CN104963201A - Method for preparing super-hydrophobic dacron fabric - Google Patents
Method for preparing super-hydrophobic dacron fabric Download PDFInfo
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Abstract
The invention discloses a method for preparing super-hydrophobic dacron fabric. Dacron fabric is taken, and is pretreated in a sodium dodecyl sulfate solution, washed with clear water and dried; dried dacron is dipped in polydimethylsiloxane emulsion, slight soluble inlaying settling is carried out at high temperature and high pressure, the treated dacron is washed, and naturally aired, and the super-hydrophobic surface dacron fabric is obtained. According to the method for preparing the super-hydrophobic dacron fabric, slight soluble inlaying settling of the polydimethylsiloxane emulsion is carried out on the obtained dacron fabric, and the superhydrophobic property is given to the dacron fabric. According to the treatment technology of the dacron fabric, slight soluble inlaying settling is carried out, and washing resistance is achieved. The water contact angle of the treated dacron fabric can be more than 150.0 degrees, the rolling angle of water drops of 10 microliter is reduced to below 10.0 degrees, and the super-hydrophobic standard is met. The preparation process of a super-hydrophobic surface is short in procedure, and large-scale production is easy.
Description
Technical field
The invention belongs to Textile Engineering technical field, particularly a kind of preparation method of super-hydrophobic dacron.
Background technology
Terylene, trade name, refers to the synthetic fiber being greater than 85% containing polyethylene terephthalate component.Its chemical name is polyethylene terephthalate, and be called for short PET, formed by terephthalic acid (TPA) and ethylene glycol polycondensation, molecular structural formula is as follows:
Polyster fibre is invented in nineteen forty-one, is just able to real suitability for industrialized production to nineteen fifty-three.Due to the physical and mechanical properties of its uniqueness, the such as elastic recovery of high strength, stretch-proof, the corrosion of wear-resisting, antioxidant and excellence, just develop into the synthetic fiber kind had the call in the world very soon, be collectively referred to as with polyamide fibre, acrylic fibers " three large fibers ".
At present, terylene accounts for about 75% of world's synthetic fiber output, is maximum, the most widely used synthetic fiber kind of world wide production.If polyster fibre is in a large number for industrial fibre goods such as textiles and filtering material, insulating materials, tire cord, conveyer belt such as dress material, bedding, various trimming cloth, defence and militaries.And in recent years, along with domestic economy maintains sustained and rapid growth and the improving constantly of consumption of resident ability, the demand of domestic area to terylene also constantly increases.China's Polyester Series product production capacity increases with surprising rapidity, the increasing rapidly of polyster fibre production capacity, makes China develop into the important processing base of world's terylene series products just gradually.
In recent years, along with deepening continuously of studying material functional, realize the finishing functions such as the differential or emulationization of polyster fibre by modifications such as physics and chemistries.Wherein super hydrophobic surface refers to and is greater than 150 °, the surface that roll angle is less than 10 ° with the contact angle of water, and it is widely used in waterproof, antifouling, automatically cleaning, fluid drag-reduction, the field such as antibacterial, is domestic and international study hotspot in recent years always.
The preparation principle of super hydrophobic surface mainly builds coarse low surface free energy surface, has lot of documents to report the method building coarse hydrophobic surface for this reason.As plasma etching, collosol and gel, LBL self-assembly, chemical vapour deposition (CVD), polymer solution film forming, mechanical stretching, mould printing and template extruding, electrospinning, electrochemical deposition etc.These methods all can prepare super hydrophobic surface, but all also there is many problems: one is that many methods in these methods not only need specific equipment, and need to carry out strict control to working condition, need the longer production cycle simultaneously, be difficult to use in large-scale industrial production; Two is that the micro-nano structure of existing super hydrophobic surface is easily damaged, and its durability is generally poor, need to improve; Three is in the material reducing Solid Surface Free Energy, and fluorochemical receives much attention because its effect is the most remarkable, but fluorine material price is higher, and there is potential safety hazard to human body and environment, and therefore its practical application is subject to a definite limitation.Thus exploitation short route, low cost, the super-hydrophobic preparation new principle of easily large-scale production, new technology not only have important theory significance, also have great application prospect.
