CN103161068A - Cord thread spinning oil - Google Patents
Cord thread spinning oil Download PDFInfo
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- CN103161068A CN103161068A CN2013100302115A CN201310030211A CN103161068A CN 103161068 A CN103161068 A CN 103161068A CN 2013100302115 A CN2013100302115 A CN 2013100302115A CN 201310030211 A CN201310030211 A CN 201310030211A CN 103161068 A CN103161068 A CN 103161068A
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- oil
- cord fabric
- thread spinning
- fabric thread
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Abstract
The invention discloses cord thread spinning oil. The cord thread spinning oil comprises, by mass, 40-60% of plant oil, 30-50% of compound fatty acid ester, 1-10% of non-ion surfactant, and the balance antioxidant. The plant oil is selected from at least one of peanut oil, soya-bean oil, linseed oil, castor oil, health oil, and rapeseed oil, refined processing is carried out on the plant oil, iodine value is higher than 70, the compound fatty acid ester is pentaerythritol ester or trimethylolpropane ester, and the non-ion surfactant is fatty alcohol-polyoxyethylene ether, fatty alcohol polyurethane propylene ether or fatty alcohol polyoxyethylene polyoxypropylene.
Description
Technical field
The present invention relates to chemical fibres assistant, be specially a kind of cord fabric thread spinning oil.This finish is high temperature resistant, and environmental protection.
Background technology
Cord fabric thread is a kind of fiber of being prepared through melt spinning by polyamide or mylar, then through the formed macromolecular material of multi beam plying, drawing-off and twisting.Cord fabric thread has very high TENSILE STRENGTH and lower bending strength at axial direction, is the material of main part of making automobile and light truck tyre framework.Cord fabric thread as framework material, is carrying and the main body of transmitting stress in tire, and the intensity of cord fabric thread, degree of stretching and DIMENSIONAL STABILITY are the keys of improving tyre performance and improving the quality of products.
The cord fabric thread spinning oil is to be mainly used in the spinning production of polyamide, polyester cord fiber and industrial yarn etc. and a kind of fine chemicals of rear process.Finish mainly plays lubricated, boundling, the antistatic and effect of adjusting coefficient of friction in the production process of cord fabric thread drawing of fiber, coiling, twisting and plying, with the spinnability that guarantees fiber and the row yielding of postorder product.At cord fabric thread high temperature, at a high speed, under the spinning manufacturing condition of heavily stressed, high friction, the quality of spinning oil directly affects the mechanical properties such as spinnability, drawing-off uniformity coefficient and fracture strength, the strength loss of cord fabric thread, the spinnability of cord fabric thread is one of key factor of enhancing productivity and reducing production costs, and mechanical property and strong damage index are the keys that affects postorder tire size stability, are the key indexs that affects fiber quality.Therefore, the high performance cord fabric thread spinning oil of exploitation is to the fiber industry that promotes China and auto industry positive meaning of tool all.
The cord fabric thread spinning oil of prior art uses mineral oil and animal fat etc. to do lubricant more, and the materials such as solvent naphtha than great share, water, alcohol, volatile solvent have been added, to lower the finish system viscosity, finish poor permeability, slower at the fiber surface spreading rate in use, flatness is not enough, cord fabric thread drawing of fiber lack of uniformity, the finished fiber fracture strength is low can not satisfy the requirement that follow-up high-grade tire is made, and resistance to elevated temperatures is relatively poor, the easy coking of finish, the amount of being fuming are large, and production environment is had considerable influence.
In the scope of applicant's literature search, be applicable to cord fabric thread spinning and postorder drawing-off, twist, weave, the environment-friendly type thermostable spinning oil of impregnation processing process, have not yet to see report.
Summary of the invention
Not enough for prior art, the technical problem that quasi-solution of the present invention is determined is, a kind of cord fabric thread spinning oil is provided, this finish is fire resistant environment-friendly, product has good physical and mechanical properties, in spinning and rear process, has good applicability, the preparation method is simple, is suitable for industrializing implementation.
