CN106544089A - A kind of Kazakhstan B series alloy cold heading technique lubricant compositions - Google Patents

A kind of Kazakhstan B series alloy cold heading technique lubricant compositions Download PDF

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Publication number
CN106544089A
CN106544089A CN201610966114.0A CN201610966114A CN106544089A CN 106544089 A CN106544089 A CN 106544089A CN 201610966114 A CN201610966114 A CN 201610966114A CN 106544089 A CN106544089 A CN 106544089A
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China
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kazakhstan
lubricant compositions
cold heading
series alloy
alloy cold
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黄福川
唐弓斌
肖锋
张姗姗
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Guangxi University
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Guangxi University
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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    • C10M2211/08Halogenated waxes
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
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    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061Esters derived from boron
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18Anti-foaming property
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of Kazakhstan B series alloy cold heading technique lubricant compositions, using oil based on HVIH base oils, coordinate various compound additives.Including:Antioxidant, metal deactivator, oiliness improver, antiwear additive, extreme pressure agent, friction improver, antirust agent, anti-foaming agent, dispersant, oxidation and corrosion inhibitor, viscosifier etc..The compositionss of the present invention have good carrying wear resistence, Squeezing ground, low temperature flow diffusibility, lubricity, cooling; film strength is big, oil film thickness keeps stable; free from extraneous odour, do not stimulate skin, improve fineness and production efficiency, protect part to be processed surface not corrosion and oxidation; reduce power consumption and burr; low temperature flow is good, and good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, reduces the generation of precipitate and paint film; profiled member easy cleaning, extends die life.

Description

A kind of Kazakhstan B series alloy cold heading technique lubricant compositions
Technical field
A kind of Kazakhstan B series alloy cold heading technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
It is serial that Hastelloy (Hastelloyalloy) is broadly divided into B, C, G tri-, it be mainly used in iron-based Cr-Ni or The strong corrosive media occasion that Cr-Ni-Mo rustless steels, nonmetallic materials etc. cannot be used.Each trade mark has specific chemistry Composition, mechanical performance have his own strong points, it is impossible to which what characteristic Hastelloy of lumping together has.Hastelloy plate is applied to various Chemical industry containing oxidation and reductant.
Kazakhstan B series is mainly B-2 (00N:70MO28).Chemical composition N≤1.0, Cr:26.0~30, MO≤ 2.0, Fe≤ 0.02, C≤0.10, Si≤1.0, CO≤ 1.0, Mn≤0.04, P≤0, S≤0.3.
Cold-heading processing is the forging method for being shaped to metal bar material jumping-up (being often gathering stock) using mould at normal temperatures. Cold-heading is another form of upsetting.More metal mold becomes theoretical, applies certain pressure to metal stock at normal temperatures, It is allowed to be deformed in die cavity.By the shape and size shaping of regulation.Cold heading technique is widely used in middle finding and various The standard component of type.
Cold heading technique is mainly characterized by without machining, and stock utilization is high, utilization rate is up to 80~90%, and metal material Stream line will not be cut off, therefore product intensity is higher than machining or casting part strength, give birth in certain batch Under the conditions of product, cold-heading processing cost is more much lower than other processing costs, it is adaptable to generally need cutting members and securing member etc. The Product processing of symmetrical shape.The dimensional accuracy of product, weight accuracy and mechanical property etc. are attained by higher requirement.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good carrying wear resistence, Squeezing ground, low temperature flow Diffusibility, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin, improves bright and clean Degree, protect part to be processed surface not corrosion and oxidation, and reduction power consumption, low temperature flow are good, good anti-foaming property, anti-breast The property changed, thermal oxide are qualitative good, reduce the generation of precipitate and paint film, the Kazakhstan B series alloy cold heading technique of profiled member easy cleaning Lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of Kazakhstan B series alloy cold heading technique lubricant compositions, using oil based on HVIH base oils, coordinate many Kind of compound additive, its each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
Antioxidant is that the pungent/butyl diphenylamines T557 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined.
Metal deactivator be the 2-mercaptobenzimidazole of mass ratio 50% and 50% benzotriazole derivant T551 be combined.
Oiliness improver is sulfuration cottonseed oil T404.
Antiwear additive is chlorinated paraffin T301.
Extreme pressure agent is acid dibutyl phosphite T304.
Friction improver is boronation phosphate ester T3011.
Antirust agent is the benzo of the barium mahogany sulfonate T701 and 40% of the alkenyl succinic acid T746 and 30% of mass ratio 30% Triazole T706 is combined.
Anti-foaming agent is acrylate and ether copolymer T911.
Dispersant is boronation polyisobutylene succinamide T154B.
Oxidation and corrosion inhibitor is Sulphurized Oxymolybdenum Dialkylthiophosphate MODTP。
Viscosifier are ethylene-propylene copolymer T613A.
It is an advantage of the current invention that:
The compositionss of the present invention have good carrying wear resistence, Squeezing ground (not plucking, pull, effectively extend punch die Service life), low temperature flow diffusibility, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, no Stimulate skin, improve fineness, protect part to be processed surface not corrosion and oxidation, reduce power consumption, low temperature flow is good, Good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, reduce the generation of precipitate and paint film, profiled member easy cleaning.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The main physical and chemical index of 1 product of embodiment:
The main physical and chemical index of 2 product of embodiment:
The main physical and chemical index of 3 product of embodiment:

