CN113045954A - Environment-friendly water-based super-wear-resistant finish paint and preparation method thereof - Google Patents
Environment-friendly water-based super-wear-resistant finish paint and preparation method thereof Download PDFInfo
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- CN113045954A CN113045954A CN202110313769.9A CN202110313769A CN113045954A CN 113045954 A CN113045954 A CN 113045954A CN 202110313769 A CN202110313769 A CN 202110313769A CN 113045954 A CN113045954 A CN 113045954A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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Abstract
The invention relates to an environment-friendly water-based super wear-resistant finish paint and a preparation method thereof, wherein the environment-friendly water-based super wear-resistant finish paint is formed by mixing a component A and a component B according to a mass ratio of 4:0.9-1.1, wherein the component A comprises the following components in parts by weight: 30-40 parts of deionized water, 0.5-2.5 parts of wetting dispersant, 0.5-1.5 parts of defoaming agent, 1.0-2.0 parts of hydrophilic nano fumed silica, 1.0-2.0 parts of scratch-resistant auxiliary agent, 5-10 parts of titanium white, 5-10 parts of quartz powder, 5-10 parts of nano aluminum oxide, 30-40 parts of aqueous epoxy curing agent, 5-15 parts of super-wear-resistant high polymer, 0.5-1.5 parts of wetting and leveling agent and 1-5 parts of aqueous color paste. The component B comprises the following components in parts by weight: 80-90 parts of flexible epoxy resin, 9-15 parts of hydrophilic epoxy active diluent and 1-5 parts of propylene glycol methyl ether. The environment-friendly water-based super wear-resistant finish paint prepared by the invention has the advantages of super wear resistance, high hardness, scratch resistance, chemical resistance, water resistance and low content of harmful substances, and has a good anti-skid effect.
Description
Technical Field
The invention relates to a coating material used in underground garages, industrial plants, schools, libraries, offices and other places, in particular to an environment-friendly water-based super wear-resistant finish paint.
Background
The environment-friendly water-based super wear-resistant finish paint is super wear-resistant, high-hardness, scratch-resistant, acid-base-resistant water-based paint, and is widely applied to ground coating protection in places such as underground garages, industrial plants, schools, libraries, offices and the like. Therefore, it is necessary to develop an environment-friendly aqueous super wear-resistant coating with the advantages of low VOC, super wear resistance, high hardness, scratch resistance, long service life, water resistance, chemical resistance, good anti-skid effect and the like.
Disclosure of Invention
The invention aims to provide an environment-friendly water-based super wear-resistant finish paint and a preparation method thereof.
The invention is realized by the following steps: an environment-friendly water-based super wear-resistant finish paint is formed by mixing a component A and a component B according to the mass ratio of 4:0.9-1.1, wherein the component A and the component B are prepared from the following components in parts by weight:
wherein the component A comprises the following components in parts by weight:
wherein the component B comprises the following components in parts by weight:
80-90 parts of flexible epoxy resin
9-15 parts of hydrophilic epoxy active diluent
1.0-5.0 parts of propylene glycol methyl ether
The further optimization scheme is as follows: the wetting dispersant is BYK190 or TEGO 740W;
the further optimization scheme is as follows: the nano fumed silica is hydrophilic fumed silica; such as M-5 of Kabet, AEROSIL 200 of Yingchuang, etc.
The further optimization scheme is as follows: the defoamer is TEGO 901W. The titanium dioxide is white boa herboria R996 titanium dioxide.
The further optimization scheme is as follows: the aqueous rheological additive is Bentonie LT bentonite produced by Haimines.
The further optimization scheme is as follows: the scratch-resistant auxiliary agent is TF1778 wax powder produced by Luborun.
The further optimization scheme is as follows: the nano alumina is nano spherical alumina produced by Jiangsu birry.
The further optimization scheme is as follows: the waterborne epoxy curing agent is a fatty amine modified waterborne epoxy curing agent produced by Guangzhou limited company which is a new linked-solid material, such as BC923 fatty amine modified waterborne epoxy curing agent.
The further optimization scheme is as follows: the super wear-resistant high molecular compound is high molecular compound resin particles with the molecular weight of about 50 ten thousand.
