CN101906714A - Environment-friendly polypropylene filament yarn oil agent and production method thereof - Google Patents
Environment-friendly polypropylene filament yarn oil agent and production method thereof Download PDFInfo
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- CN101906714A CN101906714A CN 201010244575 CN201010244575A CN101906714A CN 101906714 A CN101906714 A CN 101906714A CN 201010244575 CN201010244575 CN 201010244575 CN 201010244575 A CN201010244575 A CN 201010244575A CN 101906714 A CN101906714 A CN 101906714A
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- -1 polypropylene Polymers 0.000 title claims abstract description 108
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 58
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 58
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 239000003921 oil Substances 0.000 claims abstract description 52
- 229920000570 polyether Polymers 0.000 claims abstract description 24
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003755 preservative agent Substances 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 10
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 22
- 239000010452 phosphate Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 239000004593 Epoxy Substances 0.000 claims description 11
- CASPZMCSNJZQMV-UHFFFAOYSA-N ethane;2-methyloxirane Chemical compound CC.CC1CO1 CASPZMCSNJZQMV-UHFFFAOYSA-N 0.000 claims description 11
- 241000722946 Acanthocybium solandri Species 0.000 claims description 9
- HRPJYGWOLAXSDF-UHFFFAOYSA-N OCCN1C=NCC1.CC1=C(C(=O)O)C=CC=C1C(=O)O Chemical compound OCCN1C=NCC1.CC1=C(C(=O)O)C=CC=C1C(=O)O HRPJYGWOLAXSDF-UHFFFAOYSA-N 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- UPJLNBTXCVMRAI-UHFFFAOYSA-N methylazanium;octadecyl sulfate Chemical compound [NH3+]C.CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O UPJLNBTXCVMRAI-UHFFFAOYSA-N 0.000 claims description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 9
- 239000003760 tallow Substances 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 6
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical class C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003643 water by type Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 abstract description 13
- 229940070765 laurate Drugs 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 150000002191 fatty alcohols Chemical class 0.000 abstract 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 abstract 1
- 235000014121 butter Nutrition 0.000 abstract 1
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 abstract 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 abstract 1
- 229940049964 oleate Drugs 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 64
- 238000000034 method Methods 0.000 description 27
- 239000000047 product Substances 0.000 description 20
- 238000009987 spinning Methods 0.000 description 20
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
- 239000000126 substance Substances 0.000 description 12
- 239000004753 textile Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 238000005461 lubrication Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 8
- 239000001294 propane Substances 0.000 description 8
- 238000009736 wetting Methods 0.000 description 8
- 238000011161 development Methods 0.000 description 7
- 230000003068 static effect Effects 0.000 description 7
- 239000012209 synthetic fiber Substances 0.000 description 7
- 229920002994 synthetic fiber Polymers 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 6
- 230000000740 bleeding effect Effects 0.000 description 5
- 229940008099 dimethicone Drugs 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 241000235342 Saccharomycetes Species 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000009732 tufting Methods 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 238000009941 weaving Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 3
- 238000012805 post-processing Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 238000009965 tatting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- VJXYKHZISPADJF-KVVVOXFISA-N (z)-octadec-9-enoic acid;oxirane Chemical compound C1CO1.CCCCCCCC\C=C/CCCCCCCC(O)=O VJXYKHZISPADJF-KVVVOXFISA-N 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004746 geotextile Substances 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
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- 238000003911 water pollution Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a preparation method of an environment-friendly polypropylene filament yarn oil agent, comprising the following steps of: weighing 40 to 60 parts by weight of fatty alcohol ether phosphate potassium salt, 2 to 8 parts by weight of polysiloxane polyether copolymer, 3 to 12 parts by weight of pentaerythritol oleate, 4 to 10 parts by weight of fatty alcohol polyoxyethylene ether, 2 to 12 parts by weight of ethylene oxide-epoxypropane block polyether, 20 to 45 parts by weight of polyethylene glycol laurate, 10 to 20 parts by weight of butter alcohol amine phosphate salt and 5 to 10 parts by weight of high-carbon heterogeneous alcohol phosphate potassium salt, heating to 40 to 80 DEG C, reacting under the stirring condition, then adding 20 to 40 parts of emulsifying agent EL-40, 1 to 5 parts of methyl-1-hydroxyethyl-2-stearyl imidazoline ammonium methosulfate, 5 to 15 parts of dimethyl silicon oil, 2 to 40 parts of deionized water and 0.001 to 0.02 part of preservative, reacting under the stirring condition at 50 to 70 DEG C, and separating to obtain the environment-friendly polypropylene filament yarn oil agent.
