CN106176357B - Skin cleaning product containing grain and ginseng stem and leave fermenting products and preparation method skin cleaning product - Google Patents

Abstract

The invention relates to grain and ginseng stem and leave fermenting products and applications of the grain and ginseng stem and leave fermenting products in skin cleaning products. A method comprises the following steps: carrying out heat sterilizing on a culture medium containing grain or ginseng stem and leaves, inoculating microbes into the culture medium, and carrying out fermentation and sterilization, thus obtaining the fermentation product containing the thallus, a fermentation filtrate and solid particles. The fermentation product is used for the cleaning products. The fermentation product has the good effects of removing the grease on surface of the skin, smoothing the skin, resisting inflammation and acne, etc, and has the characteristics of being capable of nourishing the skin and mildly removing the skin cuticala, being low in irritation, and being safe and mild.

Description

Cleaning products containing cereal and gen-seng haulms fermentate and preparation method thereof

Technical field

The present invention relates to a kind of skin cleansing compositions, the skin particularly containing cereal and gen-seng haulms tunning is clear Cleansing composition.

Technical background

At present in conventional cleaning products, appropriate oil content is typically contained in formula without alveolitoid cleaning products, Sometimes a small amount of surfactant is also contained, it is characterized by foam is less, it is relatively gentleer, with the foam containing exhibiting high surface activating agent Type mildy wash is compared, and with low irritant, does not result in excessively cleaning, is adapted to the spy that Dry and sensitive are used Levy.But a disadvantage is that it is smaller to skin cleaning dynamics, while not possessing the removal unnecessary cutin function of epidermis.

Frosted type cleaning products are widely used in household chemicals field.Frosted type cleaning products its mainly constitute into Part it is：Abrasive particle, surfactant and other additives.Abrasive particle therein can be largely classified into organic abrasive particle and Inorganic abrasive particle.Wherein organic abrasive particle includes natural shell particle, fruit stone particle, oyster shell whiting, pearl powder.Inorganic frosted Particle has bamboo charcoal, kaolin, salt particle, quartz sand, calcium carbonate etc..It is mainly characterized by making except the decontamination of cleaning agent in formula With outer, can also be acted on by abrasive particle mechanical friction and remove unnecessary cutin, dust and bag spot etc..But if abrasive particle Composition is really up to the mark or improper use can cause skin friction to damage, and cuticula is excessively thin to accelerate skin exfoliation (particularly dryness and neutrality Skin consumer).

Nowadays, advocate natural Never Ending Fashion to have swept the globe, beauty and skin care circle also can not make an exception, start people to natural peace The upsurge that full skin care item are pursued, some natural, safety skin care item Effect raw materials pour in the visual field.Health of the five cereals to human body Very favorable effect is played, rich in protein, carbohydrate, fat, mineral matter and multivitamin is contained in five cereals, These nutritions are quite benefited to skin nursing.It is used to have in skin nursing especially by the cereal of microbial fermentation and protects Moisture content of skin, enhancing skin elasticity, enhancing skin barrier, promotion subcutaneous collagen albumen is held to produce and certain anti-oxidation efficacy..

KR20130019192A discloses plum, pomegranate, citrus, rice and crushes, and adds lactic acid bacteria culture, centrifugation to obtain Filtrate is obtained, for Exfoliating Scrub, but cleaning products prepared by the method have no good report for the removal of skin oil and fat.

KR20090115844A discloses Chinese herbal medicine (the particularly root of Dahurain angelica), red bean, rice bran and adds lactobacillus-fermented, filtering Filtrate, the substitute for detergent or soap cleans vagina, with the growth for preventing vagina mucosa harmful bacteria, removes different Effect of taste.But cleaning products prepared by the method are to have no to report skin surface oil stain removing.

JP2001271096A discloses application of the rice bran as cleaning agent, and the bran powder is by adding lactic acid bacteria, 58 DEG C Cultivation and fermentation 6 hours, adds citric acid 5%, dries, and sieving is obtained.The document compares ferment rice bran powder with azymic rice Bran powder cleaning skin effect, as a result shows that ferment rice bran can more improve skin hydration degree.But the powdered cleaning agent makes With it is preceding need to be mixed with liquid or egg liquid in advance size mixing after smear skin, using cumbersome, and the battalion in short time mixed-powder Foster material can not be discharged cmpletely, cause nutrition to be fully absorbed by the skin.

CN103211749A discloses by microbial fermentation glutinous rice flour the method to prepare shampoo, but it selects bacterium Strain fermentation time is up to 15 days, and the granular sensation that glutinous rice flour is carried originally can be have impact on after fermentation.Weaken the effect of its frosted cleaning Really.

Therefore there is still a need for finding a kind of suitable method for being used for cleaning products.

