CN106420518B - Skin cleaning product comprising grains and ginseng fruit shells and preparation method of skin cleaning product - Google Patents

Abstract

The invention relates to a grain and ginseng fruit shell fermentation product and application of the fermentation product in a skin cleaning product. According to a method, a culture medium comprising grains and ginseng fruit shells is heated and sterilized at first, then microorganisms are introduced, fermentation and sterilization are conducted, and a fermentation product comprising thalli, fermentation filtrate and solid particles is obtained. The fermentation product is used for the cleaning product. The fermentation product has good functions of removing skin surface grease, smoothing the skin, resisting inflammation and acne and the like, and has the advantages of nursing the skin, mildly removing skin cutin and being low in irritation, safe and mild.

Description

Cleaning products containing cereal ginseng shell and preparation method thereof

Technical field

The present invention relates to a kind of skin cleansing compositions, particularly containing the skin clean of cereal ginseng shell tunning Composition.

Technical background

At present in conventional cleaning products, without alveolitoid cleaning products appropriate oil content is contained typically in formula, Sometimes a small amount of surfactant is also contained, it is characterized by foam is less, it is relatively gentleer, with the foam containing exhibiting high surface activating agent Type mildy wash is compared, and with low irritant, does not result in excessively cleaning, is adapted to the spy that Dry and sensitive are used Levy.But a disadvantage is that it is less to skin clean dynamics, while not possessing the unnecessary cutin function of removal epidermis.

Frosted type cleaning products are widely used in household chemicals field.Frosted type cleaning products its mainly constitute into Part it is：Abrasive particle, surfactant and other additives.Abrasive particle therein can be largely classified into organic abrasive particle and Inorganic abrasive particle.Wherein organic abrasive particle includes natural shell particle, fruit stone particle, oyster shell whiting, pearl powder.Inorganic frosted Particle has bamboo charcoal, kaolin, salt particle, quartz sand, calcium carbonate etc..It is mainly characterized by making except the decontamination of cleaning agent in formula With outer, unnecessary cutin, dust and bag spot etc. can also be removed by abrasive particle mechanical friction effect.But if abrasive particle Composition is really up to the mark or improper use can cause skin friction to damage, cuticula excessively thin acceleration skin exfoliation (particularly dryness and neutrality Skin consumer).

Nowadays, advocate natural Never Ending Fashion to have swept the globe, beauty and skin care circle also can not make an exception, start people to natural peace The upsurge that full skin care item are pursued, some natural, safe skin care item Effect raw materials pour in the visual field.Health of the five cereals to human body Very favorable effect is played, rich in protein, carbohydrate, fat, mineral matter and multivitamin is contained in five cereals, These nutritions are quite benefited to skin nursing.It is used to have in skin nursing especially by the cereal of fermentable and protects Moisture content of skin is held, is strengthened skin elasticity, is strengthened skin barrier, promotes subcutaneous collagen albumen to produce and certain anti-oxidation efficacy..

KR20130019192A discloses plum, pomegranate, citrus, rice and crushes, and adds lactic acid bacteria culture, centrifugation to obtain Filtrate is obtained, for Exfoliating Scrub, but cleaning products prepared by the method are for the removal of skin oil and fat has no good report.

KR20090115844A discloses Chinese herbal medicine (the particularly root of Dahurain angelica), red bean, rice bran and adds lactobacillus-fermented, filtration Filtrate, the substitute for detergent or soap cleans vagina, with the growth for preventing vagina mucosa harmful bacteria, removes different Effect of taste.But cleaning products prepared by the method are reported skin surface oil stain removing to have no.

JP2001271096A discloses rice bran as the application of cleaning agent, the bran powder by adding lactic acid bacteria, 58 DEG C Cultivation and fermentation 6 hours, adds citric acid 5%, is dried, acquisition of sieving.The document compares ferment rice bran powder with azymic rice Bran powder cleaning skin effect, as a result shows that ferment rice bran can more improve skin hydration degree.But the powder cleaning agent makes Mixed with liquid or egg liquid in advance with front needs and smear skin after sizing mixing, using cumbersome, and the battalion in short time mixed-powder Foster material can not be discharged cmpletely, cause nutrition to be fully absorbed by the skin.

CN103211749A discloses by fermentable glutinous rice flour the method to prepare shampoo, but it selects bacterium Strain fermentation time is up to 15 days, and the granular sensation that glutinous rice flour is carried originally can be have impact on after fermentation.Weaken the effect of its frosted cleaning Really.

Therefore there is still a need for finding a kind of suitable method for being used for cleaning products.

