CN106012539A - Water-soluble spinning finish for viscose filament continuous spinning - Google Patents
Water-soluble spinning finish for viscose filament continuous spinning Download PDFInfo
- Publication number
- CN106012539A CN106012539A CN201610496551.0A CN201610496551A CN106012539A CN 106012539 A CN106012539 A CN 106012539A CN 201610496551 A CN201610496551 A CN 201610496551A CN 106012539 A CN106012539 A CN 106012539A
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- China
- Prior art keywords
- fatty alcohol
- polyoxyethylene ether
- water
- viscose filament
- diethanolamine
- Prior art date
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a water-soluble spinning finish for viscose filament continuous spinning. The spinning finish is prepared by utilizing a nonionic surfactant, an anionic surfactant and other components and comprises fatty alcohol polyoxyethylene ether with high ethylene oxide adduct number, fatty alcohol polyoxyethylene ether sulfate with high ethylene oxide adduct number, diethanolamine and water. The prepared spinning finish has the beneficial effects that the spinning finish is colorless, odorless and transparent and has good water solubility; the continuously spun viscose fiber cohesion is more than 50(r); the difference of the coefficients of static friction and dynamic friction among fibers is 0.2007-0.2262; and the specific resistance is 1.6*10<8>omega.m-7.0*10<8>omega .m.
Description
Technical field
The invention belongs to chemical products field, be specifically related to a kind of water solublity viscose filament yarn and spin oil preparation continuously.
Background technology
Spinning viscose filament yarn continuously is the parallel silk do not twisted, need oil preparation and slurry to make between viscose rayon to embrace and, and give viscose glue
The flatness of fiber, antistatic behaviour, it is possible to successfully post-treatment and weaving process, and improve viscose rayon to a certain extent
Physical property.It is currently used for spinning viscose filament finish continuously and mostly is emulsified mineral oil class, difficulty is blended with water-soluble paste, need
The stirring of long period, technique for applying complexity is loaded down with trivial details.
Summary of the invention
The problem that exists for prior art, it is an object of the invention to prepare and a kind of spins continuously for viscose filament yarn,
Foam colourless, tasteless, transparent, low, good water solubility, and the oil preparation good with water-soluble paste intersolubilities such as polyvinyl alcohol.
The technical scheme is that a kind of water solublity spins viscose filament finish, continuously mainly by the fat of high polymerization degree
Polyoxyethylenated alcohol, the material such as the fatty alcohol polyoxyethylene ether sulfate of high polymerization degree composition, specifically include following components: fat
Polyoxyethylenated alcohol, fatty alcohol polyoxyethylene ether sulfate, diethanolamine, deionized water.
The mass percent of described each component be: fatty alcohol-polyoxyethylene ether 31-35%, fatty alcohol-polyoxyethylene ether sulfur
Acid sodium 6-10%, diethanolamine 1-5%, deionized water 50-54%.
The fatty alcohol carbon number of described fatty alcohol-polyoxyethylene ether is 12-18, the ethoxymer distribution 20-of polyoxyethylene ether
30。
The fatty alcohol carbon number of described fatty alcohol polyoxyethylene ether sulfate is 12-14, the oxirane of polyoxyethylene ether adds
One-tenth number is 10-20.
The preparation technology that described a kind of water solublity viscose filament yarn spins oil preparation continuously is: first deionized water is joined reactor
In, it is heated to 85～90 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolve 1.5～2h, treat fatty alcohol
After polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, after fusing
Fatty alcohol-polyoxyethylene ether (melt temperature 60～70 DEG C) joins in reactor, after being uniformly mixed, is cooled to room temperature,
To water white thick liquid product.
Compared with prior art, the invention have the advantages that: the water solublity viscose glue prepared according to instant component
Long filament spins oil preparation continuously, its foam colourless, tasteless, transparent, low, good water solubility, and mutual with water-soluble pastes such as polyvinyl alcohol
Dissolubility is good, and short with the polyvinyl alcohol water solution mix and blend time, and technique for applying is simple to operation.
