CN106498741A - A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn - Google Patents
A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn Download PDFInfo
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- CN106498741A CN106498741A CN201610847764.3A CN201610847764A CN106498741A CN 106498741 A CN106498741 A CN 106498741A CN 201610847764 A CN201610847764 A CN 201610847764A CN 106498741 A CN106498741 A CN 106498741A
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- filament yarn
- viscose filament
- friendly type
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- 229920000297 Rayon Polymers 0.000 title claims abstract description 34
- 238000009987 spinning Methods 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 10
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 10
- -1 polyoxyethylene Polymers 0.000 claims abstract description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 9
- 229920000570 polyether Polymers 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 7
- 239000003899 bactericide agent Substances 0.000 claims abstract description 7
- 241000722946 Acanthocybium solandri Species 0.000 claims abstract description 5
- 239000004593 Epoxy Substances 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- CASPZMCSNJZQMV-UHFFFAOYSA-N ethane;2-methyloxirane Chemical compound CC.CC1CO1 CASPZMCSNJZQMV-UHFFFAOYSA-N 0.000 claims description 8
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- NYWPTMUTCHMGDH-UHFFFAOYSA-L S(=O)(=O)([O-])[O-].[Na+].N1=CC=CC=C1.[Na+] Chemical compound S(=O)(=O)([O-])[O-].[Na+].N1=CC=CC=C1.[Na+] NYWPTMUTCHMGDH-UHFFFAOYSA-L 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- 239000002002 slurry Substances 0.000 abstract description 3
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of for continuously spinning environment-friendly type finish of viscose filament yarn and preparation method thereof, finish is according to the mass fraction：20～40 parts of polyoxyethylene carboxylate, 4～15 parts of ethylene oxide propylene oxide block polyether, 5～10 parts of Gemini surface active agent, 5～13 parts of PETO, 0.3～7 part of triethanolamine, 0.2～2 part of bactericide, 20～50 parts of deionized water.The environment-friendly type oil performance stability for continuously spinning viscose filament yarn obtained by the present invention, compatible with slurry good, make viscose filament yarn product have cohesive force good, antistatic behaviour is strong, easily the characteristic such as unwinding.
Description
Technical field
A kind of the present invention relates to chemical industry finish field, more particularly to finish and its preparation side for continuously spinning viscose filament yarn
Method.
Background technology
Viscose filament yarn is one of important kind in China's staple fibre, mainly based on semicontinuous spinning.In recent ten years,
The yield of domestic viscose rayon is significantly increased, and to the quality requirement of product with application more and more extensively, society is to environment in market
Increasingly harshness is required, thus, the continuous viscose filament yarn that spins arises at the historic moment.
Spin in viscose filament yarn production continuous, the viscose produced by spinning-drawing machine is the parallel silk that does not twist, need by
Finish and slurry make fiber obvolvent each other.Preparation medium is important auxiliary products, and Main Function makes the fiber after oiling
Be smoothed out winding, be molded silk cylinder good, the generation of breakage phenomena can be reduced in stretching process, in woven or knitting process
In can be smoothed out, it is to avoid to postorder processing produce harmful effect.Domestic viscose filament finish typically adopts mineral oil, by non-
Ionic surface active agent is formed with cationic surfactant or anion surfactant compounding.Oiling method is in post processing
During emulsion oil, the oil applying rate of fiber is typically relatively low, it is impossible to meet the requirement of high speed loom, and environment can be produced negative
The impact in face.
Content of the invention
Present invention aim to overcome that above-mentioned deficiency, there is provided a kind of for continuously spin viscose filament yarn environment-friendly type finish and its
Preparation method
The purpose of the present invention is achieved through the following technical solutions：
A kind of environment-friendly type finish for continuously spinning viscose filament yarn, environment-friendly type finish is according to the mass fraction：
Polyoxyethylene carboxylate, 20～40 parts；
Epoxy ethane-epoxy propane block polyether, 4～15 parts；
Gemini surface active agent, 5～10 parts；
PETO, 5～13 parts；
Triethanolamine, 0.3～7 part；
Bactericide, 0.2～2 part；
Deionized water, 20～50 parts.
