CN108165076A - A kind of water nano antistatic epoxy floor paint and preparation method thereof - Google Patents
A kind of water nano antistatic epoxy floor paint and preparation method thereof Download PDFInfo
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- CN108165076A CN108165076A CN201711489339.2A CN201711489339A CN108165076A CN 108165076 A CN108165076 A CN 108165076A CN 201711489339 A CN201711489339 A CN 201711489339A CN 108165076 A CN108165076 A CN 108165076A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Floor Finish (AREA)
Abstract
The invention discloses a kind of water nano antistatic epoxy floor paint, including component A and B component.Component A includes following components by mass percentage：Modified aqueous epoxy resin 85~90%；Epoxy active diluent 10~15%；B component includes following components by mass percentage：Epoxy curing agent 45~50%；Titanium dioxide 2~3%, ZnOw 5~8%, aluminium oxide 5~10%, nano zine oxide 2~5%, carbon fiber 2~5%, antifoaming agent 0.5~1%, thickener 0.5~1%, dispersant 0.5~1%, pH adjusting agent 0.5~1%, surplus are water；The weight ratio of component A and B component is 1: 3~1: 5.Compatibility is good, conductive filler additive amount is small, antistatic performance is good, and has had both certain flame retardant property, the application prospect having had between the water nano antistatic epoxy floor paint each component of the present invention.
Description
Technical field
The present invention relates to a kind of floor paint more particularly to a kind of water nano antistatic epoxy floor paint and its preparation sides
Method.
Background technology
Based on solvent type, solvent therein easily pollutes environment and influences people's health traditional terrace paint coating.And
Nowadays oiliness in the market or half oiliness epoxide terrace paint, then containing a large amount of organic solvent such as toluene, dimethylbenzene etc. to human body
Harmful substance.Higher and higher in face of requirement of the every country to environmental protection, the floor paint for studying new environment-friendly type becomes as one kind
Gesture.Therefore, aqueous epoxy floor coating comes into being.Epoxide terrace paint is famous with its various advantage, as coating surface is put down
It is whole, bright and clean, can be in irreflexive dumb light state；Good integrity, gap is less or complete, seamless, thus be not easy product hide dust and
Bacterium, easy cleaning；Case hardness is high, there is certain wear-resistant and compressive resistance；It is rich in color, it is gorgeous, it is decorative strong；It is anti-
Water, anti-permeability are good, pollutant can be avoided to permeate the ground and polluted underground water and soil with dampening；It is corrosion-resistant, it can protect
From chemical attack, surface can make it new state matrix；Certain special functions, such as antistatic can be met according to demand.
Epoxy antistatic floor paint is mainly reached by the conductive filler formation conductive path added in coating prevents electrostatic
Lotus is revealed, and eliminates the purpose of the harm of accumulation of static electricity and electromagnetic interference, is mainly used for the places such as resistance, precision instrument production.It is right
In the anti-static effect of the coating, there are many influence factor, essentially consist in the formation of galvanic circle.Resin binder and conductive filler it
Between interfacial effect for galvanic circle formation influence it is very big.The conductive filler in conductive polymer composite preparation process
The Free Surface of particle gradually becomes the interface of moistening, and boundary layer is formd between base-material and filler, and system produces interface
It can be superfluous.With the increase of conductive filler, interface energy excess phenomenon constantly increases, and therefore, the critical concentration of conductive filler is one
A parameter related with interface energy.When interface energy surplus reaches a certain level, initially formed between conducting particles
Conductive network.Therefore, on the one hand being formed for conductive path has great relationship with the additive amount of conductive filler with arrangement mode, separately
On the one hand and the compatibility between conductive filler and polymer matrix also has great relationship.And common conductive filler has：Carbon
Based material (carbon black, graphite etc.), metal powder (silver powder, copper powder, nickel powder etc.), metal oxide semiconductor (tin oxide, oxidation
Iron, zinc oxide), conducting nanoparticles and antistatic auxiliary agent etc..Wherein metal powder density is big, and it is larger to form conductive path needs
Volume fraction, surface layer is oxidizable, can reduce or even lose electric conductivity, and poor corrosion resistance, so as to influence coating other
Performance, therefore metal powder is subject to certain restrictions as the application of conductive filler；Antistatic agent temperature tolerance, water resistance, oil resistivity,
Corrosion resistance, durability are poor, and antistatic property is unstable.In conclusion to work out a kind of has preferable compatibility, anti-quiet
The outstanding floor paint system of electrical property is particularly significant.
