CN1904200A - Oil agent used for polyester industrial filament - Google Patents
Oil agent used for polyester industrial filament Download PDFInfo
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- CN1904200A CN1904200A CN 200610048403 CN200610048403A CN1904200A CN 1904200 A CN1904200 A CN 1904200A CN 200610048403 CN200610048403 CN 200610048403 CN 200610048403 A CN200610048403 A CN 200610048403A CN 1904200 A CN1904200 A CN 1904200A
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Abstract
This invention discloses a kind of oil applied to the polyester industry, its characteristic is that the oil is composed of the following component: (A) 5 ~ 70 weight % refining mineral oil; (B) 10 ~ 85 weight % polyatomic alcohol fatty acid esters; (C) 5 ~ 55 weight % copolymerizations ether; (D) 2 ~ 40 weight % fatty acid polyoxyethylene ester; (E) 1 ~ 15 weight % antistat; (F) 0.1 ~ 10%'s adhesion function improver. The oil can solve these defects of the present oil that both the heat resistance and the gluing function are bad. Since the heat resistance and the flatness are good, the smoke is few, the carbon build-up is few , waste thread rates is low in spinning handicraft; original silk brute force and modulus are good, maintained extension, breaking extension are low; The brute force loss in back handicraft processing is low , there is no color difference in the dyeing process.
Description
Technical field
The invention belongs to the chemical addition agent field, particularly a kind of oil agent used for polyester industrial filament.
Background technology
High speed development along with domestic economy, automobile, building, water conservancy, traffic, industries such as advertisement are soaring year by year to the consumption of polyester industrial filament yarn, its application percentage in industry will be brought up to 2010 25% from present 15%, the industry technology of State Economic and Trade Commission's promulgation is given priority in the project, fabrics for industrial use are classified as the textile industry new growth engines, terylene industrial will become one of industry of most active and potentiality in the coming years with long filament, because its market prospects are good, demand is big, the added value of product height, domestic many manufacturers are investing the polyester industrial yarn project energetically.High Modulus And Low Shrinkage type (HMLS) polyester industrial yarn wherein, because it has high-modulus, high strength, anti-flat spot performance is excellent, extension at break is little, characteristics such as Heat stability is good, it is first-selected desirable framework material as the meridian cord fabric, but it is with high content of technology, the production difficulty is big, and domestic manufacturer introduces technology or joint founding the factory.
In high temperature, high speed and the gum dipping process in the High Modulus And Low Shrinkage polyester industrial yarn spinning technique cohesiveness of terylene cord fabric and rubber or in dyeing and finishing technology the interaction etc. of dyestuff, finishing agent and finish finish has been proposed very high requirement.This product of finish company Development and Production of countries such as present Japan, the U.S., Germany, the finish of Japan this grease of bamboo company is mainly used in the polyester industrial yarn production technology of non-cord fabric, the flatness of finish is better, but the bond properties of cord fabric and latex is poor; The finish cohesiveness of Germany S.S company is strong, but its holding and poor heat resistance.Before and after spinning and the impregnation two technologies to finish require conflicting, improved the development difficulty of finish, existing finish or flatness, holding are good, but viscosity is big, the rate that oils height, have influence on behind the polyester industrial yarn dyeability in the process or extract out as the H of cord fabric, promptly dyeability, bond properties are poor; Be that bond properties is good, but the viscosity of finish is little, heat resistance and holding are poor, and it is big to show as being fuming of finish, and tow is dispersed, and intensity is low.Can not satisfy the requirement of the big and rate that oils of flatness, holding, viscosity simultaneously.Spinning factory meets the demands to use different finishes according to the different purposes of product, makes the finish product variety various, complex operation.Especially as the polyester industrial yarn of cord fabric, because the molecular structure of polyester fiber has determined its chemical inertness and has been difficult to performance with rubber adhesion, and existing being helpless to improve the bond properties of terylene cord fabric with finish, therefore normal