The further optimization scheme is as follows: the flexible epoxy resin is a polyurethane modified epoxy resin, such as EP11825 polyurethane modified epoxy resin produced by fuzhou zhuang.
The further optimization scheme is as follows: the hydrophilic epoxy active diluent is polyethylene glycol diglycidyl ether; it adopts XY215 (polyethylene glycol diglycidyl ether) produced by Anhui new and remote chemical industry.
The preparation method of the environment-friendly water-based super wear-resistant finish paint comprises the following steps:
(1) the component A is prepared according to the following preparation method:
30-40 parts of deionized water, 0.5-2.5 parts of wetting dispersant, 0.5-1.5 parts of defoaming agent, 1.0-2.0 parts of hydrophilic nano silicon dioxide, 1.0-2.0 parts of scratch-resistant assistant, 5.0-10.0 parts of titanium dioxide, 5-10 parts of quartz powder, 5-15 parts of nano aluminum oxide, 30-40 parts of waterborne epoxy curing agent, 5.0-15.0 parts of super wear-resistant high polymer, 0.5-1.5 parts of wetting leveling agent and 1-5 parts of waterborne color paste, and dispersing for 10-15 minutes at the rotation speed of 1000 plus 1200 turns/minute until the mixture is uniform;
(2) the component B is prepared according to the following preparation method:
adding flexible epoxy resin, hydrophilic epoxy active diluent and propylene glycol methyl ether into a container, and dispersing for 10-15 minutes at the rotating speed of 600-800 rpm until the components are uniformly mixed.
(3) And uniformly mixing the prepared component A and the component B according to the mass ratio of 4: 0.9-1.1.
The component A and the component B are respectively packaged after being prepared, when in use, the prepared component A and the prepared component B are uniformly stirred and mixed at a high speed according to the mass ratio of 4:0.9-1.1, are diluted by adding 5-8% of water and then are uniformly stirred, are uniformly scraped by a flat knife and are uniformly rolled and coated by a short hair roller.
The environment-friendly water-based super wear-resistant finish paint has the following advantages: the environment-friendly water-based super wear-resistant finish paint disclosed by the invention is super wear-resistant, and has the characteristics of high hardness, scratch resistance, chemical resistance, water resistance, low content of harmful substances and good anti-skid effect.
Detailed Description
The present invention will be described in detail with reference to specific examples.
The specific implementation mode is as follows:
an environment-friendly water-based super wear-resistant finish paint is formed by mixing a component A and a component B according to the mass ratio of 4:0.8-1.1, wherein the component A and the component B are prepared from the following components in parts by weight:
wherein the component A comprises the following components in parts by weight:
wherein the component B comprises the following components in parts by weight:
80-90 parts of flexible epoxy resin
9-15 parts of hydrophilic epoxy active diluent
2-5 parts of propylene glycol methyl ether
The preparation method of the environment-friendly water-based super wear-resistant finish paint comprises the following steps:
(1) the component A is prepared according to the following preparation method:
30-40 parts of deionized water, 0.5-2.5 parts of wetting dispersant, 0.5-1.5 parts of defoaming agent, 0.5-2.0 parts of hydrophilic nano fumed silica, 1.0-2.0 parts of scratch-resistant auxiliary agent, 5-10 parts of titanium dioxide, 5-10 parts of quartz powder, 5-10 parts of nano alumina, 30-40 parts of waterborne epoxy curing agent, 5-15.0 parts of super wear-resistant high polymer, 0.5-1.0 part of wetting and leveling agent and 1-5 parts of waterborne color paste, and dispersing for 10-15 minutes at the rotating speed of 1000 plus 1200 rpm until the mixture is uniform;
(2) the component B is prepared according to the following preparation method:
adding flexible epoxy resin, hydrophilic epoxy active diluent and propylene glycol methyl ether into a container, and dispersing for 10-15 minutes at the rotating speed of 600-800 rpm until the components are uniformly mixed.
(3) And uniformly mixing the prepared component A and the component B according to the mass ratio of 4: 0.9-1.1.
