CN106466291B - A kind of still cleaning products and preparation method thereof containing fermented grain object - Google Patents

Abstract

A kind of still cleaning products and preparation method thereof containing fermented grain object, the present invention relates to a kind of fermented grain product and its applications in still cleaning products.This method is followed by fermenting into microorganism, sterilizing obtains the fermented grain product comprising thallus, ferment filtrate and solid particle first to grain culture medium heat sterilization.Using the fermented grain product in cleaning products, foaming surfactant is free of in the cleaning products, such cleaning products must remove skin surface grease, the effect of smooth skin with good after tested.Fermented grain product prepares cleaning products with nutrition skin, mildly removes skin keratin, low irritant, the mild feature of safety.

Description

A kind of still cleaning products and preparation method thereof containing fermented grain object

Technical field

The present invention relates to a kind of still cleaning compositions, the especially still skin cleaning group containing fermented grain product Object is closed, does not contain foaming surfactant more particularly.

Background technique

In currently used cleaning products, no alveolitoid cleaning products generally contain appropriate oil content in formula, Sometimes also contain a small amount of surfactant, it is characterized in that foam is less, it is relatively milder, with the foam containing exhibiting high surface activating agent Type facial cleanser is compared, and is had low irritant, not will cause excessive cleaning, the spy for being suitble to dry skin and sensitive to use Sign.But a disadvantage is that it is smaller to skin cleaning dynamics, while not having the removal extra cutin function of epidermis.

Frosted type cleaning products are widely used in daily chemicals field.Frosted type cleaning products its mainly form into Part are as follows: abrasive particle, surfactant and other additives.Abrasive particle therein can be mainly divided into organic abrasive particle and Inorganic abrasive particle.Wherein organic abrasive particle includes natural shell particle, fruit stone particle, conch meal, pearl powder.Inorganic frosted Particle has bamboo charcoal, kaolin, salt particle, quartz sand, calcium carbonate etc..It is mainly characterized by making in addition to the decontamination of cleaning agent in formula With outer, abrasive particle mechanical friction effect can also be passed through and remove extra cutin, dust and packet spot etc..But if abrasive particle Composition is really up to the mark or improper use can cause skin friction to damage, cuticula excessively thin acceleration skin exfoliation (especially stemness and neutrality Skin consumer).

Nowadays, advocate natural Never Ending Fashion to have swept the globe, beauty and skin care circle also can not make an exception, and start people to natural peace The upsurge that full skin care item are pursued, some natural, safety skin care item Effect raw materials pour in the visual field.Health of the five cereals to human body Play the role of very favorable, protein, carbohydrate, fat, minerals and multivitamin rich in five cereals, These nutritions are quite helpful to skin nursing.It is protected especially by the cereal of microbial fermentation for having in skin nursing It holds moisture content of skin, enhancing skin elasticity, enhancing skin barrier, promote the generation of subcutaneous collagen albumen and certain anti-oxidation efficacy.

KR20130019192A discloses plum, pomegranate, citrus, rice and crushes, and lactic acid bacteria culture is added, and centrifuge separation obtains Filtrate is obtained, is used for Exfoliating Scrub, but the cleaning products of this method preparation have no good report for the removal of skin oil and fat.

KR20090115844A discloses Chinese herbal medicine (the especially root of Dahurain angelica), red bean, rice bran and lactobacillus-fermented is added, filtering Filtrate cleans vagina for the substitute of detergent or soap, has the growth for preventing vagina mucosa harmful bacteria, removes different The effect of taste.But the cleaning products of this method preparation are to have no to report skin surface oil stain removing.

JP2001271096A discloses application of the rice bran as detergent, and the bran powder, which passes through, is added lactic acid bacteria, and 58 DEG C Cultivation and fermentation 6 hours, citric acid 5% is added, dry, sieving obtains.The document compares ferment rice bran powder with azymic rice bran Powder cleaning skin effect, ferment rice bran more can be improved skin hydration degree as the result is shown.But the powdered cleaning agent uses Preceding needs smear skin after sizing mixing in advance with liquid or egg liquid mixing, and use is cumbersome, and the nutrition in short time mixed-powder Substance can not be released cmpletely, cause nutrition that cannot sufficiently be absorbed by the skin.

CN103211749A discloses through microbial fermentation glutinous rice flour the method for preparing shampoo, but it selects bacterium Strain fermentation time is up to 15 days, will affect the granular sensation that glutinous rice flour has originally after fermentation.Weaken the clean effect of its frosted Fruit.

Therefore there is still a need for find a kind of method for being suitably used for still cleaning products.

Contain glutathione (GSH) in corn, be a kind of tripeptides formed by glutamic acid, cysteine, glycine combination, Wherein cysteine is able to suppress the activity of tyrosinase during melanin production, and melanin is hindered to be formed, and plays skin beauty Contour painting effect.GSH is a kind of natural, neutralizes the free radical that radiation generates, and plays delaying senility function.It is rich in corn The vitamins such as VB1, VB2, VB5, VB6, VE, VC and carrotene can enhance skin metabolism, plump subcutaneous tissue, make skin Skin high resilience and gloss.

Currently, being mainly used in field of food using microbial fermentation bread basket both at home and abroad.CN101164428A is disclosed The method that corn flour, the dregs of beans etc. of fermentation prepare biological feedstuff, the food of the viscous corn flour of CN103404779A lactobacillus-fermented Product, and Wang Zhiwei etc. " lactic acid bacteria fermented grain food --- the research of sour congee zymotechnique, processing of farm products, 2010.2,27 ~ 30 " It discloses with glutinous rice, millet, rotten rice, corn quarrel as raw material, using the excellent lactobacillus-fermented of character, measures sample ammonia after fermentation Base acid content and total amount increased significantly." the Hypolipidemic effects of lactic acid such as Immaculata bacteria fermented cereal in rats”. Banjoko et al.Lipids in Health and Disease, 2012.11,170 disclose lactobacillus acidophilus, Bifidobacterium and Lactobacillus helveticus mixed fermentation corn flour, in jade Well-grown in rice flour, corn flour reaches acceptable taste after fermentation.And find that the food of the mixed fermentation has inhibition fat The effect of absorption^[2]." the Lactic acid bacteria producing B-group vitamins:a such as Vittorio Great potential for functional cereals products ", Appl Microbiol Biotechnol, 2012,96:1383-1394 disclose and can improve VB race in fermented cereal by the screening of microorganism and the different of fermentation condition Content, develop in fermented grain product micro-organisms vitamin." Agricultural University of the Inner Mongol, master's knowledge opinion such as Wu little Yan Text, 2013 " report with lactobacillus-fermented semen coicis, and polysaccharide in fermentation liquid, content of peptides, which do not ferment, increases 4 ~ 8 times, and Fermentation liquid has good oxidation resistance.Fu Liang etc. " development of fermented type rice milk, food and mechanical, 2006,5:103 ~ 105. " with Rice is raw material, accesses a certain amount of lactic acid bacteria after the pretreatment such as gelatinization and ferments, has obtained sense organ and structural state is good Fermented type rice milk." development of millet fermented beverage, Journal of Zhengzhou Grain College, 1999,3:41 ~ 43. " use Gong Yuansheng etc. Koji and saccharomycete two-step fermentation obtain the good millet fermented beverage of taste.It can be seen that microorganism is using in cereal While nutriment, itself generates some metabolites, so that the macromolecular in cereal is decomposed into the lesser substance of molecular weight, more It is easy to absorb.Also the nutriment for being difficult to discharge in cereal is released simultaneously.In addition it can produce through microbial fermentation peculiar Substance such as lactic acid, polysaccharide, antibiotic, antioxidant and bioconversion product make product have more high bioactivity, be easy to The effects of body absorbs.But application of the fermented grain product in still cleaning products has not been reported.

Inventors have found that fermented grain product is applied in cleaning compositions, especially still skin cleans combination In object, since fermented grain product contains much starch and dextrin, there is absorption scavenging effect well to skin oil and fat, secondly, Fermented grain product is applied in cleaning products, and the granular sensation and mild frosted sense, cooperation for remaining cereal cleaned Abrasive action in journey can mildly remove skin surface aging cutin.In addition the nutriment such as bacterium in fermented grain product Body, lactic acid, polypeptide, amino acid, polysaccharide, vitamin etc. also impart cleaning products and nourish skin, prevent from cleaning excessive bring The senses of discomfort such as dry skin, tight.

Therefore, the present invention relates to by fermented grain product be applied to still skin cleansing compositions in, the composition table Face activating agent remains cereal nutrition and granular sensation in the composition, can mildly remove skin surface aging cutin, clearly Except surface grease, skin nutrition soothes the skin stimulation, while having the characteristics that low irritant, safety temperature.

Summary of the invention

The present invention relates to application of the fermented grain product in still skin cleansing compositions.The fermented grain product is logical Grain culture medium heat sterilization is crossed, is followed by fermenting into microorganism, sterilizing obtains the paddy comprising thallus, ferment filtrate and solid particle Object tunning.The fermented grain product passes through the product that cereal-granules obtain after microbial fermentation, with 0.02mm ~ 1mm, preferably 0.05mm ~ 0.4mm, the partial size of more preferable 0.15mm ~ 0.25mm.

Further, the present invention relates to the still skin cleansing compositions containing corn fermentation product, the cleaning combinations Object is essentially free of surfactant.

Corn fermentation product of the invention is prepared by following step:

1, culture medium heat sterilization

2, activated fermenting microbe is accessed

3, it ferments

4, pH is adjusted

5, it sterilizes

Wherein, culture medium is that corn particle and pure water are prepared.Grain content is 3% ~ 30 weight %, sterilizing in its culture medium Temperature is 50 DEG C ~ 120 DEG C, and the time is 10min ~ 30min.

Microbial inoculant amount is 0.1% ~ 20% volume.

Fermentation temperature is 25 DEG C ~ 45 DEG C

Adjusting pH range is 4.0 ~ 7.0.

The further pH range that adjusts is 5.0 ~ 6.0.

Sterilising temp is 65 DEG C ~ 120 DEG C.Sterilization time control is 15min ~ 60min.

Further, nutriment can be added in culture medium.The nutriment be selected from glucose, lactose, sucrose and/or Maltose, preferably glucose.

The microorganism is selected from brewer's yeast (Saccharomyces cerevisiae), candida utili Saccharomycete such as (Candida utilis) or lactobacillus acidophilus (Lactobacillus acidophilus), lactobacillus paracasei (Lactobacillus paracasei), Lactobacillus rhamnosus (Lactobacillus rhamnosus), Lactobacillus brevis (Lactobacillus brevis), lactobacillus bulgaricus (Lactobacillus bulgaricus), lactobacillus reuteri (Lactobacillus reuteri), Lactobacillus salivarius (Lactobacillus salivarius), streptococcus thermophilus (Streptococcus thermophilus), Leuconostoc mesenteroides (Leuconostoc mesenteroides), Lactococcus lactis The mixture of lactic acid bacterias or the root enzyme bacterium such as bacterium (Lactococcus lactis) or one or more of microorganisms of Aspergillus.

Being suitable for still skin cleansing compositions of the invention can be the arbitrary forms such as cleanser, cleaning gel, can Applied to facial cleansing and clean body.

In one particular embodiment, the still emulsion cleaning compositions contain:

Oily matter, typically refer to allow in hydrophobic combination or oil-phase component or cosmetics using whole grease groups Point.It can be selected from least one of conventionally used vegetable oil, mineral oil, silicone oil and synthetic oil grease or various Wax.

Being suitable for the invention silicone oil quasi-grease is, for example, 1% ~ 20 weight of dimethyl silicone polymer and ring first silicon oxygen oily matter Measure %, 2% ~ 15 weight % of preferred content, especially 3% ~ 10 weight %

10% ~ 80 weight % of fermented grain product, 20% ~ 70 weight % of preferred content, especially 30% ~ 50 weight %.

1% ~ 10 weight % of emulsifier, 2% ~ 8 weight % of preferred content, especially 3% ~ 5 weight %,

0.01% ~ 5 weight % of viscosity modifier, preferably 0.05% ~ 3 weight %, especially 0.1% ~ 1 weight %,

10% ~ 80 weight % of pure water, 15% ~ 60 weight % of preferred content, especially 20% ~ 40 weight %.

In one particular embodiment, the still gel agent cleaning compositions contain:

10% ~ 80 weight % of fermented grain product, preferably 20% ~ 70 weight %, especially 30% ~ 50 weight %

0.01% ~ 5 weight % of gelling agent, preferably 0.05% ~ 3 weight %, especially 0.1% ~ 1 weight %.

10% ~ 80 weight % of pure water, preferably 15% ~ 60 weight %, especially 20% ~ 40 weight %.

Oily matter

Siloxanes, and there are also aryl-, alkyl-or the substituted polymethyl siloxanes and ring first siloxanes of alkoxy-.

Being suitable for the invention grease further includes the straight chain and/or branch unitary and/or binary with 2-44 carbon atom Carboxylic acid and the saturations or undersaturated straight chain with 1-22 carbon atom and/or the unitary and binary esters of branched-chain alcoho.Similarly, As the difunctional aliphatic's alcohol that for grease of the invention, also can be used with 2-36 carbon atom and have 1-22 carbon former The ester of monofunctional aliphatic's carboxylic acid of son.

It, can also specifically it is preferable to use the esters of the fatty acid with 12-22 carbon atom as grease of the invention Class, such as methyl esters and isopropyl ester, such as methyl laurate, methyl stearate, methyl oleate, methyl erucate, isopropyl palmitate, Isopropyl myristate, isopropyl stearate and/or acid isopropyl.

In addition, the also specific preferably just own ester of n-butyl stearate, lauric acid, oleic acid are just as grease of the invention The different nonyl ester of last of the ten Heavenly stems ester, Ethylhexyl stearate, palmitinic acid, isononyl isononanoate, palmitinic acid 2- ethylhexyl, lauric acid 2- ethyl hexyl Base ester, stearic acid 2- hexyl decyl ester, palmitinic acid 2- octyldodecyl, oleic oil enester, erucic acid oil enester and/or oleic acid Mustard ester.

It is dicarboxylic acids esters, such as Di-n-butyl Adipate, the last of the ten Heavenly stems two as what is for grease of the invention, be also particularly suitable Sour di-n-butyl, adipic acid two (2- ethylhexyl) ester, (the 2- hexyl decyl) ester of succinic acid two and/or the different tridecane of azelaic acid two Base ester.It is diol-lipid, such as two oleic acid glycol esters, two different 13 as what is for grease of the invention, be also particularly suitable The sad neopentyl glycol ester of alkanoic acid glycol ester, two (2 ethyl hexanoic acid) propylene glycol esters, two isostearic acid butanediol esters and/or two.

As for grease of the invention, carbonic diester class can also be used, such as carbonic acid two (2- ethylhexyl) ester.

Equally applicable is the triglyceride of opposite long-chain, i.e. triple esters of glycerol and three acid molecules, these acid At least one in molecule is the acid molecule of an opposite long-chain.Here by way of example it is mentioned that fatty acid glycerine Three esters, this includes the triglyceride of mixture, the triglyceride of industrial oleic acid, the different tristearin of the caprylic/capric of synthesis The triglycerides and palm/oleic acid mixture triglyceride of acid.What additionally be can be used is linear chain or branched chain fatty alcohol Class, such as oleyl alcohol or octyldodecanol, and there are also fatty alcohol ethers, such as dicaprylyl ether etc..

As for grease of the invention, equally applicable is crude vegetal, such as olive oil, sunflower oil, soybean Oil, peanut oil, rapeseed oil, apricot kernel oil, palm oil and/or jojoba oil, and there are also the liquid of coconut oil or palm shell oil Part, and there are also animal oil, the such as liquid part of sperm oil, neat's foot oil or butter.

As for grease of the invention, squalene extracting, especially atoleine and isoparaffin can also be used.It can Example with the squalene extracting used be paraffin oil, White Mineral Oil, isohexadecane, poly decene, petroleum jelly, light liquid paraffin and/or Saualane.In addition, the esters of aryl carboxylic acid be also it is suitable, such as the esters of benzoic acid, such as satisfying with 1-22 carbon atom And/or the benzoic ether that unsaturated linear chain or branched chain alcohol and benzoic acid are formed, such as benzoic acid iso stearyl ester and benzoic acid 2- Octyldodecyl, preferably benzoic acid C12-15 Arrcostab.

According to the present invention, oily matter, the total amount based on composition, content are 1% ~ 20 weight %, preferably 2% ~ 15 weight Measure %, more preferable 3% ~ 5 weight %.

In a preferred embodiment of the still skin cleansing compositions of the present invention, oily matter can be white oil, the moon The combination of one or more of cinnamic acid, myristic acid, stearic acid, isobutyl palmitate.

Emulsifier

In still skin cleansing compositions of the invention, emulsifier is further comprised, is nonionic emulsifier.It is suitable for Oil-in-water nonionic emulsifier of the invention is selected from living as the Hydrophilic nonionic surface of hydrophilic group with polyoxyethylene chain Property agent, polyglyceryl fatty acid ester, polyglycereol fatty alcohol ether, sucrose fatty ester.

According to the present invention, based on the total amount of composition, the dosage of emulsifier is 1% ~ 10 weight %, preferably 2% ~ 8 weight Measure more preferable 3% ~ 5 weight % of %.

In a preferred embodiment of the invention, it is described with polyoxyethylene chain as hydrophilic group hydrophily it is non-from Sub- surfactant is selected from the group: polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene glycerol mono fatty acid Ester, Crodaret and Crodaret mono fatty acid ester.

As polyoxyethylene fatty acid ester, preferably polyoxyethylene caprylic ester, polyoxyethylene 2 ethyl hexanoic acid ester, polyoxyethylene Decylate, polyoxyethylene laurate, polyoxyethylene myristinate, polyoxyethylene palmitate, polyoxyethylene isostearic acid Ester, Myrj 45, polyoxyethylene oleate, Ju ethylene oxide behenic acid ester etc..

As polyoxyethylene aliphatic alcohol ether, preferably polyoxyethylene octyl ether, polyoxyethylene decyl ethers, polyoxyethylene laural base Ether, polyoxyethylene palmityl ether, polyoxyethylene iso stearyl ether, polyoxyethylene stearyl base ether, gathers at polyoxyethylene myristyl ether Ethylene oxide oleyl ether, Ju ethylene oxide Shan Yu base ether etc..

As polyoxyethylene glycerol mono fatty acid ester, preferably polyoxyethylene glycerol list caprylate, the polyoxyethylene glycerol list last of the ten Heavenly stems Acid esters, polyoxyethylene glycerol monolaurate, polyoxyethylene glycerol list myristinate, polyoxyethylene glycerol monopalmitate, Polyoxyethylene glycerol list isostearate, polyoxyethylene glycerol monostearate, TMGO 5, polyoxyethylene Gan oil Dan behenic acid ester etc..

As Crodaret, polyoxyethylene structure division preferably wherein averagely includes 20-80, preferably Those of 30-60 ethylene oxide repeating units Crodaret.

As Crodaret mono fatty acid ester, preferably Crodaret list caprylate, polyoxy Ethylene hydrogenation castor oil monkey cell, Crodaret monolaurate, Crodaret list Pork and beans Cool acid esters, Crodaret monopalmitate, Crodaret list isostearate, polyoxyethylene hydrogen Change castor oil monostearate, Crodaret monoleate, Crodaret Dan behenic acid ester etc..

As polyglyceryl fatty acid ester, the preferably mono- and more 2- ethyl hexyl of the mono- and more caprylate of polyglycereol, polyglycereol Acid esters, the mono- and more decylate of polyglycereol, polyglycereol mono- and more laurate (such as five laurate of Natrulon H-10), poly- The mono- and fleshiness myristate of glycerol, the mono- and more palmitate of polyglycereol, polyglycereol mono- and polyisocyanate stearate, poly- Mono- and heavy wool acid esters (such as polyglycereol -2 of the mono- and more stearate (such as -3 distearate of polyglycereol) of glycerol, polyglycereol Dioleate), the mono- and Duo behenic acid ester of polyglycereol etc..

As above-mentioned polyglycereol fatty alcohol ether, formed preferably wherein the polyglycereol fatty alcohol ether fatty alcohol be saturation or It is unsaturated and have 8-22 carbon atom and polyglycerol moiety averagely include gathering for 2-60 glycerol repetitive unit it is sweet Oil and fat alcohol ether.As the example, it can be mentioned that: polyglycereol Octyl Ether, polyglycereol decyl ethers, polyglycereol lauryl ether, gather it is sweet Oily myristyl ether, polyglycereol palmityl ether, polyglycereol iso stearyl ether, polyglycereol stearyl ether, polyglycereol oleyl ether, gather it is sweet You Shan Yu base ether etc..The fatty alcohol for particularly preferably wherein forming the polyglycereol fatty alcohol ether is saturated or unsaturated and has There is 8-18 carbon atom and polyglycerol moiety averagely includes the polyglycereol fatty alcohol ether of 3-15 glycerol repetitive unit, especially Be wherein formed the polyglycereol fatty alcohol ether fatty alcohol be it is saturated or unsaturated and have 10-14 carbon atom and gather Glycerol structure division averagely includes the polyglycereol fatty alcohol ether of 3-5 glycerol repetitive unit, such as -4 lauryl ether of polyglycereol.

As sucrose fatty ester, mono- and more 2 ethyl hexanoic acid ester, the sugarcane of the mono- and more caprylate of preferably sucrose, sucrose The mono- and more decylate of sugar, the mono- and more laurate (such as sucrose dilaurate) of sucrose, sucrose mono- and fleshiness cardamom Acid esters, the mono- and more palmitate (such as sucrose six palmitate) of sucrose, sucrose mono- and polyisocyanate stearate, sucrose Mono- and more stearates, the mono- and heavy wool acid esters of sucrose, mono- and Duo behenic acid ester of sucrose etc..

Viscosity-controlling agent and gelling agent can be contained in composition of the invention, be hydroaropic substance, the aqueous materials Matter is selected from water-soluble polymer.

As water-soluble polymer, natural polysaccharide class, such as xanthan gum, Arabic gum, guar gum, crust can be Plain derivative (such as quaternized hydroxypropyl chitin), hyaluronic acid, xanthan gum etc..

As water-soluble polymer, semi synthetic polymer, such as modified cellulose class can also be comprising methylol is fine Tie up element, hydroxyethyl cellulose, hydroxypropyl cellulose, quaternized cellulose etc..

According to the present invention, it is based on total composition, the content of water-soluble polymer is 0.01% ~ 5 weight %, preferably 0.05% ~ 3 weight %, 0.1% ~ 1 weight %

Further, composition of the invention can contain polyalcohol, and polyalcohol for use in the present invention is that have 1 to 6 The polyalcohol of a carbon atom, including propylene glycol, hexylene glycol, glycerol and propylene glycol.According to the present invention, it is based on total composition, it is more The content of first alcohol is 0.1% ~ 15%, preferably 1% ~ 10%, more preferable 3% ~ 5%.

Annexing ingredient

Plot composition of the invention may include annexing ingredient, these annexing ingredients can by technical staff according to it is required most The characteristic of finished product is selected, and these annexing ingredients are suitable for keeping the composition more attractive or make it have additional make Use beneficial effect.

The independent dosage of annexing ingredient is usually 0.001% to 10 weight % by weight of the composition, preferably 0.01-5 weight %.

Various other annexing ingredients can be formulated into composition of the invention.These components but it is not limited to moisturizing The compositions such as agent, whitening agent, antioxidant, thickener, conditioner, preservative, pH adjusting agent, colorant, fragrance, chelating agent.

Foaming surfactant

The present composition is substantially free of foaming surfactant, and the foaming surfactant is sent out selected from anion Foam surfactants, nonionic lather surfactants, both sexes foaming surfactant and their mixture.

Anionic lathering surfactant agent non-limitative example includes sarcosinate, sulfate, isethionate, taurine Salt, phosphate, lactate, glutamate and their mixture.

Nonionic foaming surfactant includes alkyl glucoside, alkyl polyglucoside, polyhydroxy fatty acid amide, alcoxyl Base aliphatic ester, foaming sucrose ester, amine oxide and their mixture.

" both sexes foaming surfactant " includes zwitterionic surfactant, it is small as amphoteric surfactant one Class is known to the skilled formulator of this field.It is living that quite extensive both sexes foam surface can be used in the present composition Property agent.The non-limitative example of both sexes or zwitterionic surfactant is selected from glycine betaine, sulfobetaines, weight ratio beet Alkali, alkyhminoacetates, iminodiacetic alkanoate, aminoalkanoates and their mixture.

Detailed description of the invention

Fig. 1 is compared using the still Cleansing Foam of product containing corn fermentation with the rice bran fermentation transdermal dehydration of cleaning powder face cleaning skin Figure.

Fig. 2 is compared using the still Cleansing Foam of product containing corn fermentation with rice bran fermentation cleaning powder face cleaning skin hydration degree water Figure.

Fig. 3 is using the still facial cleanser of product containing corn fermentation with fermentation glutinous rice flour cleaning agent face cleaning, the non-smooth points of skin Measure situation of change.

Fig. 4 is using the still Cleansing Foam of product containing corn fermentation with the still Cleansing Foam face cleaning of non-fermented maize, skin hydration degree Compare figure.

Fig. 5 is using the still Cleansing Foam of product containing corn fermentation with the still Cleansing Foam face cleaning of non-fermented maize, the transdermal mistake of skin Water compares figure.

Fig. 6 uses the still Cleansing Foam face cleaning of different-grain diameter fermented maize, and the non-smooth points mesh of skin compares figure.

Fig. 7 uses the still Cleansing Foam face cleaning of different-grain diameter fermented maize, removes grease and compares figure.

Fig. 8 corn fermentation product Cleansing Foam compares figure with commercially available several facial cleanser irritations.

The still Cleansing Foam face cleaning of Fig. 9 difference fermented grain product removes grease and compares figure.

The still mildy wash of Figure 10 different strain fermented maize product removes grease and compares figure.

Specific embodiment

To be best understood from the contents of the present invention, further illustrated in conjunction with some specific embodiments.

Preparation example 1: corn fermentation product preparation

It takes in 100g corn quarrel (partial size are as follows: 0.15mm ~ 0.25mm, 60 mesh ~ 80 mesh) and 900ml drinking water, heat sterilization, Sterilising conditions are 105 DEG C, 15min, and cooling room temperature is followed by into Lactobacillus casei, and inoculum concentration is 5% volume.37 DEG C fermentation for 24 hours ~ 48h.PH to 5.5 ~ 6.0 is adjusted, thallus is inactivated, sterilising conditions are 105 DEG C, 15min.

Preparation example 2: corn fermentation product preparation

Identical as 1 method of preparation example, difference is that corn is cut (partial size are as follows: 0.25mm ~ 0.5mm, 40 mesh ~ 60 mesh).

Preparation example 3: corn fermentation product preparation

Identical as 1 method of preparation example, difference is corn quarrel (partial size is 0.1mm ~ 0.15mm:80 mesh ~ 120 mesh).

Compare preparation example 1: corn fermentation product preparation

Identical as 1 method of preparation example, difference is corn quarrel (partial size are as follows: < 0.1mm, more than 120 mesh).

Compare preparation example 2: corn fermentation product preparation

Identical as 1 method of preparation example, difference is corn quarrel (partial size are as follows: > 0.5mm, below 40 mesh).

Compare preparation example 3: referring to the rice bran ferment particulate of JP2001271096A

Compare preparation example 4: referring to the glutinous rice flour tunning of CN103211749A

Compare preparation example 5: preparation method is to be added without microorganism with preparation example 1, difference

The still skin cleansing compositions sensory effects evaluation of preparation example 1-3 and comparative example 1-5

5 expert opinion group members are selected, carry out sensory evaluation in the following way

Embodiment 1-3 and the still skin cleansing compositions of comparative example 1-5 are used respectively, and then using effect makes scoring. Granular sensation is with feeling to make evaluation.Cleaning effect carries out skin oil and fat assay by MPA580 skinanalysis apparatus, according to making Comprehensive marking carried out to composition with impression, standard be when using it is non-stimulated, moistened, after use after easy to apply, use when using Clearly, 1 point is smoothly respectively accounted for using rear skin, there is one not meet and subtracts 1 point.

[1] the corn fermentation product of preparation example 1

[2] the corn fermentation product of preparation example 2

[3] the corn fermentation product of preparation example 3

[4] the corn fermentation product of preparation example 1 is compared

[5] the corn fermentation product of preparation example 2 is compared

[6] referring to the rice bran ferment particulate of JP2001271096A

[7] referring to the glutinous rice flour tunning of CN103211749A

[8] frosted particle is walnut frosted particle, and partial size is 0.15mm ~ 0.25mm, 60 mesh ~ 80 mesh.

Conclusion:

Embodiment 1 and the evaluation of the still composition effect of comparative example 3

20 volunteers are divided into two groups, are divided into the still face cream group of corn and ferment rice bran powder group, volunteer daily two It is secondary to use the still facial cleanser of corn and ferment rice bran powder face cleaning, the identical placebo creams skin care of routine use.After 48 weeks, MPA580 tests skin hydration degree and transdermal dehydration.

As the result is shown using after 48 weeks, the still facial cleanser group skin hydration degree of corn is higher than ferment rice bran group, transdermal dehydration Rate is lower than ferment rice bran group.Illustrate in the still facial cleanser of corn fermentation product that nutrition can more fill part to be absorbed by the skin, simultaneously There is stronger enhancing skin barrier function.

Embodiment 1 and the evaluation of the still composition effect of comparative example 4

20 volunteers are divided into two groups, are divided into the still Cleansing Foam group of corn and fermentation glutinous rice flour cleaning agent group, aspiration Person is using the still Cleansing Foam of corn and glutinous rice flour cleaning agent face cleaning of fermenting, and the full face analysis instrument of VISIA measures skin surface after 5min Non- smooth points amount.

The non-smooth reduced rate of the still Cleansing Foam group skin surface of corn is significantly higher than fermentation glutinous rice flour cleaning as the result is shown Agent.Illustrate the mild frosted particle effect in the still Cleansing Foam of corn fermentation product, it can be compared with removing the extra angle of skin surface by force Extra dirt around matter and pore.

The still Cleansing Foam comparison of embodiment 1-3 and comparative example 1-2

30 volunteers are divided into 6 groups, use 5 kinds of different-grain diameter Cleansing Foam face cleanings and blank control Cleansing Foam respectively.Blank Group is the still mildy wash without fermented grain product.Facial smoothness is tested after face cleaning naturally dry 5min and facial oil becomes Change situation.

Crossing 60 mesh ~ 80 mesh fermented maize particle Cleansing Foam groups as the result is shown, effect is most in smoothness and oil stain removing rate It is good.Particle is excessive cannot to be dispersed and rub very well during face cleaning, and particle is too small to lose frosted particle feeling and effect.

Embodiment 1 and the comparison still composition effect of preparation example 5 evaluation

20 volunteers are divided into two groups, are divided into the still Cleansing Foam group of corn and the still Cleansing Foam group of non-fermented maize, Volunteer twice daily uses the still Cleansing Foam of fermented maize and the still Cleansing Foam face cleaning of non-fermented maize, routine use phase TongAn Console agent creams skin care.After 48 weeks, MPA580 tests skin hydration degree and transdermal dehydration.

As the result is shown using after 48 weeks, the still Cleansing Foam group skin hydration degree of fermented maize is higher than non-fermented maize group, thoroughly Transepidermal water loss rate is lower than non-fermented maize group.Illustrate to be metabolized out the nutrition for being more easy to skin absorption after corn is fermented, increase Strong skin moisture-keeping and skin barrier function.

Embodiment 4

The still Cleansing Foam of corn fermentation product compares with commercially available several facial cleanser irritations

Sample number into spectrum	Clean composition
		Embodiment 1	Corn fermentation product
Sample 1	Sodium lauryl tri(oxyethyl) sulfate, Cocoamidopropyl betaine
		Sample 2	Glycerin monostearate, sodium cocoyl glutamate
Sample 3	Laruyl alcohol sodium sulfovinate, alkyl glycosides

Commercially available facial cleanser and corn fermentation product mildy wash to be measured is taken, is made into active material score as 10% solution, then plus Enter a certain amount of zeins (zein), in 25 DEG C of stirring 2h, then filters.Filtrate is measured with micro-Kjeldahl The mass fraction (A) of nitrogen.The mass fraction (B) of nitrogen in the surfactant solution for be not added zein can be measured with same method.

Zein value=A-B, institute nitrogen content mg (or g)/L indicates that zein value is bigger to illustrate surface-active in zein value solution Agent irritation is bigger.

Commercially available several facial cleanser Zein values are much higher than still corn fermentation Cleansing Foam as the result is shown, illustrate several containing normal See the facial cleanser irritation of surfactant much higher than still corn fermentation product mildy wash.

Embodiment 5 prepares the different still mildy wash of fermented grain particle

It is identical as 1 method of preparation example, difference be cereal be rice, millet, black rice, sorghum, semen coicis (partial size are as follows: One of 0.25mm ~ 0.5mm, 40 mesh ~ 60 mesh).Blank control group is not add the still mildy wash of fermented grain product.Its Cleaning effect is shown in attached drawing 9: several fermented grain product mildy wash removing grease effects, which are much better than, as the result is shown does not add cereal hair The blank group of ferment product.

Embodiment 6 prepares the still mildy wash of different microorganisms fermented grain particle

Identical as 1 method of embodiment, difference is using different microorganisms: saccharomyces cerevisiae is respectively adopted in microorganism (Saccharomyces cerevisiae), Rhizopus javanicus (Rhizopus ), aspergillus oryzae(Aspergillus

Oryzae)A kind of ferment.(partial size are as follows: 0.25mm ~ 0.5mm, 40 mesh ~ 60 mesh).Blank control group is not Add the still mildy wash of fermented grain product.Its cleaning effect is shown in Figure 10: several microbial fermentation product preparations as the result is shown Still mildy wash cleaning effect be much better than the still mildy wash for not adding fermented grain object.

Claims (10)

1. a kind of cleaning products composition, containing fermented grain product 10%-80 weight %, the fermented grain product is By crushing, the product obtained after microbial fermentation is described for one or more of millet, corn, black rice, sorghum, adlay With the partial size of 0.02mm-1mm after grain grinding, the cleaning compositions are without containing foaming surfactant；

Wherein the fermented grain product passes through the method included the following steps and prepares:

(1) culture medium heat sterilization, the culture medium are the particle after grain grinding,

(2) activated fermenting microbe is accessed, inoculum concentration is 0.1%-20 volume %,

(3) it ferments, temperature is 25 DEG C -45 DEG C,

(4) pH, range 4.0-7.0 are adjusted,

(5) it sterilizes, sterilising temp is 65 DEG C -120 DEG C, sterilization time 15min-60min；

The wherein microorganism mixes selected from one or more of saccharomycete, lactic acid bacteria, root enzyme bacterium, Aspergillus.

2. composition as described in claim 1, wherein with the partial size of 0.05mm-0.4mm after the grain grinding.

3. composition as described in claim 1, wherein with the partial size of 0.15mm-0.25mm after the grain grinding.

4. composition as described in claim 1 is emulsion, contains: oily matter 1%-20 weight %, fermented grain product 10%-80 weight %, emulsifier 1%-10 weight %, viscosity modifier 0.01%-5 weight %, pure water 10%-80 weight %.

5. composition as described in claim 1 is gel, contains: fermented grain product 10%-80 weight %, gelling agent 0.01%-1 weight %, pure water 10%-80 weight %.

6. composition as described in claim 1, in the culture medium, nutriment, the nutriment choosing are further added From glucose, lactose, sucrose and/or maltose.

7. composition as described in claim 1, the nutriment is selected from glucose.

8. composition as claimed in claim 4, wherein oily matter is selected from: one of vegetable oil, mineral oil and synthetic oil Or several combinations.

9. composition as claimed in claim 4, wherein the emulsifier is selected from: polyglyceryl fatty acid ester, polyglycereol fatty alcohol The combination of one or more of ether, sucrose fatty ester.

10. composition as claimed in claim 4, wherein the viscosity modifier is selected from: carbomer, carragheen, xanthan gum, hydroxyl The combination of one or more of methylcellulose.