CN107858061A - It is a kind of to can be used for the outdoor multifunctional aqueous floor paint of abrasion performance stain resistant - Google Patents
It is a kind of to can be used for the outdoor multifunctional aqueous floor paint of abrasion performance stain resistant Download PDFInfo
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- CN107858061A CN107858061A CN201711164543.7A CN201711164543A CN107858061A CN 107858061 A CN107858061 A CN 107858061A CN 201711164543 A CN201711164543 A CN 201711164543A CN 107858061 A CN107858061 A CN 107858061A
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- floor paint
- abrasion performance
- stain resistant
- multifunctional aqueous
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
It can be used for the outdoor multifunctional aqueous floor paint of abrasion performance stain resistant the invention discloses a kind of, including 50~100 parts of polymer emulsion, 1~2 part of diluent, 30~50 parts of silica flour, 5~15 parts of glass microballoon, 2~5 parts of pigment, 0.5~2 part of dispersant, 1~2 part of wetting agent, 0.5~2 part of defoamer, 0.5~2 part of scratching resistant, 0.5~2 part of levelling agent, 10~15 parts of curing agent, 1~2 part of curing accelerator.The composition and proportioning of polymer emulsion described in above-mentioned formula are as follows：60 90 parts of acrylic based resin hybrid modification aqueous epoxy resins, 5~10 parts of soluble polyurethane acrylate, 20~30 parts of chitose graft copolymer, 8~20 parts of water, 1~10 part of dimethylolpropionic acid, 1~5 part of ammoniacal liquor.Water-based floor paint provided by the present invention does not only have good anti-yellowing property and abrasion resistance properties, it is non-discolouring available for outdoor use, in addition, also good contaminated resistance, therefore factory, school, the terrace of house ornamentation be cannot be only used for, it also can use the metope in above-mentioned place to use, be a green, versatile multifunctional aqueous floor paint.
Description
Technical field
The invention belongs to technical field of macromolecules, and in particular to a kind of to can be used for outdoor abrasion performance stain resistant multifunctional water
Property floor paint.
Background technology
With the enhancing of national environmental protection regulation and people's environmental consciousness, water-based floor paint is widely paid close attention to, and will be modern
The main trend developed afterwards, the water-based floor paint that main flow uses in the market is aqueous epoxy floor paint.Aqueous epoxy floor
Paint is exactly to use epoxy source material as host, using water as decentralized medium, adds the auxiliary agents such as pigment, diluent, curing agent and passes through
The floor decorative material formed is allocated, aqueous epoxy floor paint can effectively protect ground, play dust-proof, wear-resisting, cleaning, moistureproof
Effect, so being widely used and being promoted by modern industry ground, commercial ground, garage floor etc., there is act foot in terrace industry
The effect of weight.
But traditional common water borne epoxide terrace paint also has its natural shortcoming：It is easy to change because its ageing-resistant performance is not good enough,
Open air is cannot be used in the easy yellowing in the serious region of solar exposure；It is easy to wear, often there is current more situation such as personnel, goods
Under, epoxide terrace film easily wears；Easy scratch, the wound (can repair, but have vestige) that unexpected sharp thing is streaked, cut is too deep
It should in time repair, otherwise can influence the adhesive force of film around it；In addition, common water-based floor paint is general due to contaminated resistance
All over deficiency, it is dirty and influence attractive in appearance and decorative effect easily to adsorb dust, is not suitable for being directly used in metope use, limit its
The use of metope.
