CN102587255B - Silicofluoride elastic terrace and manufacturing method thereof - Google Patents

Silicofluoride elastic terrace and manufacturing method thereof Download PDF

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Publication number
CN102587255B
CN102587255B CN201210045555.9A CN201210045555A CN102587255B CN 102587255 B CN102587255 B CN 102587255B CN 201210045555 A CN201210045555 A CN 201210045555A CN 102587255 B CN102587255 B CN 102587255B
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parts
fluorine silicon
elastic
coat
silicofluoride
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CN102587255A (en
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苗建成
陈遵厚
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Fuzhou Royal Floor Co Ltd
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Fuzhou Royal Floor Co Ltd
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Abstract

The invention relates to a silicofluoride elastic terrace and a manufacturing method thereof. The silicofluoride elastic terrace comprises a foundation, wherein the foundation is provided with a base coating layer, a silicofluoride elastic middle coating layer and a silicofluoride elastic surface coating layer in sequence from bottom to top. The manufacturing method comprises the following steps of: coating base coat on the surface of the foundation in a multi-path rolling manner by a roller so as to form the base coating layer, till a bright film is formed on the surface of the coated foundation; scratching and coating middle coat on the surface of the bottom coating layer in a multi-path scraping manner by a tooth scratching plate so as to form the silicofluoride elastic middle coating layer, wherein the coating-scratching thickness of each path is not more than 2.0mm, and the time interval for each-path coating-scratching is determined according to the conditions that the former-path coating layer is dried and cured and the needed thickness is scratched and coated; and spraying-coating surface coat on the surface of the silicofluoride elastic middle coating layer in a multi-path manner by using a spraying gun so as to form the silicofluoride elastic surface coating layer. The silicofluoride elastic terrace not only has the advantages of antiskid performance, waterproof and anti-seepage performances, wear and scratching resistance, pollution and corrosion resistance, and green and environment-friendly effects and the like, but also has the advantages of vibration absorption, buffering, and sound absorption and the like, and is widely applied in terrace ground such as hospitals, homeland, office sites, squares, swimming pools and shopping malls.

Description

A kind of fluorine silicon elastic terrace and manufacture method thereof
Technical field
The present invention relates to a kind of terrace, especially a kind of fluorine silicon elastic terrace and manufacture method thereof.
Background technology
Terrace is the part contacting with layer of concrete between bottom, and it bears the load between bottom, requires to have certain strength and stiffness, and has protection against the tide, waterproof, warming, wear-resisting performance.And the terrace in some places also needs to have the features such as shock-absorbing, pooling feature, therefore be necessary to invent a kind of fluorine silicon elastic terrace and manufacture method thereof.
Summary of the invention
In order to overcome the deficiencies in the prior art, one of object of the present invention is to provide a kind of fluorine silicon elastic terrace and manufacture method thereof with shock-absorbing, pooling feature.
To achieve these goals, one of technical scheme of the present invention is as follows: a kind of fluorine silicon elastic terrace, comprise basis, and it is characterized in that: described basis is disposed with scratch coat, fluorine silicon elasticity floating coat and fluorine silicon elastic surface coating from bottom to top; The primary coat that described scratch coat is used is comprised of following component by weight: the Polyether 220 N of 80 ~ 100 parts, the polyethers 330N of 120 ~ 140 parts, the toluene di-isocyanate(TDI) of 80 ~ 120 parts, 20 ~ 40 parts 1,4-butanediol, the butyl acetate of 40 ~ 60 parts, the ethyl acetate of 50 ~ 70 parts; The middle painting that described fluorine silicon elasticity floating coat is used is comprised of following component by weight: the Polyether 220 N of 80 ~ 100 parts, the polyethers 330N of 120 ~ 140 parts, the chlorinated paraffin wax 52 of 70 ~ 90 parts, the kaolin of 90 ~ 110 parts, the fine talc of 90 ~ 110 parts, the thick talcum of 140 ~ 160 parts, 10% chlorobenzoyl chloride of 0.2 ~ 0.8 part, the anhydrous dimethyl benzene of 260 ~ 300 parts, the toluene di-isocyanate(TDI) of 25 ~ 35 parts, the defoamer of 0.6 ~ 1 part; The face painting that described fluorine silicon elastic surface coating is used is comprised of following component by weight: the elastic resin of 50 ~ 70 parts, the pigment of 10 ~ 20 parts, A component, B component; Wherein A component is comprised of following component by weight: the modified gas aerosil of 2 ~ 4 parts, the oxidant of 4 ~ 6 parts, the wax emulsion of 1 ~ 3 part, the blanc fixe of 2 ~ 4 parts, the deionized water of 4 ~ 6 parts; Wherein B component is comprised of following component by weight: the isocyanate curing agent of 6 ~ 8 parts, the organotin catalysts of 0.6 ~ 1 part; The weight ratio of A component and B component is 8-10:1.
