CN107033991A - A kind of bell metal cold heading technique lubricant compositions - Google Patents

A kind of bell metal cold heading technique lubricant compositions Download PDF

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Publication number
CN107033991A
CN107033991A CN201610963534.3A CN201610963534A CN107033991A CN 107033991 A CN107033991 A CN 107033991A CN 201610963534 A CN201610963534 A CN 201610963534A CN 107033991 A CN107033991 A CN 107033991A
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China
Prior art keywords
lubricant compositions
cold heading
metal cold
heading technique
bell metal
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CN201610963534.3A
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Chinese (zh)
Inventor
黄福川
韦开焕
马骁飞
陈彪
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Guangxi University
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Guangxi University
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Publication of CN107033991A publication Critical patent/CN107033991A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024—Propene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/288—Partial esters containing free carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of bell metal cold heading technique lubricant compositions, using oily based on HVI400 base oils, coordinate a variety of compound additives.Including：Antioxidant, metal deactivator, oiliness improver, friction improver, extreme pressure agent, antiwear additive, antirust agent, anti-foaming agent, oxidation and corrosion inhibitor, tackifier, dispersant etc..The composition of the present invention has good carrying wear resistence, Squeezing ground, low temperature flow diffusivity, lubricity, cooling; film strength is big, oil film thickness keeps stable; free from extraneous odour, do not stimulate skin; finish is improved, part to be processed surface not corrosion and oxidation is protected, power consumption is reduced; good anti-foaming property, resistance to emulsion, thermal oxide are qualitative, shear resistant is good; the generation of sediment and paint film is reduced, molding part easy cleaning extends die life.

Description

A kind of bell metal cold heading technique lubricant compositions
Technical field
A kind of bell metal cold heading technique lubricant compositions of the present invention belong to metal working process field of lubricant.
Background technology
Bronze is that metal smelts alloy earliest in history, and the alloy of tin or lead is added in fine copper (red metal), there is special Importance and historic significance.Bronze is the name that modern gives, and ancient times bronze is that yellow is partially red, and after being embedded in soil color because Oxidation and it is steel gray, be referred to as bronze.Compared with fine copper (red metal), bronze intensity height and fusing point low (25% tin smelting bronze, fusing point 800 DEG C will be reduced to.The fusing point of fine copper (red metal) is 1083 DEG C).Bronze casting is good, and wear-resisting and chemical property is stable.
Cold-heading processing is the forging method shaped at normal temperatures to metal bar material jumping-up (being often gathering stock) using mould. Cold-heading is another form of upsetting.More metal mold becomes theoretical, applies certain pressure to metal stock at normal temperatures, It is allowed to be deformed in die cavity.Shaped by defined shape and size.Cold heading technique is widely used in middle finding and various The standard component of type.
Cold heading technique is mainly characterized by no machining, and stock utilization is high, and utilization rate is up to 80~90%, and metal material Stream line will not be cut off, therefore product intensity is higher than machining or casting part strength, be given birth in certain batch Under the conditions of production, cold-heading processing cost is more much lower than other processing costs, it is adaptable to it is generally necessary to cutting members and fastener etc. The Product processing of symmetrical shape.Dimensional accuracy, weight accuracy and mechanical property of product etc. are attained by higher requirement.
The content of the invention
There is good carrying wear resistence, Squeezing ground, low temperature flow the technical problem to be solved in the present invention is to provide a kind of Diffusivity, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin, improves bright and clean Degree, protect part to be processed surface not corrosion and oxidation, reduction power consumption, and good anti-foaming property, resistance to emulsion, thermal oxide are fixed Property it is good, reduce the generation of sediment and paint film, the bell metal cold heading technique lubricant compositions of molding part easy cleaning.
The present invention solves above-mentioned technical problem by following technical solution：
A kind of bell metal cold heading technique lubricant compositions, using oily based on HVI400 base oils, coordinate a variety of Compound additive, its each mass percent composition composition：
The mass percent summation of above each component is 100%.
Antioxidant is that the copper naphthenate and 50% dinonyldiphenylamine T558 of mass ratio 50% are combined；
Metal deactivator is that the benzotriazole derivative T551 and 50% of mass ratio 50% thiadiazole is combined.
Oiliness improver is soybean oil；
Friction improver is alkyl phosphite.
Extreme pressure agent is boronation phosphate T3011；
Antiwear additive is chlorinated paraffin T301.
Antirust agent is that the BTA T706 and 50% of mass ratio 50% alkenyl succinic acid sheep ester T747 is combined；
Anti-foaming agent is methyl-silicone oil T901.
Oxidation and corrosion inhibitor is fatty diglycollic amide phosphate；
Tackifier are ethylene-propylene copolymer T612A.
Dispersant is high molecular weight polyisobutylene base succimide T164B.
The advantage of the invention is that：The good carrying wear resistence of composition of the present invention, Squeezing ground (not plucking, pull, have The service life of effect extension punch die), low temperature flow diffusivity, lubricity, cooling, film strength is big, oil film thickness keeps steady It is fixed, free from extraneous odour, do not stimulate skin；Finish is improved, part to be processed surface not corrosion and oxidation is protected, power consumption is reduced, Low temperature flow is good, and good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, reduces the generation of sediment and paint film, molding part Easy cleaning.
Embodiment
Embodiment 1：
Following each component is pressed into the mediation of row mass percent to form：
Component Mass percentage content
HVI400 base oils Surplus
The copper naphthenate of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound 0.2%
The benzotriazole derivative (T551) of mass ratio 50% and 50% thiadiazole are compound 0.15%
Soybean oil 4.0%
Alkyl phosphite 2.0%
Boronation phosphate (T3011) 3.5%
Chlorinated paraffin (T301) 3.5%
The BTA (T706) of mass ratio 50% and 50% alkenyl succinic acid sheep ester (T747) are compound 0.2%
Methyl-silicone oil (T901) 30ppm
Fatty diglycollic amide phosphate 0.7%
Ethylene-propylene copolymer (T612A) 4.0%
High molecular weight polyisobutylene base succimide (T164B) 3.0%
Above each component mass percentage content summation is 100%.
Embodiment 2：
Following each component is pressed into the mediation of row mass percent to form：
Component Mass percentage content
HVI400 base oils Surplus
The copper naphthenate of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound 0.15%
The benzotriazole derivative (T551) of mass ratio 50% and 50% thiadiazole are compound 0.1%
Soybean oil 3.5%
Alkyl phosphite 2.0%
Boronation phosphate (T3011) 3.0%
Chlorinated paraffin (T301) 3.0%
The BTA (T706) of mass ratio 50% and 50% alkenyl succinic acid sheep ester (T747) are compound 0.1%
Methyl-silicone oil (T901) 35ppm
Fatty diglycollic amide phosphate 0.8%
Ethylene-propylene copolymer (T612A) 3.0%
High molecular weight polyisobutylene base succimide (T164B) 3.5%
Above each component mass percentage content summation is 100%.
Embodiment 3：
Following each component is pressed into the mediation of row mass percent to form：
Component Mass percentage content
HVI400 base oils Surplus
The copper naphthenate of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound 0.1%
The benzotriazole derivative (T551) of mass ratio 50% and 50% thiadiazole are compound 0.2%
Soybean oil 5.0%
Alkyl phosphite 2.0%
Boronation phosphate (T3011) 2.0%
Chlorinated paraffin (T301) 3.0%
The BTA (T706) of mass ratio 50% and 50% alkenyl succinic acid sheep ester (T747) it is combined 0.15%
Methyl-silicone oil (T901) 30ppm
Fatty diglycollic amide phosphate 0.9%
Ethylene-propylene copolymer (T612A) 5.0%
High molecular weight polyisobutylene base succimide (T164B) 3.0%
Above each component mass percentage content summation is 100%.
The main physical and chemical index of the product of embodiment 1：
The main physical and chemical index of the product of embodiment 2：
The main physical and chemical index of the product of embodiment 3：