activation processing or other method by fiber surface improves cohesiveness.Introduced a kind of finish that industry silks such as terylene, polypropylene fibre, polyamide fibre are produced that is used for as USP 5972497, form by the single, double ester of pentaerythrite or the single, double ester of pentaerythrite and antistatic additive, the flatness of this finish, excellent heat resistance, but convergence is poor, use as industrial silk oil agent, tow powerful low, the strength loss of tow is big behind the twisted weave, the poor adhesion of cord fabric.USP 5525243 disclosed finishes are by antistatic additive, emulsifying agent and polyvinyl alcohol are formed, antistatic additive mainly contains alkylphosphonic, quaternary amine, imidazoline etc., emulsifying agent mainly contains sorbitan monolaurate, the polyoxyethylene sorbitan monolaurate, the polyoxyethylene pelargonate, the polyoxyethylene caprylate, polyoxyethylene decylate etc., the characteristics of this finish are the confficients of static friction between fiber and the fiber, the coefficient of kinetic friction between fiber and the metal is low, holding between silk and the silk is strong, institute's spinning bundle is mainly as non-weaving cloth, as rope, fishnet, cord fabric etc., the shortcoming of this finish is to use as industrial silk oil agent, then the modulus of tow is low, powerful low, the bond properties of cord fabric and rubber is poor.USP 4469606 discloses a kind of high temperature resistant, oxidation resistant industrial silk oil agent and corresponding antioxidant etc., high temperature resistant, the antioxygenic property of finish have been emphasized, described finish is made up of alkyl polyoxyethylene polyalcohol, alkyl polyoxyethylene aliphatic acid, vegetable oil, antioxidant, the holding of finish, heat resistance and flatness are good, but be only applicable to the spinning technique that the emulsion state oils, and the modulus of tow and powerful low, the bond properties of cord fabric is poor.CN 1428480 disclosed finishes are made up of alkyl polyoxyethylene phosphate salt, alkyl polyoxyethylene ether or polyoxyethylene oleate, mineral oil, di-n-octyl sebacate, trimethylolpropane tris oleate etc., this finish has good flatness, heat resistance and wettability, is applicable to the civilian silk of the high-speed spinning one-step method terylene that oils with emulsion state production technology.But for convergence, heat resistance and even attached property requirement height, and flatness requires moderate industry silk, disclosed finish bad adaptability, show as and be not suitable for the spinning technique that oils with pure finish state, the holding of institute's spinning bundle is poor, powerful low, stretch surely and the disconnected height of stretching, poor as the bond properties that cord fabric uses.
Summary of the invention
The present invention be directed to the shortcomings such as heat resistance, holding and bond properties difference of finish in the prior art, and propose a kind of new oil agent used for polyester industrial filament, when this finish has good heat resistance, holding, possess excellent adhesion performance again.
Oil agent used for polyester industrial filament provided by the invention is composed of the following components:
(a) refined mineral oil of 5～70 weight %;
(b) polyol fatty acid ester of 10～85 weight %;
(c) copolyether of 5～55 weight %;
(d) polyoxyethylene carboxylate of 2～40 weight %;
(e) antistatic additive of 1～15 weight %;
(f) the bond properties improver of 0.1～10 weight %.
Wherein: component (a) is a refined mineral oil, and the kinematic viscosity in the time of 40 ℃ is 5.0～90.0mm
2/ S is preferably 10.0～50.0mm
2/ S, its shared weight percentage in finish is preferably 20～50 weight %.Be characterized in that viscosity is low, but flatness and cluster performance are good.
Component (b) is a polyol fatty acid ester, is synthesized under normal condition by polyalcohol and aliphatic acid, and polyalcohol wherein is for being selected from a kind of in glycerol, trimethylolpropane and the pentaerythrite at least, and aliphatic acid is C
4～C
40Aliphatic acid is preferably C
8～C
20Aliphatic acid, polyol fatty acid ester shared weight percentage in finish is preferably 25～60 weight %.
Component (c) is oxirane, expoxy propane copolyether, its structural formula as the formula (1):
R wherein
1Be C
2～C
18Alkyl, R
2Be C
8～C
30Alkyl, m is 5～200 integer, is preferably 10～160 integer; N is 10～160 integer, be preferably 15～140 integer, x is 1～4 integer, be preferably 1 or 2, its feature is that flatness is good, and the amount of being fuming is few, the carbon deposit function admirable, and low to the coefficient of friction of fiber, this component shared weight percentage in finish is preferably 10～40 weight %.
