CN108611862A - A kind of continuous spinning viscose filament yarn antistatic high-performance oil - Google Patents
A kind of continuous spinning viscose filament yarn antistatic high-performance oil Download PDFInfo
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- CN108611862A CN108611862A CN201810419189.6A CN201810419189A CN108611862A CN 108611862 A CN108611862 A CN 108611862A CN 201810419189 A CN201810419189 A CN 201810419189A CN 108611862 A CN108611862 A CN 108611862A
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- filament yarn
- viscose filament
- ether
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of continuous spinning viscose filament yarn antistatic high-performance oils, are a kind of antibacterial finishes, include the following raw material according to the mass fraction：30~50 parts of castor oil polyoxyethylene ether, 10~30 parts of alkyl betaine, 5~15 parts of ethylene oxide propylene oxide block polyether, 5~10 parts, 2~5 parts of antistatic agent SN of N thiocarboxylic acid types glycine betaine, 30~60 parts of deionized water.Continuous spinning viscose filament yarn antistatic high-performance oil obtained by the present invention can effectively improve viscose rayon interface performance, make it have excellent flatness, hydrophily, antistatic property and antibiotic property.
Description
Technical field
The present invention relates to chemical industry finish fields, more particularly to a kind of continuous spinning viscose filament yarn antistatic high-performance oil.
Background technology
The continuous viscose filament yarn process exploitation that spins is in the 1960s, the hair advanced by leaps and bounds in decades later
The features such as exhibition, the technique have production procedure short, and product variety is easy to adjust, and production cost is low, easy to operate.
Production is continuous spin viscose filament yarn during, it is necessary to spinning oil is used, to reach lubrication, antistatic, boundling
Effect can assign the excellent coherent of viscose rayon, flatness so that dynamic between fiber and fiber, between fiber and metal
Confficient of static friction is appropriate, good spinnability.But with the progress of spinning technique, the raising of spinning speed, to continuously spinning viscose filament yarn
Antistatic property put forward higher requirements.Electrostatic on fiber just will produce showing for lousiness or even fracture of wire as eliminated not in time
As.
Invention content
The present invention in view of the shortcomings of the prior art, provide it is a kind of continuous spin viscose filament yarn antistatic high-performance oil, can and
When eliminate electrostatic, avoid generating lousiness or even the phenomenon that fracture of wire.
The technical solution adopted by the present invention is：
A kind of continuous spinning viscose filament yarn antistatic high-performance oil, includes the raw material of following mass fraction：
30~50 parts of castor oil polyoxyethylene ether
10~30 parts of alkyl betaine
5~15 parts of epoxy ethane-epoxy propane block polyether
5~10 parts of N- thiocarboxylic acid types glycine betaine
2~5 parts of antistatic agent SN
60~90 parts of deionized water.
Described one kind is continuous to spin viscose filament yarn antistatic high-performance oil, and the castor oil polyoxyethylene ether is castor oil
Polyoxyethylene (10) ether, castor oil polyoxyethylene (30) ether, castor oil polyoxyethylene (50) ether, castor oil polyoxyethylene (70)
Ether, it is one or more of in castor oil polyoxyethylene (90) ether.
Described one kind is continuous to spin viscose filament yarn antistatic high-performance oil, and the structural formula of the alkyl betaine is RN+
(CH3)2CH2COO-, wherein R is C12~C18Alkyl.
Described one kind is continuous to spin viscose filament yarn antistatic high-performance oil, and the epoxy ethane-epoxy propane block is poly-
Ether structure formula is R1O(PO)m(EO)nH, wherein R1For C4~C50Alkyl, m and n are 5~80, and m ＜ n.
Described one kind is continuous to spin viscose filament yarn antistatic high-performance oil, the N- thiocarboxylic acids type betaine structure formula
For R1SR2N+(CH3)2CH2COO-, wherein R1For C12~C18Alkyl, R2For C1~C4Alkylidene.
Described one kind is continuous to spin viscose filament yarn antistatic high-performance oil, and the deionized water conductivity is less than 10 μ S/
Cm is more than 0 μ S/cm.
A kind of continuous preparation method for spinning viscose filament yarn antistatic high-performance oil, prepares each raw material by formula ratio, will go
Ionized water is warming up to 60~80 DEG C, sequentially adds castor oil polyoxyethylene ether, alkyl betaine, and epoxy ethane-epoxy propane is embedding
Section polyethers, N- thiocarboxylic acid type glycine betaines, antistatic agent SN are mixed 30~60 minutes, obtain continuously spinning viscose filament yarn and resist
Electrostatic high-performance oil.
