm, made mixing of materials even;
(2) 1/2 of the adding formula ratio resin, C9 petroleum resin stirred 4 hours under the rotating speed of 500rpm, made mixing of materials even;
(3) add the pigment, filler of formula ratio, 1/3 defoamer successively, under the 600rpm rotating speed, stirred 2 hours, make mixing of materials even;
(4) add remaining resin, 1/2 solvent, remaining defoamer, under the rotating speed of 500rpm, stirred 30 minutes, make mixing of materials even;
(5) above-mentioned material package is as the A component;
(6) in Scattered Kettle, add solidifying agent, under the rotating speed of 700rpm, stirred 30 minutes, make mixing of materials even, pack as the B component.
With A, the B component is even by 1: 1.1 mixed, and the performance of the solvent-borne type modified epoxy terrace intermediate coat for preparing is listed as 4 tables:
The performance of table 4 composite epoxy terrace intermediate coat
| Alkali resistance (20%NaOH, 72h) | Non-foaming, do not peel off light discolouration |
| Acid resistance (10%H 2SO 4，48h) | Non-foaming, do not peel off light discolouration |
Press composition shown in the table 5 and mass fraction, preparation solvent-borne type epoxide terrace finish paint:
The composition of table 5 composite epoxy terrace finish paint
| Component | Charging capacity (kilogram) |
| 115 solidifying agent | ??9.7 |
| Resins, epoxy E20 | ??25 |
| The C9 petroleum resin | ??12 |
| Titanium white | ??14 |
| Barium sulfate | ??12 |
| Wollastonite | ??10 |
| Talcum powder | ??8 |
| Organobentonite SD-2 | ??0.2 |
| ?BYK163 | ??0.5 |
| ?BYK-320 | ??0.5 |
| ?BYK-066 | ??0.2 |
| Scratching resistant BYK-996 | ??0.6 |
| Hexone | ??5 |
| Dimethylbenzene | ??13.5 |
| Butanols | ??4.5 |
The preparation method of this solvent-borne type modified epoxy terrace finish paint is:
(1) in Scattered Kettle, adds 2/3 solvent, dispersion agent, wetting agent of formula ratio, 1/3 defoamer, under the rotating speed of 400～500rpm, stirred 20 minutes, make mixing of materials even;
(2) 1/2 of the adding formula ratio Resins, epoxy, C9 petroleum resin stirred 20 minutes under the rotating speed of 500rpm, made mixing of materials even;
(3) add the pigment, filler of formula ratio, 1/3 defoamer successively, under the 1200rpm rotating speed, stirred 1.5 hours, make mixing of materials even;
(4) add remaining Resins, epoxy, solvent and defoamer, under the rotating speed of 400～500rpm, stirred 10-30 minute, make mixing of materials even;
(5) above-mentioned material package is as the A component;
(6) in Scattered Kettle, add solidifying agent, under the rotating speed of 400-1000rpm, stirred 0.5～1 hour, make mixing of materials even, pack as the B component.
With A, the B component is even by 1: 1 mixed, and the performance of the solvent-borne type modified epoxy terrace intermediate coat for preparing is listed as 6 tables:
The performance of table 6 composite epoxy terrace finish paint
Embodiment 4 solvent-free modified epoxy gravity flow self-leveling floor lacquers
Press composition shown in the table 7 and mass fraction, prepare composite type modified epoxy flooring coating:
The composition of the solvent-free modified epoxy gravity flow self-leveling floor lacquer of table 7
| Component | Charging capacity (kilogram) |
| Modified amine curing agent 3225 | ??50 |
| Resins, epoxy 128 | ??109 |
| The C9 petroleum resin | ??40 |
| Reactive thinner 660A | ??20 |
| Lime carbonate | ??51 |
| Quartz sand | ??90 |
| Titanium white | ??14 |
| Barium sulfate | ??12 |
| Wollastonite | ??10 |
| Talcum powder | ??8 |
| ??BYK-320 | ??0.5 |
| ??BYK-066 | ??0.2 |
| Silicon defoamer EFKA-2722 | ??2.7 |
| Fluorine-carbon modified polymer class flow agent EFKA-3777 | ??1.2 |
| ??BYK-996 | ??5.4 |
| ??DMP-30 | ??5 |
| Phenylcarbinol | ??6 |
The preparation method of this solvent-free modified epoxy gravity flow self-leveling floor lacquer is:
(1) in Scattered Kettle, adds the reactive thinner, dispersion agent, wetting agent, flow agent of formula ratio, 1/3 defoamer, under the rotating speed of 450rpm, stirred 30 minutes, make mixing of materials even;
(2) add 1/2 Resins, epoxy, petroleum resin of formula ratio, under the rotating speed of 450rpm, stirred 30 minutes, make material dissolution and mix;
(3) add the pigment, filler of formula ratio, 1/3 defoamer successively, under 900～1000rpm rotating speed, stirred 2 hours, make mixing of materials even;
(4) add remaining Resins, epoxy, 1/2 solvent, remaining defoamer, scratching resistant, under the rotating speed of 450rpm, stirred 30 minutes, make mixing of materials even;
(5) above-mentioned material package is as the A component;
(6) in Scattered Kettle, add solidifying agent, promotor, under the rotating speed of 500rpm, stirred 0.5 hour, make mixing of materials even, pack as the B component.