Component (d) is a polyoxyethylene carboxylate, and this component is synthesized under normal condition by oxirane and aliphatic acid, and wherein aliphatic acid is C
8～C
18Aliphatic acid, the mol ratio of aliphatic acid and oxirane is 1: 3～1: 24, is preferably 1: 6～1: 18.Component (d) shared weight percentage in finish is preferably 5～30 weight %, is characterized in that holding, heat resistance and emulsifiability are good.
Component (e) is an antistatic additive, is selected from a kind of in alkyl phosphate salt and the alkyl sulfate salt at least, and the molecular formula of alkyl phosphate salt is R
3OPO
3M or (R
3O)
2PO
2M, the molecular formula of alkyl sulfate salt is R
3OSO
3M, wherein R
3Be C
2～C
36Alkyl, be preferably C
8～C
20Alkyl, M is alkali metallic sodium or potassium, component (e) shared weight percentage in finish is preferably 3～12 weight %.
Component (f) is the bond properties improver, at least be selected from a kind of in oleic acid macrogol ester, vulcanized vegetable oil, isocyanates and the triethylene glycol, described oleic acid macrogol ester is synthesized into by oleic acid and polyethylene glycol, and oleic acid is vegetable oil acid, and the molecular weight of polyethylene glycol is 200～2000.Component (f) shared weight percentage in finish is preferably 0.5～8 weight %.
The preparation method of oil agent used for polyester industrial filament of the present invention is: add above-mentioned each component successively in reactor, be heated to 45～90 ℃ under stirring, constant temperature stirred 30～40 minutes, was cooled to 25～30 ℃ then, promptly got finish of the present invention.
Compared with prior art, oil agent used for polyester industrial filament provided by the present invention, owing to contain component fatty acids polyoxyethylene ester and the oxirane expoxy propane copolyether that improves the finish convergence in the finish, also contain the bond properties improver in the finish, thereby make finish provided by the present invention not only have good heat resistance, holding, convergence and flatness, and possess excellent adhesion performance.Use that finish of the present invention can reach that good spinnability, waste silk rate are low, the powerful height of precursor, effect such as strength loss is low and the cord fabric cohesiveness is strong; In spinning technique, be fuming less, carbon deposit is few, the waste silk rate is low; Precursor brute force and modulus height, stretching surely, break, it is low to stretch; Strength loss in after-processing technology is low, no color differnece phenomenon in the dyeing course.
The occupation mode of oil agent composition of the present invention is that oil tanker oils or utilizes nozzle directly to oil.
The specific embodiment
Describe the present invention in detail with specific embodiment below, but these embodiment do not limit the scope of the invention.
Embodiment 1
(40 ℃ of kinematic viscosity are 15.0mm to get 20 gram refined mineral oils successively
2/ S), 32 gram glycerol trilaurins, 30 gram polyethers (m=16, n=38, R
1Be n-octyl, R
2Be octadecyl, x=1), (aliphatic acid is C to 10 gram polyoxyethylene carboxylates
18Stearic acid, the mol ratio of aliphatic acid and oxirane are 1: 12), 3 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 5 gram oleic acid macrogol esters (molecular weight polyethylene glycol is 600) are heated to 47 ± 2 ℃ in reactor, constant temperature stirred 40 minutes, be cooled to 25 ℃ then, promptly get the invention finish A of institute.
Embodiment 2
(40 ℃ of kinematic viscosity are 35.0mm to get 20 gram refined mineral oils successively
2/ S), 50 gram glycerol trilaurins, 20 gram polyethers (m=16, n=38, R
1Be n-octyl, R
2Be octadecyl, x=1), (aliphatic acid is C to 5 gram polyoxyethylene carboxylates
18Stearic acid, the mol ratio of aliphatic acid and oxirane are 1: 12), 3 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 2 gram vulcanized vegetable oils are heated to 88 ± 2 ℃ in reactor, and constant temperature stirred 40 minutes, was cooled to 25 ℃ then, promptly got the invention finish B of institute.