Description
Technical field
The present invention relates to chemical industry finish technical field, relate in particular to a kind of environment-friendly polypropylene filament yarn oil agent and production method thereof.
Background technology
Polypropylene fiber has light weight, obdurability is good, chemical stability is good, conductivity of heat is slow, it is moist good to lead, the fabric washing shrinkage is little, intensity does not change during hygrometric state, fabric is merrily and lightheartedly warming, good springiness, low cost of manufacture, the source is abundant, cheap, characteristics such as recirculation processing is easy, though itself is non-hygroscopic, but owing to have the good wicking effect, can go out moisture transmission by the capillary in the fabric, it is refreshing that skin is remained in, be widely used in filtering material so remove, nonwoven fabric, outside the fabrics for industrial use such as geotextiles, fine-denier polypropylene more is applied to make the functional sportswear of international popular in recent years, fashion material keeps rapid growth in a very long time.Polypropylene fibre is development potentiality maximum in the four big synthetic fiber, the kind that prospect is very wide.90% carpet lining and 25% carpet face yarn are made by polypropylene fibre in the world at present, the polypropylene fibre functional textiles of Japan accounts for 39% of whole textiless, the U.S. successively develops the polypropylene of multiple functional polypropylene such as antibiotic, fire-retardant, antistatic, antifouling and metallocene catalysis system, every Western Europe country is also quite active to the polypropylene fibre research and development, successfully develops conduction, electric heating, bio-absorbable degraded polypropylene fibre.
According to the needs of processing, need use finish during the synthetic fiber weaving, on fiber surface, form one deck oil film, improve the flatness of fiber, reduce the coefficient of friction of tow, strengthen spinnability, improve the quality of finished product.The employed finish of synthetic fiber generally by the smooth, soft agent that reduces coefficient of friction between the fiber, eliminate the antistatic additive of cohesive force between static and fortifying fibre and the emulsifying agent that finish plays the stable emulsifying effect formed.Polypropylene filament yarn oil agent is converted into a kind of important intermediate medium in the process of textiles as pp material, be mainly used in the frictional behavior of regulating fiber, prevent or eliminate electrostatic accumulation, give characteristics such as fiber smooth, soft, make chemical fibre smoothly by spinning, stretch, add operations such as bullet spins, weaves, that guarantees to produce carries out smoothly, and finish plays crucial effects to stability, the product quality of producing, and is the heat subject of China's finish exploitation.In the production, it is very important correctly selecting finish and using finish, because the selection of finish can directly have influence on the quality of processing characteristics and product.Process experience high temperature because of polypropylene filament yarn rubs, and the process velocity height needs finish to possess heat-resistant stable, good antistatic behaviour and good wettability simultaneously.
Finish itself should have good heat endurance and chemical stability.The polypropylene fiber postprocessing working procedures requires finish to give fiber good convergence, increases its cohesive force, makes tow that sleave neatly and not take place, and avoids the generation of super double-length silk.Make fiber in curly course, obtain suitable crimpness and crispation number simultaneously.Require finish to give certain antistatic behaviour of tow and wettability in addition.Reduce the friction of fiber and equipment room and produce static,, it is conducted rapidly, prevent gathering of static even produced static, eliminate weaving process in because of static produce around phenomenons such as roller, broken ends.After spin finish and also need give fiber certain flatness, make the fiber softening of acquisition, smooth, good hand touch.