Further, described kaolinic order number is 1000 ~ 1500 orders, and the order number of described fine talc is 1000 ~ 1500 orders, and the order number of described thick talcum is 300 ~ 350 orders.
Further, described defoamer is LCA-908 defoamer.
Further, described oxidant is N, N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine.
Further, described elastic resin is base polyurethane prepolymer for use as.
Further, described wax emulsion is German BASF wax emulsion WE-6, and its chemical composition is dystectic OPE water-based emulsion.
To achieve these goals, technical scheme of the present invention two as follows: a kind of manufacture method of fluorine silicon elastic terrace, it is characterized in that: comprise above-mentioned a kind of fluorine silicon elastic terrace, and carry out according to the following steps: (1) with cylinder by primary coat minute multiple tracks roller coating on surface of base to form scratch coat, with till brushing rear surface of base and forming bright film; (2) with tooth scraper plate, middle painting minute multiple tracks is coated with and is scraped on scratch coat surface to form fluorine silicon elasticity floating coat, per pass is coated with to be scraped thickness and can not surpass 2.0mm, and the interval that per pass is coated with the time of scraping is one solid being as the criterion until be coated with and scrape to desired thickness in the past; (3) with spray gun, face being coated with to a minute multiple tracks is sprayed on fluorine silicon elasticity floating coat surface to form fluorine silicon elastic surface coating.
The invention has the advantages that: the construction of (1) this fluorine silicon elastic terrace is simple, it is simple to keep a public place clean, health environment-friendly, cost performance is high, quality is superior; (2) this fluorine silicon elastic terrace bright in colour, with the passing of time Chang Xin, be difficult for aging; (3) not only anti-skidding, waterproof, mildew-resistant, resistant scratch resistance against corrosion, wear-resisting of this fluorine silicon elastic terrace, and there is elasticity, comfortable safety, its shock-absorbing performance, shock-absorbing capacity and sound absorption qualities are good; (4) scope of application of this fluorine silicon elastic terrace is wide, can be widely used in the terrace ground such as hospital, home, office space, outdoor terrace, park, square, swimming pool, market, tourist sight, passage.
Accompanying drawing explanation
Fig. 1 is the organigram of the embodiment of the present invention.
In figure: 1-basis, 2-scratch coat, 3-fluorine silicon elasticity floating coat, 4-fluorine silicon elastic surface coating.
The specific embodiment
Below in conjunction with accompanying drawing 1 and specific embodiment, the present invention is further elaborated.