The invention has the advantages that：
The present invention continuously spins viscose filament yarn antistatic high-performance oil, has excellent stability, antistatic property and antibacterial
Type.Amphoteric surfactant alkyl betaine have excellent softness and antistatic property, because in structure simultaneous with anion
And cation group, proton can be provided but also receive proton, therefore electrostatic can be effectively eliminated.In addition, it is also good
Synergistic effect acts synergistically with antistatic agent SN, effectively reduces the generation of electrostatic on fiber, fiber is made to be kept away in fabrication processes
The phenomenon that exempting from the generation of lousiness or even short silk.The addition of N- thiocarboxylic acid type glycine betaines, except the purposes with general glycine betaine
Outside, the growth of fiber surface bacterium can also be inhibited.Viscose rayon is soft after oiling treatment, comfortable and easy to wear.
Specific implementation mode
The present invention is described further with reference to specific embodiment：
A kind of continuous spinning viscose filament yarn antistatic high-performance oil of embodiment 1
(1) include following mass fraction raw material：
35 parts of castor oil polyoxyethylene ether；
15 parts of alkyl betaine；
6 parts of epoxy ethane-epoxy propane block polyether；
6 parts of N- thiocarboxylic acid types glycine betaine；
2 parts of antistatic agent SN；
64 parts of deionized water.
(2) it prepares：Prepare each raw material by formula ratio, the deionized water that conductivity is 5 μ S/cm is warming up to 70 DEG C, successively
35 parts of castor oil polyoxyethylene (30) ether, alkyl betaine C is added14H29N+(CH3)2CH2COO-15 parts, ethylene oxide-epoxy third
Alkane block polyether (R C10Alkyl, m=3, n=20) 6 parts, N- thiocarboxylic acid type glycine betaines C18H37SC2H4N+(CH3)2CH2COO-It 6 parts, 2 parts of antistatic agent SN, is mixed 40 minutes, obtains continuously spinning viscose filament yarn antistatic high-performance oil.
A kind of continuous spinning viscose filament yarn antistatic high-performance oil of embodiment 2
(1) include following mass fraction raw material：
45 parts of castor oil polyoxyethylene ether
12 parts of alkyl betaine
8 parts of epoxy ethane-epoxy propane block polyether
7 parts of N- thiocarboxylic acid types glycine betaine
3 parts of antistatic agent SN
75 parts of deionized water.
(2) it prepares：Prepare each raw material by formula ratio, the deionized water that conductivity is 5 μ S/cm is warming up to 70 DEG C, successively
Castor oil polyoxyethylene (50) ether, alkyl betaine C is added12H25N+(CH3)2CH2COO-, epoxy ethane-epoxy propane block is poly-
Ether (R C8Alkyl, m=5, n=17), N- thiocarboxylic acid type glycine betaines C14H29SC2H4N+(CH3)2CH2COO-, antistatic agent
SN is mixed 40 minutes, obtains continuously spinning viscose filament yarn antistatic high-performance oil.
A kind of continuous spinning viscose filament yarn antistatic high-performance oil of embodiment 3
(1) include following mass fraction raw material：
40 parts of castor oil polyoxyethylene ether
20 parts of alkyl betaine
9 parts of epoxy ethane-epoxy propane block polyether
8 parts of N- thiocarboxylic acid types glycine betaine
3 parts of antistatic agent SN
80 parts of deionized water.
(2) it prepares：Prepare each raw material by formula ratio, the deionized water that conductivity is 5 μ S/cm is warming up to 70 DEG C, successively
Castor oil polyoxyethylene (70) ether, alkyl betaine C is added16H33N+(CH3)2CH2COO-, epoxy ethane-epoxy propane block is poly-
Ether (R C8Alkyl, m=5, n=20), N- thiocarboxylic acid type glycine betaines C16H33SC3H6N+(CH3)2CH2COO-, antistatic agent
SN is mixed 40 minutes, obtains continuously spinning viscose filament yarn antistatic high-performance oil.
A kind of continuous spinning viscose filament yarn antistatic high-performance oil of embodiment 4
(1) include following mass fraction raw material：
35 parts of castor oil polyoxyethylene ether
23 parts of alkyl betaine
12 parts of epoxy ethane-epoxy propane block polyether
7 parts of N- thiocarboxylic acid types glycine betaine
4 parts of antistatic agent SN
81 parts of deionized water.
(2) it prepares：Prepare each raw material by formula ratio, the deionized water that conductivity is 5 μ S/cm is warming up to 70 DEG C, successively
Castor oil polyoxyethylene (90) ether, alkyl betaine C is added18H37N+(CH3)2CH2COO-, epoxy ethane-epoxy propane block is poly-
Ether (R C12Alkyl, m=3, n=16), N- thiocarboxylic acid type glycine betaines C18H37SC3H6N+(CH3)2CH2COO-, antistatic agent
SN is mixed 40 minutes, obtains continuously spinning viscose filament yarn antistatic high-performance oil.