The spinning oil that uses generally is made up of following material at present: various high low viscosity mineral oil (white oil, machine oil), emulsifying agent (TX-4, TX-10, AEO-3, AEO-9, oleic acid oxirane), compositions such as antistatic additive (alkyl phosphoric acid sylvite), silicone oil, the anti-agent of splashing.In order to reach good emulsifying capacity and cleansing power, various alkylphenol polyoxyethylene APEO (TX series or NP series) in finish, have been added, and these series of products to the potential harm of environment by extensive studies and demonstration, some countries of Europe have formulated regulation limitations production and have used APEO from 1976.Now existing the clearly defining of limiting the quantity of of the APEO that outlet Europe textiles kimonos is loaded onto is no more than 30ppm.The common spinning oil that uses only can satisfy the production requirement of high-speed spinning conventional products at present, if use common high-speed spin finishes processing fine count fiber, then has serious technological difficulties and quality problems aborning.At first, polyurethane during false twisting (PU) friction disc wear is fast, lousiness, the broken end more, the product quality rate of classification of product is low, has problems such as spinnability difference, has a strong impact on thin dawn POY quality of fiber, and friction plate shortens service life greatly, have only about two weeks, so production cost is higher; Secondly, present common spinning oil does not mostly have the taking environmental conservation into consideration problem, and finish biological degradability or removeability are poor, and this has just seriously increased the environmental protection pressure of chemical fibre factory's process for producing waste water, has increased the production cost of enterprise; In addition, if containing the finish of the difficult degraded that exceeds standard, the waste water of chemical fibre factory's discharging will bring hidden danger to the protection of environment again.
The road of the Green Development Chinese development that to be the United Nations planned development administration in 2002 point out in conjunction with China's actual conditions, implementing green strategy is the inevitable choice of Economic Sustainable Development of China.Along with the domestic and international market is more and more higher, more and more tighter to the requirement of green textiles and environmental and ecological protection, simultaneously also more and more urgently, more and more stronger, the environment-friendly type textiles has become the main direction of current textile industry development.Research of International Textile ecosphere and check association explicitly call for, and textiles also must satisfy the environment-friendly quality requirement except will having required fastness ability of industry and application performance.
On the other hand, it is the global problem that the mankind face that serious day by day water pollutes, and it not only makes source of clean water shortage more, and can the healthy and vegeto-animal existence by the biological chain harm humans.The waste water that contains various preparation mediums, auxiliary agent is exactly a kind of serious pollutant, often causes water pollution owing to it is difficult at short notice degraded rapidly.Therefore according to superfine polypropylene fiber and processing characteristic thereof, problem at existing polypropylene filament yarn oil agent existence, physicochemical property and spinning technique in conjunction with polypropylene fibre, develop a kind of excellent performance, the thin dawn POY of degradable or removable environment-friendly type high-speed spinning finish with low cost, satisfy the requirement of polypropylene fibre high-speed spinning fiber finer dawn development, have important practical significance.
Summary of the invention
Technical problem to be solved by this invention is: at the deficiency that prior art exists, provide a kind of excellent performance, biodegradable, the environment-friendly polypropylene filament yarn oil agent and the production method thereof that can satisfy the requirement of polypropylene fine denier silk high-speed spinning.
For solving above-mentioned first technical problem, technical scheme of the present invention is:
A kind of environment-friendly polypropylene filament yarn oil agent is mixed and made into by the component of following weight portion:
40～60 parts of fatty alcohol ether phosphate kalium salts,
2～8 parts of polysiloxane polyether copolymers,
3～12 parts of PETO,
4～10 parts of fatty alcohol-polyoxyethylene ether,
2～12 parts of epoxy ethane-epoxy propane block polyethers,
1～5 part of methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium,
20～45 parts of polyethylene glycol fatty acid laurates,
10～20 parts of tallow alcohol amidophosphoric acid ester salt,
5～10 parts of high-carbon isomery alcohol phosphate kalium salts,
20～40 parts of Emulsifier EL-40s,
5～15 parts of dimethicones,
2～40 parts of deionized waters,
0.001～0.02 part of preservative agent.
The structural formula of described epoxy ethane-epoxy propane block polyether is [RO (PO)
m(EO)
n], wherein m is greater than n.
Wherein, described preservative agent is JKBIO-5115.
Preferably, ratio resistance 〉=5 * 10 of described deionized water
5Ohm.
Loss of strength is a difficult problem of often running in the superfine polypropylene texturing process; in the production except that adopting the low polyurethane friction plate of case hardness; improving the film strength of finish, protect fiber effectively when friction false twist, also is an effective means that reduces loss of strength.What film strength characterized is the finish ABRASION RESISTANCE, when fiber contacts false twisting with the friction plate of rotation at a high speed, oil film attached to fiber surface can not break under high temperature, high speed and certain pressure, otherwise after the rupture of oil film, just changed the friction behavior of fiber, frictional resistance increases, and not only influences spinnability, and white powder increases when also making false twisting.