Have some researchs in the prior art, such as Publication No. CN102492321B Chinese patent discloses one kind third
Olefin(e) acid ester floor paint, it is made up of first, second, the third three components；Its preparation method, comprise the following steps：(1) by carbamate propylene
Acid esters oligomer mixes heating with drying oil, cross-linking monomer, reactive diluent, and toughener, section wax, inhibition are added in stirring
Agent, it is incubated, after transparent and homogeneous mixture A to be formed, cooling；(2) compound accelerant is taken to be well mixed with part mixes A, side
Stir side and add pigment, filler, aerosil, at a high speed after scattered 28-32min, filtering, produce first component；(3) take mixed
Compound A remainder is well mixed with acrylate oligomer, produces second component；(4) third components are peroxide.But its
Preparation technology is complicated, when not can effectively solve the problem that use out of doors the problem of yellowing, abrasion and stain resistance deficiency.
The content of the invention
Goal of the invention：For weak point of the prior art, the invention provides a kind of resistance to Huang that can be used out of doors
Become wear-resistant and stain resistant water-based floor paint.The water-based floor paint of the present invention has good anti-yellowing property and wear resistance
Can, it is non-discolouring available for outdoor use, in addition, also good contaminated resistance, cannot be only used for factory, school, house ornamentation
Terrace, also can use the metope in above-mentioned place to use, solve the problems, such as traditional terrace be not suitable for metope use, have it is good
Good workability, and water-based floor paint of the present invention uses water to belong to water-based system as decentralized medium, do not contain
Solvent and formaldehyde, it is a green, versatile multifunctional aqueous floor paint.
Technical scheme：
The anti abrasive floor paint of color inhibition provided by the present invention, described floor paint include polymer emulsion 50~100
Part, 1~2 part of diluent, 30~50 parts of silica flour, 5~15 parts of glass microballoon, 2~5 parts of pigment, 0.5~2 part of dispersant, wetting
1~2 part of agent, 0.5~2 part of defoamer, 0.5~2 part of scratching resistant, 0.5~2 part of levelling agent, 10~15 parts of curing agent, accelerator
1~2 part.
Further, the composition of the polymer emulsion described in above-mentioned formula and proportioning are as follows：Acrylic based resin hydridization
60~90 parts of modified aqueous epoxy resin, 5~10 parts of soluble polyurethane acrylate, chitose graft copolymer 20~30
Part, 8~20 parts of water, 1~10 part of dimethylolpropionic acid, 1~5 part of ammoniacal liquor.The solid content of the polymer emulsion be 40~
60%.
Acrylic based resin hybrid modification aqueous epoxy resins of the present invention, it is by acrylic based resin emulsion and water
The property blended hydridization of epoxy resin obtains.Further, the comonomer of acrylic based resin emulsion of the present invention include but
It is not limited to methyl acrylate, ethyl acrylate, butyl acrylate, 2-EHA, methyl methacrylate, acetic acid second
Alkene ester, hydroxy-ethyl acrylate, acrylonitrile, acrylic acid, methacrylic acid, styrene, vinyltrimethoxy silane, vinyl three
Ethoxysilane, methacryloxypropyl trimethoxy silane etc., further, acrylic based resin of the present invention
Emulsion can be polymerize using seeded emulsion polymerization method, and described acrylic based resin emulsion includes but is not limited to pure third breast
Liquid, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion and silicone acrylic emulsion etc..The aqueous epoxy resins system epoxy resin aqueous solution or ring of the present invention
Oxygen tree fat liquor, epoxy resin water solution system of the present invention are dispersed or be dissolved in the water by liquid epoxies
Arrive；Epoxy emulsion of the present invention is not limited to following methods but can be prepared by following phase inversion：First at a high speed
First additional emulsifying agent and liquid epoxies are well mixed under shearing condition, then under certain shearing condition slowly to
Deionized water is added in system, with the gradual increase of rate of water added, whole system is also progressively changed from Water-In-Oil to oil-in-water, finally
Form uniform and stable emulsion system.