Invention content
For overcome the deficiencies in the prior art, the invention discloses a kind of water nano antistatic epoxy floor paints, this is anti-
Compatibility is good between electrostatic floor paint each component, conductive filler additive amount is small, antistatic performance is good, and has had both certain resistance
Fire performance, the application prospect having had.
In order to achieve the above object, the present invention uses following technical scheme：
A kind of water nano antistatic epoxy floor paint, including component A and B component.
Wherein, component A includes following components by mass percentage：Modified aqueous epoxy resin 85~90%；Epoxy is lived
Property diluent 10~15%；The sum of weight percent of component A is absolutely.
Wherein, B component includes following components by mass percentage：Epoxy curing agent 45~50%；Titanium dioxide 2
~3%, ZnOw 5~8%, aluminium oxide 5~10%, nano zine oxide 2~5%, carbon fiber 2~5%, antifoaming agent 0.5
~1%, thickener 0.5~1%, dispersant 0.5~1%, pH adjusting agent 0.5~1%, surplus are water；The weight percent of B component
Than the sum of for absolutely.
The weight ratio of component A and B component is 1：3~1：5.
Further, the modified aqueous epoxy resin is waterborne polyurethane modified epoxy resin, silicon-modified epoxy
Resin, inorganic nano particle modified epoxy resin wherein at least one.
Further, the inorganic nano particle modified epoxy resin is nano montmorillonite modified epoxy resin, graphene
Modified epoxy, nano-silicon dioxide modified epoxy resin wherein at least one.
Further, the epoxy active diluent for diluent HK-66,669, X-632, AGE, D-691 wherein at least
It is a kind of.
Further, the epoxy curing agent is curing agent D-8, T-31,591,701,702,703 wherein at least one
Kind.
Further, the antifoaming agent is mineral oil antifoam agent；The dispersant is polycarboxylate salt dispersant；The thickening
Agent is polyacrylic ester thickener, cellulose ethers thickener wherein at least one；The pH adjusting agent is triethylamine, isopropyl
Amine, trimethyl ethamine, ammonium hydroxide wherein at least one.
Further, the aluminium oxide is 50um ball-aluminium oxides, 20um ball-aluminium oxides, 10um ball-aluminium oxides, 2um
Ball-aluminium oxide, irregular aluminium oxide wherein at least one.
Further, the titanium dioxide, ZnOw, ball-aluminium oxide, nano zine oxide and carbon fiber pass through
Surface treatment；The surface treatment method is first respectively by titanium dioxide, ZnOw, ball-aluminium oxide, nano zine oxide
It is handled to improve the content of its surface oxygen functional group using surface oxidation method with carbon fiber material, is then impregnated again
It is handled in the hydrolyzate of silane coupling agent, it is for use after 100 DEG C of dry 3h~4h after static 6h~8h.
Further, the surface oxidation method is vapour phase oxidation process, anode electrolysis oxidizing process, plasma processing, liquid phase
Oxidizing process wherein at least one；The silane coupling agent is the silane coupling agent containing epoxy group or amino groups wherein at least one
Kind.
A kind of preparation method of water nano antistatic epoxy floor paint, which is characterized in that include the following steps：
(1) component A is prepared：Modified aqueous epoxy resin and epoxy active diluent are sequentially added into container, stirring is mixed
It closes uniformly up to component A；
(2) B component is prepared：Epoxy curing agent, titanium dioxide, ZnOw, spherical shape are sequentially added into container
Aluminium oxide, nano zine oxide, carbon fiber and water, moderate-speed mixer are uniform；Sequentially add antifoaming agent, thickener, dispersant, pH tune
Agent is saved, high-speed stirred is uniformly to get B component；
(3) water nano antistatic epoxy floor paint is prepared：By component A and B component according to 1：3~1：5 weight proportion
It is uniformly mixed, stands 15min.