The wetting dispersant in the components is BYK190 or TEGO 740W; the nano fumed silica is hydrophilic fumed silica; such as M-5 of Kabot, AEROSIL 200 of Yingchuang, etc.; the defoaming agent is TEGO901W with a digao, and the titanium dioxide is titanium dioxide; the nano alumina is nano spherical alumina produced by Jiangsu birry; the waterborne epoxy curing agent is a fatty amine modified waterborne epoxy curing agent produced by Guangzhou limited company as a new solid material, such as BC923 fatty amine modified waterborne epoxy curing agent; the super wear-resistant high molecular compound is high molecular compound resin particles with the molecular weight of about 50 ten thousand; the flexible epoxy resin is polyurethane modified epoxy resin; such as EP11825 polyurethane modified epoxy produced by quanzhou shogao. The hydrophilic epoxy active diluent adopts XY215 (polyethylene glycol diglycidyl ether) produced by Anhui new and remote chemical industry; the components can also be made into other products of the same type.
The second embodiment is as follows:
example 1: an environment-friendly water-based super wear-resistant finish paint is formed by mixing a component A and a component B according to the mass ratio of 4:0.9, wherein the component A and the component B are prepared from the following components in parts by weight:
wherein the component B comprises the following components in parts by weight:
wherein the component B comprises the following components in parts by weight:
80 parts of flexible epoxy resin
Hydrophilic epoxy active diluent 15 parts
Propylene glycol methyl ether 5 parts
The preparation method of the environment-friendly water-based super wear-resistant finish paint comprises the following steps:
(1) the component A is prepared according to the following preparation method:
40 parts of deionized water, 0.5 part of wetting dispersant, 0.5 part of defoaming agent, 1.0 part of hydrophilic nano fumed silica, 1.0 part of scratch-resistant auxiliary agent, 5.0 parts of titanium dioxide, 5.5 parts of quartz powder, 5.0 parts of nano alumina, 30 parts of waterborne epoxy curing agent, 10.0 parts of super wear-resistant high molecular polymer, 0.5 part of wetting and leveling agent and 1.0 part of waterborne color paste, and dispersing for 10-15 minutes at the rotating speed of 1000 plus materials of 1200 rpm until the components are uniformly mixed;
(2) the component B is prepared according to the following preparation method:
adding flexible epoxy resin, hydrophilic epoxy active diluent and propylene glycol methyl ether into a container, and dispersing for 10-15 minutes at the rotating speed of 600-800 rpm until the materials are uniformly mixed;
(3) the prepared environment-friendly anti-skid waterborne super wear-resistant component A and the prepared environment-friendly anti-skid waterborne super wear-resistant component B are uniformly mixed according to the mass ratio of 4: 0.9.
The wetting dispersant in the components is BYK190 or Twin4000 of Digao; the nanometer fumed silica is hydrophilic fumed silica, such as M-5 of Cambot, AEROSIL 200 of Yingchuang, etc.; the defoaming agent is TEGO901W with a digao, and the titanium dioxide is titanium dioxide; the nano alumina is nano spherical alumina produced by Jiangsu birry; the waterborne epoxy curing agent is a fatty amine modified waterborne epoxy curing agent produced by Guangzhou limited company as a new solid material, such as BC923 fatty amine modified waterborne epoxy curing agent; the super wear-resistant high molecular compound is high molecular compound resin particles with the molecular weight of about 50 ten thousand; the flexible epoxy resin is polyurethane modified epoxy resin; such as EP11825 polyurethane modified epoxy produced by quanzhou shogao. The hydrophilic epoxy active diluent adopts XY215 (polyethylene glycol diglycidyl ether) produced by Anhui new and remote chemical industry; the components can also be made into other products of the same type.
