CN104479529A - Aqueous floor paint for silicon PU rubber - Google Patents
Aqueous floor paint for silicon PU rubber Download PDFInfo
- Publication number
- CN104479529A CN104479529A CN201410724975.9A CN201410724975A CN104479529A CN 104479529 A CN104479529 A CN 104479529A CN 201410724975 A CN201410724975 A CN 201410724975A CN 104479529 A CN104479529 A CN 104479529A
- Authority
- CN
- China
- Prior art keywords
- water
- component
- floor paint
- silicon
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to aqueous floor paint for silicon PU rubber. A component A is water-dispersible isocyanate of which the solid content is 100% by mass; a component B is prepared from the following components in parts by mass: 10-20 parts of water, 3-10 parts of an aqueous acrylate dispersing body, 50-75 parts of acrylic hydroxyl emulsion, 10-20 parts of aqueous pigment paste of different colors, 0.2-0.5 part of a defoaming agent, 0.1-0.3 part of a polyether modified siloxane wetting flatting agent, 1-3 parts of a high molecular weight segmented copolymer type adhesion accelerant, 1-4 parts of high-density oxidized polyethlene wax emulsion, 0.1-0.3 part of a hybridization bactericide and 0.1-0.6 part of an organic modified montmorillonite aqueous rheological agent. Before the aqueous floor paint is used, the component A and the component B are uniformly mixed in a mass ratio of 1:(10-12), thereby obtaining the aqueous floor paint. The content of VOC of the aqueous floor paint is very low, and the paint film is excellent in property and is applicable to coating decoration and protection of silicon PU rubber floors.
Description
Technical field
The present invention relates to a kind of water-based floor paint for silicon PU plastic cement.
Background technology
Along with Chinese society expanding economy, nationwide fitness programs theory gos deep into the popular feelings just day by day, large to each city, littlely can build different classes of athletic ground to each community or unit, for body-building and match provide facility.Organic silicon modified polyurethane plastic material (hereinafter referred to as silicon PU plastic cement) has not easily aging, the advantage such as cracking, bubbling, the phenomenon such as can not to harden because of environment changes such as outdoor high and low temperature weathers, feel like jelly, when it is used as athletic ground terrace, the elastic system design of the upper hard lower bullet of its uniqueness, the enhancement Layer on upper strata retains enough bounce-back supports, for steady, multidirectional in motion, move demand fast and provide sufficient physical basis to ensure, meet the requirement of professional motion to the feel of the ball simultaneously; The elastic layer of lower floor then absorbs surging force by shrinking, and during recovery, pressurized saves up strength and forms high resilience upwards by enhancement Layer, can improve the effect of motion while the sport injury caused in the face of the reactive force of ankle, joint, ligament with effectively extenuating.Therefore, silicon PU plastic cement becomes the best athletic ground floor material that market is generally acknowledged, is thus used widely.When usual silicon PU plastic cement is used as terrace, need to apply one deck floor paint at silicon PU plastic surface, not only effectively can solve the aberration problem of enhancement Layer, there is better decorative effect, and further increase the performance such as wear resistance, resistant to chemical media of terrace, thus substantially increase the useful life longevity of whole terrace.At present, as the floor paint of silicon PU plastic cement, mainly solvent based coating, it, producing and having a large amount of organic solvent volatilizations in construction process, causes serious harm to environment and HUMAN HEALTH.In recent years, along with the raising of people's environmental consciousness, no-solvent polyurethane oiliness floor paint and water-based floor paint are necessarily developed, but, in no-solvent polyurethane oiliness floor paint, solidifying agent component still can be subject to impact and the restriction of the temperature of environment, humidity, basic unit's degree of drying and other problems at construction process, the disadvantage such as paint film easily occurs foaming, bubbling, comes off, attachment; At present then there is the sticking power problems such as especially wet adhesion is not good in institute's use floor paint, have impact on the useful life longevity of silicon PU plastics floor.
Summary of the invention
The object of the invention is: provide a kind of water-based floor paint for silicon PU plastic cement, it has fabulous dry, wet adhesion to silicon PU plastic cement, and has good wear resistance, weathering resistance and resistant to chemical media.
