CN104562708B - A kind of preparation method of the anti-electrostatic polyester tablecloth - Google Patents
A kind of preparation method of the anti-electrostatic polyester tablecloth Download PDFInfo
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Abstract
The present invention discloses a kind of preparation method of the anti-electrostatic polyester tablecloth, belongs to textile material technical field. This preparation method first by the terylene tablecloth first after through Na2CO3Mixed solution and the processing of ammonium persulfate solution continuous modification of solution, N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane composition, then be impregnated in aniline and mixing in conjugative monomer solution that p-Mercaptoaniline forms, under the synergy of perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt, after polymerisation, washing, oven dry, make the anti-electrostatic polyester tablecloth. The anti-electrostatic polyester tablecloth electrical conductivity that the inventive method is prepared into is 8.5 × 10-3～3.6×10-2S·cm-1, this invention has that preparation method is simple, product antistatic property is good and the feature such as applicability is wide.
Description
Technical field:
The invention belongs to textile material technical field, be specifically related to a kind of preparation method of the anti-electrostatic polyester tablecloth.
Background technology:
Electrostatic phenomenon is common in all kinds of textiles. Eliminate electrostatic phenomenon, obtain anti-static function is textile material research field alwaysOne of focus (YouyiXia, YunLu. " Fabricationandpropertiesofconductiveconjugatedpolymers/silkfibroincompositefibers”，《CompostieScienceandTechnology》,2008，68，1471-1479)。
The tablecloth is that a class is covered on platform, desktop in order to antifouling or increase textile attractive in appearance. As the high-grade tablecloth of one, washThe synthetic fibre class tablecloth is widely used in furnishings, dinner party, dining etc. But, because the polyester fiber hydrophily of the formation terylene class tablecloth is poor,Cause its electrostatic phenomenon very serious, thereby in processing and use procedure, often cause serious fluffing, pilling effect, special(Liu Yuqiang etc., " nano zine oxide-iron oxide mixed sols is anti-to dacron under environment, also can to produce blast, disaster hidden-troubleElectrostatic efficiency ", " textile journal ", 2013,34,17-23). Therefore, the anti-static function of the endowing terylene class tablecloth be one urgentlyProblem to be solved.
Carrying out modification in textile surface, is the common methods that solves electrostatic phenomenon. Than all kinds of antistatic additive, conjugative monomerIn the polymerization of fiber surface, convenient, nontoxic because of it, therefore develop into the new methods of preparing antistatic textile. As inState patent CN103468541A discloses a kind of simple preparation process of antistatic surface dacron, and the method is in dacron tableFace carries out aniline polymerization, has obtained anti-static fabric; Chinese patent CN102943388A discloses a kind of home position polymerization reaction preparationThe method of Antistatic polyester fabric, the method adopts home position polymerization reaction also to obtain a class anti-static fabric. Application said methodThough can obtain the terylene class tablecloth of certain antistatic behaviour, but, also there is the problems such as resistance is bigger than normal, antistatic behaviour is not good enough.
Summary of the invention:
The present invention is directed in the existing anti-electrostatic polyester tablecloth and have technical problem, a kind of preparation side of the anti-electrostatic polyester tablecloth is providedMethod.
The preparation method of a kind of anti-electrostatic polyester tablecloth provided by the invention, its concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A.
(2) described modified dacron tablecloth A being placed in to mass fraction is N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5%With in the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dryDry, obtain modified dacron tablecloth B, described N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silaneMass ratio be 6:4.
(3) described modified dacron tablecloth B being placed in to mass fraction is that 10%～20% ammonium persulfate aqueous solution soaks after 1h,Again, through distilled water washing, obtain modified dacron tablecloth C.
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D; Described mixing conjugative monomer in described solution D moleConcentration is 0.05～0.2molL-1, the mol ratio of described aniline and p-Mercaptoaniline is (10～15): 1, and described perchloric acid is in instituteThe molar concentration of stating in mixed aqueous solution is 0.5molL-1, described 4-sulfo group Thiacalixarene sodium salt is in described mixed aqueous solutionMolar concentration be 1mmolL-1, the molar concentration of described phenol red sodium salt in described mixed aqueous solution is 0.05mmol·L-1。
(5) described modified dacron tablecloth C is placed in to described solution D, under the ice water bath environment of 0 DEG C～5 DEG C, leaves standstill and soakAfter 24h, wash through massive laundering, at 40 DEG C, dry and make the anti-electrostatic polyester tablecloth; Described modified dacron tablecloth C and described moltenThe mass ratio of liquid D is 1:20.
The electrical conductivity of the prepared anti-electrostatic polyester tablecloth of the present invention is: 8.5 × 10-3～3.6×10-2S·cm-1(standard four point probe is surveyedExamination), antistatic behaviour is good. The inventive method, the association that has given full play to the conductive compositions producing after aniline and mercaptoaniline polymerizationThe same sex, impel the terylene tablecloth to have higher electrical conductivity, thereby antistatic behaviour is good. In addition, because enter early stage to the terylene tableclothGone effective processing, therefore conducting polymer particle can be grown in terylene tablecloth fiber surface securely, thereby good stability.Preparation technology of the present invention is simple, products obtained therefrom antistatic property is good, applicability is wide.