The polyoxyethylene carboxylate structural formula is RCOO (EO)nH, wherein R are C4～C20Alkyl, n be 3～40.
The epoxy ethane-epoxy propane block polyether structural formula is R1O(PO)m(EO)nH, wherein R1For C4～C50Alkane
Base, m and n are 3～100.
The structural formula of the Gemini surface active agent is
Wherein it is R1、R2Respectively C10～C20One kind in alkyl.
The bactericide is pyridine sodium sulphate, s-triazine, morpholine, the one kind in OIT
Or it is several.
The deionized water electrical conductivity is less than 10 μ S/cm.
According to the mass fraction, by deionized water 20～50 parts be warming up to 50～70 DEG C, sequentially add aliphatic acid polyethenoxy
20～40 parts of ester, 4～15 parts of epoxy ethane-epoxy propane block polyether, 5～10 parts of Gemini surface active agent, pentaerythrite oil
5～13 parts of acid esters, mixes 30～50 minutes, is subsequently adding 0.2～2 part of bactericide, and 0.3～7 part of triethanolamine is used
In the finish for continuously spinning viscose filament yarn.
Advantages of the present invention：
Environmental protection stablized by environment-friendly type finish for continuously spinning viscose filament yarn prepared by the present invention, can substitute containing mineral oil
Emulsion, good with water-soluble paste compatibility, solve that electrostatic between fiber is big, unwinding is bad and tow boundling is bad well
The problems such as.During oiling, finish and slurry around strand can form one layer and there is sufficient intensity, adhesive fastness and elasticity
And the film of Castor Oil.The lipophilic group of film towards fiber, hydrophilic group then towards air, so as to enhance the ionic conducting property of fiber
With moisture absorption electric conductivity, that is, electric discharge phenomena are generated, reduce the resistance of fiber surface, reach anlistatig purpose.Can in case
The phenomenon that only strand occurs to damage and form lousiness or broken end in motion and winding process, lousiness is few, silk to have viscose filament yarn
The not disorderly, wearability of thread is good, extends the features such as stablizing.
Specific embodiment
The present invention is described further with reference to specific embodiment：
Embodiment 1
A kind of environment-friendly type finish for continuously spinning viscose filament yarn, it is prepared by the raw material of following mass fraction：
30 parts of the deionized water that electrical conductivity is 5 μ S/cm is warming up to 60 DEG C, polyoxyethylene carboxylate [C is sequentially added10H21COO
(EO)15H] 30 parts, epoxy ethane-epoxy propane block polyether R1O(PO)m(EO)n(R is C to H6Straight chained alkyl, m=3, n=
15) 8 parts, Gemini surface active agent(R1And R2It is C10Straight chained alkyl) 6 parts, Ji Wusi
7 parts of alcohol oleate, mixes 35 minutes, is subsequently adding 1 part of morpholine, and 0.8 part of regulation pH value 8 of triethanolamine is obtained for even
The continuous finish for spinning viscose filament yarn.
Embodiment 2
A kind of environment-friendly type finish for continuously spinning viscose filament yarn, it is prepared by the raw material of following mass fraction：
35 parts of the deionized water that electrical conductivity is 5 μ S/cm is warming up to 60 DEG C, polyoxyethylene carboxylate [C is sequentially added12H25COO
(EO)18H] 30 parts, epoxy ethane-epoxy propane block polyether R1O(PO)m(EO)n(R is C to H10Straight chained alkyl, m=3, n=
20) 6 parts, Gemini surface active agent(R1And R2It is C12Straight chained alkyl) 6 parts, Ji Wusi
8 parts of alcohol oleate, mixes 35 minutes, is subsequently adding 0.8 part of OIT, and 0.8 part of regulation pH value 8 of triethanolamine is obtained
To the finish for continuously spinning viscose filament yarn.