Example 2: an environment-friendly water-based super wear-resistant finish paint is formed by mixing a component A and a component B according to the mass ratio of 4:1, wherein the component A and the component B are prepared from the following components in parts by weight:
wherein the component A comprises the following components in parts by weight:
wherein the component B comprises the following components in parts by weight:
85 parts of flexible epoxy resin
12 parts of hydrophilic epoxy active diluent
Propylene glycol methyl ether 3 parts
The preparation method of the environment-friendly anti-skid waterborne super-resistant finish paint comprises the following steps:
(1) the component A is prepared according to the following preparation method:
35.0 parts of deionized water, 1.0 part of wetting dispersant, 1.0 part of defoaming agent, 1.5 parts of hydrophilic nano fumed silica, 1.5 parts of scratch-resistant auxiliary agent, 9.0 parts of titanium dioxide, 8.0 parts of quartz powder, 10.0 parts of nano alumina, 35 parts of waterborne epoxy curing agent, 15 parts of super wear-resistant high polymer, 0.8 part of wetting and leveling agent and 3.0 parts of waterborne color paste, and the components are dispersed for 10-15 minutes at the rotating speed of 1000 plus materials of 1200 turns/minute until the components are uniformly mixed;
(2) the component B is prepared according to the following preparation method:
adding flexible epoxy resin, hydrophilic epoxy active diluent and propylene glycol methyl ether into a container, and dispersing for 10-15 minutes at the rotating speed of 600-800 rpm until the materials are uniformly mixed;
(3) and uniformly mixing the prepared main paint and the curing agent according to the mass ratio of 4: 1.0.
The wetting dispersant in the components is BYK190 or TEGO 740W; the nano fumed silica is hydrophilic fumed silica; such as M-5 of Kabot, AEROSIL 200 of Yingchuang, etc.; the defoaming agent is TEGO901W with a height of two, and the titanium dioxide is white titanium dioxide of Bailey Union R996 of the python; the nano alumina is nano spherical alumina produced by Jiangsu birry; the waterborne epoxy curing agent is a fatty amine modified waterborne epoxy curing agent produced by Guangzhou limited company as a new solid material, such as BC923 fatty amine modified waterborne epoxy curing agent; the super wear-resistant high molecular compound is high molecular compound resin particles with the molecular weight of about 50 ten thousand; the flexible epoxy resin is polyurethane modified epoxy resin; such as EP11825 polyurethane modified epoxy produced by quanzhou shogao. The hydrophilic epoxy active diluent adopts XY215 (polyethylene glycol diglycidyl ether) produced by Anhui new and remote chemical industry; the components can also be made into other products of the same type.
Example 3: an environment-friendly water-based super wear-resistant finish paint is formed by mixing a component A and a component B according to the mass ratio of 4:1.1, wherein the component A and the component B are prepared from the following components in parts by weight:
wherein the component A comprises the following components in parts by weight:
wherein the component B comprises the following components in parts by weight:
90 parts of flexible epoxy resin
9 parts of hydrophilic epoxy reactive diluent
Propylene glycol methyl ether 1 part
The preparation method of the environment-friendly water-based super wear-resistant finish paint comprises the following steps:
(1) the component A is prepared according to the following preparation method:
30.0 parts of deionized water, 2.5 parts of wetting dispersant, 1.5 parts of defoaming agent, 1.5 parts of hydrophilic nano fumed silica, 1.5 parts of scratch-resistant auxiliary agent, 10.0 parts of titanium dioxide, 10.5 parts of quartz powder, 5-15 parts of nano alumina, 40.0 parts of waterborne epoxy curing agent, 15.0 parts of super wear-resistant high molecular polymer, 1.0 part of wetting and leveling agent and 5.0 parts of waterborne color paste, and dispersing for 10-15 minutes at the rotating speed of 1000 plus 1200 rpm until the components are uniformly mixed;
(2) the component B is prepared according to the following preparation method:
adding flexible epoxy resin, hydrophilic epoxy active diluent and propylene glycol methyl ether into a container, and dispersing for 10-15 minutes at the rotating speed of 600-800 rpm until the materials are uniformly mixed;
(3) and uniformly mixing the prepared component A and the component B according to the mass ratio of 4: 1.1.
The wetting dispersant in the components is BYK190 or Twin4000 of Digao; the nano fumed silica is hydrophilic fumed silica; such as M-5 of Kabot, AEROSIL 200 of Yingchuang, etc.; the defoaming agent is TEGO901W with a height of two, and the titanium dioxide is white titanium dioxide of Bailey Union R996 of the python; the nano alumina is nano spherical alumina produced by Jiangsu birry; the waterborne epoxy curing agent is a fatty amine modified waterborne epoxy curing agent produced by Guangzhou limited company as a new solid material, such as BC923 fatty amine modified waterborne epoxy curing agent; the super wear-resistant high molecular compound is high molecular compound resin particles with the molecular weight of about 50 ten thousand; the flexible epoxy resin is polyurethane modified epoxy resin; such as EP11825 polyurethane modified epoxy produced by quanzhou shogao. The hydrophilic epoxy active diluent adopts XY215 (polyethylene glycol diglycidyl ether) produced by Anhui new and remote chemical industry; the components can also be made into other products of the same type.