The present invention introduces a kind of compound with various polarity functional group, i.e. chitosan graft in polymer emulsion
Copolymer, the molecular weight of the chitose graft copolymer is 5000-10000.The hydroxyl value of the chitose graft copolymer is
200-500mgKOH/g.It can both participate in the synthesis of aqueous polyurethane emulsion, remain again per se with a large amount of polarity officials
It can roll into a ball, raise the polarity of final products.Meanwhile modified monomer can be introduced in branch terminals, its crosslinking knot formed after hydrolyzing
Structure can further improve the water resistance of product, solvent resistance, heat resistance, mechanical property etc..The specific chitosan graft
The modified monomer of copolymer is the one or more in acrylamide, acrylic acid, 2- acrylamide-2-methyl propane sulfonics, preferably
2- acrylamide-2-methyl propane sulfonics.
In emulsion, the polar group of chitose graft copolymer disperses into water, and modified monomer part is into emulsion particle
Portion stretches, so as to help emulsion particle to be more stably scattered in aqueous medium；And when lotion applicator is when on polarity matrix, shell gathers
The polar group of sugared graft copolymer can be combined with the polarity matrix of emulsion, and the modified monomer part of low polarity can be to film surface
Diffusion, so as to form one layer of hydrophobic protective layer, enhances the stability of emulsion system；In addition, modified monomer in itself can also
Further crosslinking, so as to improve the water resistance of product and mechanical property.
Further, the mesh number of the silica flour described in above-mentioned formula is in 300-2000 mesh, preferably 800-1250 mesh.
Further, the diluent described in above-mentioned formula is butyl acetate.The defoamer is polyether-modified poly- silica
Alkane solution；The levelling agent is fluorine carbon levelling agent；The scratching resistant is polytetrafluoroethylwax wax.The curing agent is modified fat
Amine curing agent；The accelerator is amine epoxy curing accelerator.
Beneficial effect：The shortcomings of improving the easy xanthochromia of traditional aqueous epoxy floor paint, easy to wear, easy cut, both with ring
Oxygen tree fat high mechanical strength, the characteristics of Corrosion Protection is excellent, adhesive force is high, wearability is good, have acrylic resin weather-proof again
The characteristics of the characteristics of performance is good, ornamental high, also polyurethane resin hardness height, shock resistance, good wearability, combine asphalt mixtures modified by epoxy resin
The advantages of fat, acrylic resin and polyurethane resin, therefore can adapt to the needs of different application occasion.
By the present invention in that with acrylic resin and polyurethane resin modified epoxy, and add modification of chitosan grafting
Copolymer so that floor paint provided by the present invention does not only have good anti-yellowing property and abrasion resistance properties, available for open air
Using and it is non-discolouring, in addition, also good contaminated resistance, therefore the water-based floor paint of the present invention, cannot be only used for factory,
School, the terrace of house ornamentation, the metope in above-mentioned place also can use to use, solve that traditional terrace is not suitable for that metope uses asks
Topic, has good workability, and water-based floor paint of the present invention uses water to belong to water-based body as decentralized medium
System, is a green, versatile multifunctional aqueous floor paint without organic solvent and formaldehyde.
Main material of the present invention is water-based system, is easily mixed, and processing technology is simple and easy.Pass through in formula
Using a small amount of diluent dissolving and mixed aid, and apply simple scattered stirring, it is possible to realize hybridization epoxy resin,
The mixing of acrylic acid modified resin and filler, it is easy to operation.In addition, raw material of the present invention, nontoxic pollution-free, has
Beneficial to environmental protection.
Embodiment：
The raw material or additive of dated specific name are not known in the present embodiment, indicates no particular/special requirement, using this
Material known to field and dosage.
Embodiment 1
Polymer emulsion A is formulated：60 parts of acrylic based resin hybrid modification aqueous epoxy resins, soluble polyurethane propylene
5 parts of acid esters, 20 parts of chitose graft copolymer, 8 parts of water, 1 part of dimethylolpropionic acid, 1 part of ammoniacal liquor.The chitosan graft copolymerization
The modified monomer of thing is acrylic acid.The molecular weight of the chitose graft copolymer is 5000-10000, hydroxyl value 200-
500mgKOH/g.The solid content that polymer emulsion A is formulated in the present embodiment is 50%.