Compared with prior art, beneficial effects of the present invention are：
(1) nano anti-static epoxide terrace paint of the invention is filled out by the conduction of different-grain diameter, different shape, unlike material
Material collocation, wherein ZnOw and carbon fiber are easy to form bridging effect shape between the ball-aluminium oxide of larger grain size
Into conductive path, and the sky that irregular aluminium oxide, the ball-aluminium oxide of small particle and nano zine oxide then can be at them without putting up a bridge
Filling accumulation forms other conductive path between gap.Collocation between the two so that in the smaller feelings of conductive filler tune dosage
More conductive path just can be formed under condition, anti-static effect is good.
(2) conductive filler all in nano anti-static epoxide terrace paint of the invention all have passed through surface treatment.Before this
Each filler is handled by surface oxidation method so that the inactive surfaces of some fillers are also enriched some oxygen-containing functional groups, then
Again by the processing of silane coupling agent hydrolyzate, on the one hand so that be more readily formed between filler and filler bridging act on to be formed it is logical
Road on the other hand so that having preferable compatibility between filler and polymer matrix, improves the various aspects of performance of floor paint.
(3) titanium dioxide is added in nano anti-static epoxide terrace paint of the invention, on the one hand improves floor paint
Antistatic performance, on the one hand so that the floor paint has certain flame retardant effect.
Specific embodiment
The present invention is further illustrated with specific embodiment below, but the present invention does not limit to and these embodiments.
Embodiment 1
A kind of water nano antistatic epoxy floor paint, including component A and B component.
Component A includes following components by mass percentage：Waterborne polyurethane modified epoxy resin 85%；Epoxy-reactive is dilute
Release agent HK-66 15%.
B component includes following components by mass percentage：Epoxy curing agent D-8 45%；Titanium dioxide 2%, oxygen
Change zinc whisker 5%, aluminium oxide 5%, nano zine oxide 2%, carbon fiber 2%, mineral oil antifoam agent 0.5%, polyacrylate to increase
Thick dose 0.5%, polycarboxylate salt dispersant 0.5%, pH adjusting agent triethylamine 0.5%, surplus be water.
The weight ratio of component A and B component is 1：3.
Wherein, 50um ball-aluminium oxides：20um ball-aluminium oxides：10um ball-aluminium oxides：2um ball-aluminium oxides：It does not advise
Then aluminium oxide=5：2：1：1：1.
In the present embodiment titanium dioxide, ZnOw, ball-aluminium oxide, nano zine oxide and carbon fiber by etc. from
After subprocessing, then it is soaked in the hydrolyzate of the silane coupling agent containing epoxy group and is handled again, after static 6h,
It is for use after 100 DEG C of dry 3h.
The preparation method of the water nano antistatic epoxy floor paint of the present embodiment includes the following steps：
(1) component A is prepared：Modified aqueous epoxy resin and epoxy active diluent are sequentially added into container, stirring is mixed
It closes uniformly up to component A；
(2) B component is prepared：Epoxy curing agent, titanium dioxide, ZnOw, spherical shape are sequentially added into container
Aluminium oxide, nano zine oxide, carbon fiber and water, moderate-speed mixer are uniform；Sequentially add antifoaming agent, thickener, dispersant, pH tune
Agent is saved, high-speed stirred is uniformly to get B component；
(3) water nano antistatic epoxy floor paint is prepared：Component A with B component is proportionally uniformly mixed, is stood
15min.
Embodiment 2
A kind of water nano antistatic epoxy floor paint, including component A and B component.
Component A includes following components by mass percentage：Modifying epoxy resin by organosilicon 88%；Epoxy active diluent
AGE 12%.
B component includes following components by mass percentage：Epoxy curing agent 591 48%；Titanium dioxide 3%, oxygen
Change zinc whisker 6%, aluminium oxide 6%, nano zine oxide 3%, carbon fiber 3%, mineral oil antifoam agent 1%, polyacrylate thickening
Agent 1%, polycarboxylate salt dispersant 1%, pH adjusting agent triethylamine 1%, surplus are water.
The weight ratio of component A and B component is 1：4.
Wherein, 50um ball-aluminium oxides：20um ball-aluminium oxides：10um ball-aluminium oxides：2um ball-aluminium oxides：It does not advise
Then aluminium oxide=8：4：2：1：1.