Detailed description of the invention
Embodiment 1:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 20) 35 %；
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 20) sodium sulfate 10%；
Diethanolamine 5%；
Deionized water 50%；
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization
Water joins in reactor, is heated to 85 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 2h, treat fat
After fat polyoxyethylenated alcohol sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will fusing
After fatty alcohol-polyoxyethylene ether (melt temperature 60～70 DEG C) join in reactor, after being uniformly mixed, be cooled to room
Temperature, obtains water white thick liquid product.
The oil preparation obtained and 10% polyvinyl alcohol are blended with 1:1 mass ratio, then are configured to the solution of 70g/L, for viscose glue
In the continuous spinning process of fiber, viscose glue spins fibre cohesion continuously and reaches 65(and turn), confficient of static friction and the coefficient of kinetic friction between fiber
Difference is 0.2252, than resistance is。
Embodiment 2:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 12-14 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 23) 33%
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 15) sodium sulfate 9 %
Diethanolamine 5%
Deionized water 53%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization
Water joins in reactor, is heated to 90 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.5h, treat
After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten
Fatty alcohol-polyoxyethylene ether (melt temperature 60～70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to
Room temperature, obtains water white thick liquid product.
The oil preparation obtained and 10% polyvinyl alcohol are blended with 1:1 mass ratio, then are configured to the solution of 70g/L, for viscose glue
In the continuous spinning process of fiber, viscose glue spins fibre cohesion continuously and reaches 70(and turn), confficient of static friction and the coefficient of kinetic friction between fiber
Difference is 0.2262, than resistance is。
Embodiment 3:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 16-18 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 25) 31%
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 13) sodium sulfate 10%
Diethanolamine 5%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization
Water joins in reactor, is heated to 90 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.5h, treat
After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten
Fatty alcohol-polyoxyethylene ether (melt temperature 60～70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to
Room temperature, obtains water white thick liquid product.
The oil preparation obtained and 10% polyvinyl alcohol are blended with 1:1 mass ratio, then are configured to the solution of 70g/L, for viscose glue
In the continuous spinning process of fiber, viscose glue spins fibre cohesion continuously and reaches 50(and turn), confficient of static friction and the coefficient of kinetic friction between fiber
Difference is 0.2007, than resistance is。
Embodiment 4:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 14-16 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 30) 35%
Fatty alcohol (carbon number is 13) polyoxyethylene ether (ethoxymer distribution is 10) sodium sulfate 6%
Diethanolamine 5%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization
Water joins in reactor, is heated to 88 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.6h, treat
After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten
Fatty alcohol-polyoxyethylene ether (melt temperature 60～70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to
Room temperature, obtains water white thick liquid product.
Embodiment 5:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 14-16 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 30) 35%
Fatty alcohol (carbon number is 14) polyoxyethylene ether (ethoxymer distribution is 10) sodium sulfate 10%
Diethanolamine 1%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization
Water joins in reactor, is heated to 86 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.8h, treat
After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten
Fatty alcohol-polyoxyethylene ether (melt temperature 60～70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to
Room temperature, obtains water white thick liquid product.
Embodiment 6:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 14-16 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 30) 35%
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 10) sodium sulfate 7%
Diethanolamine 4%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization
Water joins in reactor, is heated to 89 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.8h, treat
After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten
Fatty alcohol-polyoxyethylene ether (melt temperature 60～70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to
Room temperature, obtains water white thick liquid product.
Claims (4)
1. one kind is spun viscose filament finish continuously with water solublity, it is characterised in that its component includes: fatty alcohol-polyoxyethylene ether,
Fatty alcohol polyoxyethylene ether sulfate, diethanolamine, deionized water.
Water solublity the most according to claim 1 spins viscose filament finish continuously, it is characterised in that the quality of described each component
Percentage ratio be: fatty alcohol-polyoxyethylene ether 31-35%, polyoxyethylenated alcohol sodium sulfate 6-10%, diethanolamine 1-5%,
Deionized water 50-54%.
