CN104372608A - Method for preparing super-hydrophobic fabric by adopting sol-gel electrochemical deposition - Google Patents
Method for preparing super-hydrophobic fabric by adopting sol-gel electrochemical deposition Download PDFInfo
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- CN104372608A CN104372608A CN201410635744.0A CN201410635744A CN104372608A CN 104372608 A CN104372608 A CN 104372608A CN 201410635744 A CN201410635744 A CN 201410635744A CN 104372608 A CN104372608 A CN 104372608A
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- fabric
- sol
- electrochemical deposition
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- weight portion
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a method for preparing a super-hydrophobic fabric by adopting sol-gel electrochemical deposition, and belongs to the technical field of spinning and chemical engineering. The method comprises the steps of preparing silane-modified hybridized sol containing a long hydrophobic chain, carrying out deposition on a fabric between a reaction electrode as a copper sheet and a counter electrode as a platinum sheet so as to enable hydrophobic components to be directionally arranged on the fabric, wherein the contact angle of the fabric can reach more than 160 degrees and the super-hydrophobic effect can be achieved. The method can be used for solving the problems of poor adhesion and cracking of a deposited film due to limited self-reaction driving force of a sol precursor; the deposited film has the adjustable thickness, residual liquid can be in recycled after being electrified, and no waste water is discharged; and besides, a nano-diamond component is added, the friction coefficient of the surface of the deposited film can be remarkably reduced, and the external force tolerance is improved; and furthermore, KNO3 and other electrolytes are not required to be added in the electrochemical process, so that the method is suitable for development of functional textiles.
Description
Technical field
Sol-gel electrochemical deposition prepares a method for superhydrophobic fabric, belongs to technical field of textile chemistry.
Background technology
The super-hydrophobicity of super hydrophobic material is realized by the lower surface energy of material surface and the coarse structure binary synergy of nano-scale, and the fields such as super hydrophobic material is anticorrosion at Liquid transfer, hull, liquid drag reduction, fluid storage have important application.Its preparation method mainly contains plasma etching method, template, Mechanical Method, phase separation method etc., but due to much preparation method's technique comparatively complicated, manufacturing equipment is expensive, and prepared material property is more unstable, is therefore not suitable for a large amount of industrial production.
Super hydrophobic material surface can be prepared by sol-gel process, by the SiO through hydrophobic treatments
2be dispersed in sol-gel precursor Deng inorganic nano-particle, and be sprayed on clean sheet glass or aluminium flake.By regulation and control nanoparticle content in the mixture and colloidal sol kind, surface and water drop static contact angle can be made to reach 160 °.But sol precursor autoreaction driving force is limited, often there is poor adhesive force so prepare sol pellicle by methods such as dip-coating, spraying and spin coatings, have the shortcomings such as slight crack, and film forming coatings is comparatively large to flexible material mechanical impact, is unwell to the flexible materials such as textiles, paper, polyethylene film.Electrochemical deposition method is the deposition modified important method of irregular material and flexible material, it combines with sol-gel technique and can be sol precursor system and provide additional hydrolysis and condensation reaction driving force, make the sol-gel films micropore of generation many, the connecting between micelle is good.
Patent CN201110352061.0 discloses a kind of method utilizing electrochemical deposition method to prepare super-hydrophobic super-oleophylic surface, first the silverskin of copper or copper alloy substrate surface formation micro nano structure will be electrochemically-deposited in, after modifying with ten dihydroxystearic acids again, the super-hydrophobic super-oleophylic surface of preparation, being 154 °-159 ° to the contact angle of water, is 0-5 ° to the contact angle of oil.In the method using the deposition substrate of electric conductivity directly as working electrode, limit the utilization of non-conducting material, and deposition after also need follow-up impregnation process, technique is more loaded down with trivial details.
Summary of the invention
The invention discloses a kind of method that sol-gel electrochemical deposition prepares superhydrophobic fabric, concrete technology is as follows:
1. the hydrophobic synthetic hybrid collosol liquid under acid catalysed conditions by sol precursor and hydrophobic silane coupling agent, and to dielectric fabric electrochemical deposition in bipolar electrode electrochemical system, give fabric super-hydrophobicity.
2. described in, the preparation method of hydrophobic hybrid collosol liquid is:
(1) take the sol precursor of 4-10 weight portion and the absolute ethyl alcohol of 15-35 weight portion and stir, and being added drop-wise at ambient temperature in the 0.2mol/L HCl of 55-75 weight portion, being prepared into sol solutions;
(2) be the Nano diamond of 200-500nm by the particle diameter of 1-8 weight portion be ultrasonic disperse 80min in 8-12% sulfonic group anion surfactant in the mass concentration of 92-99 weight portion, be prepared into nanodiamond liquid dispersion;
(3) nanodiamond liquid dispersion in 10-18 weight portion (2) is dropwise added drop-wise in the sol solutions in (1) of 82-90 weight portion, Quick uniform dispersion 3h, and with ammoniacal liquor regulation system pH to 4-5, is prepared into hybrid collosol liquid;
(4) in the hybrid collosol liquid of 88-96 weight portion, add the hydrophobic silane coupling agent of 4-12 weight portion, uniform stirring is abundant hydrolytic condensation also, obtains hydrophobic hybrid collosol liquid.
3. the sol precursor described in is at least one in tetraethyl orthosilicate, tetra-n-butyl titanate.
4. the hydrophobic silane coupling agent described in has following structure:
F
1—Si(OR)
3
Wherein R is CH
3-, CH
3cH
2-; F
1being hydrophobic grouping, can be CF
3(CF
2)
a(CH
2)
b-, CH
3(CH
2)
n-, γ-Cl (CH
2)
m-, Ph-, in formula, a, b, m, n are natural number, a and b can be 1 ~ 6; N can be 1 ~ 15; M can be 1 ~ 5;
5. the hydrophobic silane coupling agent described in can also have following structure:
F
1—Si(OR)
2—F
2
Wherein R is CH
3-, CH
3cH
2-; F
1and F
2being hydrophobic grouping, can be CF
3(CF
2)
a(CH
2)
b-, CH
3(CH
2)
n-, γ-Cl (CH
2)
m-, Ph-in one or both, in formula, a, b, m, n are natural number, a and b can be 1 ~ 6; N can be 1 ~ 15; M can be 1 ~ 5.
6. described in, fabric electrochemical deposition condition is voltage 3-20V, sedimentation time 1-15min, reaction electrode copper sheet area 4-20cm
2.
7., described in during fabric electrochemical deposition, fabric sample is vertically positioned between two electrodes, is beneficial to deposition uniformity.
8. the fabric described in can be COTTON FABRIC, silk fabrics, wool fabric, viscose fiber fabric, dacron, nylon fabric and BLENDED FABRIC thereof.
The micro-nano feature structure that modified fabric surface deposition one deck of preparing of this technology is made up of fabric fibre fold and inorganic oxide (silica or titanium dioxide) and Nano diamond, simultaneously under the synergy of silane coupler hydrophobic chain, make can reach more than 160 ° to water contact angle.Due to the existence of Nano diamond, deposited film is strengthened with fiber Tuberculous under electrochemical action, significantly reduces the coefficient of friction of fiber surface simultaneously, the ABRASION RESISTANCE of deposited film is strengthened.The hydrophobic hybrid collosol liquid prepared in this invention has that electrochemical deposition experiment condition is easy to control, depositing temperature is low, depositing device is simple, be easy to realize the advantages such as suitability for industrialized production, the method breaches electrochemical deposition only to the restriction of conductive substrate effect simultaneously, without the need to fabric is fixed on the working electrode (s, do not need in electrolyte to add KNO yet
3increase electric conductivity Deng salt, enormously simplify treatment process.
Accompanying drawing explanation
Fig. 1 is the schematic diagram that a kind of sol-gel electrochemical deposition of the present invention prepares superhydrophobic fabric, and in figure, 1 is constant-voltage DC source; 2 is Nano diamond; 3 for containing hydrophobic chain sol ingredient; 4 is copper reaction electrode; 5 is hydrophobic hybrid collosol liquid; 6 is fabric; 7 is platinum electrode.
Detailed description of the invention
To contribute to further understanding the present invention by following embodiment, but content of the present invention can not be limited.
Embodiment 1
Take the tetraethyl orthosilicate of 6 weight portions and the absolute ethyl alcohol of 30 weight portions and stir, and being added drop-wise at ambient temperature in the 0.2mol/L HCl of 64 weight portions, being prepared into sol solutions; Be the Nano diamond of 250nm by the particle diameter of 6 weight portions be ultrasonic disperse 80min in 10% heptadecyl benzimidazole sodium sulfonate in the mass concentration of 94 weight portions, be prepared into nanodiamond liquid dispersion; 10 weight portion nanodiamond liquid dispersions are dropwise added drop-wise in 90 weight portion sol solutionses, Quick uniform dispersion 3h, and with ammoniacal liquor regulation system pH to 5, are prepared into hybrid collosol liquid; In the hybrid collosol liquid of 90 weight portions, add the octyltri-ethoxysilane coupling agent of 10 weight portions, uniform stirring is abundant hydrolytic condensation also, obtains hydrophobic hybrid collosol liquid.
Vertically be positioned over by pure cotton woven fabric between bipolar electrode electrochemical system two electrode, be beneficial to deposition uniformity, electrochemical deposition condition is voltage 8V, sedimentation time 8min, reaction electrode copper sheet area 6cm
2.
Fabric sample water contact angle after electrochemical deposition is 164.5 °, achieves fabric super-hydrophobicity, and has excellent rub resistance.
Embodiment 2
Take the tetra-n-butyl titanate of 4 weight portions and the absolute ethyl alcohol of 35 weight portions and stir, and being added drop-wise at ambient temperature in the 0.2mol/L HCl of 61 weight portions, being prepared into sol solutions; Be the Nano diamond of 400nm by the particle diameter of 1 weight portion be ultrasonic disperse 80min in 11% nekal in the mass concentration of 99 weight portions, be prepared into nanodiamond liquid dispersion; 15 weight portion nanodiamond liquid dispersions are dropwise added drop-wise in 85 weight portion sol solutionses, Quick uniform dispersion 3h, and with ammoniacal liquor regulation system pH to 4, are prepared into hybrid collosol liquid; In the hybrid collosol liquid of 92 weight portions, add the MTES of 8 weight portions, uniform stirring is abundant hydrolytic condensation also, obtains hydrophobic hybrid collosol liquid.
Vertically be positioned over by polyester-cotton blend woven fabric between bipolar electrode electrochemical system two electrode, be beneficial to deposition uniformity, electrochemical deposition condition is voltage 12V, sedimentation time 12min, reaction electrode copper sheet area 10cm
2.
Fabric sample water contact angle after electrochemical deposition is 163.7 °, achieves fabric super-hydrophobicity, and has excellent rub resistance.
Embodiment 3
Take the tetraethyl orthosilicate of 10 weight portions and the absolute ethyl alcohol of 30 weight portions and stir, and being added drop-wise at ambient temperature in the 0.2mol/L HCl of 60 weight portions, being prepared into sol solutions; Be the Nano diamond of 550nm by the particle diameter of 5 weight portions be ultrasonic disperse 80min in 12%N-oleoyl-N N-methyltaurine sodium in the mass concentration of 95 weight portions, be prepared into nanodiamond liquid dispersion; 13 weight portion nanodiamond liquid dispersions are dropwise added drop-wise in 87 weight portion sol solutionses, Quick uniform dispersion 3h, and with ammoniacal liquor regulation system pH to 4, are prepared into hybrid collosol liquid; In the hybrid collosol liquid of 93 weight portions, add the dodecyl triethoxysilane of 7 weight portions, uniform stirring is abundant hydrolytic condensation also, obtains hydrophobic hybrid collosol liquid.
Vertically be positioned over by interlock machine fabric between bipolar electrode electrochemical system two electrode, be beneficial to deposition uniformity, electrochemical deposition condition is voltage 6V, sedimentation time 13min, reaction electrode copper sheet area 12cm
2.
Fabric sample water contact angle after electrochemical deposition is 161.8 °, achieves fabric super-hydrophobicity, and has excellent rub resistance.
Embodiment 4
Take the tetraethyl orthosilicate of 7 weight portions and the absolute ethyl alcohol of 32 weight portions and stir, and being added drop-wise at ambient temperature in the 0.2mol/L HCl of 57 weight portions, being prepared into sol solutions; Be the Nano diamond of 500nm by the particle diameter of 2 weight portions be ultrasonic disperse 80min in 8% Aerosol OT in the mass concentration of 98 weight portions, be prepared into nanodiamond liquid dispersion; 11 weight portion nanodiamond liquid dispersions are dropwise added drop-wise in 89 weight portion sol solutionses, Quick uniform dispersion 3h, and with ammoniacal liquor regulation system pH to 5, are prepared into hybrid collosol liquid; In the hybrid collosol liquid of 94 weight portions, add the 3-chlorine third class triethoxysilane of 6 weight portions, uniform stirring is abundant hydrolytic condensation also, obtains hydrophobic hybrid collosol liquid.
Vertically be positioned over by Woven Polyester Fabrics between bipolar electrode electrochemical system two electrode, be beneficial to deposition uniformity, electrochemical deposition condition is voltage 15V, sedimentation time 7min, reaction electrode copper sheet area 10cm
2.
Fabric sample water contact angle after electrochemical deposition is 160.2 °, achieves fabric super-hydrophobicity, and has excellent rub resistance.
Embodiment 5
Take the tetra-n-butyl titanate of 4.5 weight portions and the absolute ethyl alcohol of 38 weight portions and stir, and being added drop-wise at ambient temperature in the 0.2mol/L HCl of 57.5 weight portions, being prepared into sol solutions; Be the Nano diamond of 350nm by the particle diameter of 3.5 weight portions be ultrasonic disperse 80min in 10% neopelex in the mass concentration of 96.5 weight portions, be prepared into nanodiamond liquid dispersion; 13 weight portion nanodiamond liquid dispersions are dropwise added drop-wise in 87 weight portion sol solutionses, Quick uniform dispersion 3h, and with ammoniacal liquor regulation system pH to 4.5, are prepared into hybrid collosol liquid; In the hybrid collosol liquid of 96 weight portions, add the hexadecyl of 4 weight portions, uniform stirring is abundant hydrolytic condensation also, obtains hydrophobic hybrid collosol liquid.
Vertically be positioned over by polyester-cotton blend woven fabric between bipolar electrode electrochemical system two electrode, be beneficial to deposition uniformity, electrochemical deposition condition is voltage 18V, sedimentation time 10min, reaction electrode copper sheet area 18cm
2.
Fabric sample water contact angle after electrochemical deposition is 169.2 °, achieves fabric super-hydrophobicity, and has excellent rub resistance.
Claims (8)
1. a sol-gel electrochemical deposition prepares the method for superhydrophobic fabric, it is characterized in that the hybrid collosol liquid under acid catalysed conditions by sol precursor and hydrophobic silane coupling agent, simultaneously with nanodiamond liquid dispersion to its modification, be prepared into hydrophobic hybrid collosol liquid; To dielectric fabric electrochemical deposition in bipolar electrode electrochemical system, give fabric super-hydrophobicity and ABRASION RESISTANCE.
2. a kind of sol-gel electrochemical deposition as claimed in claim 1 prepares the method for superhydrophobic fabric, it is characterized in that the preparation method of described hydrophobic hybrid collosol liquid is:
(1) take the sol precursor of 4-10 weight portion and the absolute ethyl alcohol of 15-35 weight portion and stir, and being added drop-wise at ambient temperature in the 0.2mol/L HCl of 55-75 weight portion, being prepared into sol solutions;
(2) be the Nano diamond of 200-500nm by the particle diameter of 1-8 weight portion be ultrasonic disperse 80min in 8-12% sulfonic group anion surfactant in the mass concentration of 92-99 weight portion, be prepared into nanodiamond liquid dispersion;
(3) nanodiamond liquid dispersion in 10-18 weight portion (2) is dropwise added drop-wise in the sol solutions in (1) of 82-90 weight portion, Quick uniform dispersion 3h, and with ammoniacal liquor regulation system pH to 4-5, is prepared into hybrid collosol liquid;
(4) in the hybrid collosol liquid of 88-96 weight portion, add the hydrophobic silane coupling agent of 4-12 weight portion, uniform stirring is abundant hydrolytic condensation also, obtains hydrophobic hybrid collosol liquid.
3. a kind of sol-gel electrochemical deposition as claimed in claim 1 prepares the method for superhydrophobic fabric, it is characterized in that described sol precursor is at least one in tetraethyl orthosilicate, tetra-n-butyl titanate.
4. a kind of sol-gel electrochemical deposition as claimed in claim 1 prepares the method for superhydrophobic fabric, it is characterized in that described hydrophobic silane coupling agent has following structure:
F
1—Si(OR)
3
Wherein R is CH
3-, CH
3cH
2-; F
1being hydrophobic grouping, can be CF
3(CF
2)
a(CH
2)
b-, CH
3(CH
2)
n-, γ-Cl (CH
2)
m-, Ph-, in formula, a, b, m, n are natural number, a and b can be 1 ~ 6; N can be 1 ~ 15; M can be 1 ~ 5.
5. a kind of sol-gel electrochemical deposition as claimed in claim 1 prepares the method for superhydrophobic fabric, it is characterized in that described hydrophobic silane coupling agent can also have following structure:
F
1—Si(OR)
2—F
2
Wherein R is CH
3-, CH
3cH
2-; F
1and F
2being hydrophobic grouping, can be CF
3(CF
2)
a(CH
2)
b-, CH
3(CH
2)
n-, γ-Cl (CH
2)
m-, Ph-in one or both, in formula, a, b, m, n are natural number, a and b can be 1 ~ 6; N can be 1 ~ 15; M can be 1 ~ 5.
6. a kind of sol-gel electrochemical deposition as claimed in claim 1 prepares the method for superhydrophobic fabric, it is characterized in that described fabric electrochemical deposition condition is voltage 3-20V, sedimentation time 1-15min, reaction electrode copper sheet area 4-20cm2.
7. a kind of sol-gel electrochemical deposition as claimed in claim 1 prepares the method for superhydrophobic fabric, and when it is characterized in that described fabric electrochemical deposition, fabric sample is vertically positioned between two electrodes, is beneficial to deposition uniformity.
8. a kind of sol-gel electrochemical deposition as claimed in claim 1 prepares the method for superhydrophobic fabric, it is characterized in that described fabric can be COTTON FABRIC, silk fabrics, wool fabric, viscose fiber fabric, dacron, nylon fabric and BLENDED FABRIC thereof.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410635744.0A CN104372608B (en) | 2014-11-12 | 2014-11-12 | Method for preparing super-hydrophobic fabric through sol-gel electrochemical deposition |
| PCT/CN2014/001118 WO2016074113A1 (en) | 2014-11-12 | 2014-12-12 | Method for preparing super-hydrophobic fabric by sol-gel electrochemical deposition |
Applications Claiming Priority (1)
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|---|---|---|---|
| CN201410635744.0A CN104372608B (en) | 2014-11-12 | 2014-11-12 | Method for preparing super-hydrophobic fabric through sol-gel electrochemical deposition |
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| CN104372608A true CN104372608A (en) | 2015-02-25 |
| CN104372608B CN104372608B (en) | 2020-10-23 |
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| WO (1) | WO2016074113A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104963201A (en) * | 2015-06-26 | 2015-10-07 | 西南大学 | Method for preparing super-hydrophobic dacron fabric |
| CN105780468A (en) * | 2016-03-28 | 2016-07-20 | 北京易净星科技有限公司 | Super-hydrophobic fabric and preparation method thereof |
| CN113564918A (en) * | 2021-07-05 | 2021-10-29 | 东莞理工学院 | Janus fabric with liquid drop one-way permeability and preparation method thereof |
| CN114426809A (en) * | 2022-02-17 | 2022-05-03 | 上海映智研磨材料有限公司 | Silicon oxide modified nano diamond abrasive particles and preparation method and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3974562A1 (en) * | 2020-09-28 | 2022-03-30 | Imec VZW | Electrochemical process for forming a solid electrolyte |
Citations (1)
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| CN102409527A (en) * | 2011-10-20 | 2012-04-11 | 浙江理工大学 | Plasma finishing method for endowing fabric durable super-hydrophobic property |
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| GB750805A (en) * | 1952-07-19 | 1956-06-20 | Rhone Poulenc Sa | Improvements in or relating to waterproffing processes and materials |
| CN102493180A (en) * | 2011-12-15 | 2012-06-13 | 江南大学 | Method for preparing water repellent fabric |
| CN103114436B (en) * | 2013-03-08 | 2014-12-10 | 天津微能新材料有限公司 | Super-hydrophobic fabric preparation method and super-hydrophobic functional fabric |
| CN103147281B (en) * | 2013-03-08 | 2014-12-17 | 天津微能新材料有限公司 | Super-hydrophobic fabric preparation method and super-hydrophobic functional fabric |
| CN103599735B (en) * | 2013-11-25 | 2016-05-25 | 江南大学 | A kind of ion doping TiO that improves fabric hydrophilic-hydrophobic wetting conversion rate2Colloidal sol preparation method |
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- 2014-11-12 CN CN201410635744.0A patent/CN104372608B/en active Active
- 2014-12-12 WO PCT/CN2014/001118 patent/WO2016074113A1/en active Application Filing
Patent Citations (1)
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| CN102409527A (en) * | 2011-10-20 | 2012-04-11 | 浙江理工大学 | Plasma finishing method for endowing fabric durable super-hydrophobic property |
Non-Patent Citations (1)
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| LIAN-KUI WU ETAL: "One step sol-gel electrochemistry for the fabrication of superhydrophobic surfaces", 《JOURNAL MATERIALS CHEMISTRY A》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104963201A (en) * | 2015-06-26 | 2015-10-07 | 西南大学 | Method for preparing super-hydrophobic dacron fabric |
| CN105780468A (en) * | 2016-03-28 | 2016-07-20 | 北京易净星科技有限公司 | Super-hydrophobic fabric and preparation method thereof |
| CN105780468B (en) * | 2016-03-28 | 2019-02-19 | 北京易净星科技有限公司 | Superhydrophobic fabric and preparation method thereof |
| CN113564918A (en) * | 2021-07-05 | 2021-10-29 | 东莞理工学院 | Janus fabric with liquid drop one-way permeability and preparation method thereof |
| CN113564918B (en) * | 2021-07-05 | 2023-08-04 | 东莞理工学院 | Janus fabric with unidirectional permeability of liquid drops and preparation method thereof |
| CN114426809A (en) * | 2022-02-17 | 2022-05-03 | 上海映智研磨材料有限公司 | Silicon oxide modified nano diamond abrasive particles and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104372608B (en) | 2020-10-23 |
| WO2016074113A1 (en) | 2016-05-19 |
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