Embodiment 2
Polymer emulsion B is formulated：90 parts of acrylic based resin hybrid modification aqueous epoxy resins, soluble polyurethane propylene
10 parts of acid esters, 30 parts of chitose graft copolymer, 20 parts of water, 10 parts of dimethylolpropionic acid, 5 parts of ammoniacal liquor.The chitosan graft
The modified monomer of copolymer is acrylamide.The molecular weight of the chitose graft copolymer is 5000-10000, and hydroxyl value is
200-500mgKOH/g.The solid content that polymer emulsion B is formulated in the present embodiment is 60%.
Embodiment 3
Polymer emulsion C is formulated：90 parts of acrylic based resin hybrid modification aqueous epoxy resins, soluble polyurethane propylene
5 parts of acid esters, 20 parts of chitose graft copolymer, 20 parts of water, 10 parts of dimethylolpropionic acid, 1 part of ammoniacal liquor.The chitosan graft is total to
The modified monomer of polymers is 2- acrylamide-2-methyl propane sulfonics.The molecular weight of the chitose graft copolymer is 5000-
10000, hydroxyl value 200-500mgKOH/g.The solid content that polymer emulsion C is formulated in the present embodiment is 40%.
Embodiment 4
The formula of floor paint：50 parts of polymer emulsion, 1 part of diluent, 30 parts of silica flour, 5 parts of glass microballoon, 2 parts of pigment,
0.5 part of dispersant, 1 part of wetting agent, 0.5 part of defoamer, 0.5 part of scratching resistant, 0.5 part of levelling agent, modified fatty amine curing agent
10~15 parts, 1 part of amine epoxy curing accelerator.Described polymer emulsion uses the polymer emulsion obtained by embodiment 1
A.The defoamer is Siloxane-Oxyalkylene Copolymers solution；The levelling agent is fluorine carbon levelling agent；The scratching resistant is poly- four
PVF wax；Described diluent is butyl acetate.The silica flour mesh number is 800 mesh.
Embodiment 5
The formula of floor paint：Substantially the same manner as Example 4, difference is, polymer emulsion A is replaced with into embodiment
The polymer emulsion B of 2 gained.
Embodiment 6
The formula of floor paint：Substantially the same manner as Example 4, difference is, polymer emulsion A is replaced with into embodiment
The polymer emulsion C of 3 gained.
Embodiment 7
The formula of floor paint：100 parts of polymer emulsion, 2 parts of diluent, 50 parts of silica flour, 15 parts of glass microballoon, 5 parts of face,
2 parts of dispersant, 2 parts of wetting agent, 2 parts of defoamer, 2 parts of scratching resistant, 2 parts of levelling agent, 15 parts of modified fatty amine curing agent, amine
2 parts of Epoxy curing accelerators.Described polymer emulsion uses the polymer emulsion A obtained by embodiment 1.The defoamer is
Siloxane-Oxyalkylene Copolymers solution；The levelling agent is fluorine carbon levelling agent；The scratching resistant is polytetrafluoroethylwax wax.Described
Diluent is butyl acetate.The silica flour mesh number is 1250 mesh.
Embodiment 8
The formula of floor paint：Substantially the same manner as Example 7, difference is, polymer emulsion A is replaced with into embodiment
The polymer emulsion B of 2 gained.
Embodiment 9
The formula of floor paint：Substantially the same manner as Example 7, difference is, polymer emulsion A is replaced with into embodiment
The polymer emulsion C of 3 gained.
