CN106433935A - Monel 400 alloy cold upsetting technology lubricant composition - Google Patents

Monel 400 alloy cold upsetting technology lubricant composition Download PDF

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Publication number
CN106433935A
CN106433935A CN201610841104.4A CN201610841104A CN106433935A CN 106433935 A CN106433935 A CN 106433935A CN 201610841104 A CN201610841104 A CN 201610841104A CN 106433935 A CN106433935 A CN 106433935A
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monel
agent
alloy cold
lubricant compositions
cold heading
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黄福川
陈彪
唐弓斌
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Guangxi University
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14Synthetic waxes, e.g. polythene waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/14Metal deactivation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a Monel 400 alloy cold upsetting technology lubricant composition. The Monel 400 alloy cold upsetting technology lubricant composition is prepared by adopting 68# total loss system oil as base oil and cooperating with multiple composite additives including an antioxidant, a metal deactivator, an oiliness agent, a friction modifier, an extreme pressure agent, an antiwear agent, an anti-foaming agent, an anti-emulsifying agent, an antirust agent, an adhesive, a filling agent, a dispersing agent and the like. The composition has the advantages that the good bearing wear resistance, extrusion resistance (galling and pulling are not generated, and the service life of a punching die is effectively prolonged), low-temperature flow diffusibility, lubricity and cooling property are achieved, the oil film strength is high, the oil film thickness keeps stable, no foreign smell is generated, and the skin is not irritated; the smooth finish is improved, the surfaces of machined parts are prevented from being corroded or oxidized, power energy consumption is reduced, the low-temperature fluidity, the foaming resistance, the emulsifying resistance and the thermal oxidation stability are good, precipitates and paint films are reduced, and molded parts are easy to clean.