Embodiment 3
(40 ℃ of kinematic viscosity are 50.0mm to get 47 gram refined mineral oils successively
2/ S), 15 gram glycerol tristearates, 20 gram polyethers (m=16, n=38, R
1Be positive decyl, R
2Be dodecyl, x=1), (aliphatic acid is C to 5 gram polyoxyethylene carboxylates
18Stearic acid, the mol ratio of aliphatic acid and oxirane are 1: 12), 8 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 5 gram oleic acid macrogol esters (molecular weight polyethylene glycol is 600) are heated to 60 ± 2 ℃ in reactor, constant temperature stirred 30 minutes, be cooled to 30 ℃ then, promptly get the invention finish C of institute.
Embodiment 4
(40 ℃ of kinematic viscosity are 10.0mm to get 30 gram refined mineral oils successively
2/ S), 20 gram glycerol tristearates, 10 gram polyethers (m=17, n=28, R
1Be dodecyl, R
2Be cetyl, x=1), (aliphatic acid is laurate to 20 gram polyoxyethylene carboxylates, the mol ratio of aliphatic acid and oxirane is 1: 9), 12 gram n-octyl phosphate kalium salts, 8 gram oleic acid macrogol esters (molecular weight polyethylene glycol is 1500) are in reactor, be heated to 47 ± 2 ℃, constant temperature stirred 40 minutes, was cooled to 25 ℃ then, promptly got the invention finish D of institute.
Embodiment 5
(40 ℃ of kinematic viscosity are 7.0mm to get 10 gram refined mineral oils successively
2/ S), 65 gram pentaerythrites, four pelargonates, 10 gram polyethers (m=17, n=28, R
1Be dodecyl, R
2Be octadecyl, x=1), (aliphatic acid is laurate to 5 gram polyoxyethylene carboxylates, the mol ratio of aliphatic acid and oxirane is 1: 6), 5 gram octadecyl phosphoric acid ester sodiums, 3 gram oleic acid macrogol esters (molecular weight polyethylene glycol is 400), 2 gram isocyanates are in reactor, be heated to 88 ± 2 ℃, constant temperature stirred 30 minutes, was cooled to 30 ℃ then, promptly got the invention finish E of institute.
Embodiment 6
(40 ℃ of kinematic viscosity are 68.0mm to get 20 gram refined mineral oils successively
2/ S), 30 gram pentaerythrites, four pelargonates, 25 gram trimethylolpropane tris decylates, 10 gram polyethers (m=10, n=25, R
1, R
2Be dodecyl, x=1), (aliphatic acid is laurate to 10 gram polyoxyethylene carboxylates, the mol ratio of aliphatic acid and oxirane is 1: 18), 3 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sodium salts, 2 gram oleic acid macrogol esters (molecular weight polyethylene glycol is 1800) are in reactor, be heated to 80 ± 2 ℃, constant temperature stirred 30 minutes, was cooled to 25 ℃ then, promptly got the invention finish F of institute.
Embodiment 7
(40 ℃ of kinematic viscosity are 5.0mm to get 40 gram refined mineral oils successively
2/ S), 30 gram pentaerythrite cinnamic acid in April esters, 10 gram polyethers (m=50, n=65, R
1, R
2Be dodecyl, x=1), (aliphatic acid is n-capric acid to 10 gram polyoxyethylene carboxylates, the mol ratio of aliphatic acid and oxirane is 1: 12), 3 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sodium salts, 7 gram vulcanized vegetable oils are in reactor, be heated to 47 ± 2 ℃, constant temperature stirred 40 minutes, was cooled to 25 ℃ then, promptly got the invention finish G of institute.
Embodiment 8
(40 ℃ of kinematic viscosity are 40.0mm to get 20 gram refined mineral oils successively
2/ S), 25 gram pentaerythrites, four palmitates, 20 gram polyethers (m=100, n=120, R
1Be normal-butyl, R
2Be dodecyl, x=1), (aliphatic acid is laurate to 20 gram polyoxyethylene carboxylates, the mol ratio of aliphatic acid and oxirane is 1: 6), 7 gram octadecyl phosphate kalium salts, 4 gram triethylene glycols, 4 gram isocyanates are in reactor, be heated to 88 ± 2 ℃, constant temperature stirred 40 minutes, was cooled to 25 ℃ then, promptly got the invention finish H of institute.