The technical scheme that the present invention solve the technical problem is, designs a kind of cord fabric thread spinning oil, and the mass percent of this finish consists of:
Described vegetable oil is selected from least a in peanut oil, soya-bean oil, linseed oil, castor oil, health oil and rape seed oil, and through refinement treatment, iodine number is higher than 70;
Described Acrawax refers to pentaerythritol ester or trihydroxymethylpropanyl ester;
Described non-ionic surface active agent is fatty alcohol-polyoxyethylene ether, fatty alcohol polyoxypropylene ether or aliphatic alcohol polyethenoxy polyethenoxy ether.
compared with prior art, the present invention has used refined plant oil and high temperature resistant neopentyl polyol ester to make lubricant, to have excellent surface-active high temperature resistant non-ionic surface active agent as emulsifying agent and the viscosity modifier of system, the finish product has good physical and mechanical properties, comprise flatness, wettability, permeability, antistatic behaviour and unwinding, and has an excellent resistance to elevated temperatures, finish has wetting and spreading rate faster at fiber surface, good spinnability, drawing of fiber is even, fracture strength is higher, can obviously reduce the coking phenomenon of finish on the drawing-off hot-rolling and fall low-smoke, environmental contamination reduction, significantly increase finished fiber intensity and cord fabric impregnation intensity, finish preparation method of the present invention is simple, is suitable for industrializing implementation.
The specific embodiment
A kind of cord fabric thread spinning oil (abbreviation finish) of the present invention's design, the mass percent of this finish consists of:
Described vegetable oil is selected from least a in peanut oil, soya-bean oil, linseed oil, castor oil, health oil and rapeseed oil, and through refinement treatment, iodine number is higher than 70.Described refinement treatment is routine techniques.
Described Acrawax refers to neopentyl polyol ester, preferred pentaerythritol ester or trihydroxymethylpropanyl ester.Selected Acrawax steady chemical structure, good heat resistance has more excellent heat and hydrolytic stability than dibasic acid esters; Owing to having polynary polar group in selected synthetic fatty acid ester molecule, thereby there is very strong affinity the metal surface, has excellent high low temperature adaptability, can significantly reduce fiber and intermetallic dynamic friction wiping coefficient, high temperature lubrication property is good; Owing to having adopted higher fatty acids in selected synthetic fatty acid ester molecule, thereby antioxygenic property is good, can not produce sediment in use procedure, and condensation point is low.
Described non-ionic surface active agent is fatty alcohol-polyoxyethylene ether, fatty alcohol polyoxypropylene ether or aliphatic alcohol polyethenoxy polyethenoxy ether.Alkyl chain R in its structural formula is C8～C16 saturated fatty alcohol, and polyoxyethylene segment (EO) adduct number is n
1Be 0～20, polyoxypropylene segment (PO) adduct number n
2Be 0～20, polyoxyethylene ether and polyoxypropylene segment are random form, and molecular weight is not more than 4000.
Described antioxidant is the commercial goods.
Finish preparation method of the present invention adopts following technique:
Percentage by weight proportion of composing by cord fabric thread spinning oil of the present invention mixes each component, under 30～60 ℃, fully stirs 30～90 minutes, can obtain cord fabric thread fibre spinning finish of the present invention.
Oil formula of the present invention has designed the oil formula take refined plant oil, synthetic high-grade aliphatic ester and fatty alcohol-polyoxyethylene ether as main component, vegetable oil wherein and synthetic high-grade aliphatic ester play a part smoothly, lower coefficient of friction, prevent adhesion, can reach the reduction winding tension, make that fiberizing is good, unwinding purpose smoothly, have excellent resistance to elevated temperatures and thermal adaptability preferably; In addition, refining vegetable oil and neopentyl synthesize high-grade aliphatic ester, can obviously reduce the surface tension of fiber in spinning process, reduce lousiness bull phenomenon, make finish noncoking on the hot rod of drawing-off, and the amount of being fuming is little, significantly reduces environmental air pollution; The non-ionic surface active agent that adds in described oil formula, fatty alcohol-polyoxyethylene ether has to a certain degree regulating action to the frictional behaviour of fiber, simultaneously because of its emulsification and removeability preferably, can make the finish that is attached on fiber be easy to washing and remove in follow-up immersing glue process; The antioxidant that adds has the finish antistatic behaviour of enhancing and rub resistance.
The performance indications of cord fabric thread spinning oil product of the present invention are described in table 1 below:
The performance indications table of table 1 cord fabric thread spinning oil product
Oil performance of the present invention is stable, has excellent temperature and humidity adaptability, is applicable to the different production environment of different geographical, Various Seasonal.Finish is easy to use, can directly use the spinning of finish stoste, uses after also finish stoste can being diluted to finite concentration with deionized water.Finish manufacturing technique of the present invention is simple, and equipment is had no special requirements, and is easy to apply.