The floor paint of the gained of 4~embodiment of embodiment 9 is subjected to sample preparation maintenance by GB/T 22374-2008 standards and carried out
Performance test, the result of the test of gained are as shown in the table：
Claims (9)
1. a kind of can be used for the outdoor multifunctional aqueous floor paint of abrasion performance stain resistant, it is characterised in that described floor paint includes
50~100 parts of polymer emulsion, 1~2 part of diluent, 30~50 parts of silica flour, 5~15 parts of glass microballoon, pigment 2~5 part, point
0.5~2 part of powder, 1~2 part of wetting agent, 0.5~2 part of defoamer, 0.5~2 part of scratching resistant, 0.5~2 part of levelling agent, solidification
10~15 parts of agent, 1~2 part of accelerator.
2. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 1, its feature exist
It is as follows in the composition and proportioning of described polymer emulsion：Acrylic based resin hybrid modification aqueous epoxy resins 60-90 parts, water
5~10 parts of soluble polyurethane acrylate, 20~30 parts of chitose graft copolymer, 8~20 parts of water, dimethylolpropionic acid 1~
10 parts, 1~5 part of ammoniacal liquor.
3. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 2, its feature exist
In the molecular weight of the chitose graft copolymer be 5000-10000.
4. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 2, its feature exist
In the hydroxyl value of the chitose graft copolymer be 200-500mgKOH/g.
5. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 2, its feature exist
In the modified monomer of the chitose graft copolymer be acrylamide, acrylic acid, in 2- acrylamide-2-methyl propane sulfonics
It is one or more.
6. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 1, its feature exist
In the mesh number 800-1250 mesh of described silica flour.
7. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 1, its feature exist
In described diluent be butyl acetate.
8. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 1, its feature exist
In the defoamer be Siloxane-Oxyalkylene Copolymers solution；The levelling agent is fluorine carbon levelling agent；The scratching resistant is poly- four
PVF wax.
9. a kind of multifunctional aqueous floor paint of abrasion performance stain resistant that can be used for open air as claimed in claim 1, its feature exist
In the curing agent be modified fat amine curing agent；The accelerator is amine epoxy curing accelerator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711164543.7A CN107858061A (en) | 2017-11-21 | 2017-11-21 | It is a kind of to can be used for the outdoor multifunctional aqueous floor paint of abrasion performance stain resistant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711164543.7A CN107858061A (en) | 2017-11-21 | 2017-11-21 | It is a kind of to can be used for the outdoor multifunctional aqueous floor paint of abrasion performance stain resistant |
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| Publication Number | Publication Date |
|---|---|
| CN107858061A true CN107858061A (en) | 2018-03-30 |
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ID=61702965
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711164543.7A Pending CN107858061A (en) | 2017-11-21 | 2017-11-21 | It is a kind of to can be used for the outdoor multifunctional aqueous floor paint of abrasion performance stain resistant |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101654583A (en) * | 2009-09-24 | 2010-02-24 | 北京红狮漆业有限公司 | Compound epoxy flooring coating and preparation method thereof |
| CN105566595A (en) * | 2015-12-29 | 2016-05-11 | 优美特（北京）环境材料科技股份公司 | Aqueous polyurethane emulsion used for polar surface coating, and preparation method thereof |
| CN106811006A (en) * | 2017-02-14 | 2017-06-09 | 江苏艾科赛特新材料有限公司 | It is a kind of to can be used for the aqueous epoxy floor coating compositions and preparation method of outdoor |
-
2017
- 2017-11-21 CN CN201711164543.7A patent/CN107858061A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101654583A (en) * | 2009-09-24 | 2010-02-24 | 北京红狮漆业有限公司 | Compound epoxy flooring coating and preparation method thereof |
| CN105566595A (en) * | 2015-12-29 | 2016-05-11 | 优美特（北京）环境材料科技股份公司 | Aqueous polyurethane emulsion used for polar surface coating, and preparation method thereof |
| CN106811006A (en) * | 2017-02-14 | 2017-06-09 | 江苏艾科赛特新材料有限公司 | It is a kind of to can be used for the aqueous epoxy floor coating compositions and preparation method of outdoor |
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Application publication date: 20180330 |