CN106433934A - Lubricating agent composition for zirconium alloy cold upsetting technology - Google Patents

Lubricating agent composition for zirconium alloy cold upsetting technology Download PDF

Info

Publication number
CN106433934A
CN106433934A CN201610841088.9A CN201610841088A CN106433934A CN 106433934 A CN106433934 A CN 106433934A CN 201610841088 A CN201610841088 A CN 201610841088A CN 106433934 A CN106433934 A CN 106433934A
Authority
CN
China
Prior art keywords
agent
zircaloy
cold heading
lubricant compositions
heading technique
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610841088.9A
Other languages
Chinese (zh)
Inventor
黄福川
唐弓斌
陈帆
陈一帆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201610841088.9A priority Critical patent/CN106433934A/en
Publication of CN106433934A publication Critical patent/CN106433934A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbasedsulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/14—Metal deactivation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18—Anti-foaming property

Abstract

The invention discloses a zirconium alloy lubricating agent composition through a cold upsetting technology. Castor-based dioctyl sebacate with a mass ratio being 10-20% and an HVI 90BS base oil with a mass ratio being 80-90% are compounded to serve as a base oil, and various composite additives are used for being coordinated with the base oil to prepare the lubricating agent composition, wherein the composite additives comprise an antioxidant, a metal deactivator, an oiliness agent, a friction modifier, an antirust agent, an extreme pressure agent, an antiwear agent, an anti-foaming agent, a dispersing agent, an adhesive agent, a reinforcing agent and an oxidation and corrosion inhibitor. The composition has good bearing wear resistance, squeezing property, low temperature flow diffusibility, lubricating property and cooling property, and is high in oil film strength, free of peculiar smell, and good in low temperature fluidity, foam resistance, emulsion resistance and thermal oxidation stability; moreover, the composition does not stimulate the skin, keeps the oil film thickness stable, protects the surface of processed parts from corrosion and oxidation, reduces the power consumption, reduces the production of precipitates and paint films and can improve the finish degree, and formed parts are easy to clean.