Embodiment 3
A kind of environment-friendly type finish for continuously spinning viscose filament yarn, it is prepared by the raw material of following mass fraction：
40 parts of the deionized water that electrical conductivity is 5 μ S/cm is warming up to 60 DEG C, polyoxyethylene carboxylate [C is sequentially added14H29COO
(EO)20H] 30 parts, (R is C to epoxy ethane-epoxy propane block polyether8Straight chained alkyl, m=5, n=17) 10 parts, Shuangzi table
Face activating agent(R1And R2It is C12Straight chained alkyl) 8 parts, 10 parts of PETO,
Mix 35 minutes, be subsequently adding 1.5 parts of OIT, 0.8 part of regulation pH value 8 of triethanolamine is obtained for continuous spinning
The finish of viscose filament yarn.
Embodiment 4
A kind of environment-friendly type finish for continuously spinning viscose filament yarn, it is prepared by the raw material of following mass fraction：
35 parts of the deionized water that electrical conductivity is 5 μ S/cm is warming up to 60 DEG C, polyoxyethylene carboxylate [C is sequentially added18H37COO
(EO)25H] 30 parts, (R is C to epoxy ethane-epoxy propane block polyether8Straight chained alkyl, m=5, n=20) 10 parts, Shuangzi table
Face activating agent(R1For C12Alkane straight chain base, R2For C16Straight chained alkyl) 6 parts, Ji Wusi
8 parts of alcohol oleate, mixes 35 minutes, is subsequently adding 1 part of s-triazine, 0.8 part of regulation pH value 8 of triethanolamine, obtain for
The continuous finish for spinning viscose filament yarn.
The finish that above-described embodiment 1～4 is prepared and polyvinyl alcohol pulp in mass ratio 1:1.2 are dissolved in deionized water respectively
In, the working solution that concentration is 48g/L is configured to, and spinning starching is carried out on viscose filament continuous spinning machine.In spinning process,
Strand is good by property, and fiber softening is smooth, and feel is good, and finish of the present invention and application performance index are as shown in table 1.
1 finish of table and application performance index
| Outward appearance | Solid content (%) | Viscosity (mm2/s) | Ratio resistance (Ω cm) | Oil content (%) | |
| Examination criteria | Range estimation | HG 4266-2011 | GB 265-1988 | GB14342-1993 | GB 6504-2008 |
| Embodiment 1 | Colourless transparent liquid | 63 | 346 | 0.94×109 | 1.59 |
| Embodiment 2 | Colourless transparent liquid | 59 | 325 | 0.87×109 | 1.47 |
| Embodiment 3 | Colourless transparent liquid | 60 | 330 | 0.75×108 | 1.50 |
| Embodiment 4 | Colourless transparent liquid | 61 | 336 | 0.91×109 | 1.53 |
Claims (7)
1. a kind of for continuously spin viscose filament yarn environment-friendly type finish, it is characterised in that：Environment-friendly type finish is according to the mass fraction：
Polyoxyethylene carboxylate, 20～40 parts；
Epoxy ethane-epoxy propane block polyether, 4～15 parts；
Gemini surface active agent, 5～10 parts；
PETO, 5～13 parts；
Triethanolamine, 0.3～7 part；
Bactericide, 0.2～2 part；
Deionized water, 20～50 parts.
2. according to claim 1 for continuously spin viscose filament yarn environment-friendly type finish, it is characterised in that：The aliphatic acid
Polyoxyethylene ester structural formula is RCOO (EO)nH, wherein R are C4～C20Alkyl, n be 3～40.
3. according to claim 1 for continuously spin viscose filament yarn environment-friendly type finish, it is characterised in that：The epoxy second
Alkane-propylene oxide block polyether structure formula is R1O(PO)m(EO)nH, wherein R1For C4～C50Alkyl, m and n be 3～100.
4. according to claim 1 for continuously spin viscose filament yarn environment-friendly type finish, it is characterised in that：The Shuangzi table
The structural formula of face activating agent is
Wherein it is R1、R2Respectively C10～C20One kind in alkyl.
5. according to claim 1 for continuously spin viscose filament yarn environment-friendly type finish, it is characterised in that：The bactericide
For one or more in pyridine sodium sulphate, s-triazine, morpholine, OIT.
6. according to claim 1 for continuously spin viscose filament yarn environment-friendly type finish, it is characterised in that：The deionization
Water conductivity is less than 10 μ S/cm.