Embodiment 9
(40 ℃ of kinematic viscosity are 26.0mm to get 10 gram refined mineral oils successively
2/ S), 12 gram trimethylolpropane tris cocounut oil acid esters, 38 gram polyethers (m=12, n=15, R
1Be n-hexyl, R
2Be dodecyl, x=1), (aliphatic acid is n-capric acid to 30 gram polyoxyethylene carboxylates, the mol ratio of aliphatic acid and oxirane is 1: 9), 3 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 7 gram triethylene glycols are in reactor, be heated to 65 ± 2 ℃, constant temperature stirred 40 minutes, was cooled to 30 ℃ then, promptly got the invention finish I of institute.
Embodiment 10
(40 ℃ of kinematic viscosity are 90.0mm to get 5 gram refined mineral oils successively
2/ S), 15 gram trimethylolpropane tris decylates, 45 gram polyethers (m=12, n=15, R
1Be n-hexyl, R
2Be dodecyl, x=1), (aliphatic acid is n-capric acid to 20 gram polyoxyethylene carboxylates, the mol ratio of aliphatic acid and oxirane is 1: 9), 5 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 10 gram vulcanized vegetable oils are in reactor, be heated to 50 ± 2 ℃, constant temperature stirred 30 minutes, was cooled to 30 ℃ then, promptly got the invention finish J of institute.
Embodiment 11
(40 ℃ of kinematic viscosity are 15.0mm to get 35 gram refined mineral oils successively
2/ S), 20 gram pentaerythrites, four decylates, 20 gram polyethers (m=15, n=20, R
1Be normal-butyl, R
2Be dodecyl, x=1), 5 gram polyoxyethylene carboxylates (aliphatic acid is stearic acid, and the mol ratio of aliphatic acid and oxirane is 1: 12), 5 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 5 gram laurilsulfate sodium salts, 8 gram vulcanized vegetable oils are heated to 50 ± 2 ℃ in reactor, constant temperature stirred 35 minutes, be cooled to 25 ℃ then, promptly get the invention finish K of institute.
Embodiment 12
(40 ℃ of kinematic viscosity are 10.0mm to get 30 gram refined mineral oils successively
2/ S), 20 gram pentaerythrites, four decylates, 20 gram polyethers (m=20, n=12, R
1Be normal-butyl, R
2Be dodecyl, x=1), 12 gram polyoxyethylene carboxylates (aliphatic acid is stearic acid, and the mol ratio of aliphatic acid and oxirane is 1: 12), 5 gram 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 3 gram laurilsulfate sodium salts, 5 gram triethylene glycols, 5 gram vulcanized vegetable oils are in reactor, be heated to 50 ± 2 ℃, constant temperature stirred 35 minutes, was cooled to 30 ℃ then, promptly got the invention finish L of institute.
Embodiment 13
This embodiment is the embodiment that finish is used.
Measure the data such as heat resistance, film strength and open flash point of embodiment 1～embodiment 12 prepared 12 finish samples in the laboratory, the result is as shown in table 1:
Table 1 oil performance
| Heat resistance | Film strength, N | Open flash point, ℃ | |||
| The amount of being fuming | Coking capacity | Volatile quantity, 180 ℃, 2hr, % | |||
| Embodiment 1 | Less | Excellent | 12.3 | 980 | 170 |
| Embodiment 2 | Less | Excellent | 12.6 | 810 | 155 |
| Embodiment 3 | Less | Excellent | 19.5 | 780 | 148 |
| Embodiment 4 | Less | Excellent | 15.0 | 920 | 172 |
| Embodiment 5 | Less | Excellent | 11.6 | 830 | 156 |
| Embodiment 6 | Less | Excellent | 12.2 | 790 | 164 |
| Embodiment 7 | Less | Excellent | 18.2 | 880 | 152 |
| Embodiment 8 | Less | Excellent | 12.7 | 830 | 171 |
| Embodiment 9 | Less | Excellent | 11.4 | 780 | 182 |
| Embodiment 10 | Less | Excellent | 11.6 | 910 | 156 |
| Embodiment 11 | Less | Excellent | 14.9 | 980 | 164 |
| Embodiment 12 | Less | Excellent | 15.2 | 920 | 158 |
| Analytical method | ① | ② | ③ | GB/T3142 | GB/T3536 |
Annotate: the test of 1. smoldering: take by weighing sample 10.0 and restrain in the 50ml beaker, place electric jacket to heat in this beaker, observe temperature and the amount of being fuming size when smoldering continuously.