Description

A kind of zircaloy cold heading technique lubricant compositions
Technical field
The invention belongs to metal working lubricant field, particularly to a kind of zircaloy cold heading technique lubricant compositions.
Background technology
Zircaloy can resistance to very high temperature, as make nuclear reaction ground floor containment vessel.The thermal capture of zirconium cuts Face is little, has prominent nuclearity energy, is the development indispensable material of atomic energy industry, adds other elements composition with zirconium for base Alloy, is the refractory metal material that a class is widely used in nuclear reactor.Zirconium powder easy firing in atmosphere, can make detonating primer and nothing Pyrotechnic composition.Zirconium is a kind of rare metal, has the spies such as surprising corrosion resistance, high fusing point, the hardness of superelevation and intensity Property, it is widely used in Aero-Space, military project, nuclear reaction, atomic energy field.The plasticity of zirconium good it is easy to be processed into plate, silk etc.. Zirconium can absorb the gases such as oxygen, hydrogen, nitrogen in large quantities in heating, can be used as hydrogen storage material.
Cold-heading processing is the forging method at normal temperatures metal bar material jumping-up (often for gathering stock) being shaped using mould. Cold-heading is another form of upsetting.More metal mold becomes theoretical, applies certain pressure to metal stock at normal temperatures, It is allowed to be deformed in die cavity.Shape by the shape and size of regulation.Cold heading technique is widely used in middle finding and various The standard component of type.
Cold heading technique be mainly characterized by no machining, stock utilization is high, and utilization rate reaches 80～90%, and metal material Stream line will not be cut off, and therefore product intensity is higher than machining or casting part strength, in certain batch life Under the conditions of product, cold-heading processing cost more much lower than other processing costs it is adaptable to typically require cutting members and securing member etc. The Product processing of symmetrical shape.The dimensional accuracy of product, weight accuracy and mechanical property etc. are attained by higher requirement.
Lubricant should have the special feature that：Good carrying wear resistence, Squeezing ground (not plucking, pull, effectively extend punch die Service life), low temperature flow diffusibility, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, no Stimulate skin etc..Improve fineness, protect part to be processed surface not corrosion and oxidation, reduce power consumption, low temperature flow Well, good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, reduce the generation of precipitate and paint film, profiled member easy cleaning.
Content of the invention
The technical problem to be solved in the present invention is that offer is a kind of has good carrying wear resistence, Squeezing ground, low temperature flow Diffusibility, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin, can improve bright and clean Degree, protect part to be processed surface not corrosion and oxidation, minimizing power consumption, and low temperature flow is good, good anti-foaming property, anti-breast The property changed, thermal oxide are qualitative good, reduce the generation of precipitate and paint film, the zircaloy cold heading technique lubricant group of profiled member easy cleaning Compound.
The present invention employs the following technical solutions solution above-mentioned technical problem：
A kind of zircaloy cold heading technique lubricant compositions, using the Semen Ricini base SA dioctyl ester of mass ratio 10～20% With 90～80% HVI 90BS base oil be combined based on oil, coordinate multiple compound additives, its respective mass percent One-tenth be grouped into：
Component Mass percentage content
Base oil Surplus
Antioxidant 0.05%～0.4%
Metal deactivator 0.05%～0.2%
Oiliness improver 4%～5%
Friction improver 2%～3%
Antirust agent 0.05%～0.3%
Extreme pressure agent 3%～4%
Antiwear additive 3%～5%
Anti-foaming agent 30～50ppm
Dispersant 3%～4%
Adhesive agent 2%～6%
Reinforcing agent 2%～3%
Oxidation and corrosion inhibitor 0.5%～1.2%
Each constituent mass percentage ratio summation is 100% above.
Antioxidant is dinonyldiphenylamine T558 of mass ratio 33% and 67% DBPC 2,6 ditertiary butyl p cresol T501 Compound；Metal deactivator is benzotriazole derivant T551.
Oiliness improver is sulfurized olefin cotton oil T405.
Friction improver is sulfur molybdenum phosphate T462；Antirust agent is the benzotriazole T706 of mass ratio 50% and 50% alkane Base phosphoric acid
Imidazoline salt T708 is combined.
Extreme pressure agent is tricresyl phosphate T306.
Antiwear additive is chlorinated paraffin T502；Anti-foaming agent is acrylic acid and ether copolymer T912.
Dispersant is polybutene succinimide T161.
Adhesive agent is ethylene-propylene copolymer T613A.
Reinforcing agent is high base number calcium mahogany sulfonate T103；Oxidation and corrosion inhibitor is sulfur phosphorus fourth octyl group zinc salt T202.
The beneficial effects of the present invention is：Zircaloy cold heading technique lubricant of the present invention have good carrying wear resistence, Squeezing ground (not plucking, the service life pulled, effectively extend punch die), low temperature flow diffusibility, lubricity, cooling, oil film Intensity is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin etc..Improve fineness, protection part to be processed surface is stainless Erosion and aoxidizing, reduces power consumption, low temperature flow is good, and good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, and it is heavy to reduce Starch and the generation of paint film, profiled member easy cleaning,
Specific embodiment
Embodiment 1：
Following component is in harmonious proportion by mass percentage and forms：
Component Mass percentage content
The Semen Ricini base SA dioctyl ester of mass ratio 20% and 80%HVI 90BS base oil are combined Surplus
Dinonyldiphenylamine T558 of mass ratio 33% and 67% DBPC 2,6 ditertiary butyl p cresol T501 be combined 0.3%
Benzotriazole derivant (T551) 0.2%
Sulfurized olefin cotton oil (T405) 4%
Sulfur molybdenum phosphate (T462) 3%
The benzotriazole (T706) of mass ratio 50% and 50% alkyl phosphoric acid imidazoline salt (T708) be combined 0.3%
Tricresyl phosphate (T306) 3%
Chlorinated paraffin (T502) 3%
Acrylic acid and ether copolymer (T912) 40ppm
Polybutene succinimide (T161) 3%
Ethylene-propylene copolymer (T613A) 3%
High base number calcium mahogany sulfonate (T103) 3%
Sulfur phosphorus fourth octyl group zinc salt (T202) 1.2%
Each constituent mass percentage ratio summation is 100% above.
Embodiment 2：
Following component is in harmonious proportion by mass percentage and forms：
Component Mass percentage content
Mass ratio 15% Semen Ricini base SA dioctyl ester and 85% HVI 90BS base oil be combined Surplus
Dinonyldiphenylamine T558 of mass ratio 33% and 67% DBPC 2,6 ditertiary butyl p cresol T501 be combined 0.1%
Benzotriazole derivant (T551) 0.1%
Sulfurized olefin cotton oil (T405) 4%
Sulfur molybdenum phosphate (T462) 2.5%
The benzotriazole (T706) of mass ratio 50% and 50% alkyl phosphoric acid imidazoline salt (T708) be combined 0.2%
Tricresyl phosphate (T306) 3.5%
Chlorinated paraffin (T502) 3.5%
Acrylic acid and ether copolymer (T912) 30ppm
Polybutene succinimide (T161) 3.5%
Ethylene-propylene copolymer (T613A) 2%
High base number calcium mahogany sulfonate (T103) 2%
Sulfur phosphorus fourth octyl group zinc salt (T202) 0.8%
Each constituent mass percentage ratio summation is 100% above.
Embodiment 3：
Following component is in harmonious proportion by mass percentage and forms：
Component Mass percentage content
The Semen Ricini base SA dioctyl ester of mass ratio 15% and 85% HVI 90BS base oil be combined Surplus
Dinonyldiphenylamine T558 of mass ratio 33% and 67% DBPC 2,6 ditertiary butyl p cresol T501 be combined 0.05%
Benzotriazole derivant (T551) 0.05%
Sulfurized olefin cotton oil (T405) 4.5%
Sulfur molybdenum phosphate (T462) 2%
The benzotriazole T706 of mass ratio 50% and 50% alkyl phosphoric acid imidazoline salt T708 be combined 0.05%
Tricresyl phosphate (T306) 3%
Chlorinated paraffin (T502) 3.5%
Acrylic acid and ether copolymer (T912) 50ppm
Polybutene succinimide (T161) 3.2%
Ethylene-propylene copolymer (T613A) 3.5%
High base number calcium mahogany sulfonate (T103) 3%
Sulfur phosphorus fourth octyl group zinc salt (T202) 0.5%
Each constituent mass percentage ratio summation is 100% above.
Embodiment 1 product typical technology index：
Project Index
40 DEG C of kinematic viscosity mm2/s 212.5
Flash-point (opening)/DEG C 266
Pour point/DEG C -8
Coefficient of viscosity 121
Corrosion testing (copper sheet, 100 DEG C, 3h)/level 1
Coefficient of friction 0.07
Oxidation stability (Rotary Oxygen elasticity, 150 DEG C) min 251
Extreme pressure property (tetra-ball machine test) Pb/N 925
Sintering load PD/N 5500
Terraced nurse agrees/N 292
Mechanical admixture/% No
Water soluble acid or alkali No
Moisture Vestige
FZG, level 13

