CN113969500B - High-permeability emulsified oil processing technology suitable for fine carding of plant fibers - Google Patents

High-permeability emulsified oil processing technology suitable for fine carding of plant fibers Download PDF

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Publication number
CN113969500B
CN113969500B CN202111542373.8A CN202111542373A CN113969500B CN 113969500 B CN113969500 B CN 113969500B CN 202111542373 A CN202111542373 A CN 202111542373A CN 113969500 B CN113969500 B CN 113969500B
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China
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parts
agent
oil
container
injection
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CN202111542373.8A
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CN113969500A (en
Inventor
庄志凯
杜嵇华
李明福
连文伟
何俊燕
欧阳欢
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CHINESE ACADEMY OF TROPICAL AGRICULTURAL SCIENCES
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CHINESE ACADEMY OF TROPICAL AGRICULTURAL SCIENCES
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243Mono-, di-, or triglycerides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40Reduced friction resistance, lubricant properties; Sizing compositions
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to the technical field of plant fiber refined carding, and discloses a processing technology of a high-permeability emulsified oil agent suitable for plant fiber refined carding, which comprises the following steps: step one: the following raw materials are prepared in advance, and the raw materials comprise: mineral oil, vegetable oil, penetrating agent, smoothing agent, softening agent and emulsifying agent; step two: preparing mineral oil into rectangular or round hollow oil film blocks; step three: synchronously adding vegetable oil, penetrating agent, smoothing agent, softening agent and emulsifying agent into a container, stirring for 1-2h to form an inner core; step four: the inner core in the container is placed into the cavity of the oil film block to form the high-permeability emulsified oil. The invention forms a double-layer structure, is convenient for storing the high-permeability emulsified oil, and utilizes the instability of carbonic acid when in use, so that the raw materials are further mixed, and the health care treatment of plant fibers is improved.

Description

High-permeability emulsified oil processing technology suitable for fine carding of plant fibers
Technical Field
The invention relates to the technical field of plant fiber refined carding, and particularly discloses a processing technology of a high-permeability emulsified oil agent suitable for plant fiber refined carding.
Background
In the prior art, the application range of the plant fiber is severely limited due to the fact that the fiber is coarse and hard because of high lignin and hemicellulose content in the fiber, so that the plant fiber is subjected to fine modification (also called degumming treatment). After the refining modification, the lignin and hemicellulose of the plant fiber are partially removed, so that the plant fiber can be improved, and certain defects such as difference of plant fiber flexibility, small cohesion and the like still exist, so that the spinnability of the yarn is lower; the high degree of fineness and discreteness of each part of the fiber and low fiber strength lead to high doffing rate and low finished product yield during carding.
In order to overcome the defects in the prior art, the plant fiber needs to be refined, and the main treatment mode is as follows: the preparation of materials, the refining pretreatment, the refining modification treatment and the water washing are carried out, however, various chemical substances in the refining process inevitably have certain side effects on the fibers, so that various aspects of the fibers are affected by certain adverse effects such as reduction of moisture regain, increase of corrosiveness on the fibers, reduction of softness and the like. According to the performance characteristics of the plant fiber, the softness of the fiber can be changed by adding some oiling agents, auxiliary agents, cellulose softening agents and the like, the friction coefficient of the surface of the fiber is reduced, the cohesion is improved to a certain extent, the strength of the fiber is improved, the softness controls the generation of static electricity, and therefore the purpose of further improving the spinnability of the plant fiber is achieved, and the performance of a product is improved.
Disclosure of Invention
The invention aims to provide a processing technology of a high-permeability emulsified oil agent suitable for fine carding of plant fibers, and provides the emulsified oil agent with high permeability, so that the plant fibers are subjected to health care treatment, the friction coefficient of the surfaces of the plant fibers is reduced, the cohesion is improved, and the strength and the softness of the plant fibers are improved to a certain extent.
In order to achieve the above object, the basic scheme of the present invention is as follows: a processing technology of a high-permeability emulsified oil suitable for fine carding of plant fibers comprises the following steps:
Step one: the following raw materials are prepared in advance, and the raw materials comprise: mineral oil, vegetable oil, penetrating agent, smoothing agent, softening agent and emulsifying agent;
Step two: preparing mineral oil into rectangular or round hollow oil film blocks;
step three: synchronously adding vegetable oil, penetrating agent, smoothing agent, softening agent and emulsifying agent into a container, stirring for 1-2 h to form an inner core;
step four: the inner core in the container is placed into the cavity of the oil film block to form the high-permeability emulsified oil.
Further, the raw materials and the mass parts thereof comprise: 40-60 parts of mineral oil, 20-30 parts of vegetable oil, 1-3 parts of penetrating agent, 2-5 parts of smoothing agent, 2-5 parts of softening agent and 10-20 parts of emulsifying agent.