2. hot plate test: measure sample 1.0ml and drip in No. 45 steel test pieces, this test piece is positioned in the baking oven, 220 ℃ of following constant temperature 3 minutes, be cooled to 30 ℃ then, observe the coking behavior of finish, " excellent " represents seldom coking.
3. volatilization test: take by weighing sample 2.0 and restrain in the 50ml beaker, this beaker is positioned in the baking oven,, be cooled to 30 ℃ then, weigh and calculate the volatile quantity of finish 180 ℃ of following constant temperature 2 hours.
The use of finish
The mode that adopts nozzle to oil, the spinning production technology that the finish of embodiment 2, embodiment 5, embodiment 6 and embodiment 10 preparations is used for ordinary polyester industry silk, the finish of embodiment 1, embodiment 3, embodiment 4, embodiment 7, embodiment 8, embodiment 9, embodiment 11 and embodiment 12 preparations is used for the spinning production technology that kind is the cord fabric of 1670dtex/2, and result of use is shown in table 2 and table 3.
Table 2 finish uses the result
| Be fuming | Smell | The fracture of wire number of times, inferior/day. ingot | Wipe the roller number of times, inferior/day. ingot | The waste silk rate, % | The rate that oils, % | |
| Embodiment 1 | Less | Free from extraneous odour | 2.1 | 1.2 | 2.9 | 0.89 |
| Embodiment 2 | Less | Free from extraneous odour | 1.9 | 1.0 | 2.6 | 0.78 |
| Embodiment 3 | Less | Free from extraneous odour | 1.9 | 2.0 | 2.5 | 0.86 |
| Embodiment 4 | Less | Free from extraneous odour | 2.5 | 1.5 | 3.1 | 0.87 |
| Embodiment 5 | Less | Free from extraneous odour | 2.2 | 1.6 | 2.7 | 0.91 |
| Embodiment 6 | Less | Free from extraneous odour | 1.7 | 1.2 | 2.6 | 0.88 |
| Embodiment 7 | Less | Free from extraneous odour | 1.9 | 1.2 | 2.6 | 0.96 |
| Embodiment 8 | Less | Free from extraneous odour | 2.4 | 2.3 | 2.8 | 0.84 |
| Embodiment 9 | Less | Free from extraneous odour | 2.3 | 1.2 | 2.6 | 0.91 |
| Embodiment 10 | Less | Free from extraneous odour | 2.7 | 1.0 | 2.9 | 0.92 |
| Embodiment 11 | Less | Free from extraneous odour | 1.8 | 1.5 | 2.2 | 0.91 |
| Embodiment 12 | Less | Free from extraneous odour | 2.6 | 2.2 | 3.1 | 0.83 |
Table 3 finish uses the result
| Fracture strength, N/dtex | Fracture strength CV value, % | Elongation at specified load, % | Elongation at specified load CV value, % | Extension at break, % | Extension at break CV value, % | Dry-hot shrinkage, % | Dry-hot shrinkage CV value, % | H extracts out, N | |
| Embodiment 1 | 7.85 | 1.2 | 5.6 | 3.3 | 12.5 | 4.12 | 4.8 | 1.2 | |
| Embodiment 2 | 7.67 | 0.9 | 5.6 | 3.6 | 12.6 | 3.65 | 4.8 | 1.1 | 168 |
| Embodiment 3 | 7.86 | 2.1 | 5.8 | 3.2 | 13.1 | 3.89 | 5.3 | 1.2 | |
| Embodiment 4 | 7.49 | 1.3 | 5.8 | 3.2 | 13.1 | 4.45 | 5.5 | 1.3 | |
| Embodiment 5 | 7.56 | 1.1 | 5.6 | 3.2 | 12.7 | 4.76 | 5.3 | 1.3 | 165 |
| Embodiment 6 | 8.12 | 1.2 | 5.7 | 3.5 | 12.7 | 3.75 | 5.2 | 1.1 | 165 |
| Embodiment 7 | 8.05 | 1.8 | 5.7 | 3.5 | 12.9 | 3.98 | 4.7 | 1.4 | |