Claims (9)

1. a kind of zircaloy cold heading technique lubricant compositions it is characterised in that：Semen Ricini base certain herbaceous plants with big flowers using mass ratio 10～20% Adipate and 90～80% HVI 90BS base oil be combined based on oil, coordinate multiple compound additives, it is each The one-tenth of mass percent is grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.05%～0.4% Metal deactivator 0.05%～0.2% Oiliness improver 4%～5% Friction improver 2%～3% Antirust agent 0.05%～0.3% Extreme pressure agent 3%～4% Antiwear additive 3%～5% Anti-foaming agent 30～50ppm Dispersant 3%～4% Adhesive agent 2%～6% Reinforcing agent 2%～3% Oxidation and corrosion inhibitor 0.5%～1.2%
Each constituent mass percentage ratio summation is 100% above.
2. as claimed in claim 1 a kind of zircaloy cold heading technique lubricant compositions it is characterised in that antioxidant is quality Dinonyldiphenylamine T558 than 33% and 67% DBPC 2,6 ditertiary butyl p cresol T501 compound；Metal deactivator is benzene three Zole derivatives T551.
3. as claimed in claim 1 a kind of zircaloy cold heading technique lubricant compositions it is characterised in that oiliness improver be sulfuration Alkene Oleum Gossypii semen T405.
4. as claimed in claim 1 a kind of zircaloy cold heading technique lubricant compositions it is characterised in that friction improver is Sulfur molybdenum phosphate T462；Antirust agent is the benzotriazole T706 of mass ratio 50% and 50% alkyl phosphoric acid imidazoline salt T708 answers Close.
5. as claimed in claim 1 a kind of zircaloy cold heading technique lubricant compositions it is characterised in that extreme pressure agent is phosphoric acid Front three phenolic ester T306.
6. as claimed in claim 1 a kind of zircaloy cold heading technique lubricant compositions it is characterised in that antiwear additive is chlorination Paraffin T502；Anti-foaming agent is acrylic acid and ether copolymer T912.
7. as claimed in claim 1 a kind of zircaloy cold heading technique lubricant compositions it is characterised in that dispersant is poly- fourth Alkene succimide T161.
8. a kind of zircaloy cold heading technique lubricant compositions described in claim 1 it is characterised in that adhesive agent be second third altogether Polymers T613A.
9. as claimed in claim 1 a kind of zircaloy cold heading technique lubricant compositions it is characterised in that reinforcing agent is high-alkali Value calcium mahogany sulfonate T103；Oxidation and corrosion inhibitor is sulfur phosphorus fourth octyl group zinc salt T202.
CN201610841088.9A 2016-09-21 2016-09-21 Lubricating agent composition for zirconium alloy cold upsetting technology Pending CN106433934A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610841088.9A CN106433934A (en) 2016-09-21 2016-09-21 Lubricating agent composition for zirconium alloy cold upsetting technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610841088.9A CN106433934A (en) 2016-09-21 2016-09-21 Lubricating agent composition for zirconium alloy cold upsetting technology