At present, it is mainly used in field of food using microbial fermentation bread basket.CN101164428A discloses fermentation The method for preparing biological feedstuff such as corn flour, dregs of beans, the food of the viscous corn flour of CN103404779A lactobacillus-fermenteds, Wang Zhi Big grade " lactic acid bacteria fermented grain food --- the research of sour congee zymotechnique, processing of farm products, 2010.2,27~30 " discloses With glutinous rice, millet, rotten rice, corn quarrel as raw material, using the excellent lactobacillus-fermented of proterties, sample amino acid contains after measuring fermentation Amount and total amount showed increased." the Hypolipidemic effects of lactic acid bacteria such as Immaculata Fermented cereal in rats " .Banjoko et al.Lipids in Health and Disease, 2012.11, 170 disclose lactobacillus acidophilus, Bifidobacterium and Lactobacillus helveticus mixed fermentation corn flour, the well-grown in corn flour, hair Corn flour reaches acceptable taste after ferment.And find that the food of the mixed fermentation plays the role of to suppress fat absorption^[2]。 " the Lactic acid bacteria producing B-group vitamins such as Vittofio：a great potential For functional cereals products ", Appl Microbiol Biotechnol, 2012,96：1383-1394 Disclose and can be developed in cereal by the screening of microorganism and the different contents for improving VB races in fermented cereal of fermentation condition Fermented product micro-organisms vitamin.Wu little Yan etc. " Agricultural University of the Inner Mongol, master's knowledge paper, 2013 " is reported with breast Acid bacteria fermentation coix seed, polysaccharide in fermentation liquid, content of peptides do not ferment and increase 4~8 times, and zymotic fluid has good antioxygen The property changed." development of fermented type rice milk, food and the machinery, 2006,5 such as Fu Liang：103~105. " with rice as raw material, through gelatinization Deng a certain amount of lactic acid bacteria being accessed and being fermented after pretreatment, sense organ and the good fermented type rice milk of structural state have been obtained.Gong Yuan " development of millet fermented beverage, Journal of Zhengzhou Grain College, 1999,3 such as raw：41~43. " koji and saccharomycete two are used Step fermentation obtains the good millet fermented beverage of taste.As can be seen here, microorganism is while using nutriment in cereal, from Body produces some metabolites, the macromolecular in cereal is decomposed into the less material of molecular weight, it is easier to absorb.To also simultaneously The nutriment for being difficult to discharge in cereal is discharged.In addition through microbial fermentation can produce distinctive material for example lactic acid, polysaccharide, Antibiotic, polyphenoils and bioconversion product make product have more high bioactivity, it is easy to the effect such as body absorption.But It is that the application that fermented grain product is used in cleaning products has not been reported.

Ginseng belongs to the plant of Araliaceae Panax, and the effect reported up to now has：The work of Central nervous system With, antitumaous effect, immunoregulation effect, enhancing liver function function, cardiovascular disorder improvement, resistance to compression, antifatigue effect, anti-oxidant work Property and anti-aging suppression function.

Ginseng physiologically active composition is ginsenoside.Apply at present it is most be ginseng underground position, but ginseng Also ginsenoside composition is contained in leaf, flower, fruit, seed.Different parts in ginseng plant, the content of ginsenoside has significantly Difference.

In recent years, ginseng is widely studied as the skin function raw material of cosmetics, and wherein most all make use of ginseng Root, mainly use panaxan and ginsenoside composition.But the skin function effect disquisition brought using gen-seng haulms Very few, the research that particularly fermented rear extract of Radix Ginseng stem and leaf is used for skin has no report.

Inventor has found, fermented grain product is applied in Cleasing compositions, because fermented grain product contains largely Starch and dextrin, have good adsorption removal to act on to skin oil and fat, and secondly, fermented grain product is applied to cleaning products In, the granular sensation of cereal and gentle frosted sense are remained, coordinate the abrasive action during cleaning gently to remove skin Surface aging cutin.Nutriment such as thalline, lactic acid, polypeptide, amino acid, polysaccharide, vitamin in other fermented grain product Deng cleaning products nourish skin is also imparted, the sense of discomfort such as the excessive scaly dry skin brought of cleaning, tight is prevented.Further hair It is existing, gen-seng haulms tunning and fermented grain product is compounded and enhance in Cleasing compositions its anti-inflammatory for preparing, moisturizing, It is anti-oxidant, the effect of Sage Extract, and composition obtains the low irritant of raising, the characteristics of safe gentle.

Therefore, the present invention relates to cereal and gen-seng haulms tunning are applied in Cleasing compositions, it is in composition In remain cereal nutrition and granular sensation, can gently remove skin surface aging cutin, remove surface grease, nutrition skin Skin, skin irritatin of releiving, while the characteristics of there is low irritant, safety temperature.

The content of the invention

The present invention relates to the application of cereal and gen-seng haulms tunning in Cleasing compositions.

The fermented grain product is followed by into microorganism by grain culture medium heat sterilization, and fermentation, sterilizing must be included The fermented grain product of thalline, ferment filtrate and solid particle.The fermented grain product is sent out by cereal-granules through microorganism The product obtained after ferment, it has 0.02mm~1mm, the grain of preferably 0.05mm~0.4mm, more preferably 0.15mm~0.25mm Footpath.

