CN106519924A - Turtle shell appearance imitated type powder paint - Google Patents
Turtle shell appearance imitated type powder paint Download PDFInfo
- Publication number
- CN106519924A CN106519924A CN201610966816.9A CN201610966816A CN106519924A CN 106519924 A CN106519924 A CN 106519924A CN 201610966816 A CN201610966816 A CN 201610966816A CN 106519924 A CN106519924 A CN 106519924A
- Authority
- CN
- China
- Prior art keywords
- parts
- type powder
- moire
- polyester resin
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses turtle shell appearance imitated type powder paint which is prepared from the following raw materials in parts by weight: 30 parts of hydroxyl terminated polyester resin, 4.5 parts of tetrakisglycoluril resin, 1 part of an amine sealed sulfonic acid catalyst, 10 parts of epoxy resin, 10 parts of carboxyl terminated polyester resin, 5 parts of blocked diisocyanate, 1 part of carbon black, 3-5 parts of modified silicon dioxide, 0.5 part of a turtle shell appearance agent, 3-8 parts of a curing agent and 0.01-0.03 part of a promoter. The powder paint prepared has high hardness, high strength and good corrosion resistance; and a cured coating film has the appearance effects of the turtle shell appearance.
Description
Technical field
The present invention relates to a kind of imitative moire type powder coating, belongs to chemistry painting industry field.
Background technology
Its appearance of coat is a kind of coating type of similar Carapax et Plastrum Testudinis outward appearance to moire powdery paints as its name suggests, with strong sense of touch
With visual impression.Moire decorative paint, is the new product of Japanese the early 1990s exploitation.The coating system acrylic acid seriess of early development
Row aqueous latex paint, by bottom, in, three coating of face constitutes.Its main two kinds of base material employs the cross-linking agent of uniqueness and carries out copolymerization
And obtain, its film is fine and smooth, and tough and tensile, adhesive force is strong.Using the coating application of two kinds of base materials preparations after metope, can self-assembling formation
It is double-colored with regular floral designs, third dimension is strong, and color and luster is various.The coating also can be applied on the object planes such as timber, metal, plastics
Work.Suitable for hotel, market villa, public place of entertainment, the inner wall of building such as modern office building and family room decoration, ceiling decoration
Deng being a kind of medium-to-high grade inner wall decorative coating that social benefit is preferably worthy of popularization.
As people are no longer satisfied with the gloss or color change of dullness to own Jing such as various household electrical appliances to be coated, equipment
Decorate, art-type powder coatings obtain general decor powdery paints difficult due to making film coated surface have clearly decorative pattern attractive in appearance
With the decorative effect for reaching.
The content of the invention
It is an object of the invention to provide a kind of imitative moire type powder coating of epoxy-polyester mixed system, which can not only
The hardness strength of coating is improved, and the scratch resistance and corrosion resistance of coating can be improved by adding improved silica.
To realize the purpose of the present invention, adopt the following technical scheme that：
A kind of imitative moire type powder coating, which is made up of the raw material of following weight portion：30 parts of hydroxyl telechelic polyester resin, four methoxy first
4.5 parts of base glycoluril resin, amine 1 part of sulfonic acid catalyst of closing, 10 parts of epoxy resin, 10 parts of terminal carboxyl polyester resin close isocyanide
5 parts of acid esters, 1 part of carbon black, improved silica 3-5 parts, 0.5 part of moire agent, firming agent 3-8 parts and accelerator 0.01-0.03 parts.
The preparation method of the improved silica, comprises the following steps that：
（1）With molar ratio computing, silicon dioxide：Tannic acid：Polyvinylpyrrolidone：Ethanol：Deionized water=1:0.3:0.5:10:7,
Weigh each component to mix, ultrasonic disperse 2h,
（2）To step（1）Mixed liquor vinegar acid for adjusting pH is 5；
（3）By step（2）Mixed liquor is placed in there-necked flask, and flow back at 80 DEG C 2h while stirring；
（4）By step（3）Mixed liquor sucking filtration, obtains filter cake and is placed in drying at 90 DEG C, obtain improved silica.