Summary of the invention
An object of the present invention is harsh for solving prior art working condition, and the production cycle is long, and product durability degree is not enough, provides a kind of preparation method of super-hydrophobic dacron.
The invention provides a kind of preparation method of super-hydrophobic dacron, get dacron, preliminary treatment in sodium dodecyl sulfate solution, then with clear water washing, dry; Terylene after drying be impregnated in aqueous emulsion of dimethyl polysiloxane fluid, carry out slightly soluble and inlay arrangement, the terylene after arranging is washed, naturally dries, obtain super hydrophobic surface dacron.
Further, described dodecyl sodium sulfate concentration is 0.1%, and described pretreatment condition is 60 DEG C of washing 30min.
Further, described aqueous emulsion of dimethyl polysiloxane fluid comprises dimethyl silicone polymer and fatty alcohol-polyoxyethylene ether, and dimethyl silicone polymer and fatty alcohol-polyoxyethylene ether mass ratio are 5:1.
Further, it is that high temperature-pressure dyeing machine carries out slightly soluble damascene process that described slightly soluble inlays method for sorting, and treatment conditions are that 30min is warming up to 130 DEG C, and insulation 60min, 20min are cooled to 40 DEG C, and bath raio is 1:10.
Further, the terylene washing methods after arrangement be with 0.1% dodecyl sodium sulfate clean 2 times, then use clean water 1 time.
The super-hydrophobic dacron that the present invention also provides a kind of said method to prepare, the contact angle of described super-hydrophobic dacron and water droplet is 155.5-162.0 °, and roll angle is less than 10 °.
Further, described roll angle is 7.5-9.0 °.
Beneficial effect of the present invention is: the preparation method of super-hydrophobic dacron of the present invention, and the dacron obtained inlays arrangement through the slightly soluble of aqueous emulsion of dimethyl polysiloxane fluid, imparts dacron ultra-hydrophobicity; The treatment technology of this dacron inlays arrangement by slightly soluble, water-fastness; The dacron water contact angle processed can reach more than 150.0 °, and 10 μ L water droplets tumble angle and are reduced to less than 10.0, reach super-hydrophobic standard; This super hydrophobic surface preparation process flow process is short; Easy large-scale production.
Accompanying drawing explanation
Figure 1 shows that reference dacron of the present invention surface Electronic Speculum figure.
Figure 2 shows that the dacron surface Electronic Speculum figure that the preparation method of the super-hydrophobic dacron of the present invention obtains.
Detailed description of the invention
Hereafter will describe the specific embodiment of the invention in detail in conjunction with concrete accompanying drawing.It should be noted that the combination of technical characteristic or the technical characteristic described in following embodiment should not be considered to isolated, they can mutually be combined thus be reached better technique effect.In the accompanying drawing of following embodiment, the identical label that each accompanying drawing occurs represents identical feature or parts, can be applicable in different embodiment.
Embodiment 1:
At normal temperatures, the sodium dodecyl sulfate aqueous solution 500mL of preparation 0.1%, then wherein cleans 25g dacron dipping, cleaning condition: 60 DEG C, 30min.Then with clear water washing, 60 DEG C of dry for standby.Normal temperature preparation aqueous emulsion of dimethyl polysiloxane fluid 300mL, dimethyl silicone polymer is 10g/L, fatty alcohol-polyoxyethylene ether 2.0g/L.Then pretreated 30g dacron be impregnated in above-mentioned solution, then in high temperature-pressure dyeing machine, carry out surperficial slightly soluble inlay arrangement.Setting technological parameter: be warming up to 130 DEG C, used time 30min; 60min is incubated at 130 DEG C; Lasting 20min makes temperature be down to 40 DEG C.This process bath raio is 1:10.Slightly soluble is inlayed after arrangement terminates, and the dodecyl sodium sulfate with 0.1% cleans 2 times, then with clear water washing, naturally dries and obtains hydrophobically modified dacron.When water droplet and clothing in contact 10s, reference dacron water contact angle is 89.3 °, and it is 56.7 ° that 10 μ L water droplets tumble angle; The super-hydrophobic dacron water contact angle of preparation is 157.4 °, and it is 8.5 ° that 10 μ L water droplets tumble angle.After washing 50 times, super-hydrophobic dacron water contact angle is 156.3 °, and it is 9.0 ° that 10 μ L water droplets tumble angle.