Further, the cereal is selected from one or more in rice, millet, corn, black rice, sorghum, adlay.

Further, the present invention relates to the skin cleansing compositions containing corn and gen-seng haulms tunning.

Further, Cleasing compositions of the present invention are essentially free of surfactant.

Fermented grain product of the invention, it is prepared by following step：

1st, culture medium heat sterilization

2nd, the fermented bacterium for having activated is accessed

3rd, ferment

4th, pH is adjusted

5th, sterilize

Wherein, culture medium is that cereal-granules are prepared with pure water.Grain content is 3%~30 weight % in its culture medium, excellent Select 5%~25 weight %, more select 10%~15 weight %, its sterilising temp is 50 DEG C~120 DEG C, the time be 10min~ 30min。

Microbial inoculant amount is 0.1%%20% volume.

Fermentation temperature is 25 DEG C~45 DEG C

Regulation pH scopes are 4.0~7.0.

Further regulation pH scopes are 5.0~6.0.

Sterilising temp is 65 DEG C~120 DEG C.Sterilization time is controlled to 15min~60min.

It is prepared by the method that the gen-seng haulms tunning passes through to comprise the steps：

(1) culture medium heat sterilization, medium matrix is gen-seng haulms powder.Gen-seng haulms content is 1%~10 weight Amount %, preferably 1%~5%, more preferably 2%~3%.

(2) fermented bacterium for having activated is accessed, inoculum concentration is 0.1%~20 volume %,

(3) ferment, temperature is 25 DEG C~45 DEG C,

(4) filter, centrifugal treating obtains supernatant,

(5) pH is adjusted, scope is 4.0~7.0.

Further, nutriment can be added in culture medium.The nutriment be selected from glucose, lactose, sucrose and/or Maltose, preferably glucose.

The microorganism, selected from brewer's yeast (Saccharomyces cerevisiae), candida utili Saccharomycete such as (Candida utilis), or lactobacillus acidophilus (Lactobacillus acidophilus), lactobacillus paracasei (Lactobacillus paracasei), Lactobacillus rhamnosus (Lactobacillus rhamnosus), Lactobacillus brevis (Lactobacillus brevis), lactobacillus bulgaricus (Lactobacillus bulgaricus), lactobacillus reuteri (Lactobacillus reuteri), Lactobacillus salivarius (Lactobacillus salivarius), streptococcus thermophilus (Streptococcus thermophilus), Leuconostoc mesenteroides (Leuconostoc mesenteroides), Lactococcus lactis The lactic acid bacterias such as bacterium (Lactococcus lactis), or one or more microorganisms of root enzyme bacterium or Aspergillus mixture.

Be suitable for Cleasing compositions of the invention can be washing cream, mildy wash, the thermophilic curry of face cleaning, face cleaning Mu Si, bath foam, The arbitrary forms such as bath oil, hand cleanser, it can be applied to facial cleansing and clean body.

In one particular embodiment, the emulsion Cleasing compositions contain：

The weight % of oily matter 1%~20, preferably 2%~15 weight %, particularly 3%~10 weight %；

The weight % of tunning 10%~80, preferably 20%~70 weight %, particularly 30%~50 weight %；

The weight % of emulsifying agent 1%~10, preferably 2%~8 weight %, particularly 3%~5 weight %,

The weight % of viscosity modifier 0.01%~5, preferably 0.05%~3 weight %, particularly 0.1%~1 weight %,

The weight % of pure water 10%~80, preferably 15%~60 weight %, particularly 20%~40 weight %.

In one particular embodiment, the thermophilic curry Cleasing compositions contain：

The weight % of tunning 10%~80, preferably 20%~70 weight %, particularly 30%~50 weight %

The weight % of gel 0.01%~5, preferably 0.05%~3 weight %, particularly 0.1%~1 weight %.

The weight % of water 10%~80, preferably 15%~60 weight %, particularly 20%~40 weight %.

Oily matter

Siloxanes, and also aryl, the polymethyl siloxane of alkyl-or alkoxy-substitution and ring first siloxanes.

Also include that there is the straight chain and/or side chain unitary and/or binary of 2-44 carbon atom suitable for grease of the invention Carboxylic acid and the saturation with 1-22 carbon atom or the unitary and binary esters of undersaturated straight chain and/or branched-chain alcoho.Similarly, As for grease of the invention, it is also possible to using former with 1-22 carbon with 2-36 difunctional aliphatic's alcohol of carbon atom The ester of monofunctional aliphatic's carboxylic acid of son.

As for grease of the invention, can also specifically preferably use with the 12-22 ester of the aliphatic acid of carbon atom Class, such as methyl esters and isopropyl ester, such as methyl laurate, methyl stearate, methyl oleate, methyl erucate, isopropyl palmitate, Isopropyl myristate, isopropyl stearate and/or acid isopropyl.