The major function of spinning oil is to regulate frictional force, comprises the frictional force between fiber/intermetallic and fibre/fibre, regulates yarn cohesive force and antistatic behaviour.Frictional force between fibre/fibre must guarantee package shaping and tow weave with the tufting process in cohesive force, and the special-purpose spinning oil of polypropylene fibre also must have maximum wetting and dispersive property, so that covering surfaces immediately behind the finish contact fiber, the surface coverage of finish is good more, friction control on godet roller is just good more, the heating of can reducing friction, thus METHOD FOR POLYPROPYLENE BCF yarn tufting or tatting carpet streak fault reduced.Static load meeting makes the capillary division of tow, thereby produces problems such as fluffing, single wire fracture, package shaping instability, and the antistatic behaviour that therefore improves finish is very important.
Now increasing pp carpet is used in the automobile, therefore must consider the low mist formation of glass pane of finish volatile matter.Health and pharmaceutical polypropylene fiber also have wetting and the wicking requirement, and at first require the finish composition harmless.Postprocessing working procedures requirement heat endurance of finish own and chemical stability are good.Textile mills want the flush away finish usually before dyeing, and the volatility of finish itself, so finish must satisfy environmentally safe, avirulent requirement, require composition of raw materials to answer natural safety, biological degradability is fabulous, and is nontoxic to human body, and in the high speed spinning process, represent the good lubrication performance, product line density is even, steady quality, and heat resistance is good, no obvious smoke, the emulsion preparation is easy, and epigranular makes tow in high speed drawing-off winding process, forming, the lousiness little breakage obviously improves the filametntary high-class product rate of FDY under same process conditions, can make operation by the weaving of various backs smoothly.
In the oil formula of the present invention, described fatty alcohol ether phosphate kalium salt (MOA3PK) has antistatic behaviour, flatness, wettability, rust inhibition, as the raw material that improves spinning property in the synthetic fiber processing, has suction temperature, when low temperature, still have good antistatic behaviour, be widely used in and make antistatic additive in the preparation medium.Described fatty alcohol-polyoxyethylene ether (AEO-10) has good wetting, emulsification, decontamination, degreasing and stability in hard water energy, can be used as washing agent, wetting agent, textile finish oil composition and farm chemical emulgent etc.Described high-carbon isomery alcohol phosphate kalium salt is as surfactant, its Application Areas is also very extensive, its antistatic behaviour, emulsibility, dispersiveness, convergence and rust-preventing characteristic all are higher than the phosphate of original routine, become the indispensable branch of phosphate series of surfactants.Described Emulsifier EL-40 (castor oil and oxirane reaction product) is as the finish monomer, existing emulsification and can receive antistatic effect, and can share with other antistatic additive, effect is better.Described tallow alcohol amidophosphoric acid ester salt is compared with other phosphate ester salt, be more suitable for the antistatic additive as preparation medium, the finish that makes with it has good antistatic behaviour, and viscosity is little under super-humid conditions, have better climate adaptability, be fit to the high speed technological requirement that present chemical fibre is produced.Described polyethylene glycol fatty acid laurate (PEG400) has good boundling, antistatic, obvolvent, softness and effect such as level and smooth to synthetic fiber.Described bleeding agent oxirane (EO) expoxy propane (PO) block polyether structure is [RO (PO)
m(EO)
n], have excellent permeation performance and excellent lubrication, heat resistance, sticking temperature-sticking dense characteristic.Described PETO has better heat-resisting, and good viscosity-temperature characteristics, and good lubricating property have wide use prospect in preparation medium, aero-engine lubricating oil, metallic high temperature processing wet goods field.Described methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium can be dissolved in low-carbon (LC) alcohols and the warm water, has performances such as excellent lubrication, antistatic, soft, inhibition, antirust, emulsification, low, the easily biological-degradable of excitant.It is to reduce coefficient of friction that described dimethicone mainly acts on, and reduces the surface tension of finish, improves the antistatic behaviour of finish, improves the finish combination property.Described polysiloxane polyether copolymer has the wetting and lubrication that presses down bubble and froth breaking effect and excellence.Described preservative agent JKBIO-5115 can effectively suppress the breeding of bacterium, saccharomycete and fungi in the finish application system, and JKBIO-5115 and system have good intermiscibility, to saccharomycete control significantly.
