CN106444269B - The method for improving high speed blue printing paper developing rate - Google Patents
The method for improving high speed blue printing paper developing rate Download PDFInfo
- Publication number
- CN106444269B CN106444269B CN201610742828.3A CN201610742828A CN106444269B CN 106444269 B CN106444269 B CN 106444269B CN 201610742828 A CN201610742828 A CN 201610742828A CN 106444269 B CN106444269 B CN 106444269B
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- CN
- China
- Prior art keywords
- printing paper
- high speed
- blue printing
- developing rate
- acid
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/305—Additives other than developers
Abstract
The present invention provides a kind of method for improving high speed blue printing paper developing rate.The method for improving high speed blue printing paper developing rate is added in the photosensitive liquid of high speed blue printing paper, nitrogenous heterocyclic ketones derivant is mainly pentacyclic ketones derivant using nitrogenous heterocyclic ketones derivant as aobvious agent is promoted.Blue printing paper photosensitive liquid provided by the invention can have the stronger novel rush for promoting aobvious effect and influencing the blue printing paper shelf-life to show agent to high speed paper.
Description
Technical field
The invention belongs to blue printing paper technical field more particularly to a kind of methods for improving high speed blue printing paper developing rate.
Background technique
Blue printing paper is international photocopying materials.When manufacture, to improve its technical performance, various help will generally be added
Agent.Wherein, promoting aobvious agent is then the composition that must add.
The previous rush for middling speed (film speed) blue printing paper (hereinafter referred to as " middling speed paper ") shows agent, and type is a lot of, such as benzene
Base phosphoric acid, phenyl hypophosphorous acid and phenyl sulfinic acid, there are also thiourea derivative, polyalcohols, crown ether-like, domestic there are also AD agent etc..
And the aobvious agent of rush for being used for high speed blue printing paper (referred to as " high speed paper ") is very few.
The rush for being commonly used to high speed paper both at home and abroad shows agent, and trade name is " HI ", the entitled caprolactam of chemistry
(Caprolactam).Although it has the aobvious effect of rush, maximum disadvantage is exactly the shelf-life for being easy to influence blue printing paper.That is: exist
In the defined shelf-life, product goes bad because being coupled in advance.There are many producers in the country, therefore suffers larger economic loss.
Summary of the invention
The technical issues of agent is easy the shelf-life of influence blue printing paper is shown in order to solve above-mentioned rush, the present invention provides one kind can
There is the aobvious effect of stronger rush to high speed paper, and does not influence the method for the raising high speed blue printing paper developing rate of blue printing paper shelf-life.
The method provided by the invention for improving high speed blue printing paper developing rate, using nitrogenous heterocyclic ketones derivant as rush
Aobvious agent, is added in the photosensitive liquid of high speed blue printing paper, and nitrogenous heterocyclic ketones derivant is mainly pentacyclic ketones derivant, this
The general structure of analog derivative are as follows:
In formula: R1, R2, R3=-H ,-CH3 ,-CH3-OH, ET-OH；
The photosensitive liquid includes emulsion, coupling agent and other auxiliary agents, and the emulsion is FB, FE diazonium salt photosensitive
Agent, the coupling agent are AP-m, and the auxiliary agent includes citric acid, boric acid, FB solubilizer, thiocarbamide, zinc oxide, catalyst, saponin
And acid lake blue.
In the method a kind of preferred embodiment provided by the invention for improving high speed blue printing paper developing rate, the nitrogen-containing hetero
The ketones derivant of ring is 3,5 diketone of 1,2,4- triazolidinyl.
It is described to promote aobvious agent in the method a kind of preferred embodiment provided by the invention for improving high speed blue printing paper developing rate
Amount ranges be blue printing paper photosensitive liquid total amount 0.5-3% (w/v).
In the method a kind of preferred embodiment provided by the invention for improving high speed blue printing paper developing rate, the emulsion
For to alkyl or hydroxyalkyl aniline diazonium zine chloride double salt, or contraposition saturated heterocyclyl, ortho position or adjacent meta position alkoxy diazonium
Zinc chloride or thiocyanic acid double salt.