The technical scheme realizing the object of the invention is: a kind of water-based floor paint for silicon PU plastic cement, and it is made up of first component and second component, it is characterized in that, before using, first component mixes with ratio 1:10 ~ 12 of second components in mass portion and is water-based floor paint;
Described first component is the product B ayhydur 2547 of Bayer A.G, and it is that water dispersibles type isocyanic ester, and its solids content is 100wt%;
Described second component is made up of following each component, each constituent mass part is: water 10 ~ 20, water soluble acrylic acid ester dispersion 3 ~ 10, Acrylic hydroxyl emulsion 50 ~ 75, assorted colourant slurry 10 ~ 20, defoamer 0.2 ~ 0.5, polyether-modified silicon oxidation alkane type moistening flatting agent 0.1 ~ 0.3, high molecular weight block copolymer type adhesion promoter 1 ~ 3, high-density oxidized polyethylene wax emulsion 1 ~ 4, heterocyclic nitrogen-group fungicide 0.1 ~ 0.3, organically modified montmorillonite clay class water-based auxiliary rheological agents 0.1 ~ 0.6, wherein:
Acrylic hydroxyl emulsion is the product of environmental protection coating material company limited of CNOOC, and its trade mark is CTD-6910, and it is a kind of hydroxyl latex emulsion with coreshell type structure, and solids content is 43 ± 2wt%, hydroxy radical content 1.3 ~ 1.4wt%, pH value 7 ~ 9;
Water soluble acrylic acid ester dispersion is the product of Bayer A.G, and its trade mark is Bayhydrol XP 2542, and solids content is 50 ± 2wt%, hydroxy radical content 3.3wt%, pH value 7 ~ 9;
High molecular weight block copolymer type adhesion promoter is the product of German BYK company, and its trade mark is BYK-4500, and solids content is 40 ± 2wt%;
Organically modified montmorillonite clay class water-based auxiliary rheological agents is the product B ENTONE EW of this company of hamming of the U.S. or the product OPTIGEL SH of German South Chemical Company;
High-density oxidized polyethylene wax emulsion is the one in product A QUMAT 208, the AQUMAT263 of German BYK company;
Defoamer is the product Defoamer A 363 of Shenzhen Haichuan Company.
The above-mentioned water-based floor paint for silicon PU plastic cement, the assorted colourant slurry in second component described in it is one or more in rutile type titanium stock white, iron oxide yellow mill base, red iron oxide mill base, phthalocyanine green mill base.
The above-mentioned water-based floor paint for silicon PU plastic cement, described in it, second component is prepared as follows:
1. raw material is prepared by each amounts of components of above-mentioned second component;
2. in a reservoir, water, organically modified montmorillonite clay class water-based auxiliary rheological agents that 1. step prepares is added successively, with 2500 revs/min of dispersed with stirring 20 minutes after adding, obtained water-based auxiliary rheological agents aqueous dispersions;
3. in another container, add water soluble acrylic acid ester dispersion, Acrylic hydroxyl emulsion, assorted colourant slurry, defoamer, polyether-modified silicon oxidation alkane type moistening flatting agent, high molecular weight block copolymer type adhesion promoter, high-density oxidized polyethylene wax emulsion, heterocyclic nitrogen-group fungicide that 1. step prepares successively, after stirring 20 minutes with 2500 revs/min, add the water-based auxiliary rheological agents aqueous dispersions that 2. step is prepared, continue stirring 20 minutes;
4. material step 3. obtained 80 object silk strainer filterings are packed, and obtain the second component of the water-based floor paint for silicon PU plastic cement.