Through the pair tests, the technical performance indexes and experimental data of the environment-friendly water-based super wear-resistant finish paint of the embodiments 1-3 are shown in the following table:
from the test results of the above examples, it can be seen that: the environment-friendly water-based super wear-resistant finish paint disclosed by the invention has super wear resistance, scratch resistance, high hardness, low content of harmful substances, water resistance, acid resistance, alkali resistance and good anti-skidding effect.
The above embodiments are merely illustrative of the technical solutions of the present invention, and the present invention is not limited to the above embodiments, and any modifications or alterations according to the principles of the present invention should be within the protection scope of the present invention.
Claims (10)
1. An environment-friendly water-based super wear-resistant finish paint is characterized by comprising a component A and a component B;
the component A is prepared by mixing the following components in parts by weight:
the component B is prepared by mixing the following components in parts by weight:
80-90 parts of flexible epoxy resin
9-15 parts of hydrophilic epoxy active diluent
1-5 parts of propylene glycol methyl ether.
2. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: when in use, the component A and the component B are mixed and prepared according to the mass ratio of 4: 0.9-1.1.
3. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: the nano fumed silica is hydrophilic fumed silica; the wetting dispersant is BYK190 or TEGO740W Digao.
4. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: the antifoaming agent is TEGO 901W; the titanium dioxide is white boa herboria R996 titanium dioxide.
5. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: the scratch-resistant auxiliary agent is polyethylene wax modified by graded micronized polytetrafluoroethylene.
6. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: the nano alumina is nano spherical alumina.
7. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: the waterborne epoxy curing agent is an amine modified waterborne epoxy curing agent.
8. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: the super wear-resistant high molecular polymer is high molecular compound resin particles with the molecular weight of 30-60 ten thousand.
9. The environment-friendly water-based super wear-resistant finish paint according to claim 1, characterized in that: the flexible epoxy resin is polyurethane modified epoxy resin; the hydrophilic epoxy active diluent is polyethylene glycol diglycidyl ether.
10. A method for preparing the environment-friendly water-based super wear-resistant finish paint as recited in any one of claims 1-9, wherein the method comprises the following steps: the method comprises the following steps:
(1) the component A of the environment-friendly water-based super wear-resistant finish paint is prepared by the following preparation method:
adding 30-40 parts of deionized water, 0.5-2.5 parts of wetting dispersant, 0.5-1.5 parts of defoaming agent, 1.0-2.0 parts of nano fumed silica, 1.0-2.0 parts of scratch-resistant assistant, 5.0-10.0 parts of titanium dioxide, 5.0-10.0 parts of quartz powder, 5-15 parts of nano aluminum oxide, 30-40 parts of waterborne epoxy curing agent, 5.0-15.0 parts of super wear-resistant high polymer, 0.5-1.5 parts of wetting and leveling agent and 1.0-5.0 parts of waterborne color paste into a container, and dispersing for 10-15 minutes at the rotating speed of 1000-1200 revolutions/minute until the mixture is uniform;
(2) the component B of the environment-friendly water-based super wear-resistant finish paint is prepared by the following preparation method: adding 80-90 parts of flexible epoxy resin, 9-15 parts of hydrophilic epoxy active diluent and 1-5 parts of propylene glycol methyl ether into a container, and dispersing for 10-15 minutes at the rotating speed of 600-800 revolutions per minute until the components are uniformly mixed.
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| 耿同谋等: ""聚氨酯改性环氧及其应用"", 《化工新型材料》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114479615A (en) * | 2022-03-22 | 2022-05-13 | 东莞市诚昊机电设备工程有限公司 | Epoxy super-wear-resistant mortar self-leveling bottom plate material and production process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113045954B (en) | 2022-05-24 |
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