Embodiment 2:
At normal temperatures, the sodium dodecyl sulfate aqueous solution 500mL of preparation 0.1%, then wherein cleans 25g dacron dipping, cleaning condition: 60 DEG C, 30min.Then with clear water washing, 60 DEG C of dry for standby.Normal temperature preparation aqueous emulsion of dimethyl polysiloxane fluid 200mL, dimethyl silicone polymer is 20g/L, fatty alcohol-polyoxyethylene ether 4.0g/L.Then pretreated 20g dacron be impregnated in above-mentioned solution, then in high temperature-pressure dyeing machine, carry out surperficial slightly soluble inlay arrangement.Setting technological parameter: be warming up to 130 DEG C, used time 30min; 60min is incubated at 130 DEG C; Lasting 20min makes temperature be down to 40 DEG C.This process bath raio is 1:10.Slightly soluble is inlayed after arrangement terminates, and the dodecyl sodium sulfate cleaning cloth specimen with 0.1% 2 times, then with clear water washing, naturally dries and obtain hydrophobically modified dacron.When water droplet and clothing in contact 10s, reference dacron water contact angle is 89.3 °, and it is 56.7 ° that 10 μ L water droplets tumble angle; The super-hydrophobic dacron water contact angle of preparation is 158.6 °, and it is 7.2 ° that 10 μ L water droplets tumble angle.After washing 50 times, super-hydrophobic dacron water contact angle is 157.5 °, and it is 8.3 ° that 10 μ L water droplets tumble angle.
Embodiment 3:
At normal temperatures, the sodium dodecyl sulfate aqueous solution 500mL of preparation 0.1%, then wherein cleans 25g dacron dipping, cleaning condition: 60 DEG C, 30min.Then with clear water washing, 60 DEG C of dry for standby.Normal temperature preparation aqueous emulsion of dimethyl polysiloxane fluid 280mL, dimethyl silicone polymer concentration is 30g/L, fatty alcohol-polyoxyethylene ether 6.0g/L.Then respectively pretreated 28g dacron be impregnated in above-mentioned solution, then in high temperature-pressure dyeing machine, carry out surperficial slightly soluble inlay arrangement.Technological parameter: be warming up to 130 DEG C, used time 30min; 60min is incubated at 130 DEG C; Lasting 20min makes temperature be down to 40 DEG C.This process bath raio is 1:10.Slightly soluble is inlayed after arrangement terminates, and the dodecyl sodium sulfate cleaning cloth specimen with 0.1% 2 times, then with clear water washing, naturally dries and obtain hydrophobically modified dacron.When water droplet and clothing in contact 10s, reference dacron water contact angle is 89.3 °, and it is 56.7 ° that 10 μ L water droplets tumble angle; The water contact angle of the super-hydrophobic dacron of preparation is 163.4 °, and it is 7.0 ° that 10 μ L water droplets tumble angle.After washing 50 times, super-hydrophobic dacron water contact angle is 162.3 °, and it is 7.5 ° that 10 μ L water droplets tumble angle.