7. according to claim 1 for continuously spin viscose filament yarn environment-friendly type finish, it is characterised in that：Press mass fraction
Meter, by deionized water, 20～50 parts are warming up to 50～70 DEG C, sequentially add 20～40 parts of polyoxyethylene carboxylate, epoxy second
Alkane -4～15 parts of propylene oxide block polyethers, 5～10 parts of Gemini surface active agent, 5～13 parts of PETO, mixing is stirred
Mix 30～50 minutes, be subsequently adding 0.2～2 part of bactericide, 0.3～7 part of triethanolamine is obtained for continuously spinning viscose filament yarn
Finish.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610847764.3A CN106498741B (en) | 2016-09-23 | 2016-09-23 | A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn |
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|---|---|---|---|
| CN201610847764.3A CN106498741B (en) | 2016-09-23 | 2016-09-23 | A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn |
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| Publication Number | Publication Date |
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| CN106498741A true CN106498741A (en) | 2017-03-15 |
| CN106498741B CN106498741B (en) | 2019-02-26 |
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| CN108505342A (en) * | 2018-05-04 | 2018-09-07 | 沈阳浩博实业有限公司 | It is a kind of continuously to spin viscose filament yarn finish and its preparation method and application |
| CN108611862A (en) * | 2018-05-04 | 2018-10-02 | 沈阳浩博实业有限公司 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
| CN113774663A (en) * | 2021-09-16 | 2021-12-10 | 新乡化纤股份有限公司 | Continuous spunbonded adhesive filament oil agent composition and preparation method thereof |
| CN114381943A (en) * | 2022-01-13 | 2022-04-22 | 沈阳浩博实业有限公司 | Continuous spunbonded adhesive filament oil composition |
| CN114737391A (en) * | 2022-05-17 | 2022-07-12 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
| CN115216960A (en) * | 2021-04-15 | 2022-10-21 | 洛阳常龙新材料科技有限公司 | Compounding method of viscose continuous spinning filament oil |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108505342A (en) * | 2018-05-04 | 2018-09-07 | 沈阳浩博实业有限公司 | It is a kind of continuously to spin viscose filament yarn finish and its preparation method and application |
| CN108611862A (en) * | 2018-05-04 | 2018-10-02 | 沈阳浩博实业有限公司 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
| CN115216960A (en) * | 2021-04-15 | 2022-10-21 | 洛阳常龙新材料科技有限公司 | Compounding method of viscose continuous spinning filament oil |
| CN113774663A (en) * | 2021-09-16 | 2021-12-10 | 新乡化纤股份有限公司 | Continuous spunbonded adhesive filament oil agent composition and preparation method thereof |
| WO2023058711A1 (en) * | 2021-10-07 | 2023-04-13 | 竹本油脂株式会社 | First treatment agent for regenerated cellulose fiber, treatment agent for regenerated cellulose fiber, composition containing first treatment agent for regenerated cellulose fiber, method for preparing diluted solution of treatment agent for regenerated cellulose fiber, method for treatment of regenerated cellulose fiber, and regenerated cellulose fiber |
| CN118140023A (en) * | 2021-10-07 | 2024-06-04 | 竹本油脂株式会社 | Treatment agent 1 for regenerated cellulose fibers, treatment agent for regenerated cellulose fibers, composition containing treatment agent 1 for regenerated cellulose fibers, method for producing diluted solution of treatment agent for regenerated cellulose fibers, method for treating regenerated cellulose fibers, and regenerated cellulose fibers |
| CN114381943A (en) * | 2022-01-13 | 2022-04-22 | 沈阳浩博实业有限公司 | Continuous spunbonded adhesive filament oil composition |
| CN114737391A (en) * | 2022-05-17 | 2022-07-12 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
| CN114737391B (en) * | 2022-05-17 | 2023-09-22 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
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Address after: 110165 No. 100, Jianshe Road, Dadong District, Shenyang, Liaoning Patentee after: Shenyang Haobo Group Co.,Ltd. Address before: No. 28, Shenyang Railway, Dadong District, Shenyang, Liaoning 110165 Patentee before: SHENYANG HAOBO INDUSTRIAL Co.,Ltd. |