CN113774663A - Continuous spunbonded adhesive filament oil agent composition and preparation method thereof - Google Patents
Continuous spunbonded adhesive filament oil agent composition and preparation method thereof Download PDFInfo
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- CN113774663A CN113774663A CN202111087513.7A CN202111087513A CN113774663A CN 113774663 A CN113774663 A CN 113774663A CN 202111087513 A CN202111087513 A CN 202111087513A CN 113774663 A CN113774663 A CN 113774663A
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- continuous
- starch
- fatty acid
- composition
- oil agent
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- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 23
- 239000000853 adhesive Substances 0.000 title claims description 8
- 230000001070 adhesive effect Effects 0.000 title claims description 8
- 238000002360 preparation method Methods 0.000 title abstract description 7
- -1 polyoxyethylene Polymers 0.000 claims abstract description 22
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 16
- 239000000194 fatty acid Substances 0.000 claims abstract description 16
- 229930195729 fatty acid Natural products 0.000 claims abstract description 16
- 229920000570 polyether Polymers 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920006320 anionic starch Polymers 0.000 claims abstract description 11
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 16
- 229920002472 Starch Polymers 0.000 claims description 14
- 239000008107 starch Substances 0.000 claims description 14
- 235000019698 starch Nutrition 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract description 12
- 229920000297 Rayon Polymers 0.000 abstract description 8
- 238000009941 weaving Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000009987 spinning Methods 0.000 abstract description 4
- 238000004043 dyeing Methods 0.000 abstract description 3
- 238000007730 finishing process Methods 0.000 abstract description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 12
- 238000004513 sizing Methods 0.000 description 9
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000001294 propane Substances 0.000 description 6
- 239000003292 glue Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an oil solution composition for continuous spinning viscose filament yarns and a preparation method thereof, wherein the total weight of the oil solution is taken as a reference, and the oil solution comprises the following components in percentage by weight: 5-20% of nonionic gemini surfactant, 5-30% of ethylene oxide-propylene oxide random polyether, 10-20% of fatty acid polyoxyethylene ester, 10-40% of anionic starch and 40-70% of deionized water, wherein the deionized water is heated to 40-70% according to the weight percentage, the anionic starch is added and stirred for 10-30 minutes, then the nonionic gemini surfactant, the ethylene oxide-propylene oxide random polyether and the fatty acid polyoxyethylene ester are added and mixed and stirred for 30-60 minutes, and the continuous spunbonded filament oil agent composition is obtained. The oil agent prepared by the invention is not sticky to the roller, can endow viscose fiber with higher cohesive force and smoothness, achieves excellent weaving effect, is easy to desize and dye in the downstream dyeing and finishing process, is environment-friendly, has no pollution, and is easy to degrade.
Description
Technical Field
The invention relates to the field of chemical oil, in particular to a continuous spunbonded filament oil composition and a preparation method thereof.
Background
The sizing agent is a sizing agent which enables monofilaments to be cohered together in the production process of fibers to endow the fibers with certain cohesiveness, so that the fibers have less broken filaments and less stumbled filaments, the wear resistance is enhanced, the strength is stable, the fibers are stretched stably, the sizing agent is mixed with other oil agents to endow the fibers with smoothness and antistatic property, the fibers coated with sizing agent can ensure that the fibers are not damaged in the weaving process and the weaving stability is improved, and the sizing agent mainly used in the current market comprises polyvinyl alcohol, polyacrylic acid, carboxymethyl cellulose and the like. Although the sizing agent can meet the requirement in production, the polyvinyl alcohol sizing agent is not easy to degrade, has large environmental protection pressure and is forbidden to be used in some European countries, the polyacrylic acid sizing agent has large moisture regain, is easy to adhere and difficult to unwind in high-temperature and high-humidity weather, and the carboxymethyl starch is environment-friendly but has high price. The novel sizing agent-containing continuous spunbonded filament yarn oil agent is developed, has better cohesive force and softness for viscose fibers, is very soft after being woven into a cloth cover, can achieve the best weaving effect, is easy to desize and dye in the downstream dyeing and finishing process, is environment-friendly, pollution-free and easy to degrade.
Disclosure of Invention
The invention provides an oil solution composition for continuously spinning viscose filaments and a preparation method thereof, aiming at the prior art.
The invention provides the following technical scheme: the continuous spunbonded filament oil composition comprises the following components in percentage by mass:
5% -20% of nonionic gemini surfactant;
5 to 30 percent of ethylene oxide-propylene oxide random polyether;
10-20% of polyoxyethylene fatty acid ester;
10-40% of anionic starch;
0 to 70 percent of deionized water.
Preferably, the structural formula of the nonionic gemini surfactant is shown as follows,
wherein n is 8 to 40.
Preferably, the ethylene oxide-propylene oxide random polyether has a molecular weight of 500-3000, and the molar ratio of ethane to propane EO/PO is 1-9.
Preferably, the structural formula of the polyoxyethylene fatty acid ester is RCOO (EO)nH, wherein R is C8～C22N is 12 to 50;
preferably, the anionic starch is one or more of carboxymethyl starch, maleic acid monoester starch and sulfate starch;
heating deionized water to 40-70 ℃, adding anionic starch, stirring for 10-30 minutes, then adding a nonionic gemini surfactant, ethylene oxide-propylene oxide random polyether and fatty acid polyoxyethylene ester, mixing and stirring for 30-60 minutes to obtain the continuous spunbonded adhesive filament oil composition.
In conclusion, the beneficial technical effects of the invention are as follows:
the continuous spunbonded filament oil composition has the advantages of short process flow and simple preparation. The viscose fiber yarn spinning solution is used in the viscose fiber filament yarn spinning process, has a non-stick roller, endows viscose fiber with better cohesive force, softness and smoothness, can achieve good weaving effect, is easy to desize and dye in the downstream dyeing and finishing process, is environment-friendly, has no pollution, and is easy to degrade.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it should be apparent that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The continuous spunbonded filament oil composition comprises the following components in percentage by mass:
5% -20% of nonionic gemini surfactant;
5 to 30 percent of ethylene oxide-propylene oxide random polyether;
10-20% of polyoxyethylene fatty acid ester;
10-40% of anionic starch;
0 to 70 percent of deionized water.
Preferably, the structural formula of the nonionic gemini surfactant is shown as follows,
wherein n is 8 to 40.
The ethylene oxide-propylene oxide random polyether has a molecular weight of 500-3000, and the molar ratio of ethylene to propylene EO/PO is 1-9.
The structural formula of the polyoxyethylene fatty acid ester is RCOO (EO)nH, wherein R is C8～C22N is 12 to 50;
the anionic starch is one or more of carboxymethyl starch, maleic acid monoester starch and sulfate starch;
heating deionized water to 40-70 ℃, adding anionic starch, stirring for 10-30 minutes, then adding a nonionic gemini surfactant, ethylene oxide-propylene oxide random polyether and fatty acid polyoxyethylene ester, mixing and stirring for 30-60 minutes to obtain the continuous spunbonded adhesive filament oil composition.
Example 1
The continuous spunbonded glue filament oil agent composition is prepared from the following raw materials in percentage by mass: heating 50% deionized water to 60 deg.C, adding 25% carboxymethyl starch, stirring for 20 min, and adding 5% nonionic gemini surfactant, wherein n is 12, 8% ethylene oxide-propylene oxide random polyether, molecular weight is 1500, and molar ratio of ethane to propane EO/PO is 2, 12% C10H23COO(EO)16And mixing and stirring the H fatty acid polyoxyethylene ester for 30 minutes to obtain the continuous spunbonded filament oil composition.
Example 2
The continuous spunbonded glue filament oil agent composition is prepared from the following raw materials in percentage by mass: heating 60% deionized water to 60 deg.C, adding 20% maleic acid monoester starchPowdering, stirring for 15 min, and adding 7% of nonionic gemini surfactant, wherein n is 20, 5% ethylene oxide-propylene oxide random polyether, molecular weight is 2800, and molar ratio of ethane to propane EO/PO is 6, 8% of C18H37COO(EO)26And mixing and stirring the H fatty acid polyoxyethylene ester for 50 minutes to obtain the continuous spunbonded filament oil composition.
Example 3
The continuous spunbonded glue filament oil agent composition is prepared from the following raw materials in percentage by mass: heating 45% deionized water to 50 deg.C, adding 25% sulfate starch, stirring for 15 min, and adding 10% nonionic gemini surfactant, wherein n is 26, 8% ethylene oxide-propylene oxide random polyether, molecular weight is 1200, and molar ratio of ethane to propane EO/PO is 4, 7% C12H25COO(EO)14And mixing and stirring the H fatty acid polyoxyethylene ester for 50 minutes to obtain the continuous spunbonded filament oil composition.
Example 4
The continuous spunbonded glue filament oil agent composition is prepared from the following raw materials in percentage by mass: heating 35% deionized water to 50 deg.C, adding 30% sulfate starch, stirring for 15 min, and adding 15% nonionic gemini surfactant, wherein n is 26, 10% ethylene oxide-propylene oxide random polyether, molecular weight is 1200, and molar ratio of ethane to propane EO/PO is 4, 10% C12H25COO(EO)14And mixing and stirring the H fatty acid polyoxyethylene ester for 50 minutes to obtain the continuous spunbonded filament oil composition.