Water solublity the most according to claim 1 and 2 spins viscose filament finish continuously, it is characterised in that described poly alkyl alcohol
The fatty alcohol carbon number of oxygen vinyl Ether is 12-18, the ethoxymer distribution 20-30 of polyoxyethylene ether；Described fatty alcohol polyoxy second
The fatty alcohol carbon number of alkene ether sulphate is 12-14, the ethoxymer distribution of polyoxyethylene ether is 10-20.
Water solublity the most according to claim 1 and 2 spins viscose filament finish continuously, it is characterised in that its preparation technology is:
First joining in reactor by deionized water, be heated to 85～90 DEG C, add fatty alcohol polyoxyethylene ether sulfate, insulation is stirred
Mix, dissolve 1.5～2h, after fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then in insulation
Under conditions of stirring, the fatty alcohol-polyoxyethylene ether after fusing is joined in reactor, after being uniformly mixed, is cooled to room
Temperature, obtains water white thick liquid product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496551.0A CN106012539B (en) | 2016-06-30 | 2016-06-30 | A kind of water solubility viscose filament yarn continuously spins finish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496551.0A CN106012539B (en) | 2016-06-30 | 2016-06-30 | A kind of water solubility viscose filament yarn continuously spins finish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106012539A true CN106012539A (en) | 2016-10-12 |
| CN106012539B CN106012539B (en) | 2018-05-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610496551.0A Active CN106012539B (en) | 2016-06-30 | 2016-06-30 | A kind of water solubility viscose filament yarn continuously spins finish |
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| Country | Link |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106498778A (en) * | 2016-10-25 | 2017-03-15 | 中原工学院 | A kind of viscose fabric cold pad--batch single bath process production technology degreaser and application process |
| CN108611862A (en) * | 2018-05-04 | 2018-10-02 | 沈阳浩博实业有限公司 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
| CN113774663A (en) * | 2021-09-16 | 2021-12-10 | 新乡化纤股份有限公司 | Continuous spunbonded adhesive filament oil agent composition and preparation method thereof |
| CN114737391A (en) * | 2022-05-17 | 2022-07-12 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
Citations (3)
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|---|---|---|---|---|
| CN102400313A (en) * | 2010-09-09 | 2012-04-04 | 蒋勤 | Antistatic viscose filament oil |
| CN102400318A (en) * | 2010-09-08 | 2012-04-04 | 陈亚玉 | Viscose filament finish |
| CN102828401A (en) * | 2012-08-02 | 2012-12-19 | 太仓市中明化纤有限公司 | Viscose spinning oil |
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2016
- 2016-06-30 CN CN201610496551.0A patent/CN106012539B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102400318A (en) * | 2010-09-08 | 2012-04-04 | 陈亚玉 | Viscose filament finish |
| CN102400313A (en) * | 2010-09-09 | 2012-04-04 | 蒋勤 | Antistatic viscose filament oil |
| CN102828401A (en) * | 2012-08-02 | 2012-12-19 | 太仓市中明化纤有限公司 | Viscose spinning oil |
Non-Patent Citations (1)
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| 金燚 等: "粘胶长丝油剂HB-NJ010的研制", 《人造纤维》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106498778A (en) * | 2016-10-25 | 2017-03-15 | 中原工学院 | A kind of viscose fabric cold pad--batch single bath process production technology degreaser and application process |
| CN108611862A (en) * | 2018-05-04 | 2018-10-02 | 沈阳浩博实业有限公司 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
| CN113774663A (en) * | 2021-09-16 | 2021-12-10 | 新乡化纤股份有限公司 | Continuous spunbonded adhesive filament oil agent composition and preparation method thereof |
| CN114737391A (en) * | 2022-05-17 | 2022-07-12 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
| CN114737391B (en) * | 2022-05-17 | 2023-09-22 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
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| Publication number | Publication date |
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| CN106012539B (en) | 2018-05-15 |
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