CN106520292A - 一种环境友好不锈钢管冷轧润滑剂组合物 - Google Patents

一种环境友好不锈钢管冷轧润滑剂组合物 Download PDF

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CN106520292A
CN106520292A CN201610962457.XA CN201610962457A CN106520292A CN 106520292 A CN106520292 A CN 106520292A CN 201610962457 A CN201610962457 A CN 201610962457A CN 106520292 A CN106520292 A CN 106520292A
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stainless steel
agent
rolling lubricant
steel tube
environmental friendliness
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黄福川
李康春
邓富康
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Guangxi University
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Abstract

本发明公开了一种环境友好不锈钢管冷轧润滑剂组合物，采用质量比66.66％的硬脂酸丁酯(BS)和33.34％的合成酯(Radialube7251)复合做为复合基础油，配合多种复合添加剂，包括：抗氧防腐剂、摩擦改进剂、油性剂、极压剂、抗磨剂、防锈剂、抗泡剂、催冷剂。本发明的组合物具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤；提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性、热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。

Description

一种环境友好不锈钢管冷轧润滑剂组合物
技术领域
本发明一种环境友好不锈钢管冷轧润滑剂组合物属于金属加工工艺润滑剂领域。
背景技术
钢管一般分为无缝钢管和焊接钢(有缝)两类。钢管是一种中空长条形钢材，大量应用作输送流体的管道，也广泛应用于制造机械零件，工程结构件。通常大规格尺寸的无缝管是通过热轧工艺连续产生；而中小规格尺寸的无缝钢管主要采用热轧穿孔或连铸连轧开胚形成管材，再进行冷拔或冷轧工艺生产。不锈钢冷轧过程中，由于其表面粘性、抗氧化性以及高的变形抗力，导致其表面质量较难控制。因此其冷轧工艺具有不同于其他钢种的特点，主要表现为：1，不锈钢是高合金钢，变形抗力强，必须采用润滑冷却效果好的轧制油进行工艺润滑。2，采用特殊的焊接。3，不锈钢生产中退火是其中重要环节。4，表面质量要求高。5精整有特殊要求。6，其导热性能差，要求轧制油有良好的传热性和比热容。总之，轧制油对冷轧后的退火、酸洗和精制后加工工艺有较大的影响。
发明内容
本发明要解决的技术问题是提供一种具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤；提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性、热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗的环境友好不锈钢管冷轧润滑剂组合物。
本发明采用如下技术方案解决上述技术问题：
一种环境友好不锈钢管冷轧润滑剂组合物，采用质量比66.66％的硬脂酸丁酯(BS)和33.34％的合成酯(Radialube7251)复合做为复合基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
以上各组分的质量百分比总和为100％。
抗氧防腐剂是二烷基二硫代氨基甲酸酯。
摩擦改进剂是乙基棕榈酸酯。
油性剂是质量比50％的棕榈油和50％的工业猪油复合。
极压剂是氯化石蜡T301。
抗磨剂是硫化异丁烯T321。
防锈剂是中碱值合成磺酸钙T105。
抗泡剂是丙烯酸酯与醚共聚物T912。催冷剂是石油磺酸钠T702。
本发明的显著优点在于：本发明的组合物具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤；提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性、热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。
具体实施方式
实施例1：
将下列各组分按质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例2：
将下列各组分按质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例3：
将下列各组分按质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例3产品的典型技术指标
项目 指标
40℃运动粘度/mm2/s 130.2
酸值/(mgKOH.g-1) 0.67
皂化值/(mgKOH.g-1) 76.3
铜片腐蚀(100℃、3h)/级 1
闪点(开口)/℃ 249
凝点/℃ -36
粘度指数 137
摩擦系数 0.118
机械杂质，％ 0.03
水分，％ 痕迹
四球试验：Pb/N 876
烧结负荷PD/N 6710
氧化安定性(旋转氧弹法，156℃)，min 323
FZG/级 14
蒸发损失(Noack法,250℃,1h)(m),％ 7.2
实施例2产品的典型技术指标
项目 指标
40℃运动粘度/mm2/s 129.2
酸值/(mgKOH.g-1) 0.61
皂化值/(mgKOH.g-1) 75.6
铜片腐蚀(100℃、3h)/级 1
闪点(开口)/℃ 261
凝点/℃ -38
粘度指数 152
摩擦系数 0.118
机械杂质，％ 0.02
水分，％ 痕迹
四球试验：Pb/N 861
烧结负荷PD/N 6680
氧化安定性(旋转氧弹法，156℃)，min 319
FZG/级 14
蒸发损失(Noack法,250℃,1h)(m),％ 6.8
实施例1产品的典型技术指标
项目 指标
40℃运动粘度/mm2/s 135.2
酸值/(mgKOH.g-1) 0.65
皂化值/(mgKOH.g-1) 75.3
铜片腐蚀(100℃、3h)/级 1
闪点(开口)/℃ 259
凝点/℃ -36
粘度指数 146
摩擦系数 0.118
机械杂质，％ 0.03
水分，％ 痕迹
四球试验：Pb/N 878
烧结负荷PD/N 6690
氧化安定性(旋转氧弹法，156℃)，min 316
FZG/级 14
蒸发损失(Noack法,250℃,1h)(m),％ 7.5

Claims (9)

1.一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于：采用质量比66.66％的硬脂酸丁酯(BS)和33.34％的合成酯(Radialube7251)复合做为复合基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧防腐剂 0.5～0.8％ 摩擦改进剂 1～1.5％ 油性剂 2～3％ 极压剂 6～8％ 抗磨剂 3～5％ 防锈剂 1～2％ 抗泡剂 30～50ppm 催冷剂 1～2％
以上各组分的质量百分比总和为100％。
2.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于抗氧防腐剂是二烷基二硫代氨基甲酸酯。
3.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于摩擦改进剂是乙基棕榈酸酯。
4.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于油性剂是质量比50％的棕榈油和50％的工业猪油复合。
5.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于极压剂是氯化石蜡T301。
6.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于抗磨剂是硫化异丁烯T321。
7.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于防锈剂是中碱值合成磺酸钙T105。
8.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于抗泡剂是丙烯酸酯与醚共聚物T912。
9.如权利要求1所述的一种环境友好不锈钢管冷轧润滑剂组合物，其特征在于催冷剂是石油磺酸钠T702。
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