Embodiment 4:
At normal temperatures, the sodium dodecyl sulfate aqueous solution 500mL of preparation 0.1%, then wherein cleans 25g dacron dipping, cleaning condition: 60 DEG C, 30min.Then with clear water washing, 60 DEG C of dry for standby.Normal temperature preparation aqueous emulsion of dimethyl polysiloxane fluid 250mL, dimethyl silicone polymer concentration is 5g/L, fatty alcohol-polyoxyethylene ether 1.0g/L.Then the dacron of 25g after preliminary treatment be impregnated in above-mentioned solution, then in high temperature-pressure dyeing machine, carry out surperficial slightly soluble inlay arrangement.Technological parameter: be warming up to 130 DEG C, used time 30min; 60min is incubated at 130 DEG C; Lasting 20min makes temperature be down to 40 DEG C.This process bath raio is 1:10.Slightly soluble is inlayed after arrangement terminates, and the dodecyl sodium sulfate cleaning cloth specimen with 0.1% 2 times, then with clear water washing, naturally dries and obtain hydrophobically modified dacron.When water droplet and clothing in contact 10s, reference dacron water contact angle is 89.3 °, and it is 56.7 ° that 10 μ L water droplets tumble angle; The water contact angle of the super-hydrophobic dacron of preparation is 155.5 °, and it is 7.8 ° that 10 μ L water droplets tumble angle.After washing 50 times, super-hydrophobic dacron water contact angle is 154.3 °, and it is 8.5 ° that 10 μ L water droplets tumble angle.
Embodiment 5:
At normal temperatures, the sodium dodecyl sulfate aqueous solution 500mL of preparation 0.1%, then wherein cleans 25g dacron dipping, cleaning condition: 60 DEG C, 30min.Then with clear water washing, 60 DEG C of dry for standby.Normal temperature preparation aqueous emulsion of dimethyl polysiloxane fluid 300mL, dimethyl silicone polymer concentration is 30g/L, fatty alcohol-polyoxyethylene ether 6.0g/L.Then pretreated 30g dacron be impregnated in above-mentioned solution, then in high temperature-pressure dyeing machine, carry out surperficial slightly soluble inlay arrangement.Setting technological parameter: be warming up to 125 DEG C, used time 30min; 50min is incubated at 125 DEG C; Lasting 20min makes temperature be down to 40 DEG C.This process bath raio is 1:10.Slightly soluble is inlayed after arrangement terminates, and the dodecyl sodium sulfate cleaning cloth specimen with 0.1% 2 times, then with clear water washing, naturally dries and obtain hydrophobically modified dacron.When water droplet and clothing in contact 10s, reference dacron water contact angle is 89.3 °, and it is 56.7 ° that 10 μ L water droplets tumble angle; The water contact angle of the super-hydrophobic dacron of preparation is 160.7 °, and it is 7.1 ° that 10 μ L water droplets tumble angle.After washing 50 times, super-hydrophobic dacron water contact angle is 158.6 °, and it is 8.0 ° that 10 μ L water droplets tumble angle.
Embodiment 6:
At normal temperatures, the sodium dodecyl sulfate aqueous solution 500mL of preparation 0.1%, then wherein cleans 25g dacron dipping, cleaning condition: 60 DEG C, 30min.Then with clear water washing, 60 DEG C of dry for standby.Normal temperature preparation aqueous emulsion of dimethyl polysiloxane fluid 250mL, dimethyl silicone polymer concentration is 30g/L, fatty alcohol-polyoxyethylene ether 6g/L.Then pretreated 25g dacron be impregnated in above-mentioned solution, then in high temperature-pressure dyeing machine, carry out surperficial slightly soluble inlay arrangement.Technological parameter: be warming up to 120 DEG C, used time 30min; 40min is incubated at 120 DEG C; Lasting 20min makes temperature be down to 40 DEG C.This process bath raio is 1:10.Slightly soluble is inlayed after arrangement terminates, and the dodecyl sodium sulfate cleaning cloth specimen with 0.1% 2 times, then with clear water washing, naturally dries and obtain hydrophobically modified dacron.When water droplet and clothing in contact 10s, reference dacron water contact angle is 89.3 °, and it is 56.7 ° that 10 μ L water droplets tumble angle; The water contact angle of the super-hydrophobic dacron of preparation is 157.4 °, and it is 8.4 ° that 10 μ L water droplets tumble angle.After washing 50 times, super-hydrophobic dacron water contact angle is 156.2 °, and it is 8.8 ° that 10 μ L water droplets tumble angle.