At present, it is mainly used in field of food using fermentable bread basket.CN101164428A discloses fermentation The method for preparing biological feedstuff such as corn flour, dregs of beans, the food of the viscous corn flour of CN103404779A lactobacillus-fermenteds, Wang Zhi Big grade " lactic acid bacteria fermented grain food --- the research of sour congee zymotechnique, processing of farm products, 2010.2,27～30 " disclose It is cut as raw material with glutinous rice, millet, rotten rice, corn, using the excellent lactobacillus-fermented of proterties, measures sample amino acid after fermentation and contain Amount and total amount showed increased." the Hypolipidemic effects of lactic acid bacteria such as Immaculata Fermented cereal in rats " .Banjoko et al.Lipids in Health and Disease, 2012.11, 170 disclose lactobacillus acidophilus, Bifidobacterium and Lactobacillus helveticus mixed fermentation corn flour, and the well-grown in corn flour is sent out Corn flour reaches acceptable taste after ferment.And find that the food of the mixed fermentation plays the role of to suppress fat absorption^[2]。 " the Lactic acid bacteria producing B-group vitamins such as Vittorio：a great potential For functional cereals products ", Appl Microbiol Biotechnol, 2012,96：1383-1394 Disclosing can pass through the different contents for improving VB races in fermented cereal of the screening of microorganism and fermentation condition, develop in cereal Fermented product micro-organisms vitamin.Wu little Yan etc. " Agricultural University of the Inner Mongol, master's knowledge paper, 2013 " report with breast Acid bacteria fermentation coix seed, polysaccharide in fermentation liquid, content of peptides do not ferment and increase 4～8 times, and zymotic fluid has good antioxygen The property changed.Fu Liang etc. " development of fermented type rice milk, food and machinery, 2006,5：103～105. " with rice as raw material, Jing gelatinizations Deng a certain amount of lactic acid bacteria being accessed and being fermented after pretreatment, the good fermented type rice milk of sense organ and structural state has been obtained.Gong Yuan Raw etc. " development of millet fermented beverage, Journal of Zhengzhou Grain College, 1999,3：41～43. " using koji and saccharomycete two Step fermentation obtains the good millet fermented beverage of taste.As can be seen here, microorganism is while nutriment in using cereal, from Body produces some metabolites, makes the macromolecular in cereal be decomposed into the material of molecular weight, it is easier to absorb.To also simultaneously The nutriment for being difficult to discharge in cereal is discharged.In addition Jing fermentables can produce distinctive material for example lactic acid, polysaccharide, Antibiotic, polyphenoils and bioconversion product make product have more high bioactivity, it is easy to the effect such as body absorption.But It is that the application that fermented grain product is used in cleaning products has not been reported.

Ginseng belongs to the plant of Araliaceae Panax, and the effect reported up to now has：The work of Central nervous system With, antitumaous effect, immunoregulation effect, strengthen liver function function, cardiovascular disorder improvement, resistance to compression, antifatigue effect, anti-oxidant work Property and anti-aging suppression function.

Ginseng physiologically active composition is ginsenoside.At present using it is most be ginseng underground position, but ginseng Also ginsenoside composition is contained in leaf, flower, fruit, seed.Different parts in ginseng plant, the content of ginsenoside has significantly Difference.

In recent years, ginseng is widely studied as the skin function raw material of cosmetics, and wherein most all make use of ginseng Root, mainly use panaxan and ginsenoside composition.But the skin function effect disquisition brought using ginseng shell Very few, particularly fermented rear ginseng shell extract is used for the research of skin and has no report.

Inventor has found, fermented grain product is applied in Cleasing compositions, because fermented grain product contains in a large number Starch and dextrin, have good adsorption removal to act on to skin oil and fat, and secondly, fermented grain product is applied to cleaning products In, the granular sensation of cereal and gentle frosted sense are remained, coordinate the abrasive action during cleaning gently to remove skin Surface aging cutin.Nutriment such as thalline, lactic acid, polypeptide, amino acid, polysaccharide, vitamin in other fermented grain product Deng cleaning products nourish skin is also imparted, prevent from cleaning scaly dry skin, the sense of discomfort such as tight excessively brought.It is further to send out Existing, the tunning that ginseng shell is mixed with cereal is used to prepare enhance in Cleasing compositions its anti-inflammatory, moisturizing, antioxygen Change, the effect of Sage Extract, and composition obtains the low irritant of raising, the characteristics of safe gentle.

Therefore, the present invention relates to cereal and ginseng shell tunning are applied in Cleasing compositions, it is in composition In remain cereal and ginseng shell Dare nutrition and granular sensation, can gently remove skin surface aging cutin, remove table Face grease, skin nutrition, skin irritatin of releiving, while the characteristics of there is low irritant, safety temperature.

The content of the invention

The present invention relates to application of the cereal ginseng shell tunning in Cleasing compositions.