| Embodiment 8 | 8.11 | 1.8 | 5.4 | 3.3 | 12.4 | 3.78 | 5.6 | 1.4 | |
| Embodiment 9 | 7.64 | 0.7 | 5.4 | 3.4 | 12.5 | 3.75 | 4.9 | 1.2 | |
| Embodiment 10 | 7.38 | 0.9 | 6.1 | 3.2 | 13.8 | 4.25 | 5.5 | 1.2 | 169 |
| Embodiment 11 | 7.98 | 1.6 | 5.4 | 3.1 | 12.2 | 4.26 | 5.6 | 1.1 | |
| Embodiment 12 | 8.21 | 1.5 | 5.4 | 3.3 | 12.4 | 4.23 | 5.3 | 1.1 |
By table 1～table 3 data as can be known, from embodiment 1 to embodiment 12, fracture of wire number of times when the amount of being fuming of finish, spinning, wiping roller number of times, waste silk rate, precursor elongation at break (disconnected stretching), continuous rating elongation rate (stretching surely), dry-hot shrinkage and corresponding C V value etc. are all lower, the tar voltinism of finish is excellent, open flash point is higher, intensity height, the CV value of gained precursor are lower, and H extracts out high.The heat resistance, flatness, holding of finish of the present invention and sticking and property is good have been described, have shown as being fuming less in spinning technique, the tarring degree is low, the waste silk rate is low; Precursor intensity height, stretching surely, break, it is lower to stretch; If institute spins the industry silk and uses as cord fabric, and is then good with the bond properties of rubber, promptly H extracts out high.
Claims (5)
1. oil agent used for polyester industrial filament is characterized in that this finish is composed of the following components:
(a) refined mineral oil of 5～70 weight %;
(b) polyol fatty acid ester of 10～85 weight %;
(c) copolyether of 5～55 weight %;
(d) polyoxyethylene carboxylate of 2～40 weight %;
(e) antistatic additive of 1～15 weight %;
(f) the bond properties improver of 0.1～10 weight %;
Wherein: kinematic viscosity was 5.0～90.0mm when component (a) was 40 ℃
2The refined mineral oil of/S;
Component (b) is by the synthetic ester of polyalcohol and aliphatic acid, and described polyalcohol is for being selected from a kind of in glycerol, trimethylolpropane and the pentaerythrite at least, and aliphatic acid is C
4～C
40Aliphatic acid;
Component (c) is the copolyether of oxirane and expoxy propane, structural formula as the formula (1):
R wherein
1Be C
8～C
18Alkyl, R
2Be C
8～C
30Alkyl, m is 5～200 integer, n is 10～160 integer, x is 1～4 integer;
Component (d) is oxirane and the synthetic ester of aliphatic acid, and wherein aliphatic acid is C
8～C
18Aliphatic acid, the mol ratio of aliphatic acid and oxirane is 1: 3～1: 24;
Component (e) is for being selected from a kind of in alkyl sulfate salt and the alkyl phosphate salt at least, and wherein the molecular formula of alkyl phosphate salt is R
3OPO
3M or (R
3O)
2PO
2M, the molecular formula of alkyl sulfate salt is R
3OSO
3M, R in the formula
3Be C
2～C
36Alkyl, M is alkali metallic sodium or potassium;
Component (f) is for being selected from a kind of in oleic acid macrogol ester, vulcanized vegetable oil, isocyanates and the triethylene glycol at least.