For solving above-mentioned second technical problem, technical scheme of the present invention is:
A kind of production method of environment-friendly polypropylene filament yarn oil agent, may further comprise the steps: by weight, with 40～60 parts of fatty alcohol ether phosphate kalium salts, 2～8 parts of polysiloxane polyether copolymers, 3～12 parts of PETO, 4～10 parts of fatty alcohol-polyoxyethylene ether, 2～12 parts of epoxy ethane-epoxy propane block polyethers, 5～10 parts of high-carbon isomery alcohol phosphate kalium salts, 10～20 parts of 20～45 parts of polyethylene glycol fatty acid laurates and tallow alcohol amidophosphoric acid ester salt, mix and heat temperature raising to 40～80 ℃, stirring reaction 20～40 minutes, add 20～40 parts of Emulsifier EL-40s again, 1～5 part of methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium, 5～15 parts of dimethicones, 0.001～0.02 part of 2～40 parts of deionized waters and preservative agent, 50～70 ℃ of stirring reactions 10～30 minutes, separate obtaining the product environment-friendly polypropylene filament yarn oil agent.
The structural formula of described epoxy ethane-epoxy propane block polyether is [RO (PO)
m(EO)
n], wherein m is greater than n.
Described preservative agent is JKBIO-5115.
Ratio resistance 〉=5 * 10 of described deionized water
5Ohm.
Preferably, mix and heat temperature raising, in 30～50 minutes, be heated to 40～80 ℃.
Preferably, 50～70 ℃ of following stirring reactions 10～30 minutes, be cooled to below 30 ℃, isolated by filtration obtains the product environment-friendly polypropylene filament yarn oil agent.
Loss of strength is a difficult problem of often running in the superfine polypropylene texturing process; in the production except that adopting the low polyurethane friction plate of case hardness; improving the film strength of finish, protect fiber effectively when friction false twist, also is an effective means that reduces loss of strength.What film strength characterized is the finish ABRASION RESISTANCE, when fiber contacts false twisting with the friction plate of rotation at a high speed, oil film attached to fiber surface can not break under high temperature, high speed and certain pressure, otherwise after the rupture of oil film, just changed the friction behavior of fiber, frictional resistance increases, and not only influences spinnability, and white powder increases when also making false twisting.
The major function of spinning oil is to regulate frictional force, comprises the frictional force between fiber/intermetallic and fibre/fibre, regulates yarn cohesive force and antistatic behaviour.Frictional force between fibre/fibre must guarantee package shaping and tow weave with the tufting process in cohesive force, and the special-purpose spinning oil of polypropylene fibre also must have maximum wetting and dispersive property, so that covering surfaces immediately behind the finish contact fiber, the surface coverage of finish is good more, friction control on godet roller is just good more, the heating of can reducing friction, thus METHOD FOR POLYPROPYLENE BCF yarn tufting or tatting carpet streak fault reduced.Static load meeting makes the capillary division of tow, thereby produces problems such as fluffing, single wire fracture, package shaping instability, and the antistatic behaviour that therefore improves finish is very important.
Now increasing pp carpet is used in the automobile, therefore must consider the low mist formation of glass pane of finish volatile matter.Health and pharmaceutical polypropylene fiber also have wetting and the wicking requirement, and at first require the finish composition harmless.Postprocessing working procedures requirement heat endurance of finish own and chemical stability are good.Textile mills want the flush away finish usually before dyeing, and the volatility of finish itself, so finish must satisfy environmentally safe, avirulent requirement, require composition of raw materials to answer natural safety, biological degradability is fabulous, and is nontoxic to human body, and in the high speed spinning process, represent the good lubrication performance, product line density is even, steady quality, and heat resistance is good, no obvious smoke, the emulsion preparation is easy, and epigranular makes tow in high speed drawing-off winding process, forming, the lousiness little breakage obviously improves the filametntary high-class product rate of FDY under same process conditions, can make operation by the weaving of various backs smoothly.