In the method a kind of preferred embodiment provided by the invention for improving high speed blue printing paper developing rate, FB diazonium salt,
Matter between citric acid, boric acid, FB solubilizer, AP-M, thiocarbamide, zinc oxide, catalyst, ethylene glycol, saponin, acid lake blue and water
Amount ratio is 12:15:10:20:18:30:10:20:25:0.2:0.1:1000.
The method of raising high speed blue printing paper developing rate of the invention has the following beneficial effects:
Due to promoting the catalytic action of active group in aobvious agent, the reaction rate of azo component is improved, to accelerate high speed
The developing powder of paper.Simultaneously as development is sufficiently, dye hues saturation, so that lines seem bright-coloured pleasing.Raising of the invention
The method of high speed blue printing paper developing rate, which has high speed paper, promotees the gorgeous dual function of aobvious increasing, and it is reliable to promote effective fruit.Especially
When winter low temperature, it can guarantee that solarization is smoked and synchronize.The chemical property of this product is stablized, non-toxic, to people's fanout free region, to the various of blue printing paper
Performance also has no adverse effects.Using the high speed paper of this product, when processing replicates, the ammonia and electric power of development can be saved, improves blueprint
Efficiency has good social benefit.It is easy to operate when using this product ingredient, it is easily compatible with the various compositions of photosensitive liquid, point
It dissipates uniform.This product all uses domestic raw material, inexpensive easy purchase, and synthesis technology and condition be not severe, and yield is higher, can give birth in batches
It produces, cost is relatively low.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The method 1 for improving high speed blue printing paper developing rate adds using nitrogenous heterocyclic ketones derivant as aobvious agent is promoted
In the photosensitive liquid for entering high speed blue printing paper, nitrogenous heterocyclic ketones derivant is mainly pentacyclic ketones derivant, described photosensitive
Liquid includes emulsion, coupling agent and other auxiliary agents, and the emulsion is FB, FE diazonium salt sensitizer, and the coupling agent is AP-
M, the auxiliary agent include citric acid, boric acid, FB solubilizer, thiocarbamide, zinc oxide, catalyst, saponin and acid lake blue.
The general structure of this analog derivative are as follows:
In formula: R1, R2, R3=-H ,-CH3 ,-CH3-OH, ET-OH.
The nitrogenous heterocyclic ketones derivant is 3,5 diketone of 1,2,4- triazolidinyl.The amount ranges for promoting aobvious agent
For the 0.5-3% (w/v) of blue printing paper photosensitive liquid total amount.
The emulsion is to alkyl or hydroxyalkyl aniline diazonium zine chloride double salt, or contraposition saturated heterocyclyl, ortho position
Or adjacent meta position alkoxy diazonium zinc chloride or thiocyanic acid double salt.
FB diazonium salt, citric acid, boric acid, FB solubilizer, AP-M, thiocarbamide, zinc oxide, catalyst, ethylene glycol, saponin, acid
Property acid blue and water between mass ratio be 12:15:10:20:18:30:10:20:25:0.2:0.1:1000.
Specifically, the present invention implements example:
The photosensitive formula of liquid of high speed
| Raw material | Control group | Experimental group |
| FB diazonium salt (emulsion) | 12 grams | 12 grams |
| Citric acid | 15 grams | 15 grams |
| Boric acid | 10 grams | 10 grams |
| FB solubilizer | 20 grams | 20 grams |
| AP-M (coupling agent) | 18 grams | 18 grams |
| Thiocarbamide | 30 grams | 30 grams |
| Zinc chloride | 10 grams | 10 grams |
| TZ agent | 20 grams | |
| Ethylene glycol | 25 grams | 25 grams |
| Saponin | 0.2 gram | 0.2 gram |
| Acid lake blue | 0.1 gram | 0.1 gram |
| 40 DEG C of pure water | 1000 milliliters | 1000 milliliters |
The above solution coating is on body paper, after drying, carries out development effect test.
Test condition: ammonia concn 5%, temperature 20%, developing time 2 seconds.