Specific embodiment one: a kind of fluorine silicon elastic terrace, comprise basis 1, it is characterized in that: described basic 1 is disposed with scratch coat 2, fluorine silicon elasticity floating coat 3 and fluorine silicon elastic surface coating 4 from bottom to top; The primary coat that described scratch coat 2 is used is comprised of following component by weight: the Polyether 220 N of 80 parts, the polyethers 330N of 120 parts, the toluene di-isocyanate(TDI) of 80 parts, the BDO of 20 parts, the butyl acetate of 40 parts, the ethyl acetate of 50 parts; The middle painting that described fluorine silicon elasticity floating coat 3 is used is comprised of following component by weight: the Polyether 220 N of 80 parts, the polyethers 330N of 120 parts, the chlorinated paraffin wax 52 of 70 parts, the kaolin of 90 parts, the fine talc of 90 parts, the thick talcum of 140 parts, 10% chlorobenzoyl chloride of 0.2 part, the anhydrous dimethyl benzene of 260 parts, the toluene di-isocyanate(TDI) of 25 parts, the defoamer of 0.6 part; The face painting that described fluorine silicon elastic surface coating 4 is used is comprised of following component by weight: the elastic resin of 50 parts, the pigment of 10 parts, A component, B component; Wherein A component is comprised of following component by weight: the modified gas aerosil of 2 parts, the oxidant of 4 parts, the wax emulsion of 1 part, the blanc fixe of 2 parts, the deionized water of 4 parts; Wherein B component is comprised of following component by weight: the isocyanate curing agent of 6 parts, the organotin catalysts of 0.6 part; The weight ratio of A component and B component is 8:1.
In specific embodiment one, described kaolinic order number is 1000 orders, and the order number of described fine talc is 1000 orders, and the order number of described thick talcum is 300 orders.The optional LCA-908 defoamer of producing with Shanghai Bo Xinjing innovative material Science and Technology Ltd. of described defoamer, LCA-908 defoamer belongs to neutral latent curing agent, and defoamer can also be selected mouthful oxazole alkanes latent curing agent or imines class latent curing agent etc. certainly; Described oxidant can be selected N, and N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine, but be not limited to this; Described elastic resin can be selected base polyurethane prepolymer for use as, but is not limited to this; Described wax emulsion can be selected German BASF wax emulsion WE-6, and its chemical composition is dystectic OPE water-based emulsion, but is not limited to this.Described blanc fixe contains 99.9% barium sulfate; Described pigment can be selected versicolor toner, is generally organic toner.
Specific embodiment two: a kind of fluorine silicon elastic terrace, comprise basis 1, it is characterized in that: described basic 1 is disposed with scratch coat 2, fluorine silicon elasticity floating coat 3 and fluorine silicon elastic surface coating 4 from bottom to top; The primary coat that described scratch coat 2 is used is comprised of following component by weight: the Polyether 220 N of 90 parts, the polyethers 330N of 130 parts, the toluene di-isocyanate(TDI) of 100 parts, the BDO of 30 parts, the butyl acetate of 50 parts, the ethyl acetate of 60 parts; The middle painting that described fluorine silicon elasticity floating coat 3 is used is comprised of following component by weight: the Polyether 220 N of 90 parts, the polyethers 330N of 130 parts, the chlorinated paraffin wax 52 of 80 parts, the kaolin of 100 parts, the fine talc of 100 parts, the thick talcum of 1450 parts, 10% chlorobenzoyl chloride of 0.6 part, the anhydrous dimethyl benzene of 280 parts, the toluene di-isocyanate(TDI) of 31 parts, the defoamer of 0.8 part; The face painting that described fluorine silicon elastic surface coating 4 is used is comprised of following component by weight: the elastic resin of 60 parts, the pigment of 15 parts, A component, B component; Wherein A component is comprised of following component by weight: the modified gas aerosil of 3 parts, the oxidant of 5 parts, the wax emulsion of 2 parts, the blanc fixe of 3 parts, the deionized water of 5 parts; Wherein B component is comprised of following component by weight: the isocyanate curing agent of 7 parts, the organotin catalysts of 0.8 part; The weight ratio of A component and B component is 9:1.