Example 5
The continuous spunbonded glue filament oil agent composition is prepared from the following raw materials in percentage by mass: heating 35% deionized water to 50 deg.C, adding 30% sulfate starch, stirring for 15 min, and adding 10% nonionic gemini surfactant, wherein n is 30, 20% ethylene oxide-propylene oxide random polyether, molecular weight is 1000, and molar ratio of ethane to propane EO/PO is 4, 5% C12H25COO(EO)14H greaseAnd mixing and stirring fatty acid polyoxyethylene ester for 50 minutes to obtain the continuous spunbonded filament oil composition.
The oil solutions prepared in the above examples 1 to 5 are respectively dissolved in deionized water to prepare a working solution with a concentration of 60g/L, and the viscose filament yarn is oiled. The treated silk strips are smooth and soft, have good cohesion and have no silk breakage phenomenon.
In conclusion, the continuous spunbonded filament oil composition has the advantages of simple preparation process, high quality and low price, and can meet the requirements of domestic and foreign markets.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (6)
1. The continuous spunbonded filament oil agent composition is characterized in that the oil agent composition is prepared by mixing the following components in percentage by weight based on the total weight of the oil agent:
5% -10% of nonionic gemini surfactant;
5 to 30 percent of ethylene oxide-propylene oxide random polyether;
10-20% of polyoxyethylene fatty acid ester;
10-40% of anionic starch;
10 to 70 percent of deionized water.
2. The continuous spunbond adhesive filament finish composition of claim 1, wherein: the structural formula of the nonionic gemini surfactant is shown as follows,
wherein n is 8 to 40.
3. The continuous spunbond adhesive filament finish composition of claim 1, wherein: the ethylene oxide-propylene oxide random polyether has a molecular weight of 500-3000, and the molar ratio of ethylene to propylene EO/PO is 1-9.
4. The continuous spunbond adhesive filament finish composition of claim 1, wherein: the structural formula of the polyoxyethylene fatty acid ester is RCOO (EO)nH, wherein R is C8～C22N is 12 to 50.
5. The continuous spunbond adhesive filament finish composition of claim 1, wherein: the anionic starch is one or more of carboxymethyl starch, maleic acid monoester starch and sulfate starch.
6. A process for preparing a continuous spunbond filament finish composition as set forth in any one of claims 1-5, wherein: heating the deionized water to 40-70 ℃, adding the anionic starch, stirring for 10-30 minutes, then adding the nonionic gemini surfactant, the ethylene oxide-propylene oxide random polyether and the fatty acid polyoxyethylene ester, and mixing and stirring for 30-60 minutes to obtain the continuous spunbonded filament oil composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111087513.7A CN113774663A (en) | 2021-09-16 | 2021-09-16 | Continuous spunbonded adhesive filament oil agent composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111087513.7A CN113774663A (en) | 2021-09-16 | 2021-09-16 | Continuous spunbonded adhesive filament oil agent composition and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN113774663A true CN113774663A (en) | 2021-12-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111087513.7A Pending CN113774663A (en) | 2021-09-16 | 2021-09-16 | Continuous spunbonded adhesive filament oil agent composition and preparation method thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114381943A (en) * | 2022-01-13 | 2022-04-22 | 沈阳浩博实业有限公司 | Continuous spunbonded adhesive filament oil composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106012539A (en) * | 2016-06-30 | 2016-10-12 | 沈阳工业大学 | Water-soluble spinning finish for viscose filament continuous spinning |
| CN106498741A (en) * | 2016-09-23 | 2017-03-15 | 沈阳浩博实业有限公司 | A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn |
| CN112411185A (en) * | 2019-08-21 | 2021-02-26 | 浙江华孚色纺有限公司 | Modified cellulose fiber, environment-friendly blended yarn and fabric |
-
2021
- 2021-09-16 CN CN202111087513.7A patent/CN113774663A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106012539A (en) * | 2016-06-30 | 2016-10-12 | 沈阳工业大学 | Water-soluble spinning finish for viscose filament continuous spinning |
| CN106498741A (en) * | 2016-09-23 | 2017-03-15 | 沈阳浩博实业有限公司 | A kind of environment-friendly type finish and preparation method thereof for continuously spinning viscose filament yarn |
| CN112411185A (en) * | 2019-08-21 | 2021-02-26 | 浙江华孚色纺有限公司 | Modified cellulose fiber, environment-friendly blended yarn and fabric |
Non-Patent Citations (1)
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| 邓艳 等: "阴离子淀粉研究进展", 《大众科技》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114381943A (en) * | 2022-01-13 | 2022-04-22 | 沈阳浩博实业有限公司 | Continuous spunbonded adhesive filament oil composition |
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Application publication date: 20211210 |