Technique effect of the present invention is: technical solution of the present invention has following beneficial effect:
1. the main film forming substance in second component of the present invention is made up of jointly Acrylic hydroxyl emulsion, water soluble acrylic acid ester dispersion, good mating reaction is had each other when film forming, paint film is made to have excellent performance, this is because: do not exist easily by the group of ultraviolet light degradation in one two kinds of resins used, the paint film thus after solidification has outstanding weathering resistance; Its diacrylate hydroxyl latex emulsion constitutes the skeleton of film, the nucleocapsid structure of its uniqueness, and hydroxy functional group is distributed in the shell of emulsion particle, easily contacts and react with solidifying agent, and the paint film after solidification has the performances such as good resistant to chemical media, wear resistance; Its three Acrylic hydroxyl emulsion selected has appropriate hydroxy radical content, paint film is made to have suitable cross-linking density, thus make to average out between the performances such as the sticking power of paint film, hardness and resistant to chemical media, avoid because of hydroxy radical content too low time affect hardness, the resistant to chemical media of paint film, prevent again because of hydroxy radical content too high time cause paint film internal stress comparatively large, make loss of adhesion on silicon PU plastic cement of paint film; Its tetrapropylene acid hydroxyl latex emulsion rate of drying is fast, and water soluble acrylic acid ester dispersion rate of drying is slow, by both choose reasonable usage ratio, the rate of drying of paint film is made to control in the suitable time period, the existing suitable paint film open hour, avoid causing because drying varniss is too fast paint film lap-joint to produce aberration, do not affect again total construction speed of terrace enamelled coating simultaneously.2. the present invention adopt high molecular weight block copolymer type adhesion promoter and floor paint system compatibility of the present invention good, color stuffing particle in paint film is fettered by coupled action by the group in its molecular structure, improve the floating of paint film, face in color stuffing particle in paint film and silicon PU plastic cement, filler grain are closely linked together simultaneously, improve the sticking power of paint film on silicon PU plastic cement.3. the high-density oxidized polyethylene wax emulsion that the present invention adopts can not only improve the wear resistance of paint film, and there is good photoextinction, directly add when joining paint, very easily be uniformly dispersed, simplify the production technique of floor paint, and in storage process, not easily there is sedimentation caking, solve common matting agent in water-borne coatings, be difficult to the problems such as dispersion, interpolation and easy sedimentation caking.4. present invention uses suitable organically modified montmorillonite clay class water-based auxiliary rheological agents, appropriate thixotroping effectively can improve floating and the application property of paint vehicle, and the impact of its water tolerance on paint film wants much slight more than conventional Natvosol class water-based auxiliary rheological agents.
Embodiment
Below in conjunction with embodiment, the present invention is described further, but is not limited to this.
Embodiment and comparative example raw materials, be unless otherwise indicated coating technical grade commercially available product, buy by commercial channel, involved equipment is coatings industry conventional equipment.
Embodiment 1 ~ 2 is for the preparation of the second component of the water-based floor paint of silicon PU plastic cement
(1) fill a prescription
The second component of water-based floor paint of the present invention is made up of following each component, each constituent mass part is: water 10 ~ 20, water soluble acrylic acid ester dispersion 3 ~ 10, Acrylic hydroxyl emulsion 50 ~ 75, assorted colourant slurry 10 ~ 20, defoamer 0.2 ~ 0.5, polyether-modified silicon oxidation alkane type moistening flatting agent 0.1 ~ 0.3, high molecular weight block copolymer type adhesion promoter 1 ~ 3, high-density oxidized polyethylene wax emulsion 1 ~ 4, heterocyclic nitrogen-group fungicide 0.1 ~ 0.3, organically modified montmorillonite clay class water-based auxiliary rheological agents 0.1 ~ 0.6, the concrete formula of embodiment 1 ~ 2 is in table 1.
Table 1
(2) preparation technology
Prepare as follows:
Each amounts of components of the second component 1. provided by table 1 prepares raw material;
2. in a reservoir, water, organically modified montmorillonite clay class water-based auxiliary rheological agents that 1. step prepares is added successively, with 2500 revs/min of dispersed with stirring 20 minutes after adding, obtained water-based auxiliary rheological agents aqueous dispersions;
3. in another container, add water soluble acrylic acid ester dispersion, Acrylic hydroxyl emulsion, assorted colourant slurry, defoamer, polyether-modified silicon oxidation alkane type moistening flatting agent, high molecular weight block copolymer type adhesion promoter, high-density oxidized polyethylene wax emulsion, hydridization series bactericidal agent that 1. step prepares successively, after stirring 20 minutes with 2500 revs/min, add the water-based auxiliary rheological agents aqueous dispersions that 2. step is prepared, continue stirring 20 minutes;
4. the material 3. step obtained 80 object silk strainer filterings, to pack, obtain the second component of the water-based floor paint for silicon PU plastic cement of embodiment 1 and 2.
detect water-based floor paint paint film property of the present invention
The second component that embodiment 1,2 obtains mixes obtained water-based floor paint 1 and 2 of the present invention respectively by the mass parts of first component and second component than the proportioning for 1:11 and 1:12 respectively, wherein, first component used is the product B ayhydur 2547 of Bayer A.G, it is that water dispersibles type isocyanic ester, and its solids content is 100wt%;
With above-mentioned obtained water-based floor paint of the present invention 1 and 2, respectively in the coating of silicon PU plastic cement specimen surface, under being then placed in standard state, place after 7 days, by the properties of corresponding coating national standard method test sample plate paint film, the results are shown in Table 2.
Table 2
From the result of table 2; the VOC content that the present invention is used for the water-based floor paint of silicon PU plastic cement is extremely low; dry sticking power (sticking power namely in table 2) on silicon PU plastic surface, wet adhesion (sticking power after the immersion 30d namely in table 2) are excellent; the physical and mechanical properties of paint film, chemical-resistant and weathering resistance are excellent, are suitable for very much application decoration and the protection of silicon PU plastics floor.
Comparative example 1 ~ 2 water-based floor paint
The second component formula of comparative example 1 water-based floor paint is substantially the same manner as Example 1, difference uses the Acrylic hydroxyl emulsion that the trade mark is CTD-6924 to substitute CTD-6910 Acrylic hydroxyl emulsion, CTD-6924 Acrylic hydroxyl emulsion has identical nucleocapsid structure with the CTD-6910 Acrylic hydroxyl emulsion in embodiment 1, but hydroxy radical content is 3.5wt%, the second component of comparative example 1 water-based floor paint is specifically filled a prescription in table 3;
Comparative example 2 is mono-component aqueous floor paint, use CTD-6910 Acrylic hydroxyl emulsion and Bayhydrol XP 2542 water soluble acrylic acid ester dispersion in the aqueous polyurethane dispersion BayhydrolXP2621 alternate embodiment 1 of not hydroxy functional groups, the concrete formula of comparative example 2 water-based floor paint is in table 3.
Table 3
detect comparative example water-based floor paint paint film property
The second component that comparative example 1 obtains mixes obtained comparative example 1 water-based floor paint with the mass parts of second component than for 1:8 proportioning by first component, wherein, first component used is the product B ayhydur 2547 of Bayer A.G, it is that water dispersibles type aliphatic isocyanates, and its solids content is 100wt%;
Each component is mixed obtained comparative example 2 water-based floor paint by the formula of table 3 by comparative example 2;
With above-mentioned obtained comparative example 1 and 2 water-based floor paint, respectively in the coating of silicon PU plastic cement specimen surface, under being then placed in standard state, place after 7 days, by the properties of corresponding coating national standard method test sample plate paint film, the results are shown in Table 4.
Table 4
From the results shown in Table 4, compared with comparative example 1 water-based floor paint, water-based floor paint 1 of the present invention adopts Acrylic hydroxyl emulsion hydroxy radical content appropriate, after film curing, average out between the performances such as sticking power, hardness and resistant to chemical media on silicon PU plastic surface, there is excellent over-all properties; Compared with comparative example 2 water-based floor paint, water-based floor paint 1 performance of the present invention is better than the water-based floor paint of comparative example 2 single component comprehensively.
Comparative example 3 water-based floor paint
Formula, the preparation technology of comparative example 3 water-based floor paint second component are substantially the same manner as Example 1, and difference does not add high molecular weight block copolymer type adhesion promoter in formula.The preparation of comparative example 3 water-based floor paint and test sample plate are all identical with water-based floor paint 1 of the present invention, and detected result is in table 5.
Table 5
As can be seen from the comparative result of table 5, compared with comparative example 3, owing to the addition of high molecular weight block copolymer type adhesion promoter in second component of the present invention, not only improve the dry sticking power of film on silicon PU plastic surface (sticking power namely in table 5) and improve wet adhesion (sticking power of the 30d that namely soaks in table 5).
Comparative example 4 ~ 5 water-based floor paint
The second component formula of comparative example 4 and 5 water-based floor paint is substantially the same manner as Example 2, and difference is: comparative example 4 uses the polyurethane thickener SN-612 of Japanese Sang Nuopuke company to replace organically modified montmorillonite clay class aqueous flow to become auxiliary agent B ENTONE EW; Comparative example 5 uses the sub-Natvosol HBR-250 across imperial company of the U.S. to replace organically modified montmorillonite clay class aqueous flow to become auxiliary agent B ENTONE EW.
The preparation of comparative example 4 ~ 5 water-based floor paint and test sample plate are all identical with water-based floor paint 2 of the present invention, and detected result is in table 6.
Table 6
As can be seen from the comparative result of table 6, water-based floor paint 2 of the present invention adopts organically modified montmorillonite clay class aqueous flow to become auxiliary agent B ENTONE EW, compared with the polyurethane thickener used, improves floating and the application property of coating with comparative example 4 water-based floor paint; Compared with the Natvosol class water-based auxiliary rheological agents used with comparative example 5 water-based floor paint, its wetting ability is lower, thus on the water tolerance of paint film, acid resistance and water-fast after wet adhesion impact less.
Claims (3)
1. for a water-based floor paint for silicon PU plastic cement, it is made up of first component and second component, it is characterized in that, before using, first component mixes with ratio 1:10 ~ 12 of second components in mass portion and is water-based floor paint;
Described first component is the product B ayhydur 2547 of Bayer A.G, and it is that water dispersibles type isocyanic ester, and its solids content is 100wt%;
Described second component is made up of following each component, each constituent mass part is: water 10 ~ 20, water soluble acrylic acid ester dispersion 3 ~ 10, Acrylic hydroxyl emulsion 50 ~ 75, assorted colourant slurry 10 ~ 20, defoamer 0.2 ~ 0.5, polyether-modified silicon oxidation alkane type moistening flatting agent 0.1 ~ 0.3, high molecular weight block copolymer type adhesion promoter 1 ~ 3, high-density oxidized polyethylene wax emulsion 1 ~ 4, heterocyclic nitrogen-group fungicide 0.1 ~ 0.3, organically modified montmorillonite clay class water-based auxiliary rheological agents 0.1 ~ 0.6, wherein:
Acrylic hydroxyl emulsion is the product of environmental protection coating material company limited of CNOOC, and its trade mark is CTD-6910, and it is a kind of hydroxyl latex emulsion with coreshell type structure, and solids content is 43 ± 2wt%, hydroxy radical content 1.3 ~ 1.4wt%, pH value 7 ~ 9;
Water soluble acrylic acid ester dispersion is the product of Bayer A.G, and its trade mark is Bayhydrol XP 2542, and solids content is 50 ± 2wt%, hydroxy radical content 3.3wt%, pH value 7 ~ 9;
High molecular weight block copolymer type adhesion promoter is the product of German BYK company, and its trade mark is BYK-4500, and solids content is 40 ± 2wt%;
Organically modified montmorillonite clay class water-based auxiliary rheological agents is the product B ENTONE EW of this company of hamming of the U.S. or the product OPTIGEL SH of German South Chemical Company;
High-density oxidized polyethylene wax emulsion is the one in product A QUMAT 208, the AQUMAT263 of German BYK company;
Defoamer is the product Defoamer A 363 of Shenzhen Haichuan Company.
2. the water-based floor paint for silicon PU plastic cement according to claim 1, is characterized in that, the assorted colourant slurry in described second component is one or more in rutile type titanium stock white, iron oxide yellow mill base, red iron oxide mill base, phthalocyanine green mill base.