Further, the raw materials and the mass parts thereof comprise: 40 parts of mineral oil, 20 parts of vegetable oil, 1 part of penetrating agent, 2 parts of smoothing agent, 2 parts of softening agent and 10 parts of emulsifying agent.
Further, the raw materials and the mass parts thereof comprise: 50 parts of mineral oil, 25 parts of vegetable oil, 2 parts of penetrating agent, 3.5 parts of smoothing agent, 3.5 parts of softening agent and 15 parts of emulsifying agent.
Further, the raw materials and the mass parts thereof comprise: 60 parts of mineral oil, 30 parts of vegetable oil, 3 parts of penetrating agent, 5 parts of smoothing agent, 5 parts of softening agent and 20 parts of emulsifying agent.
Further, in the third step, 5 to 8 parts of carbonic acid solution is added to the inner core.
Further, the high-permeability emulsified oil is heated to 20-30 ℃ for use.
The principle and the beneficial effects of the invention are as follows: (1) In this scheme, utilize mineral oil in order to form outer oil film, with vegetable oil etc. through intensive mixing again to form the inner core, and fill the inner core into the oil film piece, constitute bilayer structure, reduced the inner core and received the oxidation and reduced the purpose of efficiency. The softening agent reduces the friction coefficient among plant fibers, the emulsifying agent and the penetrating agent permeate into the fiber bundles to fluffe the fibers, the flexibility and the ramie dropping rate of the fibers are improved, the fiber strength can be improved within a certain range, and the filling effect of the smoothing agent on the surfaces of the plant fibers is favorable for improving the plant fiber strength.
(2) In this scheme, added the carbonic acid solution, when high infiltration emulsifying oil solution heating was used, the oil film piece melted and fully contacted with the inner and formed intensive mixing, simultaneously, output CO 2 and form the bubble in the carbonic acid solution, the bubble in order to make high infiltration emulsifying agent produce violent effect, the bubble that forms takes place to burst in the certain time, increase high infiltration emulsifying agent and vegetable fiber's area of contact, improved the infiltration, and then do benefit to the health preserving to vegetable fiber.
Of course, the implementation of the solution of the application does not necessarily require that all of the technical effects described above be achieved simultaneously.
Drawings
FIG. 1 is a schematic diagram of a medium-high permeability emulsion oil according to an embodiment of the present invention.
Fig. 2 is a schematic structural view of a container according to a third embodiment of the present invention.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments.
In the description of the present invention, it should be understood that the terms "upper," "lower," "front," "rear," "left," "right," "top," "bottom," "inner," "outer," and the like indicate or are based on the orientation or positional relationship shown in the drawings, merely to facilitate description of the present invention and to simplify the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and thus should not be construed as limiting the present invention.
Reference numerals in the drawings of the specification include: the oil film block 11, the closing block 111, the inner core 12, the container 21, the cylinder 22, the injection plate 23, the first nozzle 24, the second nozzle 25, the stirring shaft 27, the stirring vane 28, the motor 29, the bearing 31, the closing plate 32, the through groove 33, the injection hole 34 and the injection pipe 35.
Embodiment one:
a processing technology of a high-permeability emulsified oil suitable for fine carding of plant fibers comprises the following steps:
Step one: the preparation method comprises the following steps of: 40-60 parts of mineral oil, 20-30 parts of vegetable oil, 1-3 parts of penetrating agent, 2-5 parts of smoothing agent, 2-5 parts of softening agent and 10-20 parts of emulsifying agent;
Step two: preparing mineral oil into rectangular or round hollow oil film blocks 11; substantially as shown in figure 1.
Step three: synchronously adding vegetable oil, penetrating agent, smoothing agent, softening agent and emulsifying agent into a container 21 for stirring for 1-2 h, and adding 5-8 parts of carbonic acid solution into the inner core 12 to form the inner core 12;
Step four: the inner core 12 in the container 21 is placed into the cavity of the oil film block 11 and the oil module is then closed with a closing block 111 made of mineral oil to form a high permeability emulsified oil.
When the high-permeability emulsified oil is used, the high-permeability emulsified oil is placed into a heating device until the oil film block 11 is melted and mixed with the inner core 12, carbonic acid in the carbonic acid solution is decomposed under the heating action to form carbon dioxide bubbles, mineral oil and the inner core 12 are further fully mixed under the action of the bubbles, meanwhile, the bubbles can be cracked to a certain extent, the contact area between the high-permeability emulsified oil and plant fibers is enlarged, the permeability of the high-permeability emulsified oil is further improved, and meanwhile, the effect of health maintenance treatment of the high-permeability emulsified oil is improved.