The tunning is by by the culture medium heat sterilization containing the cereal and ginseng shell crushed, being followed by giving birth in a subtle way Thing, fermentation, sterilizing obtains the cereal ginseng shell tunning comprising thalline, ferment filtrate and solid particle.The cereal ginseng The product that shell tunning is obtained by cereal and ginseng shell particle Jing after fermentable, it has 0.02mm～1mm, It is preferred that the particle diameter of 0.05mm～0.4mm, more preferably 0.15mm～0.25mm.

Further, one or more of the cereal in rice, millet, corn, black rice, Chinese sorghum, adlay.

Further, the present invention relates to the skin cleansing compositions containing corn ginseng shell tunning.

Further, Cleasing compositions of the present invention are essentially free of surfactant.

The tunning of the present invention, it is prepared by following step：

1st, culture medium heat sterilization

2nd, the fermented bacterium for having activated is accessed

3rd, ferment

4th, pH is adjusted

5th, sterilize

Wherein, culture medium is that cereal-granules, ginseng shell particle and pure water are prepared.Granulate mixture content in its culture medium For 3%～30 weight %, preferably 5%～25%, 10%～15% is more selected, wherein cereal-granules and ginseng shell particle weight Than for 70: 30-99: 1, preferably 80: 20-95: 5, more preferably 90: 10, its sterilising temp is 50 DEG C～120 DEG C, and the time is 10min～30min.

Microbial inoculant amount is 0.1%～20% volume.

Fermentation temperature is 25 DEG C～45 DEG C

It is 4.0～7.0 to adjust pH scopes.

The further pH scopes that adjust are 5.0～6.0.

Sterilising temp is 65 DEG C～120 DEG C.Sterilization time is controlled to 15min～60min.

Further, nutriment can be added in culture medium.The nutriment selected from glucose, lactose, sucrose and/or Maltose, preferred glucose.

The microorganism, selected from brewer's yeast (Saccharomyces cerevisiae), candida utili Saccharomycete such as (Candida utilis), or lactobacillus acidophilus (Lactobacillus acidophilus), lactobacillus paracasei (Lactobacillus paracasei), Lactobacillus rhamnosus (Lactobacillus rhamnosus), Lactobacillus brevis (Lactobacillus brevis), lactobacillus bulgaricus (Lactobacillus bulgaricus), lactobacillus reuteri (Lactobacillus reuteri), Lactobacillus salivarius (Lactobacillus salivarius), streptococcus thermophilus (Streptococcus thermophilus), Leuconostoc mesenteroides (Leuconostoc mesenteroides), Lactococcus lactis The lactic acid bacterias such as bacterium (Lactococcus lactis), or the mixture of one or more microorganisms of root enzyme bacterium or Aspergillus.

Be suitable for the present invention Cleasing compositions can be washing cream, mildy wash, face cleaning gel, face cleaning Mu Si, bath foam, The arbitrary forms such as bath oil, hand cleanser, it can be applicable to facial cleansing and clean body.

In one particular embodiment, the emulsion Cleasing compositions contain：

Weight % of oily matter 1%～20, preferably 2%～15 weight %, particularly 3%～10 weight %；

Weight % of tunning 10%～80, preferably 20%～70 weight %, particularly 30%～50 weight %；

Weight % of emulsifying agent 1%～10, preferably 2%～8 weight %, particularly 3%～5 weight %,

Weight % of viscosity modifier 0.01%～5, preferably 0.05%～3 weight %, particularly 0.1%～1 weight %,

Weight % of pure water 10%～80, preferably 15%～60 weight %, particularly 20%～40 weight %.

In one particular embodiment, the gel Cleasing compositions contain：

Weight % of tunning 10%～80, preferably 20%～70 weight %, particularly 30%～50 weight %

Weight % of gel 0.01%～5, preferably 0.05%～3 weight %, particularly 0.1%～1 weight %.

Weight % of water 10%～80, preferably 15%～60 weight %, particularly 20%～40 weight %.

Oily matter

Siloxanes, and also aryl-, the polymethyl siloxane and ring first siloxanes of alkyl-or alkoxyl-replacement.

Also include the straight chain with 2-44 carbon atom and/or side chain unitary and/or binary suitable for the grease of the present invention Carboxylic acid and the saturation with 1-22 carbon atom or the unitary and binary esters of undersaturated straight chain and/or branched-chain alcoho.Similarly, As the grease for the present invention, it is also possible to use difunctional aliphatic's alcohol with 2-36 carbon atom and have 1-22 carbon former The ester of monofunctional aliphatic's carboxylic acid of son.

As the grease for the present invention, the ester of the aliphatic acid with 12-22 carbon atom can also be specifically preferably used Class, such as methyl esters and isopropyl ester, such as methyl laurate, methyl stearate, methyl oleate, methyl erucate, isopropyl palmitate, Isopropyl myristate, isopropyl stearate and/or acid isopropyl.