Description

A kind of Monel 400 alloy cold heading technique lubricant compositions
Technical field
The invention belongs to metal working lubricant field, particularly to a kind of Monel 400 alloy cold heading technique lubricant Compositionss.
Background technology
Monel metal also known as nickel alloy, a kind of copper is added for matrix with metallic nickel, ferrum, other elements such as manganese form Alloy.Monel metal good corrosion resistance, is silvery white in color, and is suitable as side wire material.
The single phase solid solution being organized as high intensity of Monel 400 alloy, single phase austenite organize, it be a kind of consumption Greatly, the corrosion resistant alloy that purposes is the widest, combination property is splendid.This alloy has excellent anti-corrosion in Fluohydric acid. and fluorine gas medium Property, also there is excellent corrosion resistance to hot concentrated alkali liquid.The corruption of also resistance to neutral solution, water, sea water, air, organic compound etc. simultaneously Erosion.One key character of this alloy is typically not produce stress corrosion cracking (SCC), and cutting ability is good.
Cold-heading processing is the forging method at normal temperatures metal bar material jumping-up (often for gathering stock) being shaped using mould. Cold-heading is another form of upsetting.More metal mold becomes theoretical, applies certain pressure to metal stock at normal temperatures, It is allowed to be deformed in die cavity.Shape by the shape and size of regulation.Cold heading technique is widely used in middle finding and various The standard component of type.
Cold heading technique be mainly characterized by no machining, stock utilization is high, and utilization rate reaches 80~90%, and metal material Stream line will not be cut off, and therefore product intensity is higher than machining or casting part strength, in certain batch life Under the conditions of product, cold-heading processing cost more much lower than other processing costs it is adaptable to typically require cutting members and securing member etc. The Product processing of symmetrical shape.The dimensional accuracy of product, weight accuracy and mechanical property etc. are attained by higher requirement.
Lubricant requires to have the special feature that:Good carrying wear resistence, Squeezing ground (not plucking, pull, effectively extend punch die Service life), low temperature flow diffusibility, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, Do not stimulate skin etc..Improve fineness, protect part to be processed surface not corrosion and oxidation, reduce power consumption, low temperature flow Property good, good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, reduce the generation of precipitate and paint film, profiled member easy cleaning.
Content of the invention
The technical problem to be solved in the present invention is that offer is a kind of has good carrying wear resistence, Squeezing ground, low temperature flow Diffusibility, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin, can improve bright and clean Degree, protect part to be processed surface not corrosion and oxidation, minimizing power consumption, and low temperature flow is good, good anti-foaming property, anti-breast The property changed, thermal oxide are qualitative good, reduce the generation of precipitate and paint film, the Monel 400 alloy cold heading technique of profiled member easy cleaning Lubricant compositions.
The present invention employs the following technical solutions solution above-mentioned technical problem:
A kind of Monel 400 alloy cold heading technique lubricant compositions, based on No. 68 total loss system oil Oil, coordinates multiple compound additives, and the one-tenth of its respective mass percent is grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.03%~0.05%
Metal deactivator 0.05%~0.2%
Oiliness improver 2%~4%
Friction improver 2%~4%
Extreme pressure agent 2%~3%
Antiwear additive 3%~5%
Anti-foaming agent 10~50ppm
Anti- Emulsion 0.1%~0.3%
Antirust agent 0.05%~0.08%
Adhesive agent 3%~6%
Filler 3%~5%
Dispersant 1%~3%
Each constituent mass percentage ratio summation is 100% above.
Antioxidant is the 2,6- di-t-butyl mixed ester T502A of mass ratio 50% and 50% the answering of cupric antioxidant T543 Close;
Metal deactivator is benzotriazole derivant T551.
Oiliness improver is soybean oil.
Friction improver is oleic acid glycol ester T403B;Extreme pressure agent is acid dibutyl phosphite T304.
Antiwear additive is chlorinated paraffin T301;Anti-foaming agent is methyl-silicone oil T901.
Anti- Emulsion is polyethers macromolecular compound DL-32.
Antirust agent is the lanoline of mass ratio 67% and 33% benzotriazole T706 is combined.
Adhesive agent is ethylene-propylene copolymer T613;Filler is semi-refined paraffin wax 60.
Dispersant is polyisobutene succinimide T154.
The beneficial effects of the present invention is:The present composition has good carrying wear resistence, Squeezing ground, low temperature flow Diffusibility, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin, can improve bright and clean Degree, protect part to be processed surface not corrosion and oxidation, minimizing power consumption, and low temperature flow is good, good anti-foaming property, anti-breast The property changed, thermal oxide is qualitative good, reduces the generation of precipitate and paint film, profiled member easy cleaning.
Specific embodiment
Embodiment 1:
Following component is in harmonious proportion by mass percentage and forms:
Component Mass percentage content
No. 68 total loss system oil Surplus
The 2,6- di-t-butyl mixed ester T502A of mass ratio 50% and 50% cupric antioxidant T543 is combined 0.05%
Benzotriazole derivant (T551) 0.05%
Soybean oil 2%
Oleic acid glycol ester (T403B) 3%
Acid dibutyl phosphite (T304) 3%
Chlorinated paraffin (T301) 3%
Methyl-silicone oil (T901) 30ppm
Polyethers macromolecular compound (DL-32) 0.3%
The lanoline of mass ratio 67% and 33% benzotriazole (T706) be combined 0.08%
Ethylene-propylene copolymer (T613) 3%
Semi-refined paraffin wax 60 3%
Polyisobutene succinimide (T154) 3%
Each constituent mass percentage ratio summation is equal to 100% above.
Embodiment 2:
Following component is in harmonious proportion by mass percentage and forms:
Component Mass percentage content
No. 68 total loss system oil Surplus
The 2,6- di-t-butyl mixed ester T502A of mass ratio 50% and 50% cupric antioxidant T543 is combined 0.04%
Benzotriazole derivant (T551) 0.05%
Soybean oil 3%
Oleic acid glycol ester (T403B) 2%
Acid dibutyl phosphite (T304) 2%
Chlorinated paraffin (T301) 3%
Methyl-silicone oil (T901) 40ppm
Polyethers macromolecular compound (DL-32) 0.2%
The lanoline of mass ratio 67% and 33% benzotriazole (T706) be combined 0.08%
Ethylene-propylene copolymer (T613) 5%
Semi-refined paraffin wax 60 5%
Polyisobutene succinimide (T154) 1%
Each constituent mass percentage ratio summation is equal to 100% above.
Embodiment 3:
Following component is in harmonious proportion by mass percentage and forms:
Component Mass percentage content
No. 68 total loss system oil Surplus
The 2,6- di-t-butyl mixed ester T502A of mass ratio 50% and 50% cupric antioxidant T543 is combined 0.04%
Benzotriazole derivant (T551) 0.15%
Soybean oil 2.5%
Oleic acid glycol ester (T403B) 4%
Acid dibutyl phosphite (T304) 2.5%
Chlorinated paraffin (T301) 3%
Methyl-silicone oil (T901) 20ppm
Polyethers macromolecular compound (DL-32) 0.15%
The lanoline of mass ratio 67% and 33% benzotriazole (T706) be combined 0.07%
Ethylene-propylene copolymer (T613) 6%
Semi-refined paraffin wax 60 3.5%
Polyisobutene succinimide (T154) 1.5%
Each constituent mass percentage ratio summation is equal to 100% above.
Embodiment 3 product typical technology index:
Project Index
40 DEG C of kinematic viscosity mm2/s 73.3
Flash-point (opening)/DEG C 236
Pour point/DEG C -11
Coefficient of viscosity 97
Corrosion testing (copper sheet, 100 DEG C, 3h)/level 1
Coefficient of friction 0.08
Oxidation stability (Rotary Oxygen elasticity, 150 DEG C) min 246
Tetra-ball machine test Pb/N 795
Foaming characteristics test:24℃ 150/0
96℃ 80/0
24 DEG C afterwards 80/0
FZG, level 14
Mechanical admixture, % 0.009
Moisture, % Vestige
Evaporation loss (Angelika Noack method, 250 DEG C, 1h) (m) % 11
Water-soluble acid and alkali No
Sintering load PD/N 7520

