CN103725382A - Lubricant for cold forging of nickel and nickel alloy materials - Google Patents
Lubricant for cold forging of nickel and nickel alloy materials Download PDFInfo
- Publication number
- CN103725382A CN103725382A CN201310702989.6A CN201310702989A CN103725382A CN 103725382 A CN103725382 A CN 103725382A CN 201310702989 A CN201310702989 A CN 201310702989A CN 103725382 A CN103725382 A CN 103725382A
- Authority
- CN
- China
- Prior art keywords
- nickel
- lubricant
- cold forging
- nickel alloy
- alloy material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 25
- 238000010273 cold forging Methods 0.000 title claims abstract description 20
- 239000000314 lubricant Substances 0.000 title claims abstract description 20
- 239000000956 alloy Substances 0.000 title claims abstract description 19
- 229910000990 Ni alloy Inorganic materials 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000003921 oil Substances 0.000 claims abstract description 13
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 239000000654 additive Substances 0.000 claims abstract description 3
- 239000010729 system oil Substances 0.000 claims abstract description 3
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 10
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 10
- 238000005987 sulfurization reaction Methods 0.000 claims description 10
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 5
- 239000004166 Lanolin Substances 0.000 claims description 5
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 claims description 5
- XLXGCFTYXICXJF-UHFFFAOYSA-N ethylsilicon Chemical group CC[Si] XLXGCFTYXICXJF-UHFFFAOYSA-N 0.000 claims description 5
- 229940039717 lanolin Drugs 0.000 claims description 5
- 235000019388 lanolin Nutrition 0.000 claims description 5
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 5
- 210000000582 semen Anatomy 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000005728 strengthening Methods 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000002184 metal Substances 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000001816 cooling Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000003754 machining Methods 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 238000005242 forging Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001361 White metal Inorganic materials 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010969 white metal Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to a lubricant for cold forging of nickel and nickel alloy materials. The lubricant takes number 46 total loss system oil as base oil, integrates various composite additives, and comprises an oiliness agent, an antiwear agent, an extreme pressure agent, an antioxidant, an anti-foaming agent, a friction improver and an reinforcing agent. The lubricant for the cold forging of the nickel and nickel alloy materials is good in lubricity and strong in cooling and cleaning capability, can reduce an adhesion phenomenon of a forge piece during machining, improves oil film strength in a deformation area at the same time, reduces a friction coefficient, is stable in composition, has no corrosion to metal and molds, is non-toxic, and is free from pungent smell.
Description
Technical field
The invention belongs to the field of lubricant that non-ferrous metal forging processing and lubrication, particularly nickel and nickel alloy material cold forging are made.
Background technology
Nickel, silvery white metal, 1455 ℃ of fusing points, 2730 ℃ of boiling points, density is 8.902g/cm
3.Nickel has good physical strength and ductility, infusibility, and matter is hard, has magnetic and good plasticity-.The erosion resistance having had, not oxidized in air, resistance to highly basic again.Nickel is the metal of a medium tenacity.Metallic nickel is mainly used in electroplating industry, and the article of nickel plating are attractive in appearance, be difficult for totally, again corrosion.
Because nickel has good physical strength and ductility, infusibility is high temperature resistant, and there is very high chemical stability, the feature such as in air, be not oxidized, therefore be a kind of very important non-ferrous metal raw material, be used to manufacture stainless steel, High Nickel Steel and structural alloy steel, be widely used in the various military industrial manufacturing enterprises such as aircraft, radar, guided missile, tank, naval vessels, spaceship, reactor.In civilian industry, nickel is often made structure iron, duriron, high temperature steel etc. in a large number for various machinery manufacturing industry.Nickel also can be made beramic color and coating for protection against corrosion, and nickel cobalt (alloy) is a kind of permanent magnet material, is widely used in the fields such as electronic telecontrol, nuclear industry and ultrasonic technique.
Cold-forging technique is a kind of precision plastic forming technology, has the unrivaled advantage of machining, as the good mechanical property of goods, productivity is high and material use efficiency is high, is particularly suitable for producing in enormous quantities, can reduce production costs, and improves added value of product.Use cold-forging technique processing nickel and nickel alloy material, the most important thing is to solve its mould problem.Cold-forging technique requires high to mold performance, for extending the work-ing life of mould, must in forging process, use suitable lubricant.The cold forging lubricant of nickel and nickel alloy material can form composite lubricating film between forging and mould, avoids the adhesion of forging and mould, and slows down the gouging abrasion of metal fluid, extends die life.
Summary of the invention
The technical problem to be solved in the present invention is to provide the lubricant that a kind of nickel and nickel alloy material cold forging are made, and the lubricity of this lubricant is good, cooling, cleansing power is strong, can reduce the adherent phenomenon of course of processing forging; Increase oil film strength in distorted area simultaneously, reduce frictional coefficient; Composition is stable; Corrosion-free to metal and mould; Nontoxicity, has no irritating odor.
The present invention solves the problems of the technologies described above using following technical scheme: adopt No. 46 total loss system oil as base oil, coordinate multiple composite additive, its each component and mass percent are:
Component | Content (mass percent) |
Base oil | Surplus |
Oiliness improver | 5.0%~12.0% |
Anti-wear agent | 5.0%~8.0% |
Extreme pressure agent | 3.0%~5.0% |
Oxidation inhibitor | 0.8%~1.2% |
Kilfoam | 0.005%~0.01% |
Friction improver | 3.0%~5.0% |
Strengthening agent | 3.0%~5.0% |
Base oil is No. 46 oil for total loss system.
Oiliness improver is sulfuration Oleum Gossypii semen.
Anti-wear agent is clorafin 42.
Extreme pressure agent is boronation phosphoric acid ester.
Oxidation inhibitor is mass ratio 40%~60%2, and 6-ditertbutylparacresol and 60%~40% dialkyl diphenylamine are compound.
Kilfoam is ethyl silicon oil.
Friction improver is that mass ratio 40%~60% oleic acid ethyl ester and 60%~40% lanolin are compound.
Strengthening agent is sulfuration Trimethylmethane.
The lubricant that nickel of the present invention and nickel alloy material cold forging are made, its lubricity is good, cooling, cleansing power is strong, can reduce the adherent phenomenon of course of processing forging; Increase oil film strength in distorted area simultaneously, reduce frictional coefficient; Composition is stable, and corrosion-free to metal and mould, nontoxicity, has no irritating odor.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and is formed by mass percentage:
Component | Content (mass percent) |
No. 46 oil for total loss system | 75.8% |
Sulfuration Oleum Gossypii semen | 2.0% |
Clorafin 42 | 7.0% |
Boronation phosphoric acid ester | 5.0% |
Mass ratio 40%2,6-ditertbutylparacresol and 60% dialkyl diphenylamine | 1.19% |
Ethyl silicon oil | 0.01% |
Mass ratio 40% oleic acid ethyl ester and 60% lanolin | 4.0% |
Sulfuration Trimethylmethane | 5.0% |
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and is formed by mass percentage:
Component | Content (mass percent) |
No. 46 oil for total loss system | 78.1% |
Sulfuration Oleum Gossypii semen | 5.0% |
Clorafin 42 | 6.0% |
Boronation phosphoric acid ester | 3.0% |
Mass ratio 60%2,6-ditertbutylparacresol and 40% dialkyl diphenylamine | 0.892% |
Ethyl silicon oil | 0.008% |
Mass ratio 60% oleic acid ethyl ester and 40% lanolin | 3.0% |
Sulfuration Trimethylmethane | 4.0% |
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and is formed by mass percentage:
Component | Content (mass percent) |
No. 46 oil for total loss system | 71.5% |
Sulfuration Oleum Gossypii semen | 9.0% |
Clorafin 42 | 6.5% |
Boronation phosphoric acid ester | 4.0% |
Mass ratio 50%2,6-ditertbutylparacresol and 50% dialkyl diphenylamine | 0.993% |
Ethyl silicon oil | 0.007% |
Mass ratio 50% oleic acid ethyl ester and 50% lanolin | 4.0% |
Sulfuration Trimethylmethane | 4.0% |
Above component summation is 100%.
The main physical and chemical index of embodiment 2 products is:
Project | Quality index |
Moisture, % | Vestige |
40 ℃ of kinematic viscosity mm 2/s | 43.4 |
Flash-point (opening) ℃, | 180 |
Mechanical impurity, % | Nothing |
Last non seizure load (Pb), Kg | 103 |
Pour point, ℃, | -10 |
Water soluble acid or alkali | Nothing |
Corrosion test (copper sheet, 100 ℃, 3h), level | 1 |
Viscosity index, is not less than | 95 |
Claims (9)
1. the lubricant that nickel and nickel alloy material cold forging are made, is characterized in that adopting No. 46 total loss system oil as base oil, coordinates multiple composite additive, and its each component and mass percent are:
2. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that base oil is No. 46 oil for total loss system.
3. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that oiliness improver is sulfuration Oleum Gossypii semen.
4. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that anti-wear agent is clorafin 42.
5. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that extreme pressure agent is boronation phosphoric acid ester.
6. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that oxidation inhibitor is mass ratio 40%~60%2, and 6-ditertbutylparacresol and 60%~40% dialkyl diphenylamine are compound.
7. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that kilfoam is ethyl silicon oil.
8. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that friction improver is that mass ratio 40%~60% oleic acid ethyl ester and 60%~40% lanolin are compound.
9. the lubricant that nickel as claimed in claim 1 and nickel alloy material cold forging are made, is characterized in that strengthening agent is sulfuration Trimethylmethane.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310702989.6A CN103725382B (en) | 2013-12-18 | 2013-12-18 | The lubricant that Ni-based ultrafine powder material cold forging is made |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310702989.6A CN103725382B (en) | 2013-12-18 | 2013-12-18 | The lubricant that Ni-based ultrafine powder material cold forging is made |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103725382A true CN103725382A (en) | 2014-04-16 |
CN103725382B CN103725382B (en) | 2015-10-07 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310702989.6A Expired - Fee Related CN103725382B (en) | 2013-12-18 | 2013-12-18 | The lubricant that Ni-based ultrafine powder material cold forging is made |
Country Status (1)
Country | Link |
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CN (1) | CN103725382B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104974838A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Rotary cold-forging vanadium alloy lubricant composition |
CN106635287A (en) * | 2016-09-21 | 2017-05-10 | 广西大学 | Red copper spinning process lubricant |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103421587A (en) * | 2013-08-26 | 2013-12-04 | 广西大学 | Magnesium and magnesium alloy sheet strip cold rolling lubricating agent |
-
2013
- 2013-12-18 CN CN201310702989.6A patent/CN103725382B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103421587A (en) * | 2013-08-26 | 2013-12-04 | 广西大学 | Magnesium and magnesium alloy sheet strip cold rolling lubricating agent |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104974838A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Rotary cold-forging vanadium alloy lubricant composition |
CN106635287A (en) * | 2016-09-21 | 2017-05-10 | 广西大学 | Red copper spinning process lubricant |
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Publication number | Publication date |
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CN103725382B (en) | 2015-10-07 |
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Granted publication date: 20151007 |