A kind of imitative moire type powder coating, its preparation method are concretely comprised the following steps：
（1）By formula weigh hydroxyl telechelic polyester resin, Trimethylmethanaminium chloride Tetramine chloride resin, amine closing sulfonic acid catalyst, epoxy resin,
Terminal carboxyl polyester resin, blocked isocyanate, carbon black, improved silica, moire agent each component, put into blender, with
1000r/min stirs 4h, is then transferred to high-speed circulating sand mill, is ground to particle diameter≤5 μm；
（2）To step（1）Mixture adds the firming agent of metering, continues stirring and is completely dissolved to firming agent for 20 ~ 40 minutes, is formed
Homogeneous solution；
（3）Said mixture is cooled to into 40 DEG C ~ 50 DEG C, the accelerator stirring mixing for adding metering obtains this for 5 ~ 15 minutes
Invention coating.
Described firming agent is 4,4 '-diaminodiphenyl-methane.
Described accelerator is 2-ethyl-4-methylimidazole.
The beneficial effects of the present invention is：
（1）Easily it is grafted with resin by adding improved silica powder body, the active group in its surface, being capable of stable dispersion
In the coating, so as to strengthening the hardness and decay resistance of coating；
（2）Sulfonic acid catalyst is closed by amine and prepares the imitative moire coating of epoxy-polyesters resin type, its mechanical property is dashed forward
Go out；
（3）Preparation method is simple, and obtained coating texture third dimension is good, and high rigidity, high intensity, high scratch resistance, hardening time it is fast,
It is environment friendly and pollution-free.
Specific embodiment
Further to disclose rather than limiting the present invention, below in conjunction with example, the present invention is described in further detail.
Embodiment 1
A kind of imitative moire type powder coating, which is made up of the raw material of following weight portion：30 parts of hydroxyl telechelic polyester resin, four methoxy first
4.5 parts of base glycoluril resin, amine 1 part of sulfonic acid catalyst of closing, 10 parts of epoxy resin, 10 parts of terminal carboxyl polyester resin close isocyanide
5 parts of acid esters, 1 part of carbon black, 3 parts of improved silica, 0.5 part of moire agent, 4,3 parts of 4 '-diaminodiphenyl-methane and 2- ethyls-
0.01 part of 4-methylimidazole.
The preparation method of the improved silica, comprises the following steps that：
（1）With molar ratio computing, silicon dioxide：Tannic acid：Polyvinylpyrrolidone：Ethanol：Deionized water=1:0.3:0.5:10:7,
Weigh each component to mix, ultrasonic disperse 2h,
（2）To step（1）Mixed liquor vinegar acid for adjusting pH is 5；
（3）By step（2）Mixed liquor is placed in there-necked flask, and flow back at 80 DEG C 2h while stirring；
（4）By step（3）Mixed liquor sucking filtration, obtains filter cake and is placed in drying at 90 DEG C, obtain improved silica.
A kind of imitative moire type powder coating, its preparation method are concretely comprised the following steps：
（1）By formula weigh hydroxyl telechelic polyester resin, Trimethylmethanaminium chloride Tetramine chloride resin, amine closing sulfonic acid catalyst, epoxy resin,
Terminal carboxyl polyester resin, blocked isocyanate, carbon black, improved silica, moire agent each component, put into blender, with
1000r/min stirs 4h, is then transferred to high-speed circulating sand mill, is ground to particle diameter≤5 μm；
（2）To step（1）Mixture adds the 4 of metering, 4 '-diaminodiphenyl-methane to continue to stir 20 minutes to 4,4 '-two
Aminodiphenylmethane is completely dissolved, and forms homogeneous solution；
（3）Said mixture is cooled to into 40 DEG C, the 2-ethyl-4-methylimidazole stirring mixing for adding metering is obtained final product for 5 minutes
To coating of the present invention.
Embodiment 2
A kind of imitative moire type powder coating, which is made up of the raw material of following weight portion：30 parts of hydroxyl telechelic polyester resin, four methoxy first
4.5 parts of base glycoluril resin, amine 1 part of sulfonic acid catalyst of closing, 10 parts of epoxy resin, 10 parts of terminal carboxyl polyester resin close isocyanide
5 parts of acid esters, 1 part of carbon black, 4 parts of improved silica, 0.5 part of moire agent, 4,6 parts of 4 '-diaminodiphenyl-methane and 2- ethyls-
0.02 part of 4-methylimidazole.