3. the water-based floor paint for silicon PU plastic cement according to claim 1, is characterized in that, described second component is prepared as follows:
1. raw material is prepared by each amounts of components of second component according to claim 1;
2. in a reservoir, water, organically modified montmorillonite clay class water-based auxiliary rheological agents that 1. step prepares is added successively, with 2500 revs/min of dispersed with stirring 20 minutes after adding, obtained water-based auxiliary rheological agents aqueous dispersions;
3. in another container, add water soluble acrylic acid ester dispersion, Acrylic hydroxyl emulsion, assorted colourant slurry, defoamer, polyether-modified silicon oxidation alkane type moistening flatting agent, high molecular weight block copolymer type adhesion promoter, high-density oxidized polyethylene wax emulsion, heterocyclic nitrogen-group fungicide that 1. step prepares successively, after stirring 20 minutes with 2500 revs/min, add the water-based auxiliary rheological agents aqueous dispersions that 2. step is prepared, continue stirring 20 minutes;
4. material step 3. obtained 80 object silk strainer filterings are packed, and obtain the second component of the water-based floor paint for silicon PU plastic cement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410724975.9A CN104479529A (en) | 2014-12-03 | 2014-12-03 | Aqueous floor paint for silicon PU rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410724975.9A CN104479529A (en) | 2014-12-03 | 2014-12-03 | Aqueous floor paint for silicon PU rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104479529A true CN104479529A (en) | 2015-04-01 |
Family
ID=52754142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410724975.9A Pending CN104479529A (en) | 2014-12-03 | 2014-12-03 | Aqueous floor paint for silicon PU rubber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104479529A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057545A (en) * | 2016-12-28 | 2017-08-18 | 中国海洋石油总公司 | Applied in aqueous dual-component acroleic acid polyurethane and preparation method thereof |
| CN108047857A (en) * | 2018-01-05 | 2018-05-18 | 吕跃文 | Aqueous forest negative oxygen ion plastic paint and preparation method thereof |
| CN109535990A (en) * | 2018-11-26 | 2019-03-29 | 新疆天地金阳环保新材料有限公司 | Two-component silicon PU elastic layer and preparation method thereof and sports ground silicon PU material and preparation method thereof |
| CN114163887A (en) * | 2022-01-13 | 2022-03-11 | 衡水新光新材料科技有限公司 | Environment-friendly single-component floor paint and preparation method thereof |
| EP3904464A4 (en) * | 2018-12-27 | 2022-09-07 | Nippon Paint Industrial Coatings Co., Ltd. | Water-based coating composition and method for forming coating film |
| CN115785783A (en) * | 2022-12-05 | 2023-03-14 | 上海正欧实业有限公司 | Weather-resistant floor paint and preparation method thereof |
| CN116063916A (en) * | 2023-03-08 | 2023-05-05 | 湖南子杨建筑装饰材料有限公司 | High-hardness water-based polyurethane floor coating |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000281533A (en) * | 1999-03-30 | 2000-10-10 | Pola Chem Ind Inc | Coated powder and composition containing the same |
| CN101654589A (en) * | 2009-09-24 | 2010-02-24 | 中国海洋石油总公司 | Water-based bi-component polyurethane color paint |
| CN102634273A (en) * | 2012-05-11 | 2012-08-15 | 中国海洋石油总公司 | Environment-friendly water-based double-component polyurethane floor coating |
| CN102731717A (en) * | 2012-07-18 | 2012-10-17 | 中国海洋石油总公司 | Waterborne dispersion resin containing hydroxyl and preparation method thereof |
-
2014
- 2014-12-03 CN CN201410724975.9A patent/CN104479529A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000281533A (en) * | 1999-03-30 | 2000-10-10 | Pola Chem Ind Inc | Coated powder and composition containing the same |
| CN101654589A (en) * | 2009-09-24 | 2010-02-24 | 中国海洋石油总公司 | Water-based bi-component polyurethane color paint |
| CN102634273A (en) * | 2012-05-11 | 2012-08-15 | 中国海洋石油总公司 | Environment-friendly water-based double-component polyurethane floor coating |