The present invention does not address part and is applicable to prior art.
The below provides specific embodiments of the invention, but the application's claim protection domain is not subjected to the restriction of specific embodiment.
Embodiment 1
The percentage by weight of finish consists of:
The preparation method of finish is: at 45 ℃ of temperature, following weight percentage formula component material is joined in reactor with agitator, stir 90min, can make finish of the present invention.The viscosity 87mm of this finish
2/ s, solid content are 99.4%.
Embodiment 2
At 40 ℃ of temperature, following weight percentage formula component material is joined in reactor with agitator stir 60min, can make finish of the present invention.The viscosity 93mm of this finish
2/ s, solid content are 99.6%.Formula consists of:
Embodiment 3
At 35 ℃ of temperature, following weight percentage formula component material is joined in reactor with agitator stir 60min, can make finish of the present invention.The viscosity 76mm of this finish
2/ s, solid content 99.7%.Formula consists of:
Embodiment 4
At 50 ℃ of temperature, following weight percentage formula component material is joined in reactor with agitator stir 40min, can make finish of the present invention.The viscosity 102mm of this finish
2/ s, solid content are 99.5%.Formula consists of:
Embodiment 5
At 60 ℃ of temperature, following weight percentage formula component material is joined in reactor with agitator stir 30min, can make finish of the present invention.This finish viscosity 81mm
2/ s, solid content 99.9%.Formula consists of:
Embodiment 6
At 30 ℃ of temperature, following weight percentage formula component material is joined in reactor with agitator stir 50min, can make finish of the present invention.This finish viscosity 127mm
2/ s, solid content 99.2%.Formula consists of:
Claims (2)
1. cord fabric thread spinning oil, the mass percent of this finish consists of:
Vegetable oil 40～60%;
Acrawax 30～50%;
Non-ionic surface active agent 1～10%;
The antioxidant surplus;
Described vegetable oil is selected from least a in peanut oil, soya-bean oil, linseed oil, castor oil, health oil and rape seed oil, and through refinement treatment, iodine number is higher than 70;
Described Acrawax refers to pentaerythritol ester or trihydroxymethylpropanyl ester;
Described non-ionic surface active agent is fatty alcohol-polyoxyethylene ether, fatty alcohol polyoxypropylene ether or aliphatic alcohol polyethenoxy polyethenoxy ether.
2. the manufacture method of a cord fabric thread spinning oil, this manufacture method adopts following technique: form by cord fabric thread spinning oil percentage by weight claimed in claim 1 and mix each component, fully stirred 30 ~ 90 minutes under 30～60 ℃, namely obtain described cord fabric thread spinning oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100302115A CN103161068A (en) | 2013-01-28 | 2013-01-28 | Cord thread spinning oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100302115A CN103161068A (en) | 2013-01-28 | 2013-01-28 | Cord thread spinning oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103161068A true CN103161068A (en) | 2013-06-19 |
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ID=48584578
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013100302115A Pending CN103161068A (en) | 2013-01-28 | 2013-01-28 | Cord thread spinning oil |
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| Country | Link |
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| CN (1) | CN103161068A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN104328662A (en) * | 2014-11-27 | 2015-02-04 | 何庆堃 | Soybean fiber high stretch yarn deformation oil agent |
| CN104328658A (en) * | 2014-11-27 | 2015-02-04 | 何庆堃 | Silk fiber high stretch yarn deformation oil agent |
| CN104358126A (en) * | 2014-11-27 | 2015-02-18 | 何庆堃 | High stretch yarn transformation oil agent of bamboo charcoal fibers |