Titanium dioxide, ZnOw, ball-aluminium oxide, nano zine oxide and carbon fiber pass through gas phase in the present embodiment
It after oxidative treatment, is handled in the hydrolyzate for the silane coupling agent for being then soaked in amido-containing group again, static 8h
Afterwards, it is for use after 100 DEG C of dry 4h.
The preparation method of the water nano antistatic epoxy floor paint of the present embodiment includes the following steps：
(1) component A is prepared：Modified aqueous epoxy resin and epoxy active diluent are sequentially added into container, stirring is mixed
It closes uniformly up to component A；
(2) B component is prepared：Epoxy curing agent, titanium dioxide, ZnOw, spherical shape are sequentially added into container
Aluminium oxide, nano zine oxide, carbon fiber and water, moderate-speed mixer are uniform；Sequentially add antifoaming agent, thickener, dispersant, pH tune
Agent is saved, high-speed stirred is uniformly to get B component；
(3) water nano antistatic epoxy floor paint is prepared：Component A with B component is proportionally uniformly mixed, is stood
15min.
Embodiment 3
A kind of water nano antistatic epoxy floor paint, including component A and B component.
Component A includes following components by mass percentage：Nano montmorillonite modified epoxy resin 90%；Epoxy-reactive is dilute
Release agent D-691 10%.
B component includes following components by mass percentage：Epoxy curing agent 701 50%；Titanium dioxide 3%, oxygen
Change zinc whisker 8%, aluminium oxide 10%, nano zine oxide 3%, carbon fiber 5%, mineral oil antifoam agent 1%, polyacrylate thickening
Agent 1%, polycarboxylate salt dispersant 1%, pH adjusting agent triethylamine 1%, surplus are water.
The weight ratio of component A and B component is 1：5.
Wherein, 50um ball-aluminium oxides：20um ball-aluminium oxides：10um ball-aluminium oxides：2um ball-aluminium oxides：It does not advise
Then aluminium oxide=10：6：5：3：2.
Titanium dioxide, ZnOw, ball-aluminium oxide, nano zine oxide and carbon fiber pass through anode in the present embodiment
After electrolytic oxidation processing, handled in the hydrolyzate for the silane coupling agent for being then soaked in amido-containing group again, it is quiet
It is for use after 100 DEG C of dry 4h only after 8h.
The preparation method of the water nano antistatic epoxy floor paint of the present embodiment includes the following steps：
(1) component A is prepared：Modified aqueous epoxy resin and epoxy active diluent are sequentially added into container, stirring is mixed
It closes uniformly up to component A；
(2) B component is prepared：Epoxy curing agent, titanium dioxide, ZnOw, spherical shape are sequentially added into container
Aluminium oxide, nano zine oxide, carbon fiber and water, moderate-speed mixer are uniform；Sequentially add antifoaming agent, thickener, dispersant, pH tune
Agent is saved, high-speed stirred is uniformly to get B component；
(3) water nano antistatic epoxy floor paint is prepared：Component A with B component is proportionally uniformly mixed, is stood
15min.
The foregoing is merely the better embodiments of the present invention, and the invention is not limited in the above embodiments, are implementing
In the process there may be the small structural modification in part, if the various changes or modifications of the present invention are not departed from the essence of the present invention
God and range, and belong within the scope of the claim and equivalent technologies of the present invention, then the present invention is also intended to comprising these changes
And modification.
Claims (10)
1. a kind of water nano antistatic epoxy floor paint, including component A and B component, it is characterised in that：
Component A includes following components by mass percentage：Modified aqueous epoxy resin 85~90%；Epoxy active diluent 10
~15%；The sum of weight percent of component A is absolutely；
B component includes following components by mass percentage：Epoxy curing agent 45~50%；Titanium dioxide 2~3%, oxygen
Change zinc whisker 5~8%, aluminium oxide 5~10%, nano zine oxide 2~5%, carbon fiber 2~5%, antifoaming agent 0.5~1%, increase
Thick dose 0.5~1%, dispersant 0.5~1%, pH adjusting agent 0.5~1%, surplus be water；The sum of weight percent of B component is
Absolutely；
The weight ratio of component A and B component is 1：3~1：5.
A kind of 2. water nano antistatic epoxy floor paint according to claim 1, which is characterized in that the modified water-soluble
Epoxy resin is waterborne polyurethane modified epoxy resin, modifying epoxy resin by organosilicon, inorganic nano particle modified epoxy resin
Wherein at least one.