The preparation method of the improved silica, comprises the following steps that：
（1）With molar ratio computing, silicon dioxide：Tannic acid：Polyvinylpyrrolidone：Ethanol：Deionized water=1:0.3:0.5:10:7,
Weigh each component to mix, ultrasonic disperse 2h,
（2）To step（1）Mixed liquor vinegar acid for adjusting pH is 5；
（3）By step（2）Mixed liquor is placed in there-necked flask, and flow back at 80 DEG C 2h while stirring；
（4）By step（3）Mixed liquor sucking filtration, obtains filter cake and is placed in drying at 90 DEG C, obtain improved silica.
A kind of imitative moire type powder coating, its preparation method are concretely comprised the following steps：
（1）By formula weigh hydroxyl telechelic polyester resin, Trimethylmethanaminium chloride Tetramine chloride resin, amine closing sulfonic acid catalyst, epoxy resin,
Terminal carboxyl polyester resin, blocked isocyanate, carbon black, improved silica, moire agent each component, put into blender, with
1000r/min stirs 4h, is then transferred to high-speed circulating sand mill, is ground to particle diameter≤5 μm；
（2）To step（1）Mixture adds the 4 of metering, 4 '-diaminodiphenyl-methane to continue to stir 30 minutes to 4,4 '-two
Aminodiphenylmethane is completely dissolved, and forms homogeneous solution；
（3）Said mixture is cooled to into 40 DEG C, the 2-ethyl-4-methylimidazole stirring mixing for adding metering is obtained final product for 10 minutes
To coating of the present invention.
Embodiment 3
A kind of imitative moire type powder coating, which is made up of the raw material of following weight portion：30 parts of hydroxyl telechelic polyester resin, four methoxy first
4.5 parts of base glycoluril resin, amine 1 part of sulfonic acid catalyst of closing, 10 parts of epoxy resin, 10 parts of terminal carboxyl polyester resin close isocyanide
5 parts of acid esters, 1 part of carbon black, 5 parts of improved silica, 0.5 part of moire agent, 4,8 parts of 4 '-diaminodiphenyl-methane and 2- ethyls-
0.03 part of 4-methylimidazole.
The preparation method of the improved silica, comprises the following steps that：
（1）With molar ratio computing, silicon dioxide：Tannic acid：Polyvinylpyrrolidone：Ethanol：Deionized water=1:0.3:0.5:10:7,
Weigh each component to mix, ultrasonic disperse 2h,
（2）To step（1）Mixed liquor vinegar acid for adjusting pH is 5；
（3）By step（2）Mixed liquor is placed in there-necked flask, and flow back at 80 DEG C 2h while stirring；
（4）By step（3）Mixed liquor sucking filtration, obtains filter cake and is placed in drying at 90 DEG C, obtain improved silica.
A kind of imitative moire type powder coating, its preparation method are concretely comprised the following steps：
（1）By formula weigh hydroxyl telechelic polyester resin, Trimethylmethanaminium chloride Tetramine chloride resin, amine closing sulfonic acid catalyst, epoxy resin,
Terminal carboxyl polyester resin, blocked isocyanate, carbon black, improved silica, moire agent each component, put into blender, with
1000r/min stirs 4h, is then transferred to high-speed circulating sand mill, is ground to particle diameter≤5 μm；
（2）To step（1）Mixture adds the 4 of metering, 4 '-diaminodiphenyl-methane to continue to stir 40 minutes to 4,4 '-two
Aminodiphenylmethane is completely dissolved, and forms homogeneous solution；
（3）Said mixture is cooled to into 50 DEG C, the 2-ethyl-4-methylimidazole stirring mixing for adding metering is obtained final product for 15 minutes
To coating of the present invention.
Table 1 is the performance test of coating prepared by embodiment 1-3
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with repair
Decorations, should all belong to the covering scope of the present invention.