Embodiment two:
The second embodiment is different from the first embodiment in that a processing technology of a high-permeability emulsified oil suitable for fine carding of plant fibers comprises the following steps:
Step one: the preparation method comprises the following steps of: 50 parts of mineral oil, 25 parts of vegetable oil, 2 parts of penetrating agent, 3.5 parts of smoothing agent, 3.5 parts of softening agent and 15 parts of emulsifying agent;
Step two: preparing mineral oil into rectangular or round hollow oil film blocks 11; substantially as shown in figure 1.
Step three: synchronously adding vegetable oil, penetrating agent, smoothing agent, softening agent and emulsifying agent into a container 21 for stirring for 1-2 h, and adding 6.5 parts of carbonic acid solution into the inner core 12 to form the inner core 12;
Step four: the inner core 12 in the container 21 is placed into the cavity of the oil film block 11 and the oil module is then closed with a closing block 111 made of mineral oil to form a high permeability emulsified oil.
Embodiment III:
The third embodiment is different from the first embodiment in that a processing technology of a high-permeability emulsified oil agent suitable for fine carding of plant fibers,
Step one: the preparation method comprises the following steps of: 40-60 parts of mineral oil, 20-30 parts of vegetable oil, 1-3 parts of penetrating agent, 2-5 parts of smoothing agent, 2-5 parts of softening agent and 10-20 parts of emulsifying agent;
Step two: preparing mineral oil into rectangular or round hollow oil film blocks 11; substantially as shown in figure 1.
Step three: the vegetable oil, the penetrating agent, the smoothing agent and the softening agent are synchronously added into the container 21 for stirring, in the embodiment, basically as shown in fig. 2, the container 21 comprises a stirring structure and an injection system, the stirring structure comprises a driving piece, the driving piece is a motor 29, a stirring shaft 27 is coaxially fixed on an output shaft of the motor 29, a plurality of stirring blades 28 are arranged on the stirring shaft 27, a bearing 31 fixed on the container 21 is sleeved on the stirring shaft 27, a plurality of second spray heads 25 are fixed on the side wall of the container 21, the second spray heads 25 are communicated with injectors through pipelines, in the embodiment, the number of the injectors is five, 20-30 parts of the vegetable oil, 1-3 parts of the penetrating agent, 2-5 parts of the smoothing agent, 2-5 parts of the softening agent and 10-20 parts of the emulsifying agent are respectively filled in the injectors.
The upper part in the container 21 is vertically and slidably connected with an injection plate 23, the container 21 is fixedly connected with a cylinder 22, an output shaft of the cylinder 22 is fixedly connected with the injection plate 23, a first spray head 24 is fixed on the injection plate 23, the first spray head 24 is communicated with an injector, and 5-8 parts of carbonic acid solution is filled in the injector.
The output shaft of the air cylinder 22 is fixedly provided with a sealing plate 32, the sealing plate 32 is provided with a through groove 33, the stirring shaft 27 penetrates through the sealing groove, the lower part of the sealing plate 32 is provided with an injection hole 34, the injection hole 34 is communicated with the through groove 33, the injection hole 34 is sealed by the stirring shaft 27, the container 21 is communicated with an injection tube, a supporting plate is arranged below the injection tube, the injection tube is communicated with the container 21 and the injection hole 34, and the sealing plate 32 seals the injection tube 35.
When the inner core 12 is prepared, the motor 29 is started to drive the stirring shaft 27 and the stirring blade 28 to rotate, 20-30 parts of vegetable oil, 1-3 parts of penetrating agent, 2-5 parts of smoothing agent, 2-5 parts of softening agent and 10-20 parts of emulsifying agent are injected into the container 21 at the moment, stirring is carried out by utilizing the rotation action of the stirring shaft 27 and the stirring blade 28, the stirring time is 1-2 h, and the motor 29 is stopped;
Step four: the cylinder 22 is started, the cylinder 22 drives the injection plate 23 to move downwards, at this time, the closing plate 32 moves downwards, the injection hole 34 is communicated with the injection pipe, under the action of pressure, the inner core 12 in the container 21 is injected into the cavity of the oil film block 11, 5-8 parts of carbonic acid solution is injected into the container 21 through the injector, the carbonic acid solution washes residual liquid in the container 21 to reduce liquid residues, the carbonic acid solution also enters into the oil module, and then the oil module is closed by using the closing block 111 made of mineral oil to form the high-permeability emulsified oil.
In summary, (1) in this solution, mineral oil is used to form an outer oil film, and vegetable oil is fully mixed to form the inner core 12, and the inner core 12 is filled into the oil film block 11 to form a double-layer structure, so that the purpose of reducing the efficiency of the inner core 12 due to oxidation is reduced. The softening agent reduces the friction coefficient among plant fibers, the emulsifying agent and the penetrating agent permeate into the fiber bundles to fluffe the fibers, the flexibility and the ramie dropping rate of the fibers are improved, the fiber strength can be improved within a certain range, and the filling effect of the smoothing agent on the surfaces of the plant fibers is favorable for improving the plant fiber strength.
