CN106012539A - Water-soluble spinning finish for viscose filament continuous spinning - Google Patents

Water-soluble spinning finish for viscose filament continuous spinning Download PDF

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Publication number
CN106012539A
CN106012539A CN201610496551.0A CN201610496551A CN106012539A CN 106012539 A CN106012539 A CN 106012539A CN 201610496551 A CN201610496551 A CN 201610496551A CN 106012539 A CN106012539 A CN 106012539A
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China
Prior art keywords
fatty alcohol
polyoxyethylene ether
water
viscose filament
diethanolamine
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CN201610496551.0A
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CN106012539B (en
Inventor
鲁桂林
刘洋
孟静
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Shenyang University of Technology
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Shenyang University of Technology
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/328Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a water-soluble spinning finish for viscose filament continuous spinning. The spinning finish is prepared by utilizing a nonionic surfactant, an anionic surfactant and other components and comprises fatty alcohol polyoxyethylene ether with high ethylene oxide adduct number, fatty alcohol polyoxyethylene ether sulfate with high ethylene oxide adduct number, diethanolamine and water. The prepared spinning finish has the beneficial effects that the spinning finish is colorless, odorless and transparent and has good water solubility; the continuously spun viscose fiber cohesion is more than 50(r); the difference of the coefficients of static friction and dynamic friction among fibers is 0.2007-0.2262; and the specific resistance is 1.6*10<8>omega.m-7.0*10<8>omega .m.