| CN104532554A (en) * | 2014-12-31 | 2015-04-22 | 福建恒安集团有限公司 | Aloe spinning oil |
| KR20150092017A (en) * | 2014-02-04 | 2015-08-12 | 마쓰모토유시세이야쿠 가부시키가이샤 | Finish for synthetic fibers and application thereof |
| CN106087406A (en) * | 2016-08-29 | 2016-11-09 | 上海多纶化工有限公司 | Novel polyester filament oil preparation |
| CN108035149A (en) * | 2017-12-18 | 2018-05-15 | 江苏新瑞贝科技股份有限公司 | A kind of environment-friendly type polyacrylic fibre oil and preparation method thereof |
| CN108517585A (en) * | 2018-02-09 | 2018-09-11 | 海盐县硕创服装研究所 | Spinning oil and preparation method thereof for cord fabric thread |
| CN108940118A (en) * | 2018-07-02 | 2018-12-07 | 传化智联股份有限公司 | A kind of electrolyte-resistant anionic surfactant and its preparation method and application |
| CN110093779A (en) * | 2019-05-30 | 2019-08-06 | 浙江永金生物科技有限公司 | The preparation method of environment friendly biological texturing oil |
| CN114737280A (en) * | 2021-01-07 | 2022-07-12 | 洛阳常龙新材料科技有限公司 | Method for preparing spinning oil for nylon-66 cord threads |
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| US4469606A (en) * | 1982-07-26 | 1984-09-04 | Ciba-Geigy Corporation | Stabilization systems for fiber finishes |
| CN1084594A (en) * | 1992-09-23 | 1994-03-30 | 李文珠 | A kind of high-speed spin finishes and manufacture method |
| CN1428480A (en) * | 2001-12-27 | 2003-07-09 | 中国石化上海石油化工股份有限公司 | Spinning oil for polyester full-drafting fibre |
| CN1904200A (en) * | 2006-07-14 | 2007-01-31 | 中国石油化工集团公司 | Oil agent used for polyester industrial filament |
-
2013
- 2013-01-28 CN CN2013100302115A patent/CN103161068A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4469606A (en) * | 1982-07-26 | 1984-09-04 | Ciba-Geigy Corporation | Stabilization systems for fiber finishes |
| CN1084594A (en) * | 1992-09-23 | 1994-03-30 | 李文珠 | A kind of high-speed spin finishes and manufacture method |
| CN1428480A (en) * | 2001-12-27 | 2003-07-09 | 中国石化上海石油化工股份有限公司 | Spinning oil for polyester full-drafting fibre |
| CN1904200A (en) * | 2006-07-14 | 2007-01-31 | 中国石油化工集团公司 | Oil agent used for polyester industrial filament |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN103147168B (en) * | 2013-03-06 | 2017-06-16 | 常州市灵达化学品有限公司 | A kind of spinning oil and preparation method |
| KR102232594B1 (en) | 2014-02-04 | 2021-03-25 | 마쓰모토유시세이야쿠 가부시키가이샤 | Finish for synthetic fibers and application thereof |
| KR20150092017A (en) * | 2014-02-04 | 2015-08-12 | 마쓰모토유시세이야쿠 가부시키가이샤 | Finish for synthetic fibers and application thereof |
| CN104328662A (en) * | 2014-11-27 | 2015-02-04 | 何庆堃 | Soybean fiber high stretch yarn deformation oil agent |
| CN104328658A (en) * | 2014-11-27 | 2015-02-04 | 何庆堃 | Silk fiber high stretch yarn deformation oil agent |
| CN104358126A (en) * | 2014-11-27 | 2015-02-18 | 何庆堃 | High stretch yarn transformation oil agent of bamboo charcoal fibers |
| CN104532554A (en) * | 2014-12-31 | 2015-04-22 | 福建恒安集团有限公司 | Aloe spinning oil |
| CN106087406A (en) * | 2016-08-29 | 2016-11-09 | 上海多纶化工有限公司 | Novel polyester filament oil preparation |
| CN108035149A (en) * | 2017-12-18 | 2018-05-15 | 江苏新瑞贝科技股份有限公司 | A kind of environment-friendly type polyacrylic fibre oil and preparation method thereof |
| CN108517585A (en) * | 2018-02-09 | 2018-09-11 | 海盐县硕创服装研究所 | Spinning oil and preparation method thereof for cord fabric thread |
| CN108940118A (en) * | 2018-07-02 | 2018-12-07 | 传化智联股份有限公司 | A kind of electrolyte-resistant anionic surfactant and its preparation method and application |
| CN110093779A (en) * | 2019-05-30 | 2019-08-06 | 浙江永金生物科技有限公司 | The preparation method of environment friendly biological texturing oil |
| CN110093779B (en) * | 2019-05-30 | 2021-11-19 | 浙江永金生物科技有限公司 | Preparation method of environment-friendly biological texturing oil |
| CN114737280A (en) * | 2021-01-07 | 2022-07-12 | 洛阳常龙新材料科技有限公司 | Method for preparing spinning oil for nylon-66 cord threads |
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Application publication date: 20130619 |