Additionally, used as the grease for the present invention, the also concrete preferably just own ester of BS, laurate, oleic acid are just The different nonyl ester of last of the ten Heavenly stems ester, Ethylhexyl stearate, palmitic acid, isononyl isononanoate, palmitic acid 2- ethylhexyls, laurate 2- ethyl hexyls Base ester, stearic acid 2- hexyl decyl esters, palmitic acid 2- octyldodecyls, oleic oil alkene ester, erucic acid oil alkene ester and/or oleic acid Mustard ester.

Used as the grease for the present invention, what is be also particularly suitable is dicarboxylic acids esters, for example Di-n-butyl Adipate, the last of the ten Heavenly stems two Sour di-n-butyl, adipic acid two (2- ethylhexyls) ester, (the 2- hexyl decyls) ester of butanedioic acid two and/or the different tridecane of azelaic acid two Base ester.Used as the grease for the present invention, what is be also particularly suitable is diol-lipid, such as two oleic acid glycol esters, two different 13 The sad DOPCP of alkanoic acid glycol ester, two (2 ethyl hexanoic acid) propylene glycol esters, two isostearic acid butanediol esters and/or two.

As the grease for the present invention, carbonic diester class, such as carbonic acid two (2- ethylhexyls) ester can also be used.

Equally applicable is the triglyceride of relative long-chain, i.e. triple esters of glycerine and three acid molecules, and these are sour At least one is the acid molecule of a relative long-chain in molecule.Here by way of example it is mentioned that fatty acid glycerine Three esters, this includes triglyceride, the triglyceride of industrial oleic acid, the different tristearin of the mixture of the caprylic/capric of synthesis The triglycerides of acid and the triglyceride of palm/oleic acid mixture.Straight or branched fatty alcohol can additionally be used Class, such as oleyl alcohol or octyldodecanol, and also fatty alcohol ethers, such as dicaprylyl ether etc..

Used as the grease for the present invention, equally applicable is crude vegetal, for example olive oil, sunflower oil, soybean Oil, peanut oil, rapeseed oil, apricot kernel oil, palm oil and/or jojoba oil, and the also liquid of coconut oil or palm shell oil Part, and also animal oil, the such as liquid part of sperm oil, neat's foot oil or butter.

As the grease for the present invention, can also be using squalene extracting, particularly atoleine and isoparaffin.Can Example with the squalene extracting for using be paraffin oil, White Mineral Oil, isohexadecane, poly decene, petroleum jelly, light liquid paraffin and/or Saualane.Additionally, the esters of aryl carboxylic acid are also suitable, such as benzoic esters, such as satisfying with 1-22 carbon atom And/or the benzoic ether that undersaturated straight or branched alcohol is formed with benzoic acid, such as benzoic acid iso stearyl ester and benzoic acid 2- Octyldodecyl, preferred benzoic acid C12-15 Arrcostabs.

In a preferred embodiment of Cleasing compositions of the present invention, oily matter can be white oil, laurate, Pork and beans One or more combination in cool acid, stearic acid, isobutyl palmitate.

Emulsifying agent

In the still skin cleansing compositions of the present invention, emulsifying agent is further comprises, it is nonionic emulsifier.It is applied to The oil-in-water nonionic emulsifier of the present invention is to live selected from the Hydrophilic nonionic surface with polyoxyethylene chain as hydrophilic group Property agent, polyglyceryl fatty acid ester, polyglycereol fatty alcohol ether, sucrose fatty ester.

In a preferred embodiment of the invention, it is described with polyoxyethylene chain as hydrophilic group hydrophily it is non-from Sub- surfactant is selected from the group：Polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene glycerol mono fatty acid Ester, Crodaret and Crodaret mono fatty acid ester.

As polyoxyethylene fatty acid ester, preferred polyoxyethylene caprylic ester, polyoxyethylene 2 ethyl hexanoic acid ester, polyoxyethylene Decylate, polyoxyethylene laurate, polyoxyethylene myristinate, polyoxyethylene palmitate, polyoxyethylene isostearic acid Ester, Myrj 45, polyoxyethylene oleate, Ju oxygen ethene behenic acid esters etc..

As polyoxyethylene aliphatic alcohol ether, preferred polyoxyethylene octyl ether, polyoxyethylene decyl ethers, polyoxyethylene laural base It is ether, polyoxyethylene myristyl ether, polyoxyethylene palmityl ether, polyoxyethylene iso stearyl ether, polyoxyethylene stearyl base ether, poly- Oxygen ethene oleyl ether, Ju oxygen ethene Shan Yu base ethers etc..