Publications (1)

Publication Number Publication Date
CN106433934A true CN106433934A (en) 2017-02-22

Family

ID=58167215

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610841088.9A Pending CN106433934A (en) 2016-09-21 2016-09-21 Lubricating agent composition for zirconium alloy cold upsetting technology

Country Status (1)

Country Link
CN (1) CN106433934A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109233956A (en) * 2018-10-16 2019-01-18 广西大学 A kind of composition of the cold stamping shaped processing material lubricant of nitrogen bearing duplex stainless steel plate

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN104974842A (en) * 2015-07-20 2015-10-14 广西大学 Castor-base rotary cold-forging beryllium alloy lubricant composition
CN105482873A (en) * 2015-11-30 2016-04-13 诺泰生物科技(合肥)有限公司 Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN104974842A (en) * 2015-07-20 2015-10-14 广西大学 Castor-base rotary cold-forging beryllium alloy lubricant composition
CN105482873A (en) * 2015-11-30 2016-04-13 诺泰生物科技(合肥)有限公司 Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
董元虎: "《汽车油料使用问答》", 31 January 2009, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109233956A (en) * 2018-10-16 2019-01-18 广西大学 A kind of composition of the cold stamping shaped processing material lubricant of nitrogen bearing duplex stainless steel plate

Similar Documents

Publication Publication Date Title
CN102703194A (en) Aluminum-magnesium alloy cutting fluid
CN104862035A (en) Lubricant composition for cold spinning titanium alloy pipe
CN103602373A (en) Improved anti-corrosive cutting fluid
CN106433934A (en) Lubricating agent composition for zirconium alloy cold upsetting technology
CN104974842A (en) Castor-base rotary cold-forging beryllium alloy lubricant composition
CN103710106B (en) The lubricant of drawing beryllium and beryllium alloy line, rod, tubing
CN103666703B (en) Lubricant for stamping lead and lead alloy material
CN106433933A (en) Lubricant composition for niobium alloy cold-heading process
CN103695120A (en) Lubricant for cold forging of titanium and titanium alloy materials
CN106479634A (en) Carbon structural steel rolling screw-threads processing and lubrication cooling liquid composition
CN106520300A (en) Lubricant composition for fully-synthetic zirconium alloy power-spinning machining process
CN106635310A (en) Lubricant composition for cold heading process of hafnium and hafnium alloys
CN105038930A (en) High-temperature precise die forging low alloy steel lubricant composition
CN103602364A (en) Novel lubricating cutting fluid
CN106544089A (en) A kind of Kazakhstan B series alloy cold heading technique lubricant compositions
CN103695127B (en) Lubricant for cold die forging of nickel and nickel alloy metal plates
CN103725380B (en) Lubricant for cold forging of beryllium and beryllium alloy materials
CN106544133A (en) A kind of basis brass alloy extrusion processing technique lubricant compositions
CN106635294A (en) Lubricant composition for chromium alloy cold heading process
CN106520310A (en) Lubricant composition for aluminium alloy cold-heading process
CN106520295A (en) Manganese alloy cold heading process lubricant composition
CN106520320A (en) Full synthetic hafnium alloy powerful-spinning processing lubricant composition
CN106544113A (en) A kind of bell metal punch machining process lubricant compositions
CN106635295A (en) Lubricant composition for rolling processing of cast carbon steel
CN106520343A (en) Lubricant composition for power-spinning processing process for total-synthesis niobium alloy

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170222

RJ01 Rejection of invention patent application after publication