With A, the B component is even by 1: 1.2 mixed, and the performance such as the table 8 of the no-solvent type epoxy self-leveling floor lacquer for preparing are listed::
The performance of table 8 solvent-free epoxy self-leveling terrace lacquer
The foregoing description is a preferred implementation of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other are any not to deviate from change, the modification done under spirit of the present invention and the principle, substitute, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1, a kind of compound epoxy flooring coating, it is characterized in that, adopting mass fraction is that the Resins, epoxy of 20-60 and 5-30 and the mixture of modified resin are base-material, and described modified resin is one or more in C9 petroleum resin, Gum Rosin and the Hydroxylated acrylic resin.
2, compound epoxy flooring coating as claimed in claim 1 is characterized in that, described compound epoxy flooring coating also contains solvent and/or reactive thinner, and its content is respectively mass fraction 0.01-20,5-25.
3, compound epoxy flooring coating as claimed in claim 2 is characterized in that, described compound epoxy flooring coating also contains filler and/or pigment, and its content is respectively mass fraction 15-100 and 5-20.
4, as claim 2 or 3 described compound epoxy flooring coatings, it is characterized in that described compound epoxy flooring coating also contains dispersion agent and/or wetting agent, its content is respectively mass fraction 0.01-10,0.01-10.
5, as claim 2,3 or 4 described compound epoxy flooring coatings, it is characterized in that described compound epoxy flooring coating also contains defoamer, its content is mass fraction 0.05-5.
As the arbitrary described compound epoxy flooring coating of claim 2-5, it is characterized in that 6, described compound epoxy flooring coating also comprises scratching resistant and/or flow agent and/or thickening material, its content is respectively mass fraction 0.5-15,0.05-2,0.5-8.
As the arbitrary described compound epoxy flooring coating of claim 2-6, it is characterized in that 7, described compound epoxy flooring coating also contains the solidifying agent and the promotor of independent packing, its mass fraction is respectively 8-30,0-15.
8, as the arbitrary described compound epoxy flooring coating of claim 1-7, it is characterized in that, form by each component of following mass fraction:
Resins, epoxy 30～50;
Modified resin 8～15;
Modified resin 8～15;
Reactive thinner 5～15
Pigment 5～8;
Filler 20～100;
Dispersion agent 0.05～5;
Wetting agent 1～8;
Solidifying agent 8～30;
Promotor 0～3;
Flow agent 0.5～1
Defoamer 0.05～2;
Scratching resistant 0.5～2;
Organic solvent 0.01～20;
Thickening material 0.5～2.
As the arbitrary described compound epoxy flooring coating of claim 1-8, it is characterized in that 9, described dispersion agent is the unsaturated polycarboxylic acid polymers soln of lower molecular weight;
Described wetting agent is polyether-modified polysiloxane-based wetting agent;
Described thickening material is one or more in HEUR series thickening material and the organobentonite;
Described defoamer is polysiloxane solution or polyether-modified polysiloxane solution;
Described flow agent is a fluorine carbon flow agent;
Described scratching resistant is one or more in polyethylene wax, tetrafluoroethylene wax, the silicon dioxide microparticle;
Described reactive thinner is the Racemic glycidol ester compound;
Described solvent is one or more in dimethylbenzene, phenylcarbinol, butanols, hexone, the N-BUTYL ACETATE;
Described solidifying agent is one or more in modified fat class solidifying agent, urethane, polymeric amide, isocyanic ester, amine, the organic acid anhydride;
Described promotor is imidazoles or amine epoxy curing catalyst.
10, as the preparation method of the arbitrary described compound epoxy flooring coating of claim 1-9, it is characterized in that, may further comprise the steps:
(1) 1/3～2/3 solvent, reactive thinner, dispersion agent, wetting agent, the flow agent of adding formula ratio in Scattered Kettle stirred under the rotating speed of 900～1000rpm 15～30 minutes, made mixing of materials even;
(2) 1/3～2/3 of the adding formula ratio Resins, epoxy, all or part of modified resin stirred under the rotating speed of 400～500rpm 20～30 minutes, made mixing of materials even, and wherein partially modified resin is more than 50% of formula ratio;
(3) add pigment, filler, 1/3～2/3 defoamer of formula ratio successively, under 600～700rpm rotating speed, stirred 1.5～2 hours, make mixing of materials even;
(4) add remaining Resins, epoxy, balance solvent, remaining defoamer and scratching resistant, under the rotating speed of 400～500rpm, stirred 10-30 minute, make mixing of materials even, add thickening material regulation system viscosity at last;
(5) above-mentioned material package is as the A component;
(6) modified resin that adds solidifying agent, promotor, residue formula ratio in Scattered Kettle stirred under the rotating speed of 400-1000rpm 0.5～1 hour, made mixing of materials even, packed as the B component;
(7) A, B component are mixed according to 1～1.3 times of the curing reaction metered proportions before using.
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