In specific embodiment two, described kaolinic order number is 1250 orders, and the order number of described fine talc is 1250 orders, and the order number of described thick talcum is 325 orders.The optional LCA-908 defoamer of producing with Shanghai Bo Xinjing innovative material Science and Technology Ltd. of described defoamer, LCA-908 defoamer belongs to neutral latent curing agent, and defoamer can also be selected mouthful oxazole alkanes latent curing agent or imines class latent curing agent etc. certainly; Described oxidant can be selected N, and N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine, but be not limited to this; Described elastic resin can be selected base polyurethane prepolymer for use as, but is not limited to this; Described wax emulsion can be selected German BASF wax emulsion WE-6, and its chemical composition is dystectic OPE water-based emulsion, but is not limited to this.Described blanc fixe contains 99.9% barium sulfate; Described pigment can be selected versicolor toner, is generally organic toner.
Specific embodiment three: a kind of fluorine silicon elastic terrace, comprise basis 1, it is characterized in that: described basic 1 is disposed with scratch coat 2, fluorine silicon elasticity floating coat 3 and fluorine silicon elastic surface coating 4 from bottom to top; The primary coat that described scratch coat 2 is used is comprised of following component by weight: the Polyether 220 N of 100 parts, the polyethers 330N of 140 parts, the toluene di-isocyanate(TDI) of 120 parts, the BDO of 40 parts, the butyl acetate of 60 parts, the ethyl acetate of 70 parts; The middle painting that described fluorine silicon elasticity floating coat 3 is used is comprised of following component by weight: the Polyether 220 N of 100 parts, the polyethers 330N of 140 parts, the chlorinated paraffin wax 52 of 90 parts, the kaolin of 110 parts, the fine talc of 110 parts, the thick talcum of 160 parts, 10% chlorobenzoyl chloride of 0.8 part, the anhydrous dimethyl benzene of 300 parts, the toluene di-isocyanate(TDI) of 35 parts, the defoamer of 1 part; The face painting that described fluorine silicon elastic surface coating 4 is used is comprised of following component by weight: the elastic resin of 70 parts, the pigment of 20 parts, A component, B component; Wherein A component is comprised of following component by weight: the modified gas aerosil of 4 parts, the oxidant of 6 parts, the wax emulsion of 3 parts, the blanc fixe of 4 parts, the deionized water of 6 parts; Wherein B component is comprised of following component by weight: the isocyanate curing agent of 8 parts, the organotin catalysts of 1 part; The weight ratio of A component and B component is 10:1.
In specific embodiment three, described kaolinic order number is 1500 orders, and the order number of described fine talc is 1500 orders, and the order number of described thick talcum is 350 orders.The optional LCA-908 defoamer of producing with Shanghai Bo Xinjing innovative material Science and Technology Ltd. of described defoamer, LCA-908 defoamer belongs to neutral latent curing agent, and defoamer can also be selected mouthful oxazole alkanes latent curing agent or imines class latent curing agent etc. certainly; Described oxidant can be selected N, and N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine, but be not limited to this; Described elastic resin can be selected base polyurethane prepolymer for use as, but is not limited to this; Described wax emulsion can be selected German BASF wax emulsion WE-6, and its chemical composition is dystectic OPE water-based emulsion, but is not limited to this.Described blanc fixe contains 99.9% barium sulfate; Described pigment can be selected versicolor toner, is generally organic toner.
Simultaneously, the present invention also provides a kind of manufacture method of fluorine silicon elastic terrace, it is characterized in that: comprise a kind of fluorine silicon elastic terrace as described in specific embodiment one, specific embodiment two or specific embodiment three, and carry out according to the following steps: (1) is upper to form scratch coat 2 in basic 1 surface by primary coat minute multiple tracks roller coating with cylinder, till brushing rear basic 1 surface formation bright film; (2) with tooth scraper plate, middle painting minute multiple tracks is coated with and scrapes above to form fluorine silicon elasticity floating coat 3 in scratch coat 2 surfaces, per pass is coated with to be scraped thickness and can not surpass 2.0mm, and the interval that per pass is coated with the time of scraping is one solid being as the criterion until be coated with and scrape to desired thickness in the past; (3) with spray gun, face is coated with to a minute multiple tracks and is sprayed at fluorine silicon elasticity floating coat 3 surfaces above to form fluorine silicon elastic surface coating.