Claims (7)

1. a kind of bell metal cold heading technique lubricant compositions, it is characterised in that：Using oil based on HVI400 base oils, Coordinate a variety of compound additives, its each mass percent composition composition：
Component Mass percentage content Base oil Surplus Antioxidant 0.03%~0.3% Metal deactivator 0.03%~0.3% Oiliness improver 2.0%~6.0% Friction improver 1.0%~3.0% Extreme pressure agent 2.0%~4.0% Antiwear additive 3.0%~4.0% Antirust agent 0.03%~0.3% Anti-foaming agent 10~50ppm Oxidation and corrosion inhibitor 0.5%~1.2% Tackifier 2.0%~6.0% Dispersant 2.0%~4.0%
The mass percent summation of above each component is 100%.
2. a kind of bell metal cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is matter The copper naphthenate and 50% dinonyldiphenylamine T558 measured than 50% are compound；Metal deactivator is the benzotriazole of mass ratio 50% Derivative T551 and 50% thiadiazole is combined.
3. a kind of bell metal cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is big Soya-bean oil；Friction improver is alkyl phosphite.
4. a kind of bell metal cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is boron Change phosphate T3011；Antiwear additive is chlorinated paraffin T301.
5. a kind of bell metal cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is matter The alkenyl succinic acid sheep ester T747 for measuring the BTA T706 and 50% than 50% is combined；Anti-foaming agent is methyl-silicone oil T901.
6. a kind of bell metal cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that oxidation and corrosion inhibitor It is fatty diglycollic amide phosphate；Tackifier are ethylene-propylene copolymer T612A.
7. a kind of bell metal cold heading technique lubricant compositions as claimed in claim 1, it is characterised in that dispersant is high Molec weight polyisobutylene base succimide T164B.
CN201610963534.3A 2016-11-04 2016-11-04 A kind of bell metal cold heading technique lubricant compositions Pending CN107033991A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN105238519A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Lubricant composition and application thereof
CN105482873A (en) * 2015-11-30 2016-04-13 诺泰生物科技(合肥)有限公司 Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN105238519A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Lubricant composition and application thereof
CN105482873A (en) * 2015-11-30 2016-04-13 诺泰生物科技(合肥)有限公司 Environmentally-friendly cold heading oil with epoxidized vegetable oil as base oil, and preparation method thereof

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