The method of raising high speed blue printing paper developing rate of the invention has the following beneficial effects:
Due to promoting the catalytic action of active group in aobvious agent, the reaction rate of azo component is improved, to accelerate high speed
The developing powder of paper.Simultaneously as development is sufficiently, dye hues saturation, so that lines seem bright-coloured pleasing.Raising of the invention
The method of high speed blue printing paper developing rate, which has high speed paper, promotees the gorgeous dual function of aobvious increasing, and it is reliable to promote effective fruit.Especially
When winter low temperature, it can guarantee that solarization is smoked and synchronize.The chemical property of this product is stablized, non-toxic, to people's fanout free region, to the various of blue printing paper
Performance also has no adverse effects.Using the high speed paper of this product, when processing replicates, the ammonia and electric power of development can be saved, improves blueprint
Efficiency has good social benefit.It is easy to operate when using this product ingredient, it is easily compatible with the various compositions of photosensitive liquid, point
It dissipates uniform.This product all uses domestic raw material, inexpensive easy purchase, and synthesis technology and condition be not severe, and yield is higher, can give birth in batches
It produces, cost is relatively low.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (5)
1. it is a kind of improve high speed blue printing paper developing rate method, which is characterized in that using nitrogenous heterocyclic ketones derivant as
Promoting aobvious agent, is added in the photosensitive liquid of high speed blue printing paper, nitrogenous heterocyclic ketones derivant is mainly pentacyclic ketones derivant,
The general structure of this analog derivative are as follows:
In formula: R1, R2, R3=-H ,-CH3 ,-CH3-OH, ET-OH；
The photosensitive liquid includes emulsion, coupling agent and other auxiliary agents, and the emulsion is FB, FE diazonium salt sensitizer, institute
Stating coupling agent is AP-m, and the auxiliary agent includes citric acid, boric acid, FB solubilizer, thiocarbamide, zinc oxide, catalyst, saponin and acidity
Acid blue.
2. the method according to claim 1 for improving high speed blue printing paper developing rate, which is characterized in that the nitrogen-containing heterocycle
Ketones derivant be 3,5 diketone of 1,2,4- triazolidinyl.
3. the method according to claim 1 for improving high speed blue printing paper developing rate, which is characterized in that described to promote to show agent
Amount ranges are the 0.5-3% (w/v) of blue printing paper photosensitive liquid total amount.
4. the method according to claim 1 for improving high speed blue printing paper developing rate, which is characterized in that the emulsion is
To alkyl or hydroxyalkyl aniline diazonium zine chloride double salt, or contraposition saturated heterocyclyl, ortho position or adjacent meta position alkoxy diazonium chlorine
Change zinc or thiocyanic acid double salt.
5. the method according to claim 1 for improving high speed blue printing paper developing rate, which is characterized in that FB diazonium salt, lemon
Quality between lemon acid, boric acid, FB solubilizer, AP-M, thiocarbamide, zinc oxide, catalyst, ethylene glycol, saponin, acid lake blue and water
Ratio is 12:15:10:20:18:30:10:20:25:0.2:0.1:1000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610742828.3A CN106444269B (en) | 2016-08-26 | 2016-08-26 | The method for improving high speed blue printing paper developing rate |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610742828.3A CN106444269B (en) | 2016-08-26 | 2016-08-26 | The method for improving high speed blue printing paper developing rate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106444269A CN106444269A (en) | 2017-02-22 |
| CN106444269B true CN106444269B (en) | 2019-09-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610742828.3A Expired - Fee Related CN106444269B (en) | 2016-08-26 | 2016-08-26 | The method for improving high speed blue printing paper developing rate |
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Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6984476B2 (en) * | 2002-04-15 | 2006-01-10 | Sharp Kabushiki Kaisha | Radiation-sensitive resin composition, forming process for forming patterned insulation film, active matrix board and flat-panel display device equipped with the same, and process for producing flat-panel display device |
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- 2016-08-26 CN CN201610742828.3A patent/CN106444269B/en not_active Expired - Fee Related
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