In the oil formula of the present invention, described fatty alcohol ether phosphate kalium salt (MOA3PK) has antistatic behaviour, flatness, wettability, rust inhibition, as the raw material that improves spinning property in the synthetic fiber processing, has hygroscopicity, when low temperature, still have good antistatic behaviour, be widely used in and make antistatic additive in the preparation medium.Described fatty alcohol-polyoxyethylene ether (AEO-10) has good wetting, emulsification, decontamination, degreasing and stability in hard water energy, can be used as washing agent, wetting agent, textile finish oil composition and farm chemical emulgent etc.Described high-carbon isomery alcohol phosphate kalium salt is as surfactant, its Application Areas is also very extensive, its antistatic behaviour, emulsibility, dispersiveness, convergence and rust-preventing characteristic all are higher than the phosphate of original routine, become the indispensable branch of phosphate series of surfactants.Described Emulsifier EL-40 (castor oil and oxirane reaction product) is as the finish monomer, existing emulsification and can receive antistatic effect, and can share with other antistatic additive, effect is better.Described tallow alcohol amidophosphoric acid ester salt is compared with other phosphate ester salt, be more suitable for the antistatic additive as preparation medium, the finish that makes with it has good antistatic behaviour, and viscosity is little under super-humid conditions, have better climate adaptability, be fit to the high speed technological requirement that present chemical fibre is produced.Described polyethylene glycol fatty acid laurate (PEG400) has good boundling, antistatic, obvolvent, softness and effect such as level and smooth to synthetic fiber.Described bleeding agent oxirane (EO) expoxy propane (PO) block polyether structure is [RO (PO)
m(EO)
n], have excellent permeation performance and excellent lubrication, heat resistance, sticking temperature-sticking dense characteristic.Described PETO has better heat-resisting, and good viscosity-temperature characteristics, and good lubricating property have wide use prospect in preparation medium, aero-engine lubricating oil, metallic high temperature processing wet goods field.Described methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium can be dissolved in low-carbon (LC) alcohols and the warm water, has performances such as excellent lubrication, antistatic, soft, inhibition, antirust, emulsification, low, the easily biological-degradable of excitant.It is to reduce coefficient of friction that described dimethicone mainly acts on, and reduces the surface tension of finish, improves the antistatic behaviour of finish, improves the finish combination property.Described polysiloxane polyether copolymer has the wetting and lubrication that presses down bubble and froth breaking effect and excellence.Described preservative agent JKBIO-5115 can effectively suppress the breeding of bacterium, saccharomycete and fungi in the finish application system, and JKBIO-5115 and system have good intermiscibility, to saccharomycete control significantly.
Owing to adopted technique scheme, the invention has the beneficial effects as follows:
1, the present invention adopts rational oil formula, having solved high-speed spin finishes evenly oils, film strength, finish are to the problems such as influence of fibre structure and mechanical property, it is reasonable to make finish can satisfy the oil formula of high speed spinning and texturing craft requirement, the finish quality is uniform and stable: the film strength height, select the higher component of film strength of two keys or other polarity gene for use, and film strength reaches more than the 90kg, behind the twisting of superfine polypropylene POY drawn, the backtwisting, DTY intensity also slightly improves; The finish permeance property is good; Finish has good wettability to tow, makes the rapid absorption finish of tow energy of high-speed cruising, and sprawls rapidly on fiber surface, reaches the purpose that evenly oils; The coherent of polypropylene filament yarn is suitable behind the use finish, and coiling and molding is good, and the drafted fibre unwinding is good; Have the good temperature resistance energy, Heat stability is good, non-oxidizability is strong, does not have coking phenomenon during application, thereby needn't clean silk wheel, drawing roller etc. specially, avoids causing broken end, burr because of coking, the yellowing phenomenon can not occur during fiber process.
2, finish of the present invention volatile quantity under stable operating procedure condition is very little, can not cause the production cost height because of finish volatilizees, and is free from environmental pollution, to the healthy generation harm of operator.
3, use the present invention can improve the balance property adjusted of polypropylene fiber: (1) increases fiber softening, improves the feel of product; (2) the dustproof wrinkle resistant function of raising product is guaranteed fibre whiteness; (3) non-oxidizability of raising product; (4) improving the anti-of fiber opens and tensile strength.
4, formulation monomer of the present invention is the biological degradability material entirely, no mineral oil composition, imbibition to fiber is little, thereby moving of pigment dyed few, in spinning and behind the fiber, environment is not caused any harm in the process, having alleviated the environmental protection pressure of polypropylene fibre production process and fabrication processes, is a kind of environment-friendly type finish.
5, finish of the present invention does not have corrosion to metal, because the film strength height has good lubrication to hardware.