Additionally, used as grease of the invention is used for, the also specific preferably just own ester of BS, laurate, oleic acid are just The different nonyl ester of last of the ten Heavenly stems ester, Ethylhexyl stearate, palmitic acid, isononyl isononanoate, palmitic acid 2- ethylhexyls, laurate 2- ethyl hexyls Base ester, stearic acid 2- hexyls decyl ester, palmitic acid 2- octyldodecyls, oleic oil alkene ester, erucic acid oil alkene ester and/or oleic acid Mustard ester.

Used as grease of the invention, what is be also particularly suitable is dicarboxylic acids esters, for example Di-n-butyl Adipate, the last of the ten Heavenly stems two Sour di-n-butyl, adipic acid two (2- ethylhexyls) ester, (the 2- hexyls decyl) ester of butanedioic acid two and/or the different tridecane of azelaic acid two Base ester.Used as grease of the invention, what is be also particularly suitable is diol-lipid, such as two oleic acid glycol esters, two different 13 The sad DOPCP of alkanoic acid glycol ester, two (2 ethyl hexanoic acid) propylene glycol esters, two isostearic acid butanediol esters and/or two.

As for grease of the invention, carbonic diester class, such as carbonic acid two (2- ethylhexyls) ester can also be used.

Equally applicable is the triglyceride of relative long-chain, i.e. glycerine and three triple esters of acid molecule, these acid At least one is an acid molecule for relative long-chain in molecule.Here by way of example it is mentioned that fatty acid glycerine Three esters, this includes triglyceride, the triglyceride of industrial oleic acid, the different tristearin of the mixture of the caprylic/capric of synthesis The triglycerides of acid and the triglyceride of palm/oleic acid mixture.Straight or branched fatty alcohol can additionally be used Class, such as oleyl alcohol or octyldodecanol, and also fatty alcohol ethers, such as dicaprylyl ether etc..

Used as grease of the invention, equally applicable is crude vegetal, for example olive oil, sunflower oil, soybean Oil, peanut oil, rapeseed oil, apricot kernel oil, palm oil and/or jojoba oil, and the also liquid of coconut oil or palm shell oil Part, and also animal oil, the such as liquid part of sperm oil, neat's foot oil or butter.

As for grease of the invention, squalene extracting, particularly atoleine and isoparaffin can also be used.Can Example with the squalene extracting for using be paraffin oil, White Mineral Oil, isohexadecane, poly decene, petroleum jelly, light liquid paraffin and/or Saualane.Additionally, the esters of aryl carboxylic acid are also suitable, such as esters of benzoic acid, such as satisfying with 1-22 carbon atom And/or the benzoic ether that undersaturated straight or branched alcohol is formed with benzoic acid, such as benzoic acid iso stearyl ester and benzoic acid 2- Octyldodecyl, preferably benzoic acid C12-15 Arrcostabs.

In a preferred embodiment of Cleasing compositions of the present invention, oily matter can be white oil, laurate, Pork and beans One or more combination in cool acid, stearic acid, isobutyl palmitate.

Emulsifying agent

In still skin cleansing compositions of the invention, emulsifying agent is further comprises, it is nonionic emulsifier.It is applied to Oil-in-water nonionic emulsifier of the invention is to be lived as the Hydrophilic nonionic surface of hydrophilic group selected from polyoxyethylene chain Property agent, polyglyceryl fatty acid ester, polyglycereol fatty alcohol ether, sucrose fatty ester.

In a preferred embodiment of the invention, it is described with polyoxyethylene chain as hydrophilic group hydrophily it is non-from Sub- surfactant is selected from the group：Polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene glycerol mono fatty acid Ester, Crodaret and Crodaret mono fatty acid ester.

As polyoxyethylene fatty acid ester, preferably polyoxyethylene caprylic ester, polyoxyethylene 2 ethyl hexanoic acid ester, polyoxyethylene Decylate, polyoxyethylene laurate, polyoxyethylene myristinate, polyoxyethylene palmitate, polyoxyethylene isostearic acid Ester, Myrj 45, polyoxyethylene oleate, Ju oxygen ethene behenic acid esters etc..

As polyoxyethylene aliphatic alcohol ether, preferably polyoxyethylene octyl ether, polyoxyethylene decyl ethers, polyoxyethylene laural base It is ether, polyoxyethylene myristyl ether, polyoxyethylene palmityl ether, polyoxyethylene iso stearyl ether, polyoxyethylene stearyl base ether, poly- Oxygen ethene oleyl ether, Ju oxygen ethene Shan Yu base ethers etc..

As polyoxyethylene glycerol mono fatty acid ester, preferably polyoxyethylene glycerol list caprylate, the polyoxyethylene glycerol list last of the ten Heavenly stems Acid esters, polyoxyethylene glycerol monolaurate, polyoxyethylene glycerol list myristinate, polyoxyethylene glycerol monopalmitate, Polyoxyethylene glycerol list isostearate, polyoxyethylene glycerol monostearate, TMGO 5, polyoxyethylene Gan oil Dan behenic acid esters etc..