Description

A kind of water solublity viscose filament yarn spins oil preparation continuously
Technical field
The invention belongs to chemical products field, be specifically related to a kind of water solublity viscose filament yarn and spin oil preparation continuously.
Background technology
Spinning viscose filament yarn continuously is the parallel silk do not twisted, need oil preparation and slurry to make between viscose rayon to embrace and, and give viscose glue The flatness of fiber, antistatic behaviour, it is possible to successfully post-treatment and weaving process, and improve viscose rayon to a certain extent Physical property.It is currently used for spinning viscose filament finish continuously and mostly is emulsified mineral oil class, difficulty is blended with water-soluble paste, need The stirring of long period, technique for applying complexity is loaded down with trivial details.
Summary of the invention
The problem that exists for prior art, it is an object of the invention to prepare and a kind of spins continuously for viscose filament yarn, Foam colourless, tasteless, transparent, low, good water solubility, and the oil preparation good with water-soluble paste intersolubilities such as polyvinyl alcohol.
The technical scheme is that a kind of water solublity spins viscose filament finish, continuously mainly by the fat of high polymerization degree Polyoxyethylenated alcohol, the material such as the fatty alcohol polyoxyethylene ether sulfate of high polymerization degree composition, specifically include following components: fat Polyoxyethylenated alcohol, fatty alcohol polyoxyethylene ether sulfate, diethanolamine, deionized water.
The mass percent of described each component be: fatty alcohol-polyoxyethylene ether 31-35%, fatty alcohol-polyoxyethylene ether sulfur Acid sodium 6-10%, diethanolamine 1-5%, deionized water 50-54%.
The fatty alcohol carbon number of described fatty alcohol-polyoxyethylene ether is 12-18, the ethoxymer distribution 20-of polyoxyethylene ether 30。
The fatty alcohol carbon number of described fatty alcohol polyoxyethylene ether sulfate is 12-14, the oxirane of polyoxyethylene ether adds One-tenth number is 10-20.
The preparation technology that described a kind of water solublity viscose filament yarn spins oil preparation continuously is: first deionized water is joined reactor In, it is heated to 85~90 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolve 1.5~2h, treat fatty alcohol After polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, after fusing Fatty alcohol-polyoxyethylene ether (melt temperature 60~70 DEG C) joins in reactor, after being uniformly mixed, is cooled to room temperature, To water white thick liquid product.
Compared with prior art, the invention have the advantages that: the water solublity viscose glue prepared according to instant component Long filament spins oil preparation continuously, its foam colourless, tasteless, transparent, low, good water solubility, and mutual with water-soluble pastes such as polyvinyl alcohol Dissolubility is good, and short with the polyvinyl alcohol water solution mix and blend time, and technique for applying is simple to operation.
Detailed description of the invention
Embodiment 1:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 20) 35 %;
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 20) sodium sulfate 10%;
Diethanolamine 5%;
Deionized water 50%;
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization Water joins in reactor, is heated to 85 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 2h, treat fat After fat polyoxyethylenated alcohol sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will fusing After fatty alcohol-polyoxyethylene ether (melt temperature 60~70 DEG C) join in reactor, after being uniformly mixed, be cooled to room Temperature, obtains water white thick liquid product.
The oil preparation obtained and 10% polyvinyl alcohol are blended with 1:1 mass ratio, then are configured to the solution of 70g/L, for viscose glue In the continuous spinning process of fiber, viscose glue spins fibre cohesion continuously and reaches 65(and turn), confficient of static friction and the coefficient of kinetic friction between fiber Difference is 0.2252, than resistance is
Embodiment 2:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 12-14 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 23) 33%
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 15) sodium sulfate 9 %
Diethanolamine 5%
Deionized water 53%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization Water joins in reactor, is heated to 90 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.5h, treat After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten Fatty alcohol-polyoxyethylene ether (melt temperature 60~70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to Room temperature, obtains water white thick liquid product.
The oil preparation obtained and 10% polyvinyl alcohol are blended with 1:1 mass ratio, then are configured to the solution of 70g/L, for viscose glue In the continuous spinning process of fiber, viscose glue spins fibre cohesion continuously and reaches 70(and turn), confficient of static friction and the coefficient of kinetic friction between fiber Difference is 0.2262, than resistance is
Embodiment 3:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 16-18 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 25) 31%
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 13) sodium sulfate 10%
Diethanolamine 5%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization Water joins in reactor, is heated to 90 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.5h, treat After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten Fatty alcohol-polyoxyethylene ether (melt temperature 60~70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to Room temperature, obtains water white thick liquid product.
The oil preparation obtained and 10% polyvinyl alcohol are blended with 1:1 mass ratio, then are configured to the solution of 70g/L, for viscose glue In the continuous spinning process of fiber, viscose glue spins fibre cohesion continuously and reaches 50(and turn), confficient of static friction and the coefficient of kinetic friction between fiber Difference is 0.2007, than resistance is
Embodiment 4:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 14-16 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 30) 35%
Fatty alcohol (carbon number is 13) polyoxyethylene ether (ethoxymer distribution is 10) sodium sulfate 6%
Diethanolamine 5%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization Water joins in reactor, is heated to 88 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.6h, treat After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten Fatty alcohol-polyoxyethylene ether (melt temperature 60~70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to Room temperature, obtains water white thick liquid product.
Embodiment 5:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 14-16 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 30) 35%
Fatty alcohol (carbon number is 14) polyoxyethylene ether (ethoxymer distribution is 10) sodium sulfate 10%
Diethanolamine 1%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization Water joins in reactor, is heated to 86 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.8h, treat After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten Fatty alcohol-polyoxyethylene ether (melt temperature 60~70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to Room temperature, obtains water white thick liquid product.
Embodiment 6:
A kind of water solublity spins viscose filament finish continuously, the composition of following masses percentage ratio mix:
Fatty alcohol (carbon number is 14-16 mixed fatty alcohol) polyoxyethylene ether (ethoxymer distribution is 30) 35%
Fatty alcohol (carbon number is 12) polyoxyethylene ether (ethoxymer distribution is 10) sodium sulfate 7%
Diethanolamine 4%
Deionized water 54%
Prepare water solublity viscose filament yarn by the composition of above-mentioned mass percent and spin the preparation technology of oil preparation continuously and be: first by deionization Water joins in reactor, is heated to 89 DEG C, adds fatty alcohol polyoxyethylene ether sulfate, insulated and stirred, dissolves 1.8h, treat After fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then under conditions of insulated and stirred, will be molten Fatty alcohol-polyoxyethylene ether (melt temperature 60~70 DEG C) after change joins in reactor, after being uniformly mixed, is cooled to Room temperature, obtains water white thick liquid product.