As polyoxyethylene glycerol mono fatty acid ester, preferred polyoxyethylene glycerol list caprylate, the polyoxyethylene glycerol list last of the ten Heavenly stems Acid esters, polyoxyethylene glycerol monolaurate, polyoxyethylene glycerol list myristinate, polyoxyethylene glycerol monopalmitate, Polyoxyethylene glycerol list isostearate, polyoxyethylene glycerol monostearate, TMGO 5, polyoxyethylene Gan oil Dan behenic acid esters etc..

Used as Crodaret, polyoxyethylene structure division preferably wherein is averagely individual, preferred comprising 20-80 Those Crodarets of 30-60 ethylene oxide repeating units.

As Crodaret mono fatty acid ester, preferred Crodaret list caprylate, polyoxy Ethylene hydrogenation castor oil monkey cell, Crodaret monolaurate, Crodaret list Pork and beans Cool acid esters, Crodaret monopalmitate, Crodaret list isostearate, polyoxyethylene hydrogen Change castor oil monostearate, Crodaret monoleate, Crodaret Dan behenic acid esters etc..

As polyglyceryl fatty acid ester, the list-of preferred polyglycereol and many caprylates, the list-of polyglycereol and many 2- ethyl hexyls It is acid esters, the list-of polyglycereol and many decylates, the list-of polyglycereol and many laurates (such as the laurate of Natrulon H-10 five), poly- It is the list of glycerine-and many myristinates, the list-of polyglycereol and many palmitates, the list-of polyglycereol and many isostearates, poly- The list of glycerine-and many stearates (such as the distearate of polyglycereol -3), the list-of polyglycereol and many oleates are (such as polyglycereol -2 Dioleate), the list-of polyglycereol and Duo behenic acid esters etc..

As above-mentioned polyglycereol fatty alcohol ether, the fatty alcohol that the polyglycereol fatty alcohol ether is formed preferably wherein be saturation or It is undersaturated and with 8-22 carbon atom and polyglycerol moiety is averagely poly- sweet comprising 2-60 glycerine repetitive Oil and fat alcohol ether.As the example, it can be mentioned that：It is polyglycereol Octyl Ether, polyglycereol decyl ethers, polyglycereol lauryl ether, poly- sweet It is oily myristyl ether, polyglycereol palmityl ether, polyglycereol iso stearyl ether, polyglycereol stearyl ether, polyglycereol oleyl ether, poly- sweet You Shan Yu base ethers etc..Particularly preferably wherein forming the fatty alcohol of the polyglycereol fatty alcohol ether is saturated or unsaturated and has There is 8-18 carbon atom and polyglycerol moiety averagely includes the polyglycereol fatty alcohol ether of 3-15 glycerine repetitive, especially It is that wherein to form the fatty alcohol of the polyglycereol fatty alcohol ether be saturated or unsaturated and with 10-14 carbon atom and poly- Glycerine structure division is averagely comprising the polyglycereol fatty alcohol ether of 3-5 glycerine repetitive, such as lauryl ether of polyglycereol -4.

As sucrose fatty ester, the list-of preferably sucrose and many caprylates, the list-of sucrose and many 2 ethyl hexanoic acid esters, sugarcane The list of sugar-and many decylates, the list-of sucrose and many laurates (such as sucrose dilaurate), the list-of sucrose and many nutmegs Acid esters, the list-of sucrose and many palmitates (such as the palmitate of sucrose six), the list-of sucrose and many isostearates, sucrose Single-and many stearates, the list-of sucrose and many oleates, the list-of sucrose and many behenic acid esters etc..

Can be containing viscosity-controlling agent and gel in the composition of the present invention, it is hydroaropic substance, the aqueous materials Matter is selected from water-soluble polymer.

Can be natural polysaccharide class as water-soluble polymer, such as xanthans, Arabic gum, guar gum, crust Plain derivative (such as quaternized hydroxypropyl chitin), hyaluronic acid, xanthan gum etc..

As water-soluble polymer, semi synthetic polymer, such as modified cellulose class are can also be, it includes that methylol is fine Dimension element, hydroxyethyl cellulose, hydroxypropyl cellulose, quaternized cellulose etc..

Further, composition of the invention can contain polyalcohol, and the polyalcohol that can be used for the present invention is that have 1 to 6 The polyalcohol of individual carbon atom, including propane diols, hexylene glycol, glycerine and propane diols.

Annexing ingredient

The present invention plot composition can include annexing ingredient, these annexing ingredients can by technical staff according to it is required most The characteristic of finished product is selected, and these annexing ingredients of the moon are suitable to make said composition more attractive or make it have additional use Beneficial effect.

The independent consumption of annexing ingredient is usually by weight of the composition 0.001% to 10 weight %, preferably 0.01-5 weight %.

Various other annexing ingredients can be formulated in the composition of the present invention.These components but it is not limited to moisturizing The compositions such as agent, whitening agent, antioxidant, conditioner, preservative, pH adjusting agent, colouring agent, spices, chelating agent.