The finish that above-described embodiment 1~4 is prepared and polyvinyl alcohol pulp in mass ratio 1:1.2 are dissolved in deionized water respectively
In, it is configured to the working solution of a concentration of 48g/L.In spinning process, strand is a softer and smoother touch, and passability is good, do not occur lousiness,
The phenomenon that fracture of wire, finish and application performance index of the present invention are as shown in table 1.
1 finish of table and application performance index
Claims (7)
1. a kind of continuous spinning viscose filament yarn antistatic high-performance oil, which is characterized in that include the raw material of following mass fraction：
30~50 parts of castor oil polyoxyethylene ether
10~30 parts of alkyl betaine
5~15 parts of epoxy ethane-epoxy propane block polyether
5~10 parts of N- thiocarboxylic acid types glycine betaine
2~5 parts of antistatic agent SN
60~90 parts of deionized water.
2. a kind of continuous spinning viscose filament yarn antistatic high-performance oil according to claim 1, it is characterised in that：The castor
Sesame oil polyoxyethylene ether is castor oil polyoxyethylene (10) ether, castor oil polyoxyethylene (30) ether, castor oil polyoxyethylene (50)
Ether, castor oil polyoxyethylene (70) ether are one or more of in castor oil polyoxyethylene (90) ether.
3. a kind of continuous spinning viscose filament yarn antistatic high-performance oil according to claim 1, it is characterised in that：The alkane
The structural formula of base glycine betaine is RN+(CH3)2CH2COO-, wherein R is C12~C18Alkyl.
4. a kind of continuous spinning viscose filament yarn antistatic high-performance oil according to claim 1, it is characterised in that：The ring
Oxidative ethane-propylene oxide block polyether structure formula is R1O(PO)m(EO)nH, wherein R1For C4~C50Alkyl, m and n be 5~
80, and m ＜ n.
5. a kind of continuous spinning viscose filament yarn antistatic high-performance oil according to claim 1, it is characterised in that：The N-
Thiocarboxylic acid type betaine structure formula is R1SR2N+(CH3)2CH2COO-, wherein R1For C12~C18Alkyl, R2For C1~C4Asia
Alkyl.
6. a kind of continuous spinning viscose filament yarn antistatic high-performance oil according to claim 1, it is characterised in that：It is described to go
Ion water conductivity is less than 10 μ S/cm, is more than 0 μ S/cm.
7. a kind of continuous preparation method for spinning viscose filament yarn antistatic high-performance oil, the formula ratio according to claim 1 prepare each
Raw material, it is characterised in that：Deionized water is warming up to 60~80 DEG C, sequentially adds castor oil polyoxyethylene ether, alkyl betaine,
Epoxy ethane-epoxy propane block polyether, N- thiocarboxylic acid type glycine betaines, antistatic agent SN are mixed 30~60 minutes, obtain
Viscose filament yarn antistatic high-performance oil is spun to continuous.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810419189.6A CN108611862A (en) | 2018-05-04 | 2018-05-04 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810419189.6A CN108611862A (en) | 2018-05-04 | 2018-05-04 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
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| CN201810419189.6A Pending CN108611862A (en) | 2018-05-04 | 2018-05-04 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112301745A (en) * | 2020-11-20 | 2021-02-02 | 沈阳浩博实业有限公司 | Oil agent for continuous spunbond fibers and preparation method and application thereof |
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| CN106012539A (en) * | 2016-06-30 | 2016-10-12 | 沈阳工业大学 | Water-soluble spinning finish for viscose filament continuous spinning |
| CN106245326A (en) * | 2016-08-17 | 2016-12-21 | 河北科技大学 | A kind of rayon staple spinning oil preparation |
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| CN107227612A (en) * | 2017-06-28 | 2017-10-03 | 常州通和建筑工程有限公司 | A kind of spinning oil of resistance to volatile-type |
-
2018
- 2018-05-04 CN CN201810419189.6A patent/CN108611862A/en active Pending
Patent Citations (4)
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|---|---|---|---|---|
| CN106012539A (en) * | 2016-06-30 | 2016-10-12 | 沈阳工业大学 | Water-soluble spinning finish for viscose filament continuous spinning |
| CN106245326A (en) * | 2016-08-17 | 2016-12-21 | 河北科技大学 | A kind of rayon staple spinning oil preparation |
| CN106498741A (en) * | 2016-09-23 | 2017-03-15 | 沈阳浩博实业有限公司 | A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn |
| CN107227612A (en) * | 2017-06-28 | 2017-10-03 | 常州通和建筑工程有限公司 | A kind of spinning oil of resistance to volatile-type |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112301745A (en) * | 2020-11-20 | 2021-02-02 | 沈阳浩博实业有限公司 | Oil agent for continuous spunbond fibers and preparation method and application thereof |
| CN112301745B (en) * | 2020-11-20 | 2023-12-01 | 沈阳浩博实业有限公司 | Oiling agent for continuous spinning viscose fiber and preparation method and application thereof |
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Application publication date: 20181002 |