2. finish according to claim 1, it is characterized in that: the content of component (a) is 20～50 weight %, the content of component (b) is 25～60 weight %, the content of component (c) is 10～40 weight %, the content of component (d) is 5～30 weight %, the content of component (e) is 3～12 weight %, and the content of component (f) is 0.5～5 weight %, in the finish gross weight.
3. finish according to claim 1 and 2 is characterized in that: kinematic viscosity was 10.0～50.0mm when component (a) was 40 ℃
2The refined mineral oil of/S.
4. finish according to claim 1 is characterized in that: the m in the formula (1) is 10～160 integer, and n is 15～140 integer, and x is 1 or 2.
5. finish according to claim 1 is characterized in that: the mol ratio of aliphatic acid and oxirane is 1: 6～1: 18 in the component (d).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100484039A CN100378267C (en) | 2006-07-14 | 2006-07-14 | Oil agent used for polyester industrial filament |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100484039A CN100378267C (en) | 2006-07-14 | 2006-07-14 | Oil agent used for polyester industrial filament |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1904200A true CN1904200A (en) | 2007-01-31 |
| CN100378267C CN100378267C (en) | 2008-04-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2006100484039A Expired - Fee Related CN100378267C (en) | 2006-07-14 | 2006-07-14 | Oil agent used for polyester industrial filament |
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| CN101929068A (en) * | 2010-08-24 | 2010-12-29 | 上虞市皇马化学有限公司 | Polyester POY spinning finish and production method thereof |
| CN101519847B (en) * | 2009-03-31 | 2011-07-20 | 中国石油化工集团公司 | Short-fiber oil agent for aromatic polyamide fiber |
| CN101463560B (en) * | 2007-12-21 | 2011-07-20 | 财团法人工业技术研究院 | Anti-abrasion antistatic fiber, production method and composition for producing the same |
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| CN102828401A (en) * | 2012-08-02 | 2012-12-19 | 太仓市中明化纤有限公司 | Viscose spinning oil |
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| CN103882694A (en) * | 2013-12-25 | 2014-06-25 | 苏州晟德竹科技发展有限公司 | Oil solution for polyimide fibers |
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| WO2017030508A1 (en) * | 2015-08-19 | 2017-02-23 | Agency For Science, Technology And Research | A base oil additive |
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| US4469606A (en) * | 1982-07-26 | 1984-09-04 | Ciba-Geigy Corporation | Stabilization systems for fiber finishes |
| JPS62223372A (en) * | 1986-03-18 | 1987-10-01 | 株式会社クラレ | Spinning oil agent of fiber for fabric |
| JPH04241169A (en) * | 1991-01-11 | 1992-08-28 | Nippon Ester Co Ltd | Polyester short fiber for spun yarn |
| JPH0754269A (en) * | 1993-08-10 | 1995-02-28 | Nippon Ester Co Ltd | Polyester short fiber for spun yarn |
| CN1138034C (en) * | 1999-12-21 | 2004-02-11 | 浙江皇马化工集团有限公司 | Conventional polyester spinning oil and preparation method thereof |
| CN1428480A (en) * | 2001-12-27 | 2003-07-09 | 中国石化上海石油化工股份有限公司 | Spinning oil for polyester full-drafting fibre |
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| CN101519847B (en) * | 2009-03-31 | 2011-07-20 | 中国石油化工集团公司 | Short-fiber oil agent for aromatic polyamide fiber |
| CN101929068A (en) * | 2010-08-24 | 2010-12-29 | 上虞市皇马化学有限公司 | Polyester POY spinning finish and production method thereof |
| CN102828401A (en) * | 2012-08-02 | 2012-12-19 | 太仓市中明化纤有限公司 | Viscose spinning oil |
| CN103161068A (en) * | 2013-01-28 | 2013-06-19 | 天津工业大学 | Cord thread spinning oil |
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| CN103882694B (en) * | 2013-12-25 | 2016-01-20 | 苏州晟德竹科技发展有限公司 | For the finish of polyimide fiber |
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| CN106087406A (en) * | 2016-08-29 | 2016-11-09 | 上海多纶化工有限公司 | Novel polyester filament oil preparation |
| CN106498741A (en) * | 2016-09-23 | 2017-03-15 | 沈阳浩博实业有限公司 | A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn |
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