In above-mentioned steps (1), described basic 1 needs sufficiently dry, acting as of described primary coat penetrates into interior, the curing rear blocking underground aqueous vapor of minute aperture on basis 1 and reinforces basal plane, forming bright film is that the minute aperture that guarantees basis 1 stops up completely, should avoid under burning sun or the higher situation of basic 1 temperature under (45 ℃ of ﹥) construction to guarantee the permeability (without morning of fog precipitation weather or at dusk more suitable) of primary coat paint.On basic 1 surface strength ﹤ C20 or surface when looser, after available primary coat adds 1 times of thinner (dimethylbenzene or ethyl acetate) dilution, the thick basal plane that is applied to (strengthens its permeability, increase primary coat depth of penetration) until surface forms bright film, make basic 1 surface be reached construction requirement.
In above-mentioned steps (2), before construction, should carefully check and confirm can carry out 3 constructions of fluorine silicon elasticity floating coat after handle on basis 1, only need middle painting be adjusted to suitable construction denseness with thinner, per pass is coated with to be scraped general approximately 10 hours of the time interval, specifically depending on on-the-spot weather condition.When scraping, painting notes levelling effect, if can not levelling mention vestige, need add thinner to guarantee surperficial levelling, if temperature lower (10 ℃ of ﹤) and relative humidity lower (﹤ 60%), after need adding 3~8% water to stir, be coated with and scrape, with accelerated material, solidify, reduce interval time, concrete amount of water is depending on on-the-spot weather, should avoid constructing under fierce solar radiation, after fluorine silicon elasticity floating coat 3 is solid, by ponding method test surfaces planeness, ponding place repairs smooth, if having granular foreign material or be difficult to after removing place need be put down with grinding machine or the finishing of other instrument, surface just can strengthen construction.
In above-mentioned steps (3), A group and B group that face is coated with stir to scale, be diluted with water construction denseness, generally add 50~80% water (by fluorine silicon elastic surface coating 4 weight, to calculate, according to on-site actual situations, determine), need shaggy add special-purpose sand spray just can, lowest construction temperature is not less than 5 ℃.
The foregoing is only preferred embodiment of the present invention, all equalizations of doing according to the present patent application the scope of the claims change and modify, and all should belong to covering scope of the present invention.

Claims (12)

1. a fluorine silicon elastic terrace, comprises basis, it is characterized in that: described basis is disposed with scratch coat, fluorine silicon elasticity floating coat and fluorine silicon elastic surface coating from bottom to top;
The primary coat that described scratch coat is used is comprised of following component by weight: the Polyether 220 N of 80 ~ 100 parts, the polyethers 330N of 120 ~ 140 parts, the toluene di-isocyanate(TDI) of 80 ~ 120 parts, 20 ~ 40 parts 1,4-butanediol, the butyl acetate of 40 ~ 60 parts, the ethyl acetate of 50 ~ 70 parts;
The middle painting that described fluorine silicon elasticity floating coat is used is comprised of following component by weight: the Polyether 220 N of 80 ~ 100 parts, the polyethers 330N of 120 ~ 140 parts, the chlorinated paraffin wax 52 of 70 ~ 90 parts, the kaolin of 90 ~ 110 parts, the fine talc of 90 ~ 110 parts, the thick talcum of 140 ~ 160 parts, 10% chlorobenzoyl chloride of 0.2 ~ 0.8 part, the anhydrous dimethyl benzene of 260 ~ 300 parts, the toluene di-isocyanate(TDI) of 25 ~ 35 parts, the defoamer of 0.6 ~ 1 part;
The face painting of described fluorine silicon elastic surface coating is comprised of following component by weight: the elastic resin of 50 ~ 70 parts, the pigment of 10 ~ 20 parts, A component, B component; Wherein A component is comprised of following component by weight: the modified gas aerosil of 2 ~ 4 parts, the oxidant of 4 ~ 6 parts, the wax emulsion of 1 ~ 3 part, the blanc fixe of 2 ~ 4 parts, the deionized water of 4 ~ 6 parts; Wherein B component is comprised of following component by weight: the isocyanate curing agent of 6 ~ 8 parts, the organotin catalysts of 0.6 ~ 1 part; The weight ratio of A component and B component is 8-10:1.