Detailed description of the invention:
Embodiment 1: electrical conductivity is 8.5 × 10-3S·cm-1Anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A1。
(2) by modified dacron tablecloth A1Be placed in mass fraction and be N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5% withIn the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dry,Obtain modified dacron tablecloth B1, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is6:4。
(3) by modified dacron tablecloth B1Be placed in mass fraction and be 10% ammonium persulfate aqueous solution and soak after 1h, again through steamingHeat up in a steamer water washing, obtain modified dacron tablecloth C1。
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D1; Mix conjugative monomer in solution D1In molar concentration be0.05mol·L-1, the mol ratio of aniline and p-Mercaptoaniline is 10:1, the molar concentration of perchloric acid in mixed aqueous solution is 0.5mol·L-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL-1, phenol red sodium salt existsMolar concentration in mixed aqueous solution is 0.05mmolL-1。
(5) according to terylene tablecloth C1With solution D1Mass ratio be 1:20, by modified dacron tablecloth C1Be placed in solution D1In,Under the ice water bath environment of 0 DEG C～5 DEG C, leave standstill and soak after 24h, wash through massive laundering, at 40 DEG C, dry and make electrical conductivity and be8.5×10-3S·cm-1The anti-electrostatic polyester tablecloth.
Embodiment 2: electrical conductivity is 1.0 × 10-2S·cm-1Anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A2。
(2) by modified dacron tablecloth A2Be placed in mass fraction and be N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5% withIn the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dry,Obtain modified dacron tablecloth B2, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is6:4。
(3) by modified dacron tablecloth B2Be placed in mass fraction and be 20% ammonium persulfate aqueous solution and soak after 1h, again through steamingHeat up in a steamer water washing, obtain modified dacron tablecloth C2。
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D2; Mix conjugative monomer in solution D2In molar concentration be0.08mol·L-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, the molar concentration of perchloric acid in mixed aqueous solution is 0.5mol·L-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL-1, phenol red sodium salt existsMolar concentration in mixed aqueous solution is 0.05mmolL-1。
(5) according to terylene tablecloth C2With solution D2Mass ratio be 1:20, by modified dacron tablecloth C2Be placed in solution D2In,Under the ice water bath environment of 0 DEG C～5 DEG C, leave standstill and soak after 24h, wash through massive laundering, at 40 DEG C, dry and make electrical conductivity and be1.0×10-2S·cm-1The anti-electrostatic polyester tablecloth.
Embodiment 3: electrical conductivity is 1.4 × 10-2S·cm-1Anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A3。
(2) by modified dacron tablecloth A3Be placed in mass fraction and be N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5% withIn the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dry,Obtain modified dacron tablecloth B3, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is6:4。
(3) by modified dacron tablecloth B3Be placed in mass fraction and be 10% ammonium persulfate aqueous solution and soak after 1h, again through steamingHeat up in a steamer water washing, obtain modified dacron tablecloth C3。
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D3; Mix conjugative monomer in solution D3In molar concentration be 0.1mol·L-1, the mol ratio of aniline and p-Mercaptoaniline is 12:1, the molar concentration of perchloric acid in mixed aqueous solution is 0.5mol·L-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL-1, phenol red sodium salt existsMolar concentration in mixed aqueous solution is 0.05mmolL-1。
(5) according to terylene tablecloth C3With solution D3Mass ratio be 1:20, by modified dacron tablecloth C3Be placed in solution D3In,Under the ice water bath environment of 0 DEG C～5 DEG C, leave standstill and soak after 24h, wash through massive laundering, at 40 DEG C, dry and make electrical conductivity and be1.4×10-2S·cm-1The anti-electrostatic polyester tablecloth.
Embodiment 4: electrical conductivity is 2.0 × 10-2S·cm-1Anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A4。
(2) by modified dacron tablecloth A4Be placed in mass fraction and be N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5% withIn the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dry,Obtain modified dacron tablecloth B4, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is6:4。
(3) by modified dacron tablecloth B4Be placed in mass fraction and be 10% ammonium persulfate aqueous solution and soak after 1h, again through steamingHeat up in a steamer water washing, obtain modified dacron tablecloth C4。
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D4; Mix conjugative monomer in solution D4In molar concentration be0.12mol·L-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, the molar concentration of perchloric acid in mixed aqueous solution is 0.5mol·L-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL-1, phenol red sodium salt existsMolar concentration in mixed aqueous solution is 0.05mmolL-1。
(5) according to terylene tablecloth C4With solution D4Mass ratio be 1:20, by modified dacron tablecloth C4Be placed in solution D4In,Under the ice water bath environment of 0 DEG C～5 DEG C, leave standstill and soak after 24h, wash through massive laundering, at 40 DEG C, dry and make electrical conductivity and be2.0×10-2S·cm-1The anti-electrostatic polyester tablecloth.