As depicted in figs. 1 and 2, reference terylene smooth surface, there is pitting local, and fiber is square, and has corner angle; Adopt method of the present invention, after certain density aqueous emulsion of dimethyl polysiloxane fluid slightly soluble inlays arrangement, PET fiber surface is rounded, corner angle disappear, roughness significantly improves, simultaneously, raw surface layer obviously has loose structure, furthermore achieved that formation rough surface structure while reduction dacron surface free energy, thus obtain super-hydrophobic dacron.
The preparation method of super-hydrophobic dacron of the present invention, in high temperature high pressure process process, because dimethyl silicone polymer is in aqueous dispersed, easy diffusion and be adsorbed on PET fiber surface, and under high-temperature and high-pressure conditions, the large molecule polyester molecule chain generation chain movement of polyster fibre, make hydrophobic dimethyl silicone polymer can immerse PET fiber surface layer, produce slightly soluble, thus make this surface have certain fluidity, and produce mobile under aqueous solution External Force Acting, then produce rough surface.Simultaneously, under normal temperature condition, polyester macromolecule molecular chain movement stops, the dimethyl silicone polymer molecular moiety with low surface free energy is made to be embedded in PET fiber surface layer firmly, furthermore achieved that formation rough surface structure while reduction dacron surface free energy, thus obtain super-hydrophobic dacron.
The dacron that preparation method of the present invention obtains inlays arrangement through the slightly soluble of aqueous emulsion of dimethyl polysiloxane fluid, imparts dacron ultra-hydrophobicity; The treatment technology of this dacron inlays arrangement by slightly soluble, water-fastness; The dacron water contact angle processed can reach more than 150.0 °, and 10 μ L water droplets tumble angle and are reduced to less than 10.0, reach super-hydrophobic standard; This super hydrophobic surface preparation process flow process is short; Easy large-scale production.
Although give some embodiments of the present invention, it will be understood by those of skill in the art that without departing from the spirit of the invention herein, can change embodiment herein.Above-described embodiment is exemplary, should using embodiment herein as the restriction of interest field of the present invention.
Claims (8)
1. a preparation method for super-hydrophobic dacron, is characterized in that, gets dacron, preliminary treatment in sodium dodecyl sulfate solution, then with clear water washing, dries; Terylene after drying be impregnated in aqueous emulsion of dimethyl polysiloxane fluid, carry out slightly soluble and inlay arrangement, the terylene after arranging is washed, naturally dries, obtain super hydrophobic surface dacron.
2. preparation method as claimed in claim 1, it is characterized in that, described dodecyl sodium sulfate concentration is 0.1%, and described pretreatment condition is 60 DEG C of washing 30min.
3. as the preparation method that claim 1 obtains, it is characterized in that, described aqueous emulsion of dimethyl polysiloxane fluid comprises dimethyl silicone polymer and fatty alcohol-polyoxyethylene ether, and dimethyl silicone polymer and fatty alcohol-polyoxyethylene ether mass ratio are 5:1.
4. preparation method as claimed in claim 1, it is characterized in that, described slightly soluble inlays method for sorting for carry out slightly soluble damascene process in high temperature-pressure dyeing machine, treatment conditions for be warming up to 130 DEG C from normal temperature in 30min, insulation 60min, 20min are cooled to 40 DEG C, and bath raio is 1:10.
5. preparation method as claimed in claim 1, is characterized in that, the terylene washing methods after described arrangement be with 0.1% dodecyl sodium sulfate clean 2 times, then use clean water 1 time.
6. a super-hydrophobic dacron, is characterized in that, the contact angle of described super-hydrophobic dacron and water droplet is 155.5-162.0 °.
7. a kind of super-hydrophobic dacron as claimed in claim 6, is characterized in that, the roll angle of described super-hydrophobic dacron and water droplet is 7.5-9.0 °.