6, finish of the present invention can be given the fiber good processing properties, not only can be fast, evenly oil, and the polyurethane friction plate there is not swelling, can satisfy the technological requirement of back processing such as superfine polypropylene high speed spinning and draw false twisting, use back POY, DTY product quality that raising is in various degree all arranged.
The specific embodiment
Further set forth the present invention below in conjunction with specific embodiment.
Embodiment 1
With fatty alcohol ether phosphate kalium salt (MOA3PK) 44Kg, polysiloxane polyether copolymer 2.5Kg, PETO 6Kg, fatty alcohol-polyoxyethylene ether (AEO-10) 5Kg, bleeding agent epoxy ethane-epoxy propane block polyether 4.3Kg, polyethylene glycol fatty acid laurate (PEG400) 31Kg, tallow alcohol amidophosphoric acid ester salt 14.5Kg and high-carbon isomery alcohol phosphate kalium salt 5.3Kg, adding reactor mixes and heat temperature raising, in 30 minutes, be warming up to 45 ℃, stirring reaction 25 minutes, add Emulsifier EL-40 35Kg again, methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium 2.3Kg, dimethicone 5Kg, deionized water 25Kg and preservative agent JKBIO-5115 0.004Kg, the ratio resistance of described deionized water is 5 * 10
5Ohm 50 ℃ of stirring reactions 15 minutes, is cooled to below 30 ℃, and isolated by filtration obtains the product environment-friendly polypropylene filament yarn oil agent.
The quality index of the environment-friendly polypropylene filament yarn oil agent of above method preparation is:
Embodiment 2
With fatty alcohol ether phosphate kalium salt (MOA3PK) 51Kg, polysiloxane polyether copolymer 4Kg, PETO 6.2Kg, fatty alcohol-polyoxyethylene ether (AEO-10) 6.4Kg, bleeding agent epoxy ethane-epoxy propane block polyether 6.2Kg, polyethylene glycol fatty acid laurate (PEG400) 36Kg, tallow alcohol amidophosphoric acid ester salt 16.3Kg and high-carbon isomery alcohol phosphate kalium salt 6.6Kg, adding reactor mixes and heat temperature raising, in 35 minutes, be warming up to 50 ℃, stirring reaction 30 minutes, add Emulsifier EL-40 38Kg again, methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium 3.6Kg, dimethicone 6Kg, deionized water 30Kg and preservative agent JKBIO-5115 0.006Kg, the ratio resistance of described deionized water is 5 * 10
5Ohm 55 ℃ of stirring reactions 20 minutes, is cooled to below 30 ℃, and isolated by filtration obtains the product environment-friendly polypropylene filament yarn oil agent.
The quality index of the environment-friendly polypropylene filament yarn oil agent of above method preparation is:
Embodiment 3
With fatty alcohol ether phosphate kalium salt (MOA3PK) 56Kg, polysiloxane polyether copolymer 5.5Kg, PETO 7.2Kg, fatty alcohol-polyoxyethylene ether (AEO-10) 8.2Kg, bleeding agent epoxy ethane-epoxy propane block polyether 6.4Kg, polyethylene glycol fatty acid laurate (PEG400) 41Kg, tallow alcohol amidophosphoric acid ester salt 19Kg and high-carbon isomery alcohol phosphate kalium salt 7.9Kg, adding reactor mixes and heat temperature raising, in 50 minutes, be warming up to 60 ℃, stirring reaction 40 minutes, add Emulsifier EL-40 40Kg again, methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium 4.2Kg, dimethicone 7Kg, deionized water 35Kg and preservative agent JKBIO-5115 0.012Kg, the ratio resistance of described deionized water is 5 * 10
5Ohm 60 ℃ of stirring reactions 20 minutes, is cooled to below 30 ℃, and isolated by filtration obtains the product environment-friendly polypropylene filament yarn oil agent.
The quality index of the environment-friendly polypropylene filament yarn oil agent of above method preparation is:
Claims (10)
1. environment-friendly polypropylene filament yarn oil agent is characterized in that being mixed and made into by the component of following weight portion:
40～60 parts of fatty alcohol ether phosphate kalium salts,
2～8 parts of polysiloxane polyether copolymers,
3～12 parts of PETO,
4～10 parts of fatty alcohol-polyoxyethylene ether,
2～12 parts of epoxy ethane-epoxy propane block polyethers,
1～5 part of methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium,
20～45 parts of polyethylene glycol fatty acid laurates,
10～20 parts of tallow alcohol amidophosphoric acid ester salt,
5～10 parts of high-carbon isomery alcohol phosphate kalium salts,
20～40 parts of Emulsifier EL-40s,
5～15 parts of dimethicones,
2～40 parts of deionized waters,
0.001～0.02 part of preservative agent.
2. environment-friendly polypropylene filament yarn oil agent as claimed in claim 1 is characterized in that: the structural formula of described epoxy ethane-epoxy propane block polyether is [RO (PO)
m(EO)
n], wherein m is greater than n.
3. environment-friendly polypropylene filament yarn oil agent as claimed in claim 1 is characterized in that: described preservative agent is JKBIO-5115.
4. environment-friendly polypropylene filament yarn oil agent as claimed in claim 1 is characterized in that: ratio resistance 〉=5 * 10 of described deionized water
5Ohm.
5. the production method of an environment-friendly polypropylene filament yarn oil agent, it is characterized in that may further comprise the steps: by weight, with 40～60 parts of fatty alcohol ether phosphate kalium salts, 2～8 parts of polysiloxane polyether copolymers, 3～12 parts of PETO, 4～10 parts of fatty alcohol-polyoxyethylene ether, 2～12 parts of epoxy ethane-epoxy propane block polyethers, 5～10 parts of high-carbon isomery alcohol phosphate kalium salts, 10～20 parts of 20～45 parts of polyethylene glycol fatty acid laurates and tallow alcohol amidophosphoric acid ester salt, mix and heat temperature raising to 40～80 ℃, stirring reaction 20～40 minutes, add 20～40 parts of Emulsifier EL-40s again, 1～5 part of methyl isophthalic acid-hydroxyethyl-2-imidazoline-based stearyl sulfate methyl ammonium, 5～15 parts of dimethicones, 0.001～0.02 part of 2～40 parts of deionized waters and preservative agent, 50～70 ℃ of stirring reactions 10～30 minutes, separate obtaining the product environment-friendly polypropylene filament yarn oil agent.
6. the production method of a kind of environment-friendly polypropylene filament yarn oil agent as claimed in claim 5, it is characterized in that: the structural formula of described epoxy ethane-epoxy propane block polyether is [RO (PO)
m(EO)
n], wherein m is greater than n.
7. environment-friendly polypropylene filament yarn oil agent as claimed in claim 5 is characterized in that: described preservative agent is JKBIO-5115.
8. environment-friendly polypropylene filament yarn oil agent as claimed in claim 5 is characterized in that: ratio resistance 〉=5 * 10 of described deionized water
5Ohm.
9. the production method of a kind of environment-friendly polypropylene filament yarn oil agent as claimed in claim 5 is characterized in that: mix and heat temperature raising, be heated to 40～80 ℃ in 30～50 minutes.
10. the production method of a kind of environment-friendly polypropylene filament yarn oil agent as claimed in claim 5 is characterized in that: 50～70 ℃ of following stirring reactions 10～30 minutes, be cooled to below 30 ℃, isolated by filtration obtains the product environment-friendly polypropylene filament yarn oil agent.
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Inventor after: Guo Xiangrong Inventor after: Xiong Jiguang Inventor after: Zhu Haohui Inventor after: Wen Zhanping Inventor after: Guo Xueyang Inventor after: Zhuang Qing Inventor after: Guo Ziwen Inventor after: Wang Cui Inventor after: Guo Yankai Inventor after: Zhang Yunling Inventor after: Wang Xiaoli Inventor after: Sun Jiangyan Inventor before: Guo Xueyang Inventor before: Ding Aimei Inventor before: Wen Zhanping Inventor before: Zhang Jinglong |
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Free format text: CORRECT: INVENTOR; FROM: GUO XUEYANG DING AIMEI WEN ZHANPING ZHANG JINGLONG TO: GUO XIANGRONG GUO XUEYANG ZHUANG QING GUO ZIWEN WANG CUI GUO YANKAI ZHANG YUNLING WANG XIAOLI SUN JIANGYAN XIONG JIGUANG ZHU HAOHUI WEN ZHANPING |
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Granted publication date: 20120718 Termination date: 20160801 |
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| CF01 | Termination of patent right due to non-payment of annual fee |