CN106635292A - 一种铝及其合金热连精轧乳化液的组合物 - Google Patents

一种铝及其合金热连精轧乳化液的组合物 Download PDF

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CN106635292A
CN106635292A CN201610838981.6A CN201610838981A CN106635292A CN 106635292 A CN106635292 A CN 106635292A CN 201610838981 A CN201610838981 A CN 201610838981A CN 106635292 A CN106635292 A CN 106635292A
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rolling emulsion
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黄福川
张姗姗
潘发存
胡雄风
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Guangxi University
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Abstract

本发明公开了一种铝及其合金热连精轧乳化液的组合物，采用MVI基础油作为基础油，配合多种复合添加剂，包括：油性剂、摩擦改进剂、极压剂、抗磨剂、表面活性剂、抗泡剂、防锈剂、杀菌剂、偶合剂等。本发明的组合物具有适中的冷却特性，良好的润滑特性、宽范围轧制压下量适用性、抗高温氧化性、扩散性、清洗性。

Description

一种铝及其合金热连精轧乳化液的组合物
技术领域
本发明属于金属加工润滑剂领域，特别涉及一种铝及其合金热连精轧乳化液的组合物。
背景技术
铝合金密度低，但强度比较高，接近或超过优质钢，塑性好，可加工成各种型材，具有优良的导电性、导热性和抗蚀性，工业上广泛使用，使用量仅次于钢。一些铝合金可以采用热处理获得良好的机械性能，物理性能和抗腐蚀性能。在航空、航天、汽车、机械制造、船舶及化学工业中已大量应用。
针对热精连轧工艺质量要求，乳化液必须具备：适中的冷却特性、优良的润滑剂特性、连轧易吸入性和使用品质的稳定性。相对热粗轧，由于连轧温度较低，为稳定辊温、控制板材并保证乳液润滑性，要求乳化液具有适中的冷却性能。连轧温度较低，坯料较薄，对润滑条件要求更苛刻，为保证低温、高速、大变形率条件下热轧卷表面质量，克服粘铝缺陷，乳化液必须具备优良的润滑剂特性。热连轧直接接触的轧制介质为乳化液，乳化液要实现铝及其合金在低温、高速、大变形率条件下的冷却、润滑和咬入的良好协同难度较大。为适应连轧高速、大变形率下稳定的优良表面质量，不粘铝、不打滑，要求乳化液必须保持现场使用品质的稳定性。
发明内容
本发明要解决的技术问题是提供一种具有适中的冷却特性，良好的润滑特性、宽范围轧制压下量适用性、抗高温氧化性、扩散性、清洗性的铝及其合金热连精轧乳化液的组合物。
本发明采用以下技术方案解决上述技术问题：
一种铝及其合金热连精轧乳化液的组合物，采用MVI基础油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
以上各组分质量百分比总和为100％。
油性剂是硫化烯烃棉籽油-1T405；摩擦改进剂是磷酸酯。
极压剂是酸性亚磷酸二丁酯T304；抗磨剂是氯化石蜡T302。
表面活性剂是质量比67％的聚异丁烯丁二酸酰胺与33％的异构醇醚类复合；抗泡剂是甲基硅油脂T903。
防锈剂是质量比50％的苯并三氮唑T706与50％的咪唑啉及其衍生物复合。
杀菌剂是三羟甲基-硝基甲烷；偶合剂是质量比80％的十八醇与20％的苯甲酸钠复合。
本发明的有益效果在于：本发明组合物具有适中的冷却特性，良好的润滑特性、宽范围轧制压下量适用性、抗高温氧化性、扩散性、清洗性。
具体实施方式
实施例1：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
MVI基础油 余量
硫化烯烃棉籽油-1(T405) 2％
磷酸酯 2％
酸性亚磷酸二丁酯(T304) 4％
氯化石蜡(T302) 5％
质量比67％的聚异丁烯丁二酸酰胺与33％的异构醇醚类复合 20％
甲基硅油脂(T903) 50ppm
质量比50％的苯并三氮唑(T706)与50％的咪唑啉及其衍生物复合 0.5％
三羟甲基-硝基甲烷 0.1％
质量比80％的十八醇与20％的苯甲酸钠复合 1％
以上各组分质量百分比总和等于100％。
实施例2：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
MVI基础油 余量
硫化烯烃棉籽油-1(T405) 4％
磷酸酯 2％
酸性亚磷酸二丁酯(T304) 3％
氯化石蜡(T302) 5％
质量比67％的聚异丁烯丁二酸酰胺与33％的异构醇醚类复合 25％
甲基硅油脂(T903) 50ppm
质量比50％的苯并三氮唑(T706)与50％的咪唑啉及其衍生物复合 0.2％
三羟甲基-硝基甲烷 0.2％
质量比80％的十八醇与20％的苯甲酸钠复合 1％
以上各组分质量百分比总和等于100％。
实施例3：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
MVI基础油 余量
硫化烯烃棉籽油-1(T405) 5％
磷酸酯 3％
酸性亚磷酸二丁酯(T304) 3％
氯化石蜡(T302) 3％
质量比67％的聚异丁烯丁二酸酰胺与33％的异构醇醚类复合 22％
甲基硅油脂(T903) 50ppm
质量比50％的苯并三氮唑(T706)与50％的咪唑啉及其衍生物复合 0.2％
三羟甲基-硝基甲烷 0.1％
质量比80％的十八醇与20％的苯甲酸钠复合 1％
以上各组分质量百分比总和等于100％。
实施例3产品的主要理化指标：

Claims (6)

1.一种铝及其合金热连精轧乳化液的组合物，其特征在于：采用MVI基础油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 油性剂 2％～6％ 摩擦改进剂 2％～4％ 极压剂 3％～4％ 抗磨剂 3％～6％ 表面活性剂 15％～25％ 抗泡剂 30～60ppm 防锈剂 0.08％～0.5％ 杀菌剂 0.08％～0.2％ 偶合剂 1％～2％
以上各组分质量百分比总和为100％。
2.如权利要求1所述的一种铝及其合金热连精轧乳化液的组合物，其特征在于油性剂是硫化烯烃棉籽油-1T405；摩擦改进剂是磷酸酯。
3.如权利要求1所述的一种铝及其合金热连精轧乳化液的组合物，其特征在于极压剂是酸性亚磷酸二丁酯T304；抗磨剂是氯化石蜡T302。
4.如权利要求1所述的一种铝及其合金热连精轧乳化液的组合物，其特征在于表面活性剂是质量比67％的聚异丁烯丁二酸酰胺与33％的异构醇醚类复合；抗泡剂是甲基硅油脂T903。
5.如权利要求1所述的一种铝及其合金热连精轧乳化液的组合物，其特征在于防锈剂是质量比50％的苯并三氮唑T706与50％的咪唑啉及其衍生物复合。
6.如权利要求1所述的一种铝及其合金热连精轧乳化液的组合物，其特征在于杀菌剂是三羟甲基-硝基甲烷；偶合剂是质量比80％的十八醇与20％的苯甲酸钠复合。
CN201610838981.6A 2016-09-21 2016-09-21 一种铝及其合金热连精轧乳化液的组合物 Pending CN106635292A (zh)

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Application publication date: 20170510