Claims (4)

1. one kind is spun viscose filament finish continuously with water solublity, it is characterised in that its component includes: fatty alcohol-polyoxyethylene ether, Fatty alcohol polyoxyethylene ether sulfate, diethanolamine, deionized water.
Water solublity the most according to claim 1 spins viscose filament finish continuously, it is characterised in that the quality of described each component Percentage ratio be: fatty alcohol-polyoxyethylene ether 31-35%, polyoxyethylenated alcohol sodium sulfate 6-10%, diethanolamine 1-5%, Deionized water 50-54%.
Water solublity the most according to claim 1 and 2 spins viscose filament finish continuously, it is characterised in that described poly alkyl alcohol The fatty alcohol carbon number of oxygen vinyl Ether is 12-18, the ethoxymer distribution 20-30 of polyoxyethylene ether;Described fatty alcohol polyoxy second The fatty alcohol carbon number of alkene ether sulphate is 12-14, the ethoxymer distribution of polyoxyethylene ether is 10-20.
Water solublity the most according to claim 1 and 2 spins viscose filament finish continuously, it is characterised in that its preparation technology is: First joining in reactor by deionized water, be heated to 85~90 DEG C, add fatty alcohol polyoxyethylene ether sulfate, insulation is stirred Mix, dissolve 1.5~2h, after fatty alcohol polyoxyethylene ether sulfate all dissolves, add liquid diethanolamine, then in insulation Under conditions of stirring, the fatty alcohol-polyoxyethylene ether after fusing is joined in reactor, after being uniformly mixed, is cooled to room Temperature, obtains water white thick liquid product.
CN201610496551.0A 2016-06-30 2016-06-30 A kind of water solubility viscose filament yarn continuously spins finish Active CN106012539B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498778A (en) * 2016-10-25 2017-03-15 中原工学院 A kind of viscose fabric cold pad--batch single bath process production technology degreaser and application process
CN108611862A (en) * 2018-05-04 2018-10-02 沈阳浩博实业有限公司 A kind of continuous spinning viscose filament yarn antistatic high-performance oil
CN113774663A (en) * 2021-09-16 2021-12-10 新乡化纤股份有限公司 Continuous spunbonded adhesive filament oil agent composition and preparation method thereof
CN114737391A (en) * 2022-05-17 2022-07-12 沈阳浩博实业有限公司 Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102400313A (en) * 2010-09-09 2012-04-04 蒋勤 Antistatic viscose filament oil
CN102400318A (en) * 2010-09-08 2012-04-04 陈亚玉 Viscose filament finish
CN102828401A (en) * 2012-08-02 2012-12-19 太仓市中明化纤有限公司 Viscose spinning oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102400318A (en) * 2010-09-08 2012-04-04 陈亚玉 Viscose filament finish
CN102400313A (en) * 2010-09-09 2012-04-04 蒋勤 Antistatic viscose filament oil
CN102828401A (en) * 2012-08-02 2012-12-19 太仓市中明化纤有限公司 Viscose spinning oil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
金燚 等: "粘胶长丝油剂HB-NJ010的研制", 《人造纤维》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498778A (en) * 2016-10-25 2017-03-15 中原工学院 A kind of viscose fabric cold pad--batch single bath process production technology degreaser and application process
CN108611862A (en) * 2018-05-04 2018-10-02 沈阳浩博实业有限公司 A kind of continuous spinning viscose filament yarn antistatic high-performance oil
CN113774663A (en) * 2021-09-16 2021-12-10 新乡化纤股份有限公司 Continuous spunbonded adhesive filament oil agent composition and preparation method thereof
CN114737391A (en) * 2022-05-17 2022-07-12 沈阳浩博实业有限公司 Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof
CN114737391B (en) * 2022-05-17 2023-09-22 沈阳浩博实业有限公司 Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof

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