As Crodaret, polyoxyethylene structure division preferably wherein averagely comprising 20-80, preferably 30-60 those Crodarets of ethylene oxide repeating units.

As Crodaret mono fatty acid ester, preferably Crodaret list caprylate, polyoxy Ethylene hydrogenation castor oil monkey cell, Crodaret monolaurate, Crodaret list Pork and beans Cool acid esters, Crodaret monopalmitate, Crodaret list isostearate, polyoxyethylene hydrogen Change castor oil monostearate, Crodaret monoleate, Crodaret Dan behenic acid esters etc..

As polyglyceryl fatty acid ester, the preferably list of polyglycereol-and many caprylates, the list-of polyglycereol and many 2- ethyl hexyls It is acid esters, the list-of polyglycereol and many decylates, the list-of polyglycereol and many laurates (such as laurate of Natrulon H-10 five), poly- It is the list of glycerine-and many myristinates, the list-of polyglycereol and many palmitates, the list-of polyglycereol and many isostearates, poly- The list of glycerine-and many stearates (such as distearate of polyglycereol -3), the list-of polyglycereol and many oleates (such as polyglycereol -2 Dioleate), the list-of polyglycereol and Duo behenic acid esters etc..

As above-mentioned polyglycereol fatty alcohol ether, the fatty alcohol that the polyglycereol fatty alcohol ether is formed preferably wherein be saturation or It is undersaturated and averagely poly- sweet comprising 2-60 glycerine repeat unit with 8-22 carbon atom and polyglycerol moiety Oil and fat alcohol ether.As the example, it can be mentioned that：It is polyglycereol Octyl Ether, polyglycereol decyl ethers, polyglycereol lauryl ether, poly- sweet It is oily myristyl ether, polyglycereol palmityl ether, polyglycereol iso stearyl ether, polyglycereol stearyl ether, polyglycereol oleyl ether, poly- sweet You Shan Yu base ethers etc..The fatty alcohol for particularly preferably wherein forming the polyglycereol fatty alcohol ether is saturated or unsaturated and has There is 8-18 carbon atom and polyglycerol moiety is averagely comprising the 3-15 polyglycereol fatty alcohol ether of glycerine repeat unit, especially It is that wherein to form the fatty alcohol of the polyglycereol fatty alcohol ether be saturated or unsaturated and with 10-14 carbon atom and poly- Glycerine structure division is averagely comprising the 3-5 polyglycereol fatty alcohol ether of glycerine repeat unit, such as lauryl ether of polyglycereol -4.

As sucrose fatty ester, the list-of preferably sucrose and many caprylates, the list-of sucrose and many 2 ethyl hexanoic acid esters, sugarcane The list of sugar-and many decylates, the list-of sucrose and many laurates (such as sucrose dilaurate), the list-of sucrose and many nutmegs Acid esters, the list-of sucrose and many palmitates (such as palmitate of sucrose six), the list-of sucrose and many isostearates, sucrose Single-and many stearates, the list-of sucrose and many oleates, the list-of sucrose and many behenates etc..

Viscosity-controlling agent and gel can be contained in composition of the invention, it is hydroaropic substance, the aqueous materials Matter is selected from water-soluble polymer.

Can be natural polysaccharide class as water-soluble polymer, such as xanthans, Arabic gum, guar gum, crust Plain derivative (such as quaternized hydroxypropyl chitin), hyaluronic acid, xanthan gum etc..

As water-soluble polymer, semi synthetic polymer, such as modified cellulose class are can also be, it includes that methylol is fine Dimension element, hydroxyethyl cellulose, hydroxypropyl cellulose, quaternized cellulose etc..

Further, composition of the invention can contain polyalcohol, and can be used for polyalcohol of the invention is have 1 to 6 The polyalcohol of individual carbon atom, including propane diols, hexylene glycol, glycerine and propane diols.

Annexing ingredient

Plot composition of the invention can include annexing ingredient, these annexing ingredients can by technical staff according to it is required most The characteristic of finished product is selected, and these annexing ingredients are suitable to make said composition more attractive or make it have additional use Beneficial effect.

The independent consumption of annexing ingredient is usually 0.001% to 10 weight % by weight of the composition, preferably 0.01-5 weight %.

Various other annexing ingredients can be formulated into composition of the invention.These components but it is not limited to moisturizing The compositions such as agent, whitening agent, antioxidant, conditioner, preservative, pH adjusting agent, colouring agent, spices, chelating agent.

Foaming surfactant

The present composition is substantially free of foaming surfactant, and the foaming surfactant foams selected from anion Surfactant, nonionic lather surfactants, both sexes foaming surfactant and their mixture.

Anionic lathering surfactant agent non-limitative example includes sarcosinate, sulfate, isethionate, taurine Salt, phosphate, lactate, glutamate and their mixture.

Nonionic foaming surfactant includes alkyl glucoside, alkyl polyglucoside, polyhydroxy fatty acid amide, alcoxyl Base fatty acid ester, foaming sucrose ester, amine oxide and their mixture.