Embodiment 5: electrical conductivity is 2.8 × 10-2S·cm-1Anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A5。
(2) by modified dacron tablecloth A5Be placed in mass fraction and be N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5% withIn the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dry,Obtain modified dacron tablecloth B5, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is6:4。
(3) by modified dacron tablecloth B5Be placed in mass fraction and be 20% ammonium persulfate aqueous solution and soak after 1h, again through steamingHeat up in a steamer water washing, obtain modified dacron tablecloth C5。
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D5; Mix conjugative monomer in solution D5In molar concentration be0.15mol·L-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, the molar concentration of perchloric acid in mixed aqueous solution is 0.5mol·L-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL-1, phenol red sodium salt existsMolar concentration in mixed aqueous solution is 0.05mmolL-1。
(5) according to terylene tablecloth C5With solution D5Mass ratio be 1:20, by modified dacron tablecloth C5Be placed in solution D5In,Under the ice water bath environment of 0 DEG C～5 DEG C, leave standstill and soak after 24h, wash through massive laundering, at 40 DEG C, dry and make electrical conductivity and be2.8×10-2S·cm-1The anti-electrostatic polyester tablecloth.
Embodiment 6: electrical conductivity is 3.6 × 10-2S·cm-1Anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A6。
(2) by modified dacron tablecloth A6Be placed in mass fraction and be N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5% withIn the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dry,Obtain modified dacron tablecloth B6, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is6:4。
(3) by modified dacron tablecloth B6Be placed in mass fraction and be 20% ammonium persulfate aqueous solution and soak after 1h, again through steamingHeat up in a steamer water washing, obtain modified dacron tablecloth C6。
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D6; Mix conjugative monomer in solution D6In molar concentration be0.2mol·L-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, the molar concentration of perchloric acid in mixed aqueous solution is 0.5mol·L-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL-1, phenol red sodium salt existsMolar concentration in mixed aqueous solution is 0.05mmolL-1。
(5) according to terylene tablecloth C6With solution D6Mass ratio be 1:20, by modified dacron tablecloth C6Be placed in solution D6In,Under the ice water bath environment of 0 DEG C～5 DEG C, leave standstill and soak after 24h, wash through massive laundering, at 40 DEG C, dry and make electrical conductivity and be3.6×10-2S·cm-1The anti-electrostatic polyester tablecloth.
Claims (1)
1. a preparation method for the anti-electrostatic polyester tablecloth, is characterized in that these preparation method's concrete steps are as follows:
(1) the terylene tablecloth being impregnated in to mass fraction is 2% Na2CO330min in solution, after a large amount of distilled water washings,At 40 DEG C, dry, obtain modified dacron tablecloth A;
(2) described modified dacron tablecloth A being placed in to mass fraction is N-(2-aminoethyl)-3-aminopropyl trimethoxysilane of 0.5%With in the mixed solution of vinyltrimethoxy silane composition, soak after 30min, wash respectively through methyl alcohol, water, at 40 DEG C, dryDry, obtain modified dacron tablecloth B, described N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silaneMass ratio be 6:4;
(3) described modified dacron tablecloth B being placed in to mass fraction is that 10%～20% ammonium persulfate aqueous solution soaks after 1h,Again, through distilled water washing, obtain modified dacron tablecloth C;
(4) by aniline and p-Mercaptoaniline composition mix conjugative monomer be dissolved in perchloric acid, 4-sulfo group Thiacalixarene sodium salt withAnd in the mixed aqueous solution of phenol red sodium salt composition, obtain solution D; Described mixing conjugative monomer in described solution D moleConcentration is 0.05～0.2molL-1, the mol ratio of described aniline and p-Mercaptoaniline is (10～15): 1, and described perchloric acid is in instituteThe molar concentration of stating in mixed aqueous solution is 0.5molL-1, described 4-sulfo group Thiacalixarene sodium salt is in described mixed aqueous solutionMolar concentration be 1mmolL-1, the molar concentration of described phenol red sodium salt in described mixed aqueous solution is 0.05mmol·L-1；
(5) described modified dacron tablecloth C is placed in to described solution D, under the ice water bath environment of 0 DEG C～5 DEG C, leaves standstill and soak 24After h, wash through massive laundering, at 40 DEG C, dry and make the anti-electrostatic polyester tablecloth; Described modified dacron tablecloth C and described solutionThe mass ratio of D is 1:20.
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| CN105463833B (en) * | 2015-12-02 | 2017-10-31 | 马鞍山金姿纺织装饰用品有限公司 | A kind of preparation method of antistatic polyester kind fabric |
| CN106676720A (en) * | 2016-11-25 | 2017-05-17 | 威海恒基伟业信息科技发展有限公司 | Antistatic cloth production method |
| CN106480752A (en) * | 2016-12-01 | 2017-03-08 | 西南大学 | Colouring method of the sulfuretin to dacron |
| CN108677525A (en) * | 2018-05-06 | 2018-10-19 | 邳州易萨新型材料有限公司 | A kind of preparation method of novel antistatic polyester fabric |
| CN115948816B (en) * | 2023-02-14 | 2023-09-05 | 无锡聚新科技股份有限公司 | Manufacturing method of white polyester composite conductive fiber |
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