Claims (7)

1. a kind of Kazakhstan B series alloy cold heading technique lubricant compositions, it is characterised in that:Based on HVIH base oils Oil, coordinates various compound additives, its each mass percent into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.05%~0.5% Metal deactivator 0.06%~0.6% Oiliness improver 3.0%~6.0% Antiwear additive 4.0%~7.0% Extreme pressure agent 2.0%~4.0% Friction improver 2.0%~4.0% Antirust agent 0.03%~0.3% Anti-foaming agent 10~50ppm Dispersant 2.0%~4.0% Oxidation and corrosion inhibitor 0.2%~0.6% Viscosifier 3.0%~6.0%
The mass percent summation of above each component is 100%.
2. a kind of Kazakhstan B series alloy cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant Be mass ratio 50% sulfenyl phenolate T504 and 50% pungent/butyl diphenylamines T557 be combined;Metal deactivator is mass ratio 50% 2-mercaptobenzimidazole and 50% benzotriazole derivant T551 be combined.
3. a kind of Kazakhstan B series alloy cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver It is sulfuration cottonseed oil T404;Antiwear additive is chlorinated paraffin T301.
4. a kind of Kazakhstan B series alloy cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent It is acid dibutyl phosphite T304;Friction improver is boronation phosphate ester T3011.
5. a kind of Kazakhstan B series alloy cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent Be the alkenyl succinic acid T746 and 30% of mass ratio 30% barium mahogany sulfonate T701 and 40% BTA T706 be combined; Anti-foaming agent is acrylate and ether copolymer T911.
6. a kind of Kazakhstan B series alloy cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that dispersant It is boronation polyisobutylene succinamide T154B;Oxidation and corrosion inhibitor is Sulphurized Oxymolybdenum Dialkylthiophosphate MODTP。
7. a kind of Kazakhstan B series alloy cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that viscosifier It is ethylene-propylene copolymer T613A.
CN201610966114.0A 2016-11-04 2016-11-04 A kind of Kazakhstan B series alloy cold heading technique lubricant compositions Withdrawn CN106544089A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109913298A (en) * 2019-03-07 2019-06-21 山东小松油品有限公司 A kind of preparation method of high speed continuity cold headers punching oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031722A (en) * 2014-05-22 2014-09-10 丘寿勇 Lubricating oil
CN104962368A (en) * 2015-07-20 2015-10-07 广西大学 Rhenium bar rotary-swaging lubricant composition
CN105238519A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Lubricant composition and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031722A (en) * 2014-05-22 2014-09-10 丘寿勇 Lubricating oil
CN104962368A (en) * 2015-07-20 2015-10-07 广西大学 Rhenium bar rotary-swaging lubricant composition
CN105238519A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Lubricant composition and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109913298A (en) * 2019-03-07 2019-06-21 山东小松油品有限公司 A kind of preparation method of high speed continuity cold headers punching oil

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