" both sexes foaming surfactant " includes zwitterionic surfactant, and it is small as amphoteric surfactant one Class is known to the skilled formulator of this area.Can be lived using quite extensive both sexes foam surface in the present composition Property agent.The non-limitative example of both sexes or zwitterionic surfactant is selected from glycine betaine, sulfobetaines, weight ratio beet Alkali, alkyhminoacetates, iminodiacetic alkanoate, aminoalkanoates and their mixture.

Brief description of the drawings

Fig. 1 is used containing corn and gen-seng haulms tunning Cleansing Foam with rice bran fermentation cleaning powder face cleaning skin transdermal dehydration Compare figure.

Fig. 2 is used containing corn and gen-seng haulms tunning Cleansing Foam with rice bran fermentation cleaning powder face cleaning skin hydration degree water Compare figure.

Fig. 3 is used containing corn and gen-seng haulms tunning mildy wash with the non-smooth points amount of glutinous rice yeast powder face cleaning skin Compare figure.

Fig. 4 uses different-grain diameter fermented maize and the still Cleansing Foam face cleaning of gen-seng haulms, and non-smooth the counting out of skin is compared Figure.

Fig. 5 uses different-grain diameter fermented maize and gen-seng haulms Cleansing Foam face cleaning, removes grease and compares figure.

Fig. 6 corns and the still Cleansing Foam of gen-seng haulms tunning compare with several Cleansing Foam excitants.

Fig. 7 difference cereal and gen-seng haulms tunning Cleansing Foam face cleaning remove grease and compare figure.

The mildy wash of Fig. 8 different strains fermented maize and gen-seng haulms product removes grease and compares figure.

Fig. 9 compares using containing corn and gen-seng haulms tunning Cleansing Foam with the still Cleansing Foam face cleaning anti-inflammatory of fermented maize Figure.

Figure 10 is removed certainly using containing corn and gen-seng haulms tunning Cleansing Foam with the still Cleansing Foam face cleaning of fermented maize Figure is compared by base.

Specific embodiment

To be best understood from present disclosure, further illustrated with reference to some specific implementation examples.

Preparation example 1：It is prepared by corn fermentation product

(particle diameter is to take 100g corns quarrel：0.15mm~0.25mm, 60 mesh~80 mesh) with 900ml drinking water in, heating is gone out Bacterium, sterilising conditions are 105 DEG C, 15min, and cooling room temperature is followed by into Lactobacillus casei, and inoculum concentration is 5% volume.37 DEG C of fermentation 24h ~48h.Regulation PH to 5.5~6.0, inactivates thalline, and sterilising conditions are 105 DEG C, 15min.

Preparation example 2：It is prepared by corn fermentation product

Identical with the method for preparation example 1, difference is that (particle diameter is corn quarrel：0.25mm~0.5mm, 40 mesh~60 mesh).

Preparation example 3：It is prepared by corn fermentation product

Identical with the method for preparation example 1, difference is that (particle diameter is 0.1mm~0.15mm to corn quarrel：80 mesh~120 mesh).

Preparation example 4：It is prepared by gen-seng haulms tunning

Take in 20g gen-seng haulms powder addition 980ml drinking water, heat sterilization, sterilising temp is 121 DEG C, and 15min is cold But Lactobacillus casei is accessed after room temperature, inoculum concentration is 5% volume, and 37 DEG C of 24~48h of fermentation are filtered to remove gen-seng haulms powder, Impurity is centrifuged off, PH to 5.5~6.0 is adjusted.

It is prepared by fermentation composition

Fermentation composition preparation example 1：

10 parts with 4 gen-seng haulms tunning of preparation example of 90 parts of 1 corn fermentation product of preparation example mixes.

Fermentation composition preparation example 2：

10 parts with 4 gen-seng haulms tunning of preparation example of 90 parts of 2 corn fermentation product of preparation example mixes.

Fermentation composition preparation example 3：

10 parts with 4 gen-seng haulms tunning of preparation example of 90 parts of 3 corn fermentation product of preparation example mixes.

Contrast preparation example 1：It is prepared by tunning

Identical with the method for preparation example 1, difference is that (particle diameter is corn quarrel：＜ 0.1mm, more than 120 mesh).

Contrast preparation example 2：It is prepared by tunning

Identical with the method for preparation example 1, difference is that (particle diameter is corn quarrel：＞ 0.5mm, below 40 mesh).

Contrast preparation example 3：With reference to the rice bran ferment particulate of JP2001271096A

Contrast preparation example 4：With reference to the glutinous rice flour tunning of CN103211749A

Contrast preparation example 5：Frosted particle is walnut frosted particulate, and particle diameter is 0.15mm~0.25mm, 60 mesh~80 mesh.