8. the super-hydrophobic dacron as described in any one of claim 6 or 7, is characterized in that, described super-hydrophobic dacron adopts the method for claim 1-5 to prepare.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106219995A (en) * | 2016-07-28 | 2016-12-14 | 华南理工大学 | A kind of free-floride, nontoxic, economy, the super hydrophobic material of environmental protection and one-step calcination preparation method thereof |
| CN107130435A (en) * | 2017-06-07 | 2017-09-05 | 苏州榕绿纳米科技有限公司 | A kind of synthesis of environmental protection fluorine-free hydrophobic film coating liuqid and method for sorting |
| CN109736080A (en) * | 2019-01-04 | 2019-05-10 | 广州中科检测技术服务有限公司 | A kind of superhydrophobic fabric and the preparation method and application thereof |
| CN111982738A (en) * | 2020-07-22 | 2020-11-24 | 石家庄海关技术中心 | Quantitative analysis method of cross-linked lyocell fibers and viscose fibers |
| CN112593456A (en) * | 2020-12-14 | 2021-04-02 | 盛秀群 | High-toughness decorative paper and preparation method thereof |
| CN113684689A (en) * | 2021-08-03 | 2021-11-23 | 扬州大学 | Preparation method of super-hydrophobic fabric based on emulsion impregnation and application of super-hydrophobic fabric in seawater desalination |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101545200A (en) * | 2009-05-04 | 2009-09-30 | 西南大学 | Method for endowing terylene with functional group by means of inlaying |
| CN102850890A (en) * | 2012-09-05 | 2013-01-02 | 江苏正泰医药化工有限公司 | Waterproof coating material |
| CN103088629A (en) * | 2012-12-18 | 2013-05-08 | 华南理工大学 | Method for carrying out super-hydrophobic modification on PET fabric surface |
| CN104372608A (en) * | 2014-11-12 | 2015-02-25 | 江南大学 | Method for preparing super-hydrophobic fabric by adopting sol-gel electrochemical deposition |
-
2015
- 2015-06-26 CN CN201510364147.3A patent/CN104963201A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101545200A (en) * | 2009-05-04 | 2009-09-30 | 西南大学 | Method for endowing terylene with functional group by means of inlaying |
| CN102850890A (en) * | 2012-09-05 | 2013-01-02 | 江苏正泰医药化工有限公司 | Waterproof coating material |
| CN103088629A (en) * | 2012-12-18 | 2013-05-08 | 华南理工大学 | Method for carrying out super-hydrophobic modification on PET fabric surface |
| CN104372608A (en) * | 2014-11-12 | 2015-02-25 | 江南大学 | Method for preparing super-hydrophobic fabric by adopting sol-gel electrochemical deposition |
Non-Patent Citations (1)
| Title |
|---|
| 薛朝华等: "PDMS基多孔网状涂层超疏水涤纶织物的制备及其性能研究", 《中国化学会第29届学术年会摘要集——第01分会：表面物理化学》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106219995A (en) * | 2016-07-28 | 2016-12-14 | 华南理工大学 | A kind of free-floride, nontoxic, economy, the super hydrophobic material of environmental protection and one-step calcination preparation method thereof |
| CN107130435A (en) * | 2017-06-07 | 2017-09-05 | 苏州榕绿纳米科技有限公司 | A kind of synthesis of environmental protection fluorine-free hydrophobic film coating liuqid and method for sorting |
| CN109736080A (en) * | 2019-01-04 | 2019-05-10 | 广州中科检测技术服务有限公司 | A kind of superhydrophobic fabric and the preparation method and application thereof |
| CN109736080B (en) * | 2019-01-04 | 2021-09-24 | 中科检测技术服务(广州)股份有限公司 | Super-hydrophobic fabric and preparation method and application thereof |
| CN111982738A (en) * | 2020-07-22 | 2020-11-24 | 石家庄海关技术中心 | Quantitative analysis method of cross-linked lyocell fibers and viscose fibers |
| CN112593456A (en) * | 2020-12-14 | 2021-04-02 | 盛秀群 | High-toughness decorative paper and preparation method thereof |
| CN113684689A (en) * | 2021-08-03 | 2021-11-23 | 扬州大学 | Preparation method of super-hydrophobic fabric based on emulsion impregnation and application of super-hydrophobic fabric in seawater desalination |
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Application publication date: 20151007 |