(2) In this scheme, added the carbonic acid solution, when high infiltration emulsifying oil solution heating was used, oil film piece 11 melted and fully contacted with the inner and form intensive mixing, simultaneously, output CO 2 and form the bubble in the carbonic acid solution, the bubble is in order to make high infiltration emulsifying agent produce violent effect, the bubble that forms takes place to burst in the certain time, increase high infiltration emulsifying agent and vegetable fiber's area of contact, improved the osmotic effect, and then do benefit to the health preserving to vegetable fiber.
The foregoing is merely exemplary of the present application and the specific structures and/or characteristics of the present application that are well known in the art have not been described in detail herein. It should be noted that modifications and improvements can be made by those skilled in the art without departing from the structure of the present application, and these should also be considered as the scope of the present application, which does not affect the effect of the implementation of the present application and the utility of the patent. The protection scope of the present application is subject to the content of the claims, and the description of the specific embodiments and the like in the specification can be used for explaining the content of the claims.

Claims (4)

1. The high-permeability emulsified oil processing container suitable for fine carding of plant fibers is characterized by comprising a stirring structure and an injection system, wherein the stirring structure comprises a driving piece, the driving piece is a motor, a stirring shaft is coaxially fixed on an output shaft of the motor, a plurality of stirring blades are arranged on the stirring shaft, a bearing fixed on the container is sleeved on the stirring shaft, a plurality of second spray heads are fixed on the side wall of the container, and the second spray heads are communicated with an injector through pipelines;
The upper part in the container is vertically and slidably connected with an injection plate, the container is fixedly connected with an air cylinder, an output shaft of the air cylinder is fixedly connected with the injection plate, a first spray head is fixed on the injection plate, and the first spray head is communicated with an injector; a sealing plate is fixed on the output shaft of the air cylinder, a through groove is arranged on the sealing plate, the stirring shaft penetrates through the sealing groove, an injection hole is arranged at the lower part of the sealing plate, the injection hole is communicated with the through groove, the injection hole is sealed by the stirring shaft,
The container is communicated with an injection tube, a supporting plate is arranged below the injection tube, the injection tube is communicated with the container and the injection hole, and the injection tube is sealed by a sealing plate;
The processing technology of the high-permeability emulsified oil agent for finely carding plant fibers by using the container comprises the following steps:
Step one: the preparation method comprises the following raw materials in parts by weight: 40-60 parts of mineral oil, 20-30 parts of vegetable oil, 1-3 parts of penetrating agent, 2-5 parts of smoothing agent, 2-5 parts of softening agent, 10-20 parts of emulsifying agent and 5-8 parts of carbonic acid solution;
Step two: preparing mineral oil into rectangular or round hollow oil film blocks;
Step three: synchronously adding vegetable oil, penetrating agent, smoothing agent, softening agent and emulsifying agent into a container, stirring for 1-2 h to form an inner core, and filling a carbonic acid solution into a syringe communicated with a first spray head;
Step four: starting the air cylinder, driving the injection plate to move downwards by the air cylinder, at the moment, enabling the sealing plate to move downwards, enabling the injection hole to be communicated with the injection pipe, enabling an inner core in the container to be in a cavity of the oil film block under the action of pressure, injecting 5-8 parts of carbonic acid solution into the container through the injector, flushing residual liquid in the container by the carbonic acid solution to reduce liquid residues, enabling the carbonic acid solution to enter the oil module, and sealing the oil module by using a sealing block made of mineral oil to form the high-permeability emulsified oil.
2. The high-permeability emulsified oil processing container suitable for fine carding of plant fibers as set forth in claim 1, wherein the raw materials and the parts by weight thereof include: 40 parts of mineral oil, 20 parts of vegetable oil, 1 part of penetrating agent, 2 parts of smoothing agent, 2 parts of softening agent and 10 parts of emulsifying agent.
3. The high penetration emulsifying oil processing container suitable for fine carding of plant fibers as claimed in claim 1, wherein: the raw materials and the parts by weight thereof are as follows: 50 parts of mineral oil, 25 parts of vegetable oil, 2 parts of penetrating agent, 3.5 parts of smoothing agent, 3.5 parts of softening agent and 15 parts of emulsifying agent.
4. The high-permeability emulsified oil processing container suitable for fine carding of plant fibers as set forth in claim 1, wherein the raw materials and the parts by weight thereof include: 60 parts of mineral oil, 30 parts of vegetable oil, 3 parts of penetrating agent, 5 parts of smoothing agent, 5 parts of softening agent and 20 parts of emulsifying agent.
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