The still skin cleansing compositions sensory effects of fermentation composition preparation example 1-3 and comparative example 1-5 are evaluated

5 expert opinion group members of selection, carry out sensory evaluation in such a way

Embodiment 1-3 and the still skin cleansing compositions of comparative example 1-5 are used respectively, and then using effect makes scoring. Granular sensation is with feeling to make evaluation.Cleaning effect carries out skin oil and fat assay by MPA580 skinanalysis apparatus, according to making Carry out comprehensive marking to composition with impression, standard is non-stimulated when using, it is easy to apply when using, use after moisten, use after Clearly, 1 point is respectively accounted for using rear skin is smooth, there is one not meet and subtract 1 point.

[1] the corn ginseng cauline leaf tunning of fermentation composition preparation example 1

[2] the corn ginseng cauline leaf tunning of fermentation composition preparation example 2

[3] the corn ginseng cauline leaf tunning of fermentation composition preparation example 3

[4] the corn ginseng cauline leaf tunning of preparation example 1 is contrasted

[5] the corn ginseng cauline leaf tunning of preparation example 2 is contrasted

[6] with reference to the rice bran ferment particulate of JP2001271096A

[7] with reference to the glutinous rice flour tunning of CN103211749A

[8] frosted particle is walnut frosted particulate, and particle diameter is 0.15mm~0.25mm, 60 mesh~80 mesh.

Conclusion：Perceptual effect is optimal after the corn ginseng cauline leaf tunning cleaning of embodiment 1-3, and has good grease Elimination effect, the wherein particle sizes of grains of embodiment 1 are more excellent with gen-seng haulms fermentate mixed effect in 0.15mm~0.25mm.

Embodiment 1 and the composition effect evaluation of comparative example 3

20 volunteers are divided into two groups, are divided into the still mildy wash group of corn ginseng cauline leaf tunning and ferment rice bran Powder group, volunteer twice daily uses corn ginseng cauline leaf tunning mildy wash and ferment rice bran powder face cleaning, routine use phase With placebo creams skin care.After 8 weeks, MPA580 test skin hydration degree and transdermal dehydration.

Using after 8 weeks, corn ginseng cauline leaf tunning mildy wash group skin hydration degree is higher than ferment rice bran for result display Group, transdermal percentage of water loss is less than ferment rice bran group.Illustrate in the still mildy wash of tunning that nutrition can more fill part to be inhaled by skin Receive, while there is stronger enhancing skin barrier function.

Embodiment 1 and the still composition effect evaluation of comparative example 4

20 volunteers are divided into two groups, are divided into the still Cleansing Foam group of corn ginseng cauline leaf tunning and fermentation glutinous rice Powder cleaning agent group, volunteer uses the still Cleansing Foam of corn ginseng cauline leaf and fermentation glutinous rice flour cleaning agent face cleaning, VISIA after 5min Full face analysis instrument determines the non-smooth points amount of skin surface.

The result display non-smooth reduced rate of the still Cleansing Foam group skin surface of corn ginseng cauline leaf tunning is significantly high In fermentation glutinous rice flour cleaning agent.Illustrate the relatively strong removal skin of gentle frosted particle effect in the still Cleansing Foam of corn fermentation product Unnecessary dirt around excess surface cutin and pore.

The still Cleansing Foam contrasts of embodiment 1-3 and comparative example 1-2

30 volunteers are divided into 6 groups, and 5 kinds of different-grain diameter corns and gen-seng haulms Cleansing Foam face cleaning and blank pair are used respectively According to Cleansing Foam.Blank group is the still mildy wash without tunning.Face cleaning dry naturally test after 5min facial smoothness and Facial oil situation of change.

Result showed 60 mesh~80 mesh sieve corn particles and gen-seng haulms tunning Cleansing Foam group in non-smooth point drop Best results in low rate and oil stain removing rate.Particle is excessive cannot very well to be disperseed and rub during face cleaning, and particle is too small Frosted particle is lost to feel and effect.

Embodiment 4

The still Cleansing Foam of corn ginseng cauline leaf tunning compares with commercially available several mildy wash excitants

Commercially available mildy wash to be measured and corn ginseng cauline leaf tunning mildy wash are taken, it is 10% to be made into active material fraction Solution, adds a certain amount of zeins (zein), and 2h is stirred at 25 DEG C, then filters.Filtrate is fixed with micro kelvin Nitrogen method measures the mass fraction (A) of nitrogen.The quality of nitrogen in the surfactant solution for be not added with zein can be measured with same method Fraction (B).

Zein values=A-B, institute's nitrogen content mg (or g)/L is represented in zein value solution, and the bigger explanation surface of zein values is lived Property agent excitant is bigger.

As a result (accompanying drawing 6) shows that commercially available several mildy wash Zein values are washed one's face far above still corn ginseng cauline leaf fermentation Breast, illustrates that several mildy wash excitants containing Common surface activating agent are far above still corn fermentation product mildy wash.