Foaming surfactant

The present composition is substantially free of foaming surfactant, and the foaming surfactant foams selected from anion Surfactant, nonionic lather surfactants, both sexes foaming surfactant and their mixture.

Anionic lathering surfactant agent non-limitative example includes sarcosinate, sulfate, isethionate, taurine Salt, phosphate, lactate, glutamate and their mixture.

Nonionic foaming surfactant includes alkyl glucoside, alkyl polyglucoside, polyhydroxy fatty acid amide, alcoxyl Base fatty acid ester, foaming sucrose ester, amine oxide and their mixture.

" both sexes foaming surfactant " includes zwitterionic surfactant, and it is little as amphoteric surfactant one Class is known to the skilled formulator of this area.Can be lived using quite extensive both sexes foam surface in the present composition Property agent.The non-limitative example of both sexes or zwitterionic surfactant is selected from glycine betaine, sulfobetaines, weight ratio beet Alkali, alkyhminoacetates, iminodiacetic alkanoate, aminoalkanoates and their mixture.

Description of the drawings

Fig. 1 is using the tunning Cleansing Foam of shell containing corn ginseng with rice bran fermentation cleaning powder face cleaning skin transdermal dehydration ratio Relatively scheme.

Fig. 2 is using the tunning Cleansing Foam of shell containing corn ginseng with rice bran fermentation cleaning powder face cleaning skin hydration degree water ratio Relatively scheme.

Fig. 3 is using the tunning mildy wash of shell containing corn ginseng with the non-smooth points amount ratio of glutinous rice yeast powder face cleaning skin Relatively scheme.

Fig. 4 uses the still Cleansing Foam face cleaning of different-grain diameter fermented maize ginseng shell, the non-smooth comparison diagram of counting out of skin.

Fig. 5 uses different-grain diameter fermented maize ginseng shell Cleansing Foam face cleaning, removes grease comparison diagram.

The still Cleansing Foam of Fig. 6 corn ginseng shell tunnings compares with several Cleansing Foam excitants.

Fig. 7 difference cereal ginseng shell tunning Cleansing Foam face cleanings remove grease comparison diagram.

The mildy wash of Fig. 8 different strain fermented maize ginseng shell products removes grease comparison diagram.

Fig. 9 is compared using the tunning Cleansing Foam of shell containing corn ginseng with the still Cleansing Foam face cleaning anti-inflammatory of fermented maize Figure.

Figure 10 is removed freely using the tunning Cleansing Foam of shell containing corn ginseng with the still Cleansing Foam face cleaning of fermented maize Base comparison diagram.

Specific embodiment

To be best understood from present disclosure, it is embodied as example with reference to some and further illustrates.

Preparation example 1：It is prepared by corn and ginseng shell tunning

(particle diameter is to take 90g corns quarrel and 10g ginseng shell particles：0.15mm～0.25mm, 60 mesh～80 mesh) and 900ml In drinking water, heat sterilization, sterilising conditions are 105 DEG C, 15min, and cooling room temperature is followed by into Lactobacillus casei, and inoculum concentration is 5% Volume.37 DEG C of fermentation 24h～48h.PH to 5.5～6.0 is adjusted, thalline is inactivated, sterilising conditions are 105 DEG C, 15min.

Preparation example 2：It is prepared by corn and ginseng shell tunning

Identical with the method for preparation example 1, difference is that (particle diameter is granulate mixture：0.25mm～0.5mm, 40 mesh～60 Mesh).

Preparation example 3：It is prepared by corn and ginseng shell tunning

Identical with the method for preparation example 1, difference is that (particle diameter is 0.1mm～0.15mm to granulate mixture：80 mesh～120 Mesh).

Contrast preparation example 1：It is prepared by tunning

Identical with the method for preparation example 1, difference is that (particle diameter is granulate mixture：＜ 0.1mm, more than 120 mesh).

Contrast preparation example 2：It is prepared by corn fermentation product

Identical with the method for preparation example 1, difference is that (particle diameter is granulate mixture：＞ 0.5mm, below 40 mesh).

Contrast preparation example 3：With reference to the rice bran ferment particulate of JP2001271096A

Contrast prepares ice-cold 4：With reference to the glutinous rice flour tunning of CN103211749A

Contrast preparation example 5：Frosted particle, is walnut frosted particulate, and particle diameter is 0.15mm～0.25mm, 60 mesh～80 mesh.

Fermentation composition preparation example 1-3 and the still skin cleansing compositions sensory effects of comparative example 1-5 are evaluated

5 expert opinion group members are selected, sensory evaluation is carried out in such a way

Respectively using embodiment 1-3 and the still skin cleansing compositions of comparative example 1-5, then using effect makes scoring. Granular sensation is with feeling to make evaluation.Cleaning effect carries out skin oil and fat assay by MPA580 skinanalysis apparatus, according to making Carry out comprehensive marking to composition with impression, standard is non-stimulated when using, it is easy to apply when using, use it is rear moisten, use after Clearly, 1 point is respectively accounted for using rear skin is smooth, has one not meet and deduct 1 point.