2. a kind of fluorine silicon elastic terrace according to claim 1, is characterized in that: described kaolinic order number is 1000 ~ 1500 orders, and the order number of described fine talc is 1000 ~ 1500 orders, and the order number of described thick talcum is 300 ~ 350 orders.
3. a kind of fluorine silicon elastic terrace according to claim 1, is characterized in that: described defoamer is LCA-908 defoamer.
4. a kind of fluorine silicon elastic terrace according to claim 1, is characterized in that: described oxidant is N, N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine.
5. a kind of fluorine silicon elastic terrace according to claim 1, is characterized in that: described elastic resin is base polyurethane prepolymer for use as.
6. a kind of fluorine silicon elastic terrace according to claim 1, is characterized in that: described wax emulsion is German BASF wax emulsion WE-6, and its chemical composition is dystectic OPE water-based emulsion.
7. the manufacture method of a fluorine silicon elastic terrace, it is characterized in that: comprise a kind of fluorine silicon elastic terrace as claimed in claim 1, and carry out according to the following steps: (1) with cylinder by primary coat minute multiple tracks roller coating on surface of base to form scratch coat, with till brushing rear surface of base and forming bright film; (2) with tooth scraper plate, middle painting minute multiple tracks is coated with and is scraped on scratch coat surface to form fluorine silicon elasticity floating coat, per pass is coated with to be scraped thickness and can not surpass 2.0mm, and the interval that per pass is coated with the time of scraping is one solid being as the criterion until be coated with and scrape to desired thickness in the past; (3) with spray gun, face being coated with to a minute multiple tracks is sprayed on fluorine silicon elasticity floating coat surface to form fluorine silicon elastic surface coating.
8. the manufacture method of a kind of fluorine silicon elastic terrace according to claim 7, is characterized in that: described kaolinic order number is 1000 ~ 1500 orders, and the order number of described fine talc is 1000 ~ 1500 orders, and the order number of described thick talcum is 300 ~ 350 orders.
9. the manufacture method of a kind of fluorine silicon elastic terrace according to claim 7, is characterized in that: described defoamer is LCA-908 defoamer.
10. the manufacture method of a kind of fluorine silicon elastic terrace according to claim 7, is characterized in that: described oxidant is N, N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine.
The manufacture method of 11. a kind of fluorine silicon elastic terraces according to claim 7, is characterized in that: described elastic resin is base polyurethane prepolymer for use as.
The manufacture method of 12. a kind of fluorine silicon elastic terraces according to claim 7, is characterized in that: described wax emulsion is German BASF wax emulsion WE-6, and its chemical composition is dystectic OPE water-based emulsion.
CN201210045555.9A 2012-02-25 2012-02-25 Silicofluoride elastic terrace and manufacturing method thereof Expired - Fee Related CN102587255B (en)

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CN103755912B (en) * 2014-01-15 2016-08-17 上海后先聚氨酯有限公司 A kind of preparation method of modified polyurethane material
CN105507117B (en) * 2015-12-08 2017-10-13 江阴市江丽装饰材料有限公司 The preparation technology of polyvinyl chloride environment-friendly type outdoor sport exclusively material

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CN101723613A (en) * 2008-10-28 2010-06-09 武汉菲凡士建材有限公司 Concrete curing material
CN101832031A (en) * 2009-03-11 2010-09-15 上海市建筑装饰工程有限公司 Original traceless repairing method of multiple cracking broken terrace stone of historical protective buildings

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CN1962527A (en) * 2005-11-11 2007-05-16 中国电力工程顾问集团华东电力设计院 Antiseptic acidproof heat-proof concrete and its uses
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