Claims (5)
1. a kind of imitative moire type powder coating, it is characterised in that：Which is made up of the raw material of following weight portion：Hydroxyl telechelic polyester resin
30 parts, 4.5 parts of Trimethylmethanaminium chloride Tetramine chloride resin, amine 1 part of sulfonic acid catalyst of closing, 10 parts of epoxy resin, terminal carboxyl polyester resin
10 parts, 5 parts of blocked isocyanate, 1 part of carbon black, improved silica 3-5 parts, 0.5 part of moire agent, firming agent 3-8 parts and promotion
Agent 0.01-0.03 parts.
2. imitative moire type powder coating according to claim 1, it is characterised in that：The preparation method of improved silica,
Comprise the following steps that：
（1）With molar ratio computing, silicon dioxide：Tannic acid：Polyvinylpyrrolidone：Ethanol：Deionized water=1:0.3:0.5:10:7,
Weigh each component mixing, ultrasonic disperse 2h；
（2）To step（1）Mixed liquor vinegar acid for adjusting pH is 5；
（3）By step（2）Mixed liquor is placed in there-necked flask, and flow back at 80 DEG C 2h while stirring；
（4）By step（3）Mixed liquor sucking filtration, obtains filter cake and is placed in drying at 90 DEG C, obtain improved silica.
3. imitative moire type powder coating according to claim 1, it is characterised in that：Described firming agent is 4,4 '-diamino
Base diphenyl methane.
4. imitative moire type powder coating according to claim 1, it is characterised in that：Described accelerator is 2- ethyl -4-
Methylimidazole..
It is 5. a kind of to prepare the method for imitating moire type powder coating as claimed in claim 1, it is characterised in that：Concretely comprise the following steps：
（1）By formula weigh hydroxyl telechelic polyester resin, Trimethylmethanaminium chloride Tetramine chloride resin, amine closing sulfonic acid catalyst, epoxy resin,
Terminal carboxyl polyester resin, blocked isocyanate, carbon black, improved silica, moire agent each component, put into blender, with
1000r/min stirs 4h, is then transferred to high-speed circulating sand mill, is ground to particle diameter≤5 μm；
（2）To step（1）Mixture adds the firming agent of metering, continues stirring and is completely dissolved to firming agent for 20 ~ 40 minutes, is formed
Homogeneous solution；
（3）Said mixture is cooled to into 40 DEG C ~ 50 DEG C, the accelerator stirring mixing for adding metering obtains this for 5 ~ 15 minutes
Invention coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610966816.9A CN106519924A (en) | 2016-10-28 | 2016-10-28 | Turtle shell appearance imitated type powder paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610966816.9A CN106519924A (en) | 2016-10-28 | 2016-10-28 | Turtle shell appearance imitated type powder paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519924A true CN106519924A (en) | 2017-03-22 |
Family
ID=58327078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610966816.9A Pending CN106519924A (en) | 2016-10-28 | 2016-10-28 | Turtle shell appearance imitated type powder paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106519924A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151475A (en) * | 2017-06-16 | 2017-09-12 | 安徽省华安进出口有限公司 | A kind of powdery paints dry-mixed additive and its powdery paints of offer grain effect |
| CN112143315A (en) * | 2020-09-28 | 2020-12-29 | 湖南连心科技有限公司 | Powder coating with moire effect and preparation method thereof |
| CN112300621A (en) * | 2020-09-25 | 2021-02-02 | 廊坊艾格玛新立材料科技有限公司 | Low-temperature iron-chromium black infrared ray reflection powder coating and production process thereof |
| CN113801536A (en) * | 2021-09-16 | 2021-12-17 | 安徽华辉塑业科技股份有限公司 | Antirust coating for electric appliance rack and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101143921A (en) * | 2007-08-03 | 2008-03-19 | 安徽神剑新材料有限公司 | Preparation method for thermosetting pure polyester resin |
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN101928509A (en) * | 2009-06-19 | 2010-12-29 | 扬州市金晨化工有限公司 | Super-weatherable polyether powder coating and preparation method thereof |