Claims (9)

1. a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that:Using No. 68 total loss system oil Based on oil, coordinate multiple compound additives, the one-tenth of its respective mass percent is grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.03%~0.05% Metal deactivator 0.05%~0.2% Oiliness improver 2%~4% Friction improver 2%~4% Extreme pressure agent 2%~3% Antiwear additive 3%~5% Anti-foaming agent 10~50ppm Anti- Emulsion 0.1%~0.3% Antirust agent 0.05%~0.08% Adhesive agent 3%~6% Filler 3%~5% Dispersant 1%~3%
Each constituent mass percentage ratio summation is 100% above.
2. as claimed in claim 1 a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that antioxidant Be the 2,6- di-t-butyl mixed ester T502A of mass ratio 50% and 50% cupric antioxidant T543 compound;Metal deactivator It is benzotriazole derivant T551.
3. as claimed in claim 1 a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that oiliness improver It is soybean oil.
4. a kind of Monel 400 alloy cold heading technique lubricant compositions change it is characterised in that rubbing as claimed in claim 1 Entering agent is oleic acid glycol ester T403B;Extreme pressure agent is acid dibutyl phosphite T304.
5. as claimed in claim 1 a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that antiwear additive is Chlorinated paraffin T301;Anti-foaming agent is methyl-silicone oil T901.
6. as claimed in claim 1 a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that anti-Emulsion It is polyethers macromolecular compound DL-32.
7. as claimed in claim 1 a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that antirust agent It is the lanoline of mass ratio 67% and 33% benzotriazole T706 is combined.
8. as claimed in claim 1 a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that adhesive agent It is ethylene-propylene copolymer T613;Filler is semi-refined paraffin wax 60.
9. as claimed in claim 1 a kind of Monel 400 alloy cold heading technique lubricant compositions it is characterised in that dispersant It is polyisobutene succinimide T154.
CN201610841104.4A 2016-09-21 2016-09-21 Monel 400 alloy cold upsetting technology lubricant composition Pending CN106433935A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103627483A (en) * 2013-11-04 2014-03-12 广西大学 Lubricating agent for middle cold rolling of vanadium and vanadium alloy plate strip thereof
CN103725381A (en) * 2013-12-18 2014-04-16 广西大学 Lubricant for cold forging of carbon steel and low alloy steel materials
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN105482873A (en) * 2015-11-30 2016-04-13 诺泰生物科技(合肥)有限公司 Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103627483A (en) * 2013-11-04 2014-03-12 广西大学 Lubricating agent for middle cold rolling of vanadium and vanadium alloy plate strip thereof
CN103725381A (en) * 2013-12-18 2014-04-16 广西大学 Lubricant for cold forging of carbon steel and low alloy steel materials
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN105482873A (en) * 2015-11-30 2016-04-13 诺泰生物科技(合肥)有限公司 Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王九 等: "《石油产品添加剂基础知识》", 31 October 2009, 中国石化出版社 *

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