A kind of 3. water nano antistatic epoxy floor paint according to claim 2, which is characterized in that the inorganic nano
Particle modified epoxy resin is nano montmorillonite modified epoxy resin, graphene modified epoxy, nano-silicon dioxide modified
Epoxy resin wherein at least one.
A kind of 4. water nano antistatic epoxy floor paint according to claim 1, which is characterized in that the epoxy-reactive
Diluent is diluent HK-66,669, X-632, AGE, D-691 wherein at least one.
A kind of 5. water nano antistatic epoxy floor paint according to claim 1, which is characterized in that the epoxy resin
Curing agent is the wherein at least one of curing agent D-8, T-31,591,701,702,703.
6. a kind of water nano antistatic epoxy floor paint according to claim 1, which is characterized in that the antifoaming agent is
Mineral oil antifoam agent；The dispersant is polycarboxylate salt dispersant；The thickener is polyacrylic ester thickener, cellulose ether
Class thickener wherein at least one；The pH adjusting agent is triethylamine, isopropylamine, trimethyl ethamine, ammonium hydroxide wherein at least one.
7. a kind of water nano antistatic epoxy floor paint according to claim 1, which is characterized in that the aluminium oxide is
50um ball-aluminium oxides, 20um ball-aluminium oxides, 10um ball-aluminium oxides, 2um ball-aluminium oxides, irregular aluminium oxide are wherein extremely
Few one kind.
A kind of 8. water nano antistatic epoxy floor paint according to claim 1, which is characterized in that the titanium dioxide
Titanium, ZnOw, ball-aluminium oxide, nano zine oxide and carbon fiber are by surface treatment；The surface treatment method is
First respectively by titanium dioxide, ZnOw, ball-aluminium oxide, nano zine oxide and carbon fiber material using surface oxidation method into
Then row processing is soaked in the hydrolyzate of silane coupling agent again with improving the content of its surface oxygen functional group
It manages, it is for use after 100 DEG C of dry 3h~4h after static 6h~8h.
A kind of 9. water nano antistatic epoxy floor paint according to claim 8, which is characterized in that the surface oxidation
Method is vapour phase oxidation process, anode electrolysis oxidizing process, plasma processing, liquid phase oxidation wherein at least one；The silane is even
Connection agent is the silane coupling agent wherein at least one containing epoxy group or amino groups.
It is 10. a kind of such as a kind of preparation side of water nano antistatic epoxy floor paint according to any one of claims 1 to 8
Method, which is characterized in that include the following steps：
(1) component A is prepared：Modified aqueous epoxy resin and epoxy active diluent are sequentially added into container, is stirred
Even component A to obtain the final product；
(2) B component is prepared：Epoxy curing agent, titanium dioxide, ZnOw, spherical oxidation are sequentially added into container
Aluminium, nano zine oxide, carbon fiber and water, moderate-speed mixer are uniform；Antifoaming agent, thickener, dispersant, pH is sequentially added to adjust
Agent, high-speed stirred is uniformly to get B component；
(3) water nano antistatic epoxy floor paint is prepared：By component A and B component according to 1：3~1：5 weight proportion mixing
Uniformly, 15min is stood.
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| CN110240852A (en) * | 2019-06-28 | 2019-09-17 | 山东大学 | Composite Nano TiO2With ZnO aqueous epoxy resins terrace surface paint and preparation method thereof |
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| CN113214723A (en) * | 2021-05-24 | 2021-08-06 | 江苏德莱利建筑装饰工程有限公司 | High-strength high-temperature-resistant epoxy floor coating and preparation method thereof |
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| CN113045954B (en) * | 2021-03-24 | 2022-05-24 | 三棵树(上海)新材料研究有限公司 | Environment-friendly water-based super-wear-resistant finish paint and preparation method thereof |
| CN113214723A (en) * | 2021-05-24 | 2021-08-06 | 江苏德莱利建筑装饰工程有限公司 | High-strength high-temperature-resistant epoxy floor coating and preparation method thereof |
| CN113337188A (en) * | 2021-07-26 | 2021-09-03 | 力特克新材料(广东)有限公司 | Seven-color toughened terrace and preparation method thereof |
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