[1] the corn ginseng shell tunning of fermentation composition preparation example 1

[2] the corn ginseng shell tunning of fermentation composition preparation example 2

[3] the corn ginseng shell tunning of fermentation composition preparation example 3

[4] the corn ginseng shell tunning of preparation example 1 is contrasted

[5] the corn ginseng shell tunning of preparation example 2 is contrasted

[6] with reference to the rice bran ferment particulate of JP2001271096A

[7] with reference to the glutinous rice flour tunning of CN103211749A

[8] frosted particle be walnut frosted particulate, particle diameter be 0.15mm～0.25mm, 60 mesh～80 mesh.

Conclusion：Perceptual effect is optimal after the corn ginseng shell tunning cleaning of embodiment 1-3, and has good grease Elimination effect, the wherein particle sizes of grains of embodiment 1 are more excellent with ginseng shell fermentate mixed effect in 0.15mm～0.25mm.

Embodiment 1 and the composition effect evaluation of comparative example 3

20 volunteers are divided into two groups, are divided into the still mildy wash group of corn ginseng shell tunning and ferment rice bran Powder group, volunteer is twice daily using corn ginseng shell tunning mildy wash and ferment rice bran powder face cleaning, routine use phase With placebo creams skin care.After 8 weeks, MPA580 tests skin hydration degree and transdermal dehydration.

As a result show that corn ginseng shell tunning mildy wash group skin hydration degree is higher than ferment rice bran using after 8 weeks Group, transdermal percentage of water loss is less than ferment rice bran group.Illustrate in the still mildy wash of tunning that nutrition can more fill part to be inhaled by skin Receive, while there is stronger enhancing skin barrier function.

Embodiment 1 and the ice-cold 4 still composition effect evaluation of contrast

20 volunteers are divided into two groups, are divided into the still Cleansing Foam group of corn ginseng shell tunning and fermentation glutinous rice Powder cleaning agent group, volunteer uses the still Cleansing Foam of corn ginseng shell and fermentation glutinous rice flour cleaning agent face cleaning, VISIA after 5min Full face analysis instrument determines the non-smooth points amount of skin surface.

As a result show that the non-smooth reduced rate of the still Cleansing Foam group skin surface of corn ginseng shell tunning is significantly high In fermentation glutinous rice flour cleaning agent.Illustrate that the effect of the gentle frosted particle in the still Cleansing Foam of corn fermentation product removes more by force skin Unnecessary dirt around excess surface cutin and pore.

Embodiment 1-3 and the still Cleansing Foam contrasts of the ice-cold 1-2 of contrast

30 volunteers are divided into 6 groups, respectively using 5 kinds of different-grain diameter corn ginseng shell Cleansing Foam face cleanings and blank Cleansing Foam.Blank group is the still mildy wash without tunning.Face cleaning is dried and test after 5min facial smoothness and face naturally Portion's grease situation of change.

As a result showed that 60 mesh～80 mesh sieve corn particle ginseng shell tunning Cleansing Foam groups were reduced in non-smooth point Best results in rate and oil stain removing rate.Particle is excessive cannot very well to be disperseed and rub during face cleaning, the too small funeral of particle Lose frosted particle to feel and effect.

Embodiment 4

The still Cleansing Foam of corn ginseng shell tunning compares with commercially available several mildy wash excitants

Sample number into spectrum	Cleaning composition
		Embodiment 2	Corn ginseng shell tunning
Sample 1	Sodium lauryl tri(oxyethyl) sulfate, Cocoamidopropyl betaine
		Sample 2	Glycerin monostearate, sodium cocoyl glutamate
Sample 3	Laruyl alcohol sodium sulfovinate, APG
		Sample 4	Odium stearate, Sodium myristate

Commercially available mildy wash to be measured and corn ginseng shell tunning mildy wash are taken, it is 10% to be made into active material fraction Solution, adds a certain amount of zeins (zein), and at 25 DEG C 2h is stirred, and then filters.Filtrate is fixed with micro kelvin Nitrogen method measures the mass fraction (A) of nitrogen.The quality of nitrogen in the surfactant solution for be not added with zein can be measured with same method Fraction (B).

Zein values=A-B, institute's nitrogen content mg (or g)/L is represented in zein value solution, and the bigger explanation surface of zein values is lived Property agent excitant is bigger.

As a result (accompanying drawing 6) shows that commercially available several mildy wash Zein values are washed one's face far above still corn ginseng shell fermentation Breast, illustrates that several mildy wash excitants containing Common surface activating agent are far above still corn fermentation product mildy wash.

Embodiment 5 prepares the still mildy wash of different cereal ginseng shell ferment particulates

Identical with the method for tunning preparation example 1, it is rice, millet, black rice, Chinese sorghum, coix seed (grain that difference is cereal Footpath is：0.25mm～0.5mm, 40 mesh～60 mesh) in one kind.Blank control group is the mildy wash without tunning.Its Cleaning effect is shown in accompanying drawing 7：As a result rice, millet, black rice, Chinese sorghum, coix seed tunning and ginseng shell tunning are shown Mildy wash remove grease effect and be much better than blank group without tunning.

Embodiment 6 prepares the still mildy wash of different microorganisms fermented grain particle

Identical with the method for embodiment 1, difference is to use different microorganisms：Microorganism is respectively adopted saccharomyces cerevisiae The one of (Saccharomyces cerevisiae), Rhizopus javanicus (Rhizopus), aspergillus oryzae (Aspergill us oryzae) Plant and fermented.(particle diameter is：0.25mm～0.5mm, 40 mesh～60 mesh).Blank control group is without the still of tunning Mildy wash.Its cleaning effect is shown in Fig. 8：As a result show that still mildy wash cleaning effect prepared by several microbial fermentation products is far excellent In the still mildy wash without fermented grain thing.

The corn of embodiment 7 and the still mildy wash of ginseng shell fermentation compare with corn fermentation mildy wash antiphlogistic effects.

20 long-term volunteers with scytitis and acne recurrent exerbation, are equally divided into two groups, are corn ginseng fruit The still Cleansing Foam group of shell tunning and the still Cleansing Foam group of non-fermented maize, volunteer twice daily uses corn ginseng shell The still Cleansing Foam of tunning and the still Cleansing Foam face cleaning of non-fermented maize, the identical placebo creams skin care of routine use.Using 4 Zhou Hou, compares the degree of acne and scytitis, and its result shows and uses corn and the still mildy wash group face of fermented ginseng scorching Disease improves degree and is substantially better than control group.As a result accompanying drawing 9 is seen.

The corn of embodiment 8 and the still mildy wash of ginseng shell fermentation compare with corn fermentation mildy wash non-oxidizability effect.

The corn fermentation product mildy wash and corn of the present invention and ginseng shell tunning mildy wash difference 10 dilute Times.Experiment samples 1ml with vitamin C as positive control, adds the DPPH- ethanol solution 3.0ml of 0.04mg/ml, lucifuge to stand 30min, 12000rpm are centrifuged 10min, the mensuration absorbance under 517nm.Calculate DPPH clearance rates.As a result fementative composition is shown Thing mildy wash has more excellent antioxidation activity.As a result accompanying drawing 10 is seen.

Claims (6)

1. a kind of skin cleansing compositions, it contains weight % of tunning 10%～80, and the tunning is by cereal and people Ginseng shell co-fermentation is formed, and wherein cereal and the weight ratio of ginseng shell are 80: 20-95: 5, and the tunning is cereal After crushing with ginseng shell, the product that Jing fermentables are obtained, the cereal and ginseng shell of the crushing are with 0.15mm The particle of～0.25mm particle diameters,

One or more of the cereal in rice, millet, corn, black rice, Chinese sorghum, adlay,

The tunning is prepared by the method for following step：

(1) culture medium heat sterilization, it is cereal-granules and ginseng shell particle to support base,

(2) fermented bacterium for having activated is accessed, inoculum concentration is 0.1%～20% volume,

(3) ferment, temperature is 25 DEG C～45 DEG C, fermentation time is 24-48 hours,

(4) pH is adjusted, scope is 4.0～7.0,

(5) sterilize, sterilising temp is 65 DEG C～120 DEG C, sterilization time is 15min～60min.

2. composition as claimed in claim 1, it is characterised in that composition is that washing cream, mildy wash, face cleaning gel, face cleaning are solemn This, bath foam, bath oil, hand cleanser.

3. composition as claimed in claim 1, wherein described microorganism is selected from saccharomycete, lactobacillus, lactic acid bacteria, root enzyme One or more mixing in bacterium, Aspergillus.

4. composition as claimed in claim 1, in described culture medium, further adds nutriment, the nutriment Selected from glucose, lactose, sucrose and/or maltose.

5. composition as claimed in claim 1, it is emulsion, is contained：Weight % of oily matter 1%～20, tunning 10%～80 weight %, weight % of emulsifying agent 1%～10, weight % of viscosity modifier 0.01%～5, the weight of pure water 10%～80 Amount %.

6. composition as claimed in claim 1, it is gel, and it contains：Weight % of tunning 10%～80, gel 0.01%～1 weight %, weight % of pure water 10%～80.