| CN102731717A (en) * | 2012-07-18 | 2012-10-17 | 中国海洋石油总公司 | Waterborne dispersion resin containing hydroxyl and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057545A (en) * | 2016-12-28 | 2017-08-18 | 中国海洋石油总公司 | Applied in aqueous dual-component acroleic acid polyurethane and preparation method thereof |
| CN107057545B (en) * | 2016-12-28 | 2019-08-02 | 中国海洋石油总公司 | Applied in aqueous dual-component acroleic acid polyurethane and preparation method thereof |
| CN108047857A (en) * | 2018-01-05 | 2018-05-18 | 吕跃文 | Aqueous forest negative oxygen ion plastic paint and preparation method thereof |
| CN109535990A (en) * | 2018-11-26 | 2019-03-29 | 新疆天地金阳环保新材料有限公司 | Two-component silicon PU elastic layer and preparation method thereof and sports ground silicon PU material and preparation method thereof |
| EP3904464A4 (en) * | 2018-12-27 | 2022-09-07 | Nippon Paint Industrial Coatings Co., Ltd. | Water-based coating composition and method for forming coating film |
| CN114163887A (en) * | 2022-01-13 | 2022-03-11 | 衡水新光新材料科技有限公司 | Environment-friendly single-component floor paint and preparation method thereof |
| CN115785783A (en) * | 2022-12-05 | 2023-03-14 | 上海正欧实业有限公司 | Weather-resistant floor paint and preparation method thereof |
| CN115785783B (en) * | 2022-12-05 | 2024-01-30 | 上海正欧实业有限公司 | Weather-resistant floor paint and preparation method thereof |
| CN116063916A (en) * | 2023-03-08 | 2023-05-05 | 湖南子杨建筑装饰材料有限公司 | High-hardness water-based polyurethane floor coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104479529A (en) | Aqueous floor paint for silicon PU rubber | |
| CN105256687B (en) | outdoor polyurethane floor | |
| CN102634273B (en) | Environment-friendly water-based double-component polyurethane floor coating | |
| CN102775898B (en) | Solventless polyurethane self-leveling floor paint and preparation method thereof | |
| CN101654589B (en) | Water-based bi-component polyurethane color paint | |
| CN105017906B (en) | A kind of colorful sealing wax of water-water and preparation method thereof | |
| CN106519796B (en) | A kind of high damage resistant aqueous transparent ink and preparation method thereof | |
| CN102533070A (en) | Luminant white paint and preparation method thereof | |
| CN106811006A (en) | It is a kind of to can be used for the aqueous epoxy floor coating compositions and preparation method of outdoor | |
| CN105419603A (en) | Easy-to-polish water-based woodware double-component white primer and preparation method thereof | |
| CN101880508B (en) | Preparation method of high abrasion water-borne wood coating | |
| CN101445694A (en) | Environment-friendly aqueous carpentry paint | |
| CN102433052A (en) | Aqueous polyurethane modified silicon-acrylate multifunctional waterproof heat-insulation elastic paint and preparation method thereof | |
| CN101717603A (en) | Aqueous dull finishing coat, preparation method and use method thereof | |
| CN104610863A (en) | Single-component and double-component compound water-based wood top-coat paint and preparation method thereof | |
| CN107586504A (en) | Color sand self-leveling floor coating of one kind floating and preparation method thereof | |
| WO2022048065A1 (en) | Highly wear-resistant water-based elastomeric coating for surface decoration of plastic materials | |
| CN105623493A (en) | Dual-curing unsaturated polyester white primer and preparation method thereof | |
| CN102993882A (en) | Interior wall coating and preparation method thereof | |
| CN105176376A (en) | Nanometer negative ion functional water-based wood paint and preparation method thereof | |
| CN112521817A (en) | Single-component matte clear finish paint and preparation method thereof | |
| CN113604143A (en) | Two-component waterborne polyurethane scratch-resistant wear-resistant PVC coating and preparation method thereof | |
| CN102367359A (en) | Water-based sealing primer and its preparation method | |
| CN112280450A (en) | PVC artificial leather water-based color-changing treatment agent and preparation method thereof | |
| CN102367358B (en) | Waterborne single-component full-glossy white finish and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150401 |