| CN102134417A (en) * | 2010-01-24 | 2011-07-27 | 商新学 | Amine-blocked sulfonic acid catalyst |
-
2016
- 2016-10-28 CN CN201610966816.9A patent/CN106519924A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN101143921A (en) * | 2007-08-03 | 2008-03-19 | 安徽神剑新材料有限公司 | Preparation method for thermosetting pure polyester resin |
| CN101928509A (en) * | 2009-06-19 | 2010-12-29 | 扬州市金晨化工有限公司 | Super-weatherable polyether powder coating and preparation method thereof |
| CN102134417A (en) * | 2010-01-24 | 2011-07-27 | 商新学 | Amine-blocked sulfonic acid catalyst |
Non-Patent Citations (3)
| Title |
|---|
| 崔金海: "《涂料生产与涂装技术》", 30 June 2014 * |
| 汪多仁: "《现代高分子材料生产及应用手册》", 31 May 2002 * |
| 谢品雄: "水纹粉末涂料在3C产品上的应用", 《涂料技术与文摘》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151475A (en) * | 2017-06-16 | 2017-09-12 | 安徽省华安进出口有限公司 | A kind of powdery paints dry-mixed additive and its powdery paints of offer grain effect |
| CN107151475B (en) * | 2017-06-16 | 2019-09-13 | 安徽省华安进出口有限公司 | A kind of powdery paints of the dry-mixed additive of powdery paints and its offer grain effect |
| CN112300621A (en) * | 2020-09-25 | 2021-02-02 | 廊坊艾格玛新立材料科技有限公司 | Low-temperature iron-chromium black infrared ray reflection powder coating and production process thereof |
| CN112143315A (en) * | 2020-09-28 | 2020-12-29 | 湖南连心科技有限公司 | Powder coating with moire effect and preparation method thereof |
| CN113801536A (en) * | 2021-09-16 | 2021-12-17 | 安徽华辉塑业科技股份有限公司 | Antirust coating for electric appliance rack and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106519924A (en) | Turtle shell appearance imitated type powder paint | |
| CN101210129B (en) | Crackle lacquer, preparing method thereof and spraying method for the same | |
| CN103184004B (en) | A kind of water-based crackle paint and preparation method thereof and method of application | |
| CN105199558B (en) | Special coil coating of anodic oxidation special-effect of a kind of aluminium sheet coiled material and preparation method thereof | |
| CN101747818B (en) | Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof | |
| CN101921501B (en) | Nano coating additive and coating composition containing same | |
| CN101328039A (en) | Artificial stone panel and manufacturing method thereof | |
| CN102585630A (en) | Water-based glass baking paint and preparation method thereof | |
| CN102618135A (en) | Aqueous environment-friendly wood lacquer and application and use method thereof | |
| CN103113828B (en) | Water-based paint special for pinewood of furniture for children | |
| CN105837074A (en) | Novel chemical sand dyeing process | |
| CN109021654A (en) | A kind of lacquer and preparation method thereof | |
| CN109181545A (en) | A kind of granitic lacquer of high emulation and its preparation process | |
| CN108129968A (en) | Anti-ultraviolet nano polyurethane woodenware investment precoat and preparation method thereof | |
| CN107573788A (en) | A kind of true mineral varnish coating of exterior wall | |
| CN110078412A (en) | A kind of water-base resin sand lacquer and preparation method thereof | |
| CN109534728A (en) | Quick-dry type lacquer, quick-dry type thickness matter lacquer imitate flag material and preparation method thereof | |
| CN108178965A (en) | A kind of aqueous epoxy resins antirust paint and preparation method thereof | |
| WO2008003205A1 (en) | Coating composition for artificial pearls | |
| CN108793835A (en) | A kind of new type natural lacquer and preparation method thereof | |
| CN105254210B (en) | A kind of many color stone paints of environment-friendly type and preparation method thereof | |
| CN109233458A (en) | A kind of aqueousance artificial granite coating and preparation method thereof | |
| CN108047929A (en) | A kind of high hot water resistance coating | |
| CN108676460B (en) | Crystal color floor decorative coating and preparation method thereof | |
| CN102127354A (en) | Water-based paint highly simulating granite and marble and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |