CN104631103A - Oil agent composition for spinning chinlon - Google Patents
Oil agent composition for spinning chinlon Download PDFInfo
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Abstract
The invention relates to an oil agent composition for spinning chinlon. The oil agent composition for spinning the chinlon comprises the following components: a smoothing agent, an antistatic agent, an emulsifying agent, a cohesion agent, a stabilizing agent, a pH adjusting agent, a viscosity improving agent, an anti-ultraviolet agent, a fire retardant, an antibacterial agent and a nano additive. By virtue of the oil agent composition for spinning the chinlon, the problem that the function of a chinlon oil agent is relatively single is solved; the oil agent has good heat resistance, smoothness and antistatic property; the cohesion force of wire bundles can be enhanced and the friction coefficients are reduced; more importantly, functional auxiliary agents including the anti-ultraviolet agent, the antibacterial agent, the fire retardant and the like are added so that the antibacterial property of the oil agent can be increased; processed chinlon yarns have the anti-ultraviolet and fire retarding properties.
Description
Technical field
The present invention relates to synthetic fiber processing aid technical field, particularly relate to a kind of extrusion spinning oil agent composition.
Background technology
Polyamide fibre is the trade name of China's capron(e), and external trade name is nylon, 1938, and Germany executes clarke, and to have studied successfully with single caprolactam be raw material, the polycaprolactam that heated polymerizable is made, and applied for patent.As far back as nineteen fifty-five, du pont company has just applied for the patent spinning polyamide fibre by the speed of 5500 ms/min, nylon fibre function admirable, except having total corrosion-resistant of each synthetic fiber, resistance to mildew and rot, wet strength is high, is not afraid of and damages by worms, outside hydroscopicity is low, its main feature or fracture strength is high, except aramid fiber, is almost powerful the highest a kind of fiber; Excellent in abrasion resistance is a kind of fiber that in textile fabric, ABRASION RESISTANCE is best; From 12nd century middle nineteen thirties, the external research and development just starting preparation medium, the exploitation due to external finish is all completed by large enterprises, and its achievement in research commercial value is fine in addition, so disclosed oil formula is little, the exploitation of finish is the most active with Japan with production, and the company of exploitation finish has pine originally, Supreme Being people, Asahi Chemical Industry, flower king, and the Henkel of Germany, the large Xiang Meihuadeng company of the U.S..
Nineteen fifties, for adapting to the common spinning technique of chinlon filament, developing and being the theme with mineral oil, add the finish of emulsifying agent and antistatic agent.Middle nineteen sixties starts, and experimental branch line develops into and is deformed into main production technology with large package with spindle type, produce with aliphatic acid and PO/EO polyethers and finish.The eighties is to the nineties, and chemical-fibres filaments develops into high speed, ultrahigh speed and multifunction.Develop the PO/EO polyethers of modification and there is low friction, super heat-resisting, the easily finish of the specific function such as wetting and additive.After 21st century, experimental branch line is to maximization, and high speed, differential, functionalization develops, and single line ability expands, and polymer quality improves, and it is also proposed new requirement to finish.
Through the retrieval to prior art, Chinese invention patent 201010284459.0 (publication date on January 19th, 2011) discloses a kind of polyamide fibre FDY finish and preparation method, and wherein finish consists of the following composition: Ethylhexyl stearate, scouring agent, oleic acid, coconut oil diethanol amine, rilanit special polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, oleic acid methyl amimoacetic acid, hypophosphorous acid, potassium hydroxide, wetting agent.This finish Heat stability is good, volatilization less, noncoking.But owing to adding a lot of vegetable oil and mineral oil, in use, these greases are easy to go bad, produce bacterium, can finish corruption be caused, affect the serviceability of finish.
Chinese invention patent 201210237550.6 (publication date: on November 14th, 2012) discloses the pure finish of a kind of non-emulsion-type chinlon 6 filament high speed spinning, wherein smooth agent is made up of three kinds of polyether nonionic surfactants, is fatty alcohol ethylene oxide propylene oxide copolyether, fatty alcohol-polyoxyethylene ether, polyoxyethylated alkyl phenol respectively.Collecting agent is non-ionic surface active agent aliphatic acid polyethenoxy ether ester, and antistatic agent is fatty alcohol-polyoxyethylene ether phosphate, alkyl phosphate amine (potassium) salt, and cementitious additives is Ac, and adjusting agent is water.This finish be fuming little, not gel, do not assemble, do not precipitate, heat endurance and chemical property good, but this finish only has flatness and the static electricity resistance of common finish, do not give chemical fibre some functional characters, Component comparison is single.
Chinese invention patent 201010278753.0 (publication date: on 04 04th, 2012) discloses a kind of nylon oiling agent, and this finish is made up of mineral oil, potassium cetyl phosphate, 1-isobutyl-3,5-dimethylhexylphosphoric acid diethanolammonium salts, castor oil polyoxyethylene (40) ester, sorbitan monostearate.The present invention fills a prescription rationally, and result of use is good, and production cost is low.But this oil formula is relatively simple, only has the conventional func of smooth agent and antistatic additive and emulsification in formula, and mineral oil add the increase that membership causes volatile substance, very large impact is caused on environment.
In prior art, usual extrusion spinning oil agent composition adopts following method preparation and obtains: under stirring condition (1000 revs/min), get Ethylhexyl stearate 70 parts, scouring agent 6 parts, oleic acid 15 parts, coconut oil diethanol amine 3 parts, hypophosphorous acid 2 parts, oleic acid methyl amimoacetic acid 2 parts, 1 part, potassium hydroxide, wetting agent 1 part mix, stir 30 minutes, to obtain final product.
For verifying the oil effect of composition of the present invention to polyamide fibre, embodiment 1-5 and comparative example 1 are tested as follows.Implementation result is as shown in table 1.
Table 1 comparative example and embodiment test result
As shown in table 1, applicant finds that polyamide fibre high speed spinning finish effect prepared by each embodiment is all better than comparative example, specifically:
Emulsion ordinary temperature stability, as shown in Table 1, finish prepared by comparative example 1 at 25 degrees c, will present milk shape after 7 days, have wall cling phenomenon to occur, less stable, affects it and uses and preserve; And finish prepared by embodiment 1-5 all presents translucent, occur without any wall cling phenomenon, there is extraordinary stability; Especially embodiment 5, applicant finds, then places the longer time, and also there will not be wall cling phenomenon, other embodiments then there will be a little wall cling phenomenon, therefore finish prepared by embodiment 5 has best implementation result;
As can be seen from Table 1, comparative example 1 has the generation of a small amount of breakdown of emulsion in high-temperature stability test, prove that this system emulsifying effectiveness is unsatisfactory, and from embodiment 1-5, after adding nanometer additive and functional aid, the high temperature stability performance of spinning oil is better, and 80 DEG C, 8h demulsifying phenomenon does not occur.
Finish smoke point is one of important index, as can be seen from Table 1, the smoke point of comparative example 1 is 135 DEG C, and the smoke point of embodiment 1-5 is all greater than 140 DEG C, even the smoke point of embodiment 5 can reach 157 DEG C, and solution resistance to elevated temperatures significantly improves, this may be because the adding of nano assistant and fire retardant, nano-micelle can be formed in finish, smooth agent and emulsifier package are overlayed in micelle volume, thus improve the temperature of being fuming of finish.
Generally multi mineral oil can be added in synthetic fiber spinning finish, with surfactant, this can to being supplied to bacterium good growing environment, as can be seen from Table 1, after adding antiseptic, by the test result of Bacteria Culture, substantially increase finish to colibacillary antibiotic property, wherein the antibiotic rate of optimum process embodiment 5 reaches 97%.This, concerning comparatively useful the preservation of finish and use, can prevent the putrid and deteriorated of finish, affect the performance that oils of fiber.
As can be seen from the above data, after adding nano assistant and function additive, two kinds of additives can well act synergistically, and on the volume basis increasing antistatic behaviour and flatness, give finish better antibiotic property, anti-flammability and UV resistance performance.And finish is functional.
For checking the present invention is to the implementation result of fiber after oiling, carry out the test of following index:
Flame-proof treatment: 45 DEG C of gradient methods, instrument regulation sample is with 45 DEG C of slant settings, and measure the severe degree that chinlon filament lights after-combustion, severe degree is the smaller the better, and speed is more slow better.
Anti-uv: ultra-violet radiation protection index (UPF) is that ultra-violet radiation makes skin reach to occur the threshold dose required time value of erythema and without the ratio of time value reaching same extent of injury during shielding, be worth larger, protection effect is better.Chinlon filament is neatly wrapped on cardboard, the ultraviolet protection function of test arrangement plane.
Flatness: coefficient of kinetic friction μ K is the important indicator of finish flatness, and μ K is less, and flatness is less.
Antistatic behaviour: volume resistivity ρ V is the index of finish antistatic behaviour, and ρ V is less, and antistatic behaviour is better.
Convergence: wet cohesive force represents the coherent of slurry oil silk on hygrometric state, its value is larger, and in representative, slurry oil convergence is better, and it is better to fall to starching performance.Table 2 shows to add affects result on fiber after oiling after each function additive.
Fibre property test result after table 2 oils
From table 2, applicant finds, add nanometer additive and antiseptic, fire retardant, after ultraviolet functionalization auxiliary agent, corresponding index increases all to some extent, the anti-flammability of fiber after wherein oiling, improve obviously, the combustion testing of embodiment 1-5 shows, the combustibility of POLYAMIDE YARNS obviously can be reduced after adding fire retardant, wherein embodiment 5 adds tetrahydroxy phosphorus chloride fire retardant, which gives the highest flame retardant effect, and its fire resistance improves 30%, in ultraviolet-resistent property, embodiment 5 improves 15 points than comparative example 2.
The flatness of fiber of oiling is important index, from table 2, applicant finds, after adding nano assistant and three kinds of functionalization auxiliary agents, can't have an impact to the flatness of fabric, this is because preparing in finish process, various function additive has been carried out sufficient stirring and dispersion by applicant, makes it be evenly distributed in finish.
Applicant also finds further, the resistant fiber static behaviour of embodiment 1-5 can promote to some extent, this is because nano assistant and antistatic additive can have collaborative antistatic effect, because the membership that adds of nano assistant forms a kind of nano thin-film at fiber surface, the repulsive force of polyamide fibre and antistatic additive can be reduced, make cationic surfactant more easily be attached to polyamide fibre surface, increase the antistatic behaviour of polyamide fibre.
In order to improve the functional of finish further, the formula of applicant to nanometer additive is optimized design, applicant surprisingly finds, composite antistatic behaviour and the antibiotic property that can increase finish between nano assistant, the best nanometer additive of effect is titanium dioxide and zinc oxide, and best compound proportion is titanium dioxide: antistatic behaviour and the antibiotic property that effectively can promote finish when zinc oxide weight ratio is 2:1.The results are shown in Table 3, as can be seen from Table 3, when other conditions are all consistent, when the adding proportion of nanometer additive is 2:1, antibiotic property and the static electricity resistance of the fiber that oils are all the highest.This is because nano titanium oxide and zinc oxide belong to photocatalyst, but both have activity to the light of different wave length, thus the two is carried out composite after, can the response range of maximized increase visible ray, carry out bactericidal action within a large range.Its sterilization mechanism is, under having visible ray to exist, it can discharge the free radical with Strong oxdiative character, the bacterial classification in solution is carried out oxidation and kills, thus further can improve the antibiotic property of finish.
And nano assistant and antistatic additive can have collaborative antistatic effect, because the membership that adds of nano assistant forms a kind of nano thin-film at fiber surface, the repulsive force of polyamide fibre and antistatic additive can be reduced, make cationic surfactant more easily be attached to polyamide fibre surface, increase the antistatic behaviour of polyamide fibre.
The antibiotic property of the composite nanometer additive of table 3 on the fiber that oils and the impact of antistatic property
Further, the usage ratio of applicant to three kinds of functionalization finishing agents is inquired into, wish the maximize efficiency of functionalization auxiliary agent, a kind of auxiliary agent is used to replace three kinds of auxiliary agents, preparation one efficiently feels antibacterial, UV resistance, flame-retardant multifunctional finishing agent, after a large amount of experiments, applicant finds, three kinds of functional finishing adjuvants can be composite to using together, can't affect respective functional, and after adding UV resistance auxiliary agent and antiseptic, also can improve the anti-flammability of finish, there is the effect of compound synergic, this may be because, antiseptic contains halogen, the phosphorus flame retardant added in membership and fire retardant of halogen acts synergistically, the fire resistance of accelerating auxiliaries.
The best of three kinds of functionalization auxiliary agents makes used additives be the preferred bronopol of antiseptic, the preferred benzotriazole of UV resistance auxiliary agent, the preferred Tetrakis hydroxymethyl phosphonium chloride of fire retardant, the coefficient optimum proportion of three is 4:2:1, to add after multifunctional assistant when other components are constant, the antibiotic property of finish excellence can be given, UV resistance performance and anti-flammability.
Summary of the invention
Provide hereinafter about brief overview of the present invention, to provide about the basic comprehension in some of the present invention.Should be appreciated that this general introduction is not summarize about exhaustive of the present invention.It is not that intention determines key of the present invention or pith, and nor is it intended to limit the scope of the present invention.Its object is only provide some concept in simplified form, in this, as the preorder in greater detail discussed after a while.
The object of this invention is to provide a kind of extrusion spinning oil agent composition, in order to solve the comparatively single problem of nylon oiling agent function.
The object of this invention is to provide a kind of extrusion spinning oil agent composition, described finish comprises each component of following parts by weight:
Smooth agent 50-70,
Antistatic agent 3-7,
Emulsifying agent 5-15,
Obvolvent agent 2-5,
Stabilizing agent 1-4,
PH adjusting agent 1-4,
Viscosity-improving agents 3-6,
UV resistance agent 2-4,
Fire retardant 1-4,
Anti-microbial inoculum 5-15,
Nanometer additive 2-5.
Compared with prior art, the present invention has following beneficial effect: the invention solves the problem that nylon oiling agent function is comparatively single, finish of the present invention has good heat resistance, flatness and static electricity resistance, can increase the cohesive force of tow, reduces coefficient of friction, the most important thing is by adding UV resistance agent, anti-microbial inoculum, fire retardant can increase the functional of nylon fibre, makes it more easily preserve and application.
Detailed description of the invention
Embodiments of the invention are described below.The element described in one embodiment of the invention and feature can combine with the element shown in one or more other embodiment and feature.It should be noted that for purposes of clarity, in explanation, eliminate expression and the description of unrelated to the invention, parts known to persons of ordinary skill in the art and process.
Embodiment 1
The present embodiment relates to a kind of extrusion spinning oil agent composition and preparation method thereof, and extrusion spinning oil agent composition comprises each component of following parts by weight:
10# mineral oil 25,
12# mineral oil 25,
Octadecyl alcolol phosphate kalium salt 3,
Castor oil polyoxyethylene ether 5,
Laurate dibasic acid esters 2,
Pentaerythrite 1,
Triethanolamine 1,
Polyisobutene 3,
Bronopol 5,
2,4-DihydroxyBenzophenone 3,
Phosphite ester 2,
Zinc oxide 2.
The preparation method of extrusion spinning oil agent composition is:
Step one, under stirring condition, gets 25 parts, 10# mineral oil, 25 parts, 12# mineral oil, octadecyl alcolol phosphate kalium salt 3 parts, castor oil polyoxyethylene ether 5 parts, laurate dibasic acid esters 2 parts, pentaerythrite 1 part, polyisobutene 3 parts adds reactor, is warming up to 20-80 DEG C, fully mixes, insulation 10-50min, obtains mixture;
Step 2, is cooled to room temperature by mixture, is slowly added in mixture by triethanolamine 1 part, stirring at room temperature 10-40min;
Step 3, adds in the mixture of step 2 gained by 2 parts, zinc oxide, accelerates to stir, and is warming up to 20-60 DEG C, make zinc oxide dispersed, add bronopol 5 parts afterwards successively, 4-dihydroxy benaophenonel 3 parts, phosphite ester 2 parts, stirs 20-40min, obtains described finish.
Embodiment 2
The present embodiment relates to a kind of extrusion spinning oil agent composition, and described extrusion spinning oil agent composition comprises each component of following parts by weight, and preparation method is with reference to embodiment 1.
Fatty glyceride 70,
Cationic surfactant 7,
Octadecyl alcolol phosphate kalium salt 3,
Laurate polyoxyethylene ether 15,
Propylene glycol 5,
Sorbierite 4,
Potassium hydroxide 4,
Polyvinyl n-butyl ether 6,
Dibromo nitroethyl alcohol 15,
Benzotriazole 7,
Phosphate 5,
Magnesia 4.
Embodiment 3
The present embodiment relates to a kind of extrusion spinning oil agent composition, and described extrusion spinning oil agent composition comprises each component of following parts by weight, and preparation method is with reference to embodiment 1.
Mineral oil 55,
Octadecyl alcolol phosphate kalium salt 4,
Castor oil polyoxyethylene ether 7,
Polyethylene Glycol Oleate 2,
Laurate dibasic acid esters 2.5,
Pentaerythrite 2,
Triethanolamine 2,
Polyvinyl n-butyl ether 4,
Bronopol 8,
HMPA 4,
Phosphite ester 2.5,
Titanium dioxide 2.5.
Embodiment 4
The present embodiment relates to a kind of extrusion spinning oil agent composition, and described extrusion spinning oil agent composition comprises each component of following parts by weight, and preparation method is with reference to embodiment 1.
Polyethers 65,
Octadecyl alcolol phosphate kalium salt 6,
Castor oil polyoxyethylene ether 12,
Laurate dibasic acid esters 4,
Polyethylene glycol laurate dibasic acid esters 3 parts,
Pentaerythrite 3,
Potassium hydroxide 3,
Polyvinyl n-butyl ether 5,
Dibromo cyano group propionamide 12,
Benzotriazole 4,
Phosphate 3.5,
Calcium oxide 3.5.
Embodiment 5
The present embodiment relates to a kind of extrusion spinning oil agent composition, and described extrusion spinning oil agent composition comprises each component of following parts by weight, and preparation method is with reference to embodiment 1.
Fatty alcohol phosphate 55,
Octadecyl alcolol phosphate kalium salt 4,
Castor oil polyoxyethylene ether 7,
Polyethylene glycol laurate dibasic acid esters 2.5,
Pentaerythrite 2,
Sorbierite 2,
Triethanolamine 2,
Polyvinyl n-butyl ether 4,
Bronopol 8,
Benzotriazole 4.5,
Tetrakis hydroxymethyl phosphonium chloride 3,
Titanium dioxide 2.5.
Comparative example 1
Embodiment 6
The present embodiment relates to a kind of extrusion spinning oil agent composition, and the preparation method of described finish is with reference to embodiment 1.Described extrusion spinning oil agent composition comprises each component of following parts by weight:
Fatty alcohol phosphate 55,
Octadecyl alcolol phosphate kalium salt 4,
Castor oil polyoxyethylene ether 7,
Polyethylene glycol laurate dibasic acid esters 2.5,
Pentaerythrite 2,
Triethanolamine 2,
Polyvinyl n-butyl ether 4,
Bronopol 8,
Benzotriazole 4,
Tetrakis hydroxymethyl phosphonium chloride 2,
Titanium dioxide 2.5.
Comparative example 2
This comparative example relates to a kind of extrusion spinning oil agent composition, and the preparation method of described finish is with reference to embodiment 1.Described extrusion spinning oil agent composition comprises each component of following parts by weight:
Fatty alcohol phosphate 55,
Octadecyl alcolol phosphate kalium salt 4,
Castor oil polyoxyethylene ether 7,
Polyethylene glycol laurate dibasic acid esters 2.5,
Pentaerythrite 2,
Triethanolamine 2,
Polyvinyl n-butyl ether 4,
Titanium dioxide 2.5.
Table 4 multifunction finishing agent compound proportion is on the impact of fibre property
As known from Table 4, when three kinds of functionalization auxiliary agents are at optimal proportion, its antibiotic property is 98.6%, and by contrasting with embodiment 1-5, finds that its uvioresistant performance and anti-flammability also have a certain upgrade.
In sum, the invention solves the problem that nylon oiling agent function is comparatively single, finish of the present invention has good heat resistance, flatness and static electricity resistance, can increase the cohesive force of tow, reduces coefficient of friction, the most important thing is by adding UV resistance agent, anti-microbial inoculum, fire retardant can increase the functional of nylon fibre, makes it more easily preserve and application.
Last it is noted that above embodiment is only in order to illustrate technical scheme of the present invention, be not intended to limit; Although with reference to previous embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (12)
1. an extrusion spinning oil agent composition, is characterized in that, described oil agent composition comprises each component of following parts by weight:
Smooth agent 50-70,
Antistatic agent 3-7,
Emulsifying agent 5-15,
Obvolvent agent 2-5,
Stabilizing agent 1-4,
PH adjusting agent 1-4,
Viscosity-improving agents 3-6,
UV resistance agent 2-4,
Fire retardant 1-4,
Anti-microbial inoculum 5-15,
Nanometer additive 2-5.
2. extrusion spinning oil agent composition according to claim 1, is characterized in that, described smooth agent is 10#-30# mineral oil, the fatty acid ester of C12-C18, C6-C12 fatty acid diester, C12-C18 fatty glyceride, polyethers, the mixing of one or more in phosphate.
3. extrusion spinning oil agent composition according to claim 1, is characterized in that, described antistatic agent is cationic surfactant or octadecyl alcolol phosphate kalium salt.
4. extrusion spinning oil agent composition according to claim 1, it is characterized in that, described emulsifying agent is alkylphenol polyoxyethylene, Polyethylene Glycol Oleate, laurate polyoxyethylene ether, and castor oil polyoxyethylene ether, molecular weight are one or more in the oxirane of 1500-3000 and the random copolymerization ether of expoxy propane.
5. extrusion spinning oil agent composition according to claim 1, is characterized in that, described obvolvent agent is polyethylene glycol laurate dibasic acid esters, propylene glycol, rubber cracking oil, one or more in castor-oil plant alcohol ethylene oxide adduct.
6. extrusion spinning oil agent composition according to claim 1, is characterized in that, described stabilizing agent is xylitol, sorbierite, one or more in pentaerythrite.
7. extrusion spinning oil agent composition according to claim 1, is characterized in that, described pH adjusting agent is one or more in triethanolamine, potassium hydroxide, citric acid, sorbic acid, sodium bicarbonate, sodium hydrogen phosphate.
8. extrusion spinning oil agent composition according to claim 1, is characterized in that, described viscosity-improving agents is polyvinyl n-butyl ether, polymethacrylates, one or more in polyisobutene.
9. extrusion spinning oil agent composition according to claim 1, is characterized in that, described UV resistance agent is benzotriazole, 2,4-DihydroxyBenzophenone, one or more in HMPA.
10. extrusion spinning oil agent composition according to claim 1, is characterized in that, described fire retardant is Tetrakis hydroxymethyl phosphonium chloride, phosphite ester, one or more in phosphate.
11. extrusion spinning oil agent compositions according to claim 1, is characterized in that, described anti-microbial inoculum is dibromo nitroethyl alcohol, bronopol or dibromo cyano group propionamide, benzyldimethyldodecylammonium ammonium chloride, one or more in potassium sorbate.
12. extrusion spinning oil agent compositions according to claim 1, is characterized in that, described nanometer additive is zinc oxide, titanium dioxide, magnesia, cupric oxide, calcium oxide, diatomite, kaolin, one or more in imvite.
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| CN104562303A (en) * | 2015-01-20 | 2015-04-29 | 南通恒润化工有限公司 | Industrial spinning oil agent for FDY chinlon 66 and preparation method thereof |
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