CN106433919A - Tantalum alloy col-upsetting process lubricant composition - Google Patents

Tantalum alloy col-upsetting process lubricant composition Download PDF

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CN106433919A
CN106433919A CN201610839024.5A CN201610839024A CN106433919A CN 106433919 A CN106433919 A CN 106433919A CN 201610839024 A CN201610839024 A CN 201610839024A CN 106433919 A CN106433919 A CN 106433919A
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tantalum alloy
agent
lubricant compositions
cold heading
alloy cold
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黄福川
黄军
肖锋
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Guangxi University
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
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    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18Anti-foaming property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/56Boundary lubrication or thin film lubrication
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/20Metal working
    • C10N2040/243Cold working

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a tantalum alloy col-upsetting process lubricant composition which adopts VHVI12 base oil as base oil and cooperates with a variety of composite additives. The tantalum alloy col-upsetting process lubricant composition is prepared from an antioxidant, a metal deactivator, an anti-rust agent, an oily agent, a friction improver, an extreme pressure agent, an anti-abrasion agent, an antifoaming agent, a dispersant, an adhesive, an oxidation and corrosion inhibitor and the like. The composition has good bearing and abrasion resistance properties, compression resistance, low-temperature flow diffusivity, lubricity and cooling performance, an oil film is high in strength, oil film thickness is kept stable, no peculiar smell is produced, the composition is non-irritant to the skin, the roughness can be improved, the surfaces of machined parts are protected against rusting and oxidation, power consumption is reduced, the low-temperature fluidity is good, anti-foaming, demulsibility and thermal oxidation stability are good, production of precipitates and paint films is reduced, and formed parts are easy to clean.

Description

A kind of tantalum alloy cold heading technique lubricant compositions
Technical field
A kind of present invention tantalum alloy cold heading technique lubricant compositions belong to metal working lubricant field.
Background technology
Tantalum, metallic element, the quality of tantalum is very hard, and hardness can reach 6-6.5.Up to 2996 DEG C of its fusing point.Main In tantalite to be present in, with niobium symbiosis.The quality of tantalum is very hard, and tantalum is rich in ductility, can pull into filament formula thin foil. Its thermal coefficient of expansion very little.Tantalum has very outstanding chemical property, has high corrosion resistance.Either in cold and hot bar Under part, hydrochloric acid, red fuming nitric acid (RFNA) and " chloroazotic acid " are not reacted.May be utilized in fabricating evaporator boat etc., also can do the electrode of electron tube, whole Stream device, electrolysis, electric capacity.Medically it is used for laminating or fine rule, the tissue that destroy is sewed and mend.The characteristic that tantalum has, makes its Application is very wide.In the equipment producing various inorganic acids, tantalum can be substituted for stainless steel, and the life-span carries than stainless steel High tens times.Additionally, chemical industry, electronics, electrically etc. in industry, tantalum can replace needs in the past by precious metal platinum undertake times Business, makes required expense substantially reduce.Tantalum has been manufactured into electric capacity and has been provided in military equipment.Tantalum be rare metal mineral products resource it One, it is electronics industry and the space technology indispensable strategic material of development.
Cold-heading processing is the forging method at normal temperatures metal bar material jumping-up (often for gathering stock) being shaped using mould. Cold-heading is another form of upsetting.More metal mold becomes theoretical, applies certain pressure to metal stock at normal temperatures, It is allowed to be deformed in die cavity.Shape by the shape and size of regulation.Cold heading technique is widely used in middle finding and various The standard component of type.
Cold heading technique be mainly characterized by no machining, stock utilization is high, and utilization rate reaches 80~90%, and metal material Stream line will not be cut off, and therefore product intensity is higher than machining or casting part strength, in certain batch life Under the conditions of product, cold-heading processing cost more much lower than other processing costs it is adaptable to typically require cutting members and securing member etc. The Product processing of symmetrical shape.The dimensional accuracy of product, weight accuracy and mechanical property etc. are attained by higher requirement.
Lubricant should have the special feature that:Good carrying wear resistence, Squeezing ground (not plucking, pull, effectively extend punch die Service life), low temperature flow diffusivity, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, no Stimulate skin etc..Improve fineness, protect part to be processed surface not corrosion and oxidation, reduce power consumption, low temperature flow Well, good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, reduce the generation of sediment and paint film, profiled member easy cleaning.
Content of the invention
The technical problem to be solved in the present invention is that offer is a kind of has good carrying wear resistence, Squeezing ground, low temperature flow Diffusivity, lubricity, cooling, film strength is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin, can improve bright and clean Degree, protect part to be processed surface not corrosion and oxidation, minimizing power consumption, and low temperature flow is good, good anti-foaming property, anti-breast The property changed, thermal oxide are qualitative good, reduce the generation of sediment and paint film, the tantalum alloy cold heading technique lubricant group of profiled member easy cleaning Compound.
The present invention employs the following technical solutions solution above-mentioned technical problem:
A kind of tantalum alloy cold heading technique lubricant compositions, using oil based on VHVI 12 base oil, cooperation is multiple multiple Close additive, the one-tenth of its respective mass percent is grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.05%~0.4%
Metal deactivator 0.03%~0.2%
Antirust agent 0.03%~0.3%
Oiliness improver 3%~8%
Friction improver 0.3%~1.5%
Extreme pressure agent 3%~5%
Antiwear additive 5%~8%
Anti-foaming agent 10~50ppm
Dispersant 2~4%
Adhesive 3~8%
Oxidation and corrosion inhibitor 0.3~0.8%
Each constituent mass percentage summation is 100% above.
Antioxidant be the cupric antioxidant T543 of mass ratio 50% and 50% 2,6- di-t-butyl-α dimethylamino to first Phenol T521's is compound;Metal deactivator is the benzotriazole derivative T551 of mass ratio 50% and 50% thiadiazoles derivative T561 Compound.
Antirust agent be the barium dinonyl napthalene sulphonate T705A of mass ratio 50% and 50% benzotriazole T706 compound Thing.
Oiliness improver is sulfurized lard;Friction improver is dialkyldithiocarbamacompositions tungsten.
Extreme pressure agent is boronation phosphamidon ester T3011.
Antiwear additive is chlorinated paraffin T301;Anti-foaming agent is acrylic acid and ether copolymer T912.
Dispersant is boronation polyisobutene succinimide T154B.
Adsorbent is polyisobutene T603D.
Oxidation and corrosion inhibitor is double octyl group basic zinc salt T203 of sulphur phosphorus.
The beneficial effects of the present invention is:Tantalum alloy cold heading technique lubricant of the present invention have good carrying wear resistence, Squeezing ground (not plucking, the service life pulled, effectively extend punch die), low temperature flow diffusivity, lubricity, cooling, oil film Intensity is big, oil film thickness keeps stable, free from extraneous odour, does not stimulate skin etc..Improve fineness, protection part to be processed surface is stainless Erosion and aoxidizing, reduces power consumption, low temperature flow is good, and good anti-foaming property, resistance to emulsion, thermal oxide are qualitative good, and it is heavy to reduce Starch and the generation of paint film, profiled member easy cleaning.
Specific embodiment
Embodiment 1:
Following component is in harmonious proportion by mass percentage and forms:
Each constituent mass percentage summation is 100% above.
Embodiment 2:
Following component is in harmonious proportion by mass percentage and forms:
Each constituent mass percentage summation is 100% above.
Embodiment 3:Following component is in harmonious proportion by mass percentage and forms:
Each constituent mass percentage summation is 100% above.
Embodiment 2 product typical technology index:
Project Index
100 DEG C of kinematic viscosity mm2/s 12.5
Flash-point (opening)/DEG C 255
Pour point/DEG C -16
Viscosity index (VI) 131
Coefficient of friction 0.09
Corrosion experiment (copper sheet, 100 DEG C, 3h)/level 1
Oxidation stability (Rotary Oxygen elasticity, 150 DEG C) min 420
FZG, level 14
Tetra-ball machine test Pb/N 952
Tetra-ball machine test PD/N 8280
Terraced nurse agrees/N 330
24 DEG C of foaming characteristics test 300/0
96℃ 200/0
24 DEG C afterwards 200/0
Evaporation loss (Angelika Noack method, 250 DEG C, 1h) (m) % 11
Mechanical admixture, % No
Moisture, % Vestige
Water-soluble acid and alkali No
Saturated hydrocarbons (m) % 97
82 DEG C of demulsification number (40 37 3), min 13

Claims (9)

1. a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that:Using oil based on VHVI 12 base oil, Coordinate multiple compound additives, the one-tenth of its respective mass percent is grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.05%~0.4% Metal deactivator 0.03%~0.2% Antirust agent 0.03%~0.3% Oiliness improver 3%~8% Friction improver 0.3%~1.5% Extreme pressure agent 3%~5% Antiwear additive 5%~8% Anti-foaming agent 10~50ppm Dispersant 2~4% Adhesive 3~8% Oxidation and corrosion inhibitor 0.3~0.8%
Each constituent mass percentage summation is 100% above.
2. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that antioxidant is quality Cupric antioxidant T543 than 50% and 50% 2,6- di-t-butyl-α dimethylamino-p-cresol T521 compound;Metal deactivating Agent be the benzotriazole derivative T551 of mass ratio 50% and 50% thiadiazoles derivative T561 compound.
3. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that antirust agent is quality Barium dinonyl napthalene sulphonate T705A than 50% and 50% benzotriazole T706 compound.
4. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that oiliness improver be sulfuration Lard;Friction improver is dialkyldithiocarbamacompositions tungsten.
5. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that extreme pressure agent is boronation Phosphamidon ester T3011.
6. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that antiwear additive is chlorination Paraffin T301;Anti-foaming agent is acrylic acid and ether copolymer T912.
7. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that dispersant is boronation Polyisobutene succinimide T154B.
8. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that adsorbent is poly- different Butylene T603D.
9. as claimed in claim 1 a kind of tantalum alloy cold heading technique lubricant compositions it is characterised in that oxidation and corrosion inhibitor is Double octyl group basic zinc salt T203 of sulphur phosphorus.
CN201610839024.5A 2016-09-21 2016-09-21 Tantalum alloy col-upsetting process lubricant composition Pending CN106433919A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN104962368A (en) * 2015-07-20 2015-10-07 广西大学 Rhenium bar rotary-swaging lubricant composition
CN105132092A (en) * 2015-07-20 2015-12-09 广西大学 Lubricant composition for Al-Mg alloy precision die forging
CN105238519A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Lubricant composition and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403738A (en) * 2014-09-30 2015-03-11 宁波保润石化有限公司 Multi-station cold heading oil and preparation method thereof
CN104962368A (en) * 2015-07-20 2015-10-07 广西大学 Rhenium bar rotary-swaging lubricant composition
CN105132092A (en) * 2015-07-20 2015-12-09 广西大学 Lubricant composition for Al-Mg alloy precision die forging
CN105238519A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Lubricant composition and application thereof

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Application publication date: 20170222