Embodiment 5 prepares the different still mildy wash of cereal gen-seng haulms ferment particulate

Identical with the method for tunning preparation example 1, difference is that cereal is rice, millet, black rice, sorghum, coix seed (grain Footpath is：0.25mm~0.5mm, 40 mesh~60 mesh) in one kind.Blank control group is the mildy wash without tunning.Its Cleaning effect is shown in accompanying drawing 7：Result display rice, millet, black rice, sorghum, coix seed tunning and gen-seng haulms tunning Mildy wash remove grease effect and be much better than blank group without tunning.

Embodiment 6 prepares the different microorganisms still mildy wash of fermented grain particle

Identical with the method for embodiment 1, difference is to use different microorganisms：Microorganism is respectively adopted saccharomyces cerevisiae The one of (Saccharomyces cerevisiae), Rhizopus javanicus (Rhizopus), aspergillus oryzae (Aspergill us oryzae) Plant and fermented.(particle diameter is：0.25mm~0.5mm, 40 mesh~60 mesh).Blank control group is without the still of tunning Mildy wash.Its cleaning effect is shown in Fig. 8：Result shows that still mildy wash cleaning effect prepared by several microbial fermentation products is far excellent In the still mildy wash without fermented grain thing.

The corn of embodiment 7 and the still mildy wash of gen-seng haulms fermentation compare with corn fermentation mildy wash antiphlogistic effects.

20 long-term volunteers with scytitis and acne recurrent exerbation, are equally divided into two groups, are corn ginseng stem The still Cleansing Foam group of leaf tunning and the still Cleansing Foam group of non-fermented maize, volunteer twice daily use corn ginseng cauline leaf The still Cleansing Foam of tunning and the still Cleansing Foam face cleaning of non-fermented maize, the identical placebo creams skin care of routine use.Use 4 Zhou Hou, compares the degree of acne and scytitis, and the display of its result is scorching using corn and the still mildy wash group face of fermented ginseng Disease improves degree and is substantially better than control group.Result is shown in accompanying drawing 9.

The corn of embodiment 8 and the still mildy wash of gen-seng haulms fermentation compare with corn fermentation mildy wash inoxidizability effect.

Corn fermentation product mildy wash of the invention and corn and gen-seng haulms tunning mildy wash difference 10 dilute Times.Experiment samples 1ml with vitamin C as positive control, adds the DPPH- ethanol solution 3.0ml of 0.04mg/ml, and lucifuge stands 30min, 12000rpm are centrifuged 10min, the mensuration absorbance under 517nm.Calculate DPPH clearance rates.Result shows fementative composition Thing mildy wash has more excellent antioxidation activity.Result is shown in accompanying drawing 10.

Claims (7)

1. a kind of skin cleansing compositions, it contains the weight % of tunning 10%~80, and the tunning is by fermented grain Product and gen-seng haulms tunning are mixed in proportion, and wherein fermented grain product accounts for 80%~95 weight of tunning Amount %, gen-seng haulms fermentate accounts for 5%~20 weight % of tunning, and the fermented grain product is ground cereal, through micro- The product obtained after biofermentation, the ground cereal is the particle with 0.15mm~0.25mm particle diameters,

The cereal be selected from rice, millet, corn, black rice, sorghum, adlay in one or more,

The fermented grain product is prepared by the method for following step：

(1) culture medium heat sterilization, it is cereal-granules to support base,

(2) fermented bacterium for having activated is accessed, inoculum concentration is 0.1%~20% volume,

(3) ferment, temperature is 25 DEG C~45 DEG C, fermentation time is 24-48 hours,

(4) pH is adjusted, scope is 4.0~7.0,

(5) sterilize, sterilising temp is 65 DEG C~120 DEG C, sterilization time is 15min~60min.

2. composition as claimed in claim 1, it is characterised in that composition is solemn washing cream, mildy wash, face cleaning gel, face cleaning This, bath foam, bath oil, hand cleanser.

3. composition as claimed in claim 1, wherein the gen-seng haulms tunning passes through the method for comprising the steps Prepare：

(1) culture medium heat sterilization, medium matrix is gen-seng haulms powder, and gen-seng haulms content is 1%~10 weight %,

(2) fermented bacterium for having activated is accessed, inoculum concentration is 0.1%~20 volume %,

(3) ferment, temperature is 25 DEG C~45 DEG C,

(4) filter, centrifugal treating obtains supernatant,

(4) pH is adjusted, scope is 4.0~7.0.

4. composition as claimed in claim 1, wherein described microorganism is selected from saccharomycete, lactobacillus, lactic acid bacteria, root enzyme One or more mixing in bacterium, Aspergillus.

5. composition as claimed in claim 1, in described culture medium, further adds nutriment, the nutriment Selected from glucose, lactose, sucrose and/or maltose.

6. composition as claimed in claim 1, it is emulsion, is contained：The weight % of oily matter 1%~20, tunning 10%~80 weight %, the weight % of emulsifying agent 1%~10, the weight % of viscosity modifier 0.01%~5, the weight of pure water 10%~80 Amount %.

7. composition as claimed in claim 1, it is gel, and it contains：The weight % of tunning 10%~80, gel 